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  • Dr. Mohammad Rehan Associate Professor Head of Solid Waste Management Unit Ranked in top 2% Scientists Worldwide (Sta... moreedit
This study examines point and non-point sources of air pollution and particulate matter and their associated socioeconomic and health impacts in South Asian countries, primarily India, China, and Pakistan. The legislative frameworks,... more
This study examines point and non-point sources of air pollution and particulate matter and their associated socioeconomic and health impacts in South Asian countries, primarily India, China, and Pakistan. The legislative frameworks, policy gaps, and targeted solutions are also scrutinized. The major cities in these countries have surpassed the permissible limits defined by WHO for sulfur dioxide, carbon monoxide, particulate matter, and nitrogen dioxide. As a result, they are facing widespread health problems, disabilities, and causalities at extreme events. Populations in these countries are comparatively more prone to air pollution effects because they spend more time in the open air, increasing their likelihood of exposure to air pollutants. The elevated level of air pollutants and their long-term exposure increases the susceptibility to several chronic/acute diseases, i.e., obstructive pulmonary diseases, acute respiratory distress, chronic bronchitis, and emphysema. More in-depth spatial-temporal air pollution monitoring studies in China, India, and Pakistan are recommended. The study findings suggest that policymakers at the local, national, and regional levels should devise targeted policies by considering all the relevant parameters, including the country's economic status, local meteorological conditions, industrial interests, public lifestyle, and national literacy rate. This approach will also help design and implement more efficient policies which are less likely to fail when brought into practice.
Editorial on the Research Topic
Design and application of biocatalysts for biofuel and bio-based material
production
The organic Rankine cycle (ORC) has recently emerged as a practical approach for generating electricity from low-to-high-temperature waste industrial streams. Several ORC-based waste heat utilization plants are already operational;... more
The organic Rankine cycle (ORC) has recently emerged as a practical approach for generating electricity from low-to-high-temperature waste industrial streams. Several ORC-based waste heat utilization plants are already operational; however, improving plant cost-effectiveness and competitiveness is challenging. The use of thermally efficient and cost-competitive working fluids (WFs) improves the overall efficiency and economics of ORC systems. This study evaluates ORC systems, facilitated by biogas combustion flue gases, using n-butanol, i-butanol, and methylcyclohexane, as WFs technically and economically, from a process system engineering perspective. Furthermore, the performance of the aforementioned WFs is compared with that of toluene, a well-known WF, and it is concluded that i-butanol and n-butanol are the most competitive alternatives in terms of work output, exergy efficiency, thermal efficiency, total annual cost, and annual profit. Moreover, the i-butanol and n-butanol-based ORC systems yielded 24.4 and 23.4% more power, respectively, than the toluene-based ORC system; in addition, they exhibited competitive thermal (18.4 and 18.3%, respectively) and exergy efficiencies (38 and 37.7%, respectively). Moreover, economically, i-butanol and n-butanol showed the potential of generating 48.7 and 46% more profit than that of toluene. Therefore, this study concludes that i-butanol and n-butanol are promising WFs for high-temperature ORC systems, and their technical and economic performance compares with that of toluene. The findings of this study will lead to energy efficient ORC systems for generating power.
Fabrication of superior and cost-effective cathodic materials is vital in manufacturing sustainable microbial electrolysis cells (MECs) for biofuels production. In the present study, a novel manganese dioxide (MnO 2) coated felt cathode... more
Fabrication of superior and cost-effective cathodic materials is vital in manufacturing sustainable microbial electrolysis cells (MECs) for biofuels production. In the present study, a novel manganese dioxide (MnO 2) coated felt cathode (Mn/CF) has been developed for MECs using electrodeposition method via potentiostat. MnO 2 is considered to encourage exogenous electron exchange and, in this way, improves the reduction of carbon dioxide (CO 2). MnO 2 , as a cathodic catalyst, enhances the rate of biofuel production, electron transfer, and significantly reduces the cost of MECs. A maximum stabilized current density of 3.70 ± 0.5 mA/m 2 was obtained in case of MnO 2-coated Mn/CF based MEC, which was more than double the non-coated carbon felt (CF) cathode (1.70 ± 0.5 mA/m 2). The dual chamber Mn/CF-MEC achieved the highest production rate of acetic acid (37.9 mmol/L) that was significantly higher (43.0%) in comparison to the non-coated CF-MEC. The cyclic voltammograms further verified the substantial enhancement in the electron transfer between the MnO 2 coated cathode and microbes. The obtained results demonstrate that MnO 2 interacted electrochemically with microbial cells and enhanced the extracellular electron transfer, therefore validating its potential role in biofuel production. The MnO 2 coated CF further offered higher electrode surface area and better electron transfer efficiency, suggesting its applicability in the large-scale MECs.
The world is facing severe environmental challenges, including increasing consumption of fossil-based energy and its consequent devastative impact, i.e. global warming and climate change. Biofuels are promising alternatives to fossil... more
The world is facing severe environmental challenges, including increasing consumption of fossil-based energy and its consequent devastative impact, i.e. global warming and climate change. Biofuels are promising alternatives to fossil fuels with tremendous environmental and socio-economic benefits. There has been a considerable deal of research and development carried out on the production of biofuels in the last 2 decades. However, there is still a huge potential for achieving more cost-effective and efficient biofuel production processes through the application of nanotechnology. The exceptional properties of nanomaterials (nanocatalysts) such as high surface area, catalytic performance, crystallinity, durability, energy storage capacity, etc. offer great potential for optimizing biofuel production systems. Nanocatalysts could also serve recovery, reusability, and recycling purposes.
Black liquor (BL) rich phenolic and complex compounds is generated from pulp and paper mill manufacturing processes which should be treated before reaching the environment. The potential of achieving several sustainable development goals... more
Black liquor (BL) rich phenolic and complex compounds is generated from pulp and paper mill manufacturing processes which should be treated before reaching the environment. The potential of achieving several sustainable development goals (SDGs) by recovering energy and valuable by-products from BL was extensively investigated. Results revealed that under a dark-fermentation process, the organic content in BL was effectively bio-degraded by anaerobes to achieve a hydrogen yield (HY) of 0.62 ± 0.04 mol/mol glucose. Fortunately, the HY was significantly increased up to 1.41 ± 0.13 mol/mol glucose by immobilizing the anaerobes onto magnetite nanoparticles (MN). α-amylase, xylanase, CM-cellulase, polygalacturinase, and protease enzymes activities were increased by 2.3, 23.7, 2.7, 26.8, and 31.1 folds with supplementation of MN. Moreover, the conversion efficiencies of protein and carbohydrate were improved by values of 36 and 113.3% and total phenolic compounds (TPC) were enhanced by 23.5% compared with the control test. Electron-equivalent and COD mass balances were estimated to comprehensively describe the effect of Mn supplementation on the HY performance and fermentation pathways. Digestate generated from the fermentation process was utilized to produce biochar, having C (58.2%), O (32.4%), Na (4.7%), and P (1.1%). The study outputs were interlinked to bio-energy generation, pollution minimization, biochar as a soil amendment, nanoparticles and paper manufacturing industrialization, meeting environmental, economic, and social related SDGs.
The articles published in this special issue focus on recent developments in sustainable waste-to-energy systems and waste management practices and highlight the critical challenges and potential solutions. The editorial paper aims to... more
The articles published in this special issue focus on recent developments in sustainable waste-to-energy systems and waste management practices and highlight the critical challenges and potential solutions. The editorial paper aims to give a brief overview of the key findings and future perspectives proposed in these 25 selected papers. It is worth noting that although the articles presented in this special issue covered a wider range of topics, they are categorized into five categories. These include the latest developments in 1) waste-to-energy technologies, 2) biofuels and bioenergy, 3) waste valorization, 4) emerging renewable and sustainable energy systems, and finally, 5) biorefineries and circular economy.
The global demand for clean products obtained from biobased resources has increased significantly with the rapid growth of the world's population. In this context, microbially-produced compounds are highly attractive for their safety,... more
The global demand for clean products obtained from biobased resources has increased significantly with the rapid growth of the world's population. In this context, microbially-produced compounds are highly attractive for their safety, reliability, being environment friendly and sustainability. Nevertheless, the cost of the carbon sources required for such approaches accounts for greater than 60% of the total expenses, which further limits the scaling up of industries. In recent years, algae have been used in numerous industrial areas because of their rapid growth rate, easy cultivation, ubiquity and survival in harsh conditions. Over the past decade, notable advances have been observed in the extraction of high-value compounds from algae biomass (ABs). However, few studies have investigated ABs as green substrates for microbial conversion into value-added products. This review presents the potential of ABs as the substrates for microbial growth to produce industrially-important products, which sheds light on the importance of the symbiotic relationship between ABs and microbial species. Moreover, the successful algal-bacterial gene transformation paves the way for accommodating green technology advancements. With the escalated need for natural pigments, biosurfactants, natural plastics and biofuels, ABs have been new resources for microbial biosynthesis of these value-added products, resolving the problem of high carbon consumption. In this review, the fermentative routes, process conditions, and accessibility of sugars are discussed, together with the related metabolic pathways and involved genes. To conclude, the full potential of ABs needs to be explored to support microbial green factories, producing novel bioactive compounds to meet global needs.
The sustainable and ecological economic growth of a country is associated with its economic progress and the advancement of its bioenergy sector. Biowaste can be used to produce bioenergy and is increasingly being recognized as a... more
The sustainable and ecological economic growth of a country is associated with its economic progress and the advancement of its bioenergy sector. Biowaste can be used to produce bioenergy and is increasingly being recognized as a promising resource for filling the energy gap. However, in developing countries, biowaste-to-energy techniques are relatively immature owing to economic and technological crises, forcing these countries to export cheap biowaste and obtain expensive energy imports. In this study, country-wise export data of potential biowaste materials were gathered, assessed, and filtered according to the feasibility of bioenergy generation. Five developing countries (Argentina, Brazil, India, Thailand, and Ukraine) were selected for the economic assessment on the basis of the export value and revealed comparative advantage (RCA). Argentina has the most exports (10.3 billion USD), with six biowaste products having RCA > 1. The product space model (PSM) was employed to evaluate the income potential of biowaste country-level sophistication, and a suitable economic policy was proposed according to PSM indicators. All the considered biowastes have low income potential. Thailand has the highest country-level sophistication, followed by India, Brazil, Ukraine, and Argentina. However, according to the PSM, the EXPY values exhibit growth only for India (15.4%) and Thailand (5.7%); for the remaining countries, they decline. On the PSM industrial policy map, India, Thailand, and Ukraine lie in ample space, while Brazil and Argentine are in a “parsimonious industrial policy” region. Moreover, a comparison between bioenergy and current exports ensures that the implementation of suggested industrial policies can enhance energy-production capabilities through export diversification and assist countries in achieving their projected gross domestic products.
Investment in biofuels, as sustainable alternatives for fossil fuels, has gained momentum over the last decade due to the global environmental and health concerns regarding fossil fuel consumption. Hence, effective management of biofuel... more
Investment in biofuels, as sustainable alternatives for fossil fuels, has gained momentum over the last decade due to the global environmental and health concerns regarding fossil fuel consumption. Hence, effective management of biofuel supply chain (BSC) components, including biomass feedstock production, biomass logistics, biofuel production in biorefineries, and biofuel distribution to consumers, is crucial in transitioning towards a low-carbon and circular economy (CE). The present study aims to render an inclusive knowledge map of the BSC-related scientific production. In this vein, a systematic review, supported by a keywords co-occurrence analysis and qualitative content analysis, was carried out on a total of 1,975 peer-reviewed journal articles in the target literature. The analysis revealed four major research hotspots in the BSC literature, namely (1) biomass-to-biofuel supply chain design and planning, (2) environmental impacts of biofuel production, (3) biomass to bioenergy, and (4) techno-economic analysis of biofuel production. Besides, the findings showed that the following subject areas of research in the BSC research community have recently attracted more attention: (i) global warming and climate change mitigation, (ii) development of the third-generation biofuels produced from algal biomass, which has recently gained momentum in the CE debate, and (iii) government incentives, pricing, and subsidizing policies. The provided insights shed light on the understanding of researchers, stakeholders, and policy-makers involved in the sustainable energy sector by outlining the main research backgrounds, developments, and tendencies within the BSC arena. Looking at the provided knowledge map, potential research directions in BSCs towards implementing the CE model, including (i) integrative policy convergence at macro, meso, and micro levels, and (ii) industrializing algae-based biofuel production towards the CE transition, were proposed.
This study aims to examine the potential of non-edible seed oil (Cucumis melo var. agrestis), seed oil content 29.1%, FFA 0.64 (mg KOH/g) for biodiesel production via nanocatalyst. The catalyst was characterized using X-ray diffraction... more
This study aims to examine the potential of non-edible seed oil (Cucumis melo var. agrestis), seed oil content 29.1%, FFA 0.64 (mg KOH/g) for biodiesel production via nanocatalyst. The catalyst was characterized using X-ray diffraction spectroscopy (XRD), Fourier transform infrared spectroscopy (FTIR), scanning electron microscopy (SEM), and energy dispersive X-ray spectroscopy (EDX). The maximum biodiesel yield (93%) was attained under optimized conditions, i.e., 9:1 methanol to oil molar ratio, 2 wt% catalyst (MgO) at 60°C. The synthesized biodiesel yield was optimized through response surface technology via Box Behnken design (BBD). Biodiesel was characterized by advanced analytical techniques, including gas chromatography and mass spectroscopy, FTIR, and nuclear magnetic resonance (NMR). Fuel properties of synthesized biodiesel, including density (0.800 kg/L), K. viscosity @ 40°C (4.23 cSt), cloud point −12°C, pour point −7°C, sulfur content (0.0001%), flash point (73.5°C), total acid no (0.167 mg KOH/g) were found in lines with international standard of American Society of Testing Materials (ASTM). Cucumis melo var. agrestic seed oil and nano MgO catalyst appeared as economical, sustainable, and feasible candidates to overcome global energy glitches and environmental issues. The study findings involving unpalatable seed oil will be a promising step toward non-food biomass biorefinery.
As the global population and economy grow, so does the energy demand. Over-reliance on non-renewable resources leads to depletion and price spikes, making renewable alternatives necessary. Biodiesel is an eco-friendly and non-toxic fuel... more
As the global population and economy grow, so does the energy demand. Over-reliance on non-renewable resources leads to depletion and price spikes, making renewable alternatives necessary. Biodiesel is an eco-friendly and non-toxic fuel that closely resembles traditional fossil fuels. It is produced from various sources, including animal fat, palm oil, and non-edible plant oil. Biodiesel releases fewer harmful air pollutants and greenhouse gases than fossil fuels and is simpler to manage. Despite these advantages, it cannot replace traditional diesel fuel on a large scale. This overview summarizes biodiesel production, explaining the different types of feedstock utilized and their benefits and drawbacks. Various biodiesel production methodologies are discussed. The primary objective of this article is to inform engineers, industrialists, and researchers involved in waste biodiesel, as well as to highlight waste biodiesel as a potential substitute for fossil fuels. This review article discusses the nanoadditives in biodiesel and applications of internet of things, artificial intelligence, and machine learning in biofuel. This review shows that nano-additives can potentially improve biodiesel fuel properties, favorable economic and policy environments promoting biodiesel production, and internet of things, artificial intelligence, and machine learning technologies optimize the biodiesel production processes. These advances can help promote biodiesel as a cleaner, renewable energy source, lowering the consumption of fossil fuels. It also suggests further biofuel development by improving efficiency, expanding feedstock options, creating policy support, developing infrastructure, and increasing public awareness.
The current study analyzed the high heating values (HHVs) of various waste biomass materials intending to the effective management and more sustainable consumption of waste as clean energy source. Various biomass waste samples including... more
The current study analyzed the high heating values (HHVs) of various waste biomass materials intending to the effective management and more sustainable consumption of waste as clean energy source. Various biomass waste samples including date leaves, date branches, coconut leaves, grass, cooked macaroni, salad, fruit and vegetable peels, vegetable scraps, cooked food waste, paper waste, tea waste, and cardboard were characterized for proximate analysis. The results revealed that all the waste biomass were rich in organic matter (OM). The total OM for all waste biomass ranged from 79.39% to 98.17%. Likewise, the results showed that all the waste biomass resulted in lower ash content and high fixed carbon content associated with high fuel quality. Based on proximate analysis, various empirical equations (HHV=28.296-0.2887(A)-656.2/VM, HHV=18.297-0.4128(A)+35.8/FC and HHV=22.3418-0.1136(FC)-0.3983(A)) have been tested to predict HHVs. It was observed that the heterogeneous nature of various biomass waste considerably affects the HHVs and hence has different fuel characteristics. Similarly, the HHVs of waste biomass were also determined experimentally using the bomb calorimeter, and it was observed that among all the selected waste biomass, the highest HHVs (21.19 MJ kg − 1) resulted in cooked food waste followed by cooked macaroni (20.25 MJ kg − 1). The comparison revealed that experimental HHVs for the selected waste biomass were slightly deviated from the predicted HHVs. Based on HHVs, various thermochemical and biochemical technologies were critically overviewed to assess the suitability of waste biomass to energy products. It has been emphasized that valorizing waste-to-energy technologies provides the dual benefits of sustainable management and production of cleaner energy to reduce fossil fuels dependency. However, the key bottleneck in commercializing waste-to-energy systems requires proper waste collection, sorting, and continuous feedstock supply. Moreover, related stakeholders should be involved in designing and executing the decision-making process to facilitate the global recognition of waste biorefinery concept.
The current electricity demand of Kingdom of Saudi Arabia (KSA) is around 55 GW, which is projected to reach upto 120 GW by 2032. This energy is mainly produced from fossil fuels, posing a serious risk to human health and environment.... more
The current electricity demand of Kingdom of Saudi Arabia (KSA) is around 55 GW, which is projected to reach upto 120 GW by 2032. This energy is mainly produced from fossil fuels, posing a serious risk to human health and environment. Moving towards a sustainable model, KSA government has initiated a plan called King Abdullah City of Atomic and Renewable Energy (KACARE) to utilize the indigenous renewable energy resources to generate a further 54 GW energy from solar, wind, nuclear, geothermal and waste-to-energy (WTE). The arid nature of the KSA increases the importance of water in daily life and makes the country the third-largest per capita water user worldwide. There are about 12 thousand industries working in different sectors, which produce large quantities of wastes and waste sludge on daily basis. It has been estimated that 2.4 and 0.77 billion m3/ year of municipal and industrial wastewater respectively is produced in KSA, totalling to 3.17 billion m3/ year. Therefore, ther...
Envirocities eMagazine The energy demand and waste generation have increased significantly in the developing world in the last few decades with rapid urbanization and population growth. The adequate treatment of the waste or sustainable... more
Envirocities eMagazine The energy demand and waste generation have increased significantly in the developing world in the last few decades with rapid urbanization and population growth. The adequate treatment of the waste or sustainable waste management is essential not only from a sanitation point of view but also due to its economic and environmental values including its potential contribution to energy generation in the developing countries. Many of the developed nations have adopted the approach and strategies of the integrated waste management system (Figure 1) to maximize the waste-based revenues in the form of energy, fuels, heat, recyclables, valueadded products, and chemicals along with more jobs and business opportunities. As a result, waste is no longer seen as refuse or discarded material, but an asset or resource to reduce not only the landfill volumes but also the dependency on fossil fuels by generating clean fuels. Dr. Abdul-Sattar Nizami Centre of Excellence in Envi...
Millions of Muslims from all over the world visit the Holy Cities of Saudi Arabia: Makkah and Madinah every year to perform Hajj and Umrah. The rapid growth in urbanization and the local population of Makkah city along with an ever... more
Millions of Muslims from all over the world visit the Holy Cities of Saudi Arabia: Makkah and Madinah every year to perform Hajj and Umrah. The rapid growth in urbanization and the local population of Makkah city along with an ever increasing number of visitors result in huge municipal solid waste (MSW) generation every year. Most of this waste is currently dumped into landfill sites without any treatment, thus causing environmental and health issues. For example, on average around 2.4 thousand tons of waste is dumped into Makkah city’s landfill sites every day that increases to around 3.1 and 4.6 thousand tons per day during Ramadan and Hajj periods, respectively. Around 23% on average of this waste is a plastic waste in the form of plastic bottles, water cups, food plates and shopping bags (Abdul Aziz et al. 2007). A pilot scale catalytic pyrolysis process has been used to convert plastic waste into liquid fuel at Center of Excellence in Environmental Studies (CEES) of King Abdulaziz University, Jeddah. The produced liquid fuel has been found to have a high energy value of around 40 MJ/Kg, the viscosity of 0.9 mm2/s, the density of 0.92 g/cm3, the flash point of 30°C, pour point of -18°C and freezing point of -64°C, characteristics similar to conventional diesel. Thus the produced liquid fuel has the potential to be used in several energy-related applications such as electricity generation, transportation fuel, and heating purposes. It has been estimated that the plastic waste in Makkah city in 2016 could produce around 87.91 MW of electricity with net revenue of 297.52 million SAR. This is projected to increase up to around 172.80 MW of electricity and a total net revenue of 584.83 million SAR by 2040.
Today, the world is facing the challenges of the security of food, water and energy, economic growth and jobs and increased competitiveness and innovation. The nations have to change the traditional linear economy model having the pattern... more
Today, the world is facing the challenges of the security of food, water and energy, economic growth and jobs and increased competitiveness and innovation. The nations have to change the traditional linear economy model having the pattern of taking, making, consuming and throwing away with a circular economy model that inherit the principles of sharing, leasing, reusing, repairing, refurbishing and recycling. Currently, the poor municipal solid waste management (MSW) in developing countries is resulting in several environments and public health issues such as the contamination of soil and groundwater, greenhouse gasses (GHG) emissions, disease spreading vectors, flies and rodents, fire outbreaks, odors and air and waterborne pollutants. Although, many developing countries have ambitious plans to improve MSW standards like developed nations, but due to limited allocated budgets to MSW, poor enforcement of the waste handling regulations, lacking necessary infrastructure and machinery ...
Biodiesel is a promising liquid fuel that is mainly derived from triglycerides and is utilized in diesel engines directly or after blending with conventional gasoline. Triglycerides comprise fatty acid methyl esters (FAME), which are... more
Biodiesel is a promising liquid fuel that is mainly derived from triglycerides and is utilized in diesel engines directly or after blending with conventional gasoline. Triglycerides comprise fatty acid methyl esters (FAME), which are generated from plant or animal based sources. Biodiesel generated from vegetable oils is expensive than petroleum-based diesel and has concerns with food vs. fuels debate. Therefore, biodiesel from renewable sources such as non-food feedstocks has attained a considerable interest in last two decades. This paper aims to examine the biodiesel generation from the non-food feedstocks available in the Kingdom of Saudi Arabia (KSA) as a source of renewable energy and valueadded products along with and a solution to current waste disposal problems. In KSA, non-food feedstocks such as animal fats, waste cooking oil (WCO), agricultural wastes, sewage sludge, and microalgae are promising sources for biodiesel production. These feedstocks are relatively cheap, eas...
Proper treatment and disposal of industrial pollutants of all kinds are a global issue that presents significant techno-economical challenges. The presence of pollutants such as heavy metal ions (HMIs) and organic dyes (ODs) in wastewater... more
Proper treatment and disposal of industrial pollutants of all kinds are a global issue that presents significant techno-economical challenges. The presence of pollutants such as heavy metal ions (HMIs) and organic dyes (ODs) in wastewater is considered a significant problem owing to their carcinogenic and toxic nature. Additionally, industrial gaseous pollutants (GPs) are considered to be harmful to human health and may cause various environmental issues such as global warming, acid rain, smog and air pollution, etc. Conductive polymer-based nanomaterials have gained significant interest in recent years, compared with ceramics and metal-based nanomaterials. The objective of this review is to provide detailed insights into different conductive polymers (CPs) and their nanocomposites that are used as adsorbents for environmental remediation applications. The dominant types of CPs that are being used as adsorbent materials include polyaniline (PANI), polypyrrole (Ppy), and polythiophen...
The world is facing severe environmental challenges, including increasing consumption of fossil-based energy and its consequent devastative impact, i.e. global warming and climate change. Biofuels are promising alternatives to fossil... more
The world is facing severe environmental challenges, including increasing consumption of fossil-based energy and its consequent devastative impact, i.e. global warming and climate change. Biofuels are promising alternatives to fossil fuels with tremendous environmental and socio-economic benefits. There has been a considerable deal of research and development carried out on the production of biofuels in the last 2 decades. However, there is still a huge potential for achieving more cost-effective and efficient biofuel production processes through the application of nanotechnology. The exceptional properties of nanomaterials (nanocatalysts) such as high surface area, catalytic performance, crystallinity, durability, energy storage capacity, etc. offer great potential for optimizing biofuel production systems. Nanocatalysts could also serve recovery, reusability, and recycling purposes.
The organic Rankine cycle (ORC) has recently emerged as a practical approach for generating electricity from low-to-high-temperature waste industrial streams. Several ORC-based waste heat utilization plants are already operational;... more
The organic Rankine cycle (ORC) has recently emerged as a practical approach for generating electricity from low-to-high-temperature waste industrial streams. Several ORC-based waste heat utilization plants are already operational; however, improving plant cost-effectiveness and competitiveness is challenging. The use of thermally efficient and cost-competitive working fluids (WFs) improves the overall efficiency and economics of ORC systems. This study evaluates ORC systems, facilitated by biogas combustion flue gases, using n-butanol, i-butanol, and methylcyclohexane, as WFs technically and economically, from a process system engineering perspective. Furthermore, the performance of the aforementioned WFs is compared with that of toluene, a well-known WF, and it is concluded that i-butanol and n-butanol are the most competitive alternatives in terms of work output, exergy efficiency, thermal efficiency, total annual cost, and annual profit. Moreover, the i-butanol and n-butanol-bas...
Black liquor (BL) rich phenolic and complex compounds is generated from pulp and paper mill manufacturing processes which should be treated before reaching the environment. The potential of achieving several sustainable development goals... more
Black liquor (BL) rich phenolic and complex compounds is generated from pulp and paper mill manufacturing processes which should be treated before reaching the environment. The potential of achieving several sustainable development goals (SDGs) by recovering energy and valuable by-products from BL was extensively investigated. Results revealed that under a dark-fermentation process, the organic content in BL was effectively bio-degraded by anaerobes to achieve a hydrogen yield (HY) of 0.62 ± 0.04 mol/mol glucose. Fortunately, the HY was significantly increased up to 1.41 ± 0.13 mol/mol glucose by immobilizing the anaerobes onto magnetite nanoparticles (MN). α-amylase, xylanase, CM-cellulase, polygalacturinase, and protease enzymes activities were increased by 2.3, 23.7, 2.7, 26.8, and 31.1 folds with supplementation of MN. Moreover, the conversion efficiencies of protein and carbohydrate were improved by values of 36 and 113.3% and total phenolic compounds (TPC) were enhanced by 23....
This paper reviews the status of microbial electrolysis cells (MEC) as a mean for hydrogen (H2) production and urban wastewater treatment method. A case study of the Kingdom of Saudi Arabia (KSA) under MEC concept was developed. KSA is... more
This paper reviews the status of microbial electrolysis cells (MEC) as a mean for hydrogen (H2) production and urban wastewater treatment method. A case study of the Kingdom of Saudi Arabia (KSA) under MEC concept was developed. KSA is the world’s third largest per capita water user country with no lakes and rivers. Every year, around 1.17 and 0.38 billionm3 of domestic and industrial wastewater is generated respectively. The KSA government is seeking sustainable solutions for wastewater treatment and waste-to-energy (WTE) production to bridge the ever increasing water and energy demand-supply gap. However, there is no WTE facility exists to convert the wastewater into energy. Moreover, the potential of wastewater is not examined as an energy recovery substrate. This study, for the first time, estimated that a total electricity of 434 MWe can be produced in 2015 from the KSA’s wastewater if MEC technology is employed. Similarly, an estimated total electricity of 612 and 767 MWe can be produced for the years 2025 and 2035 from the domestic and industrial wastewater by using MEC technology. A surplus electricity of 508 and 637 MWe for the years 2025 and 2035 respectively can be added to the national grid after fulfilling the energy requirement of MEC wastewater treatment plants. Collectively, MEC will contribute 20.4% and 25.6% share of the KSA government’s WTE target of 3GW in 2025 and 2035 respectively. A number of challenges in MEC such as ohmic and concentration losses, saturation kinetics and competing reactions that lower the H2 production are discussed with their potential solutions including, the improvements in MEC design and the use of appropriate electrolytes, antibiotics and air or oxygen.
This study examines point and non-point sources of air pollution and particulate matter and their associated socioeconomic and health impacts in South Asian countries, primarily India, China, and Pakistan. The legislative frameworks,... more
This study examines point and non-point sources of air pollution and particulate matter and their associated socioeconomic and health impacts in South Asian countries, primarily India, China, and Pakistan. The legislative frameworks, policy gaps, and targeted solutions are also scrutinized. The major cities in these countries have surpassed the permissible limits defined by WHO for sulfur dioxide, carbon monoxide, particulate matter, and nitrogen dioxide. As a result, they are facing widespread health problems, disabilities, and causalities at extreme events. Populations in these countries are comparatively more prone to air pollution effects because they spend more time in the open air, increasing their likelihood of exposure to air pollutants. The elevated level of air pollutants and their long-term exposure increases the susceptibility to several chronic/acute diseases, i.e., obstructive pulmonary diseases, acute respiratory distress, chronic bronchitis, and emphysema. More in-de...
Waste-to-energy (WTE) production is one of the sustainable solutions to fulfill energy demands and minimize the environmental problems associated with waste landfilling. This work investigates the biogas production and methane (CH4)... more
Waste-to-energy (WTE) production is one of the sustainable solutions to fulfill energy demands and minimize the environmental problems associated with waste landfilling. This work investigates the biogas production and methane (CH4) enrichment for anaerobic digestion (AD) of fruit and vegetable waste (FVW). The effect of pH and temperature were studied using a lab scale batch anaerobic digester. The raw biogas was pebbled through water, NaOH, Ca(OH)2 and triethanolamine (TEA) for biogas purification and CH4 enrichment. The results showed that mixed fruit waste (MFW) provides 10 % more biogas yield than mixed fruit vegetable waste (MFVW). The maximum biogas yield of 0.030 (g/g volatile solids) was achieved at thermophilic temperature (TT). The optimum pH range under mesophilic temperature (MT) and TT condition was in between 8.3 - 8.8. The use of NaOH, Ca(OH)2 and TEA increased CH4 enrichment upto 5 %, 9 % and 7 %. Biogas having 71 % CH4 contents with 28 % reduced CO2 and 150 ppm H2S was produced using Ca(OH)2.
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Municipal Solid Waste (MSW) management is a chronic environmental problem in most of the developing countries, including the Kingdom of Saudi Arabia (KSA). The concept of Waste-to-Energy (WTE) is known as one of the several technologies... more
Municipal Solid Waste (MSW) management is a chronic environmental problem in most of the developing countries, including the Kingdom of Saudi Arabia (KSA). The concept of Waste-to-Energy (WTE) is known as one of the several technologies capable of benefiting a society, which desires to reduce fossil-fuel addiction. Currently, there is no WTE facility existing in the KSA. The MSW is collected and disposed in landfills untreated. A substantial increase in the population by 3.4 %/y over the last 35 y coupled with urbanization and raised living standards have resulted in high generation rate of MSW. In 2014, about 15.3 Mt of MSW was generated in KSA. The food and plastic waste are the two main waste streams, which covers 70 % of the total MSW. The waste is highly organic (up to 72 %) in nature and food waste covers 50.6 % of it. An estimated electricity potential of 2.99 TWh can be generated annually, if all of the food waste is utilized in anaerobic digestion (AD) facilities. Similarly, 1.03 and 1.55 TWh electricity can be produced annually if all of the plastics and other mixed waste are processed in the pyrolysis and refuse derived fuel (RDF) technologies respectively. The aim of this paper is to review the prospective WTE technologies in Saudi Arabia. However, the real selection of the conversion technologies will be done in conjunction with the fieldwork on waste characterization and laboratory examination of selected technologies and further socioeconomic and environmental evaluations.
Waste-to-energy (WTE) production is one of the sustainable solutions to fulfill energy demands and minimize the environmental problems associated with waste landfilling. This work investigates the biogas production and methane (CH4)... more
Waste-to-energy (WTE) production is one of the sustainable solutions to fulfill energy demands and minimize the environmental problems associated with waste landfilling. This work investigates the biogas production and methane (CH4) enrichment for anaerobic digestion (AD) of fruit and vegetable waste (FVW). The effect of pH and temperature were studied using a lab scale batch anaerobic digester. The raw biogas was pebbled through water, NaOH, Ca(OH)2 and triethanolamine (TEA) for biogas purification and CH4 enrichment. The results showed that mixed fruit waste (MFW) provides 10 % more biogas yield than mixed fruit vegetable waste (MFVW). The maximum biogas yield of 0.030 (g/g volatile solids) was achieved at thermophilic temperature (TT). The optimum pH range under mesophilic temperature (MT) and TT condition was in between 8.3-8.8. The use of NaOH, Ca(OH)2 and TEA increased CH4 enrichment upto 5 %, 9 % and 7 %. Biogas having 71 % CH4 contents with 28 % reduced CO2 and 150 ppm H2S was produced using Ca(OH)2.
Zinc carbonate hydroxide Zn 5 (CO 3) 2 (OH) 6 nanoparticles have been successfully synthesised by the hydrothermal treatment of an aqueous solution of zinc acetate dihydrate (Zn(CH 3 COO) 2 •2H 2 O) and urea (NH 2 CONH 2) at 120 °C. The... more
Zinc carbonate hydroxide Zn 5 (CO 3) 2 (OH) 6 nanoparticles have been successfully synthesised by the hydrothermal treatment of an aqueous solution of zinc acetate dihydrate (Zn(CH 3 COO) 2 •2H 2 O) and urea (NH 2 CONH 2) at 120 °C. The as-synthesized nanoparticles were characterized by X-ray Diffraction (XRD), Scanning Electron Microscopy (SEM) and Thermogravimetric Analysis (TGA). XRD and SEM revealed Zn 5 (CO 3) 2 (OH) 6 nanoparticles produced in 20-40 nm size range with spherical morphology. TGA showed the expected one-step decomposition of zinc carbonate hydroxide to zinc oxide (ZnO) between temperatures of 180 °C and 350 °C. The hydrothermal reaction time (2, 3 and 4 hours) studied did not show any significant effect on the particle size and morphology. However, the crystallinity of the synthesised nanoparticles seems to be enhanced at longer hydrothermal reaction time by showing larger XRD diffraction peaks.
The increasing population, urbanization and industrial growth are causing serious environmental challenges including air pollution worldwide. According to WHO, the indoor and outdoor air pollution exposure has caused around 7 million... more
The increasing population, urbanization and industrial growth are causing serious environmental challenges including air pollution worldwide. According to WHO, the indoor and outdoor air pollution exposure has caused around 7 million deaths globally only in 2012. The major air pollution sources include transportation and petrochemical based industry. Motor vehicle repair workshops (MVRW) pose many environmental as well as occupational health challenges. Workers safety and protection at workplace has been a great concern for employees, employers, governments and the entire society for years. This review article highlights the prominent air pollutants and health and safety challenges at MVRW. Many scientific articles studying pollutants that are detrimental to health e.g. benzene, PAHs, VOCs, heavy metals, PM, NO x and SO x are reviewed here. The national and international environmental legislations and health and safety standards by Occupational Safety and Health Administration (OSHA), US Environmental Protection Agency (USEPA) and Presidency of Meteorology and Environment (PME) Saudi Arabia have been mentioned and compared for air quality both outdoor and in occupational environment. Latest developments in ambient air pollution monitoring and occupational personals health risk assessment methods and strategies have also been reviewed coherently, including the prominent physical, chemical, biological, musculoskeletal and accidental safety hazards at MVRW. The current environmental challenges and perspectives for Saudi Arabia in terms of both ambient air pollution as well as in occupational settings are also discussed. The review ends with identifying gaps and limitations in monitoring and legislation in the subject area, and suggesting the way forward for Saudi Arabia including further research and development needed in the subject area.
Millions of Muslims from all over the world visit the Holy Cities of Saudi Arabia: Makkah and Madinah every year to worship in form of Pilgrimage (Hajj) and Umrah. The rapid growth in local population, urbanization, and living standards... more
Millions of Muslims from all over the world visit the Holy Cities of Saudi
Arabia: Makkah and Madinah every year to worship in form of Pilgrimage
(Hajj) and Umrah. The rapid growth in local population, urbanization, and
living standards in Makkah city along with continually increasing number of
visitors result in huge municipal solid waste generation every year. Most of
this waste is disposed to landfills or dumpsites without material or energy
recovery, thus posing substantial environmental and health risks. The municipal
plastic waste is the second largest waste stream (up to 23% of total
municipal waste) that is comprised of plastic bottles, water cups, food
plates, and shopping bags. The sustainable disposal of plastic waste is
challenging task due to its clogging effects, very slow biodegradation
rates, and presence of toxic additives and dyes. Pyrolysis is one of the
promising waste-to-energy technology for converting municipal plastic
waste into energy (liquid fuel) and value-added products like char. The
produced liquid fuel has the potential to be used in several energy-related
applications such as electricity generation, transportation fuel, and heating
purposes. It has been estimated that the plastic waste in Makkah city in
2016 can produce around 87.91 MW of electricity. This is projected to
increase up to around 172.80 MW of electricity by 2040. A global warming
potential of 199.7 thousand Mt.CO2 eq. will be achieved with savings of 7.9
thousand tons emission of CH4, if pyrolysis technology is developed in
Makkah city. Furthermore, a total savings of 297.52 million SAR from landfill
diversion, electricity generation, and carbon credits would be possible to
achieve in 2016 from pyrolysis. These economic benefits will increase every
year and will reach up to 584.83 million SAR in 2040.
• First study on the incidence of FRs from different micro-environments of KSA • First study in literature reporting emerging Br/Cl FRs and OPFRs in AC filter dust • Chlorinated alkyl phosphate, BDE-209, and DBDPE were major chemicals. •... more
• First study on the incidence of FRs from different micro-environments of KSA • First study in literature reporting emerging Br/Cl FRs and OPFRs in AC filter dust • Chlorinated alkyl phosphate, BDE-209, and DBDPE were major chemicals. • Lower levels were observed in house dust than those of car and AC filter dust. • Estimated risk assessment of BDE-99 for toddlers was high than the RfD values. Different flame retardants (FRs) namely polybrominated diphenyl ethers (PBDEs), emerging brominated/chlori-nated flame retardants (Br/Cl FRs), and organophosphate FRs (OPFRs) were analyzed in cars, air conditioner (AC) filters and floor dust of different households from Jeddah, Kingdom of Saudi Arabia (KSA). To the best of our knowledge, this is first study in literature reporting emerging Br/Cl FRs and OPFRs in AC filter dust and also first to report on their occurrence in dust from KSA. Chlorinated alkyl phosphate, penta-BDEs, BDE-209, and decabromodiphenylethane (DBDPE) were the major chemicals in dust samples from all microenvironments. ΣOPFRs occurred at median concentrations (ng/g dust) of 15,400, 10,500, and 3750 in AC filter, car and house floor dust, respectively. For all analyzed chemicals, relatively lower levels were observed in floor dust than car and AC filter dust. The profiles of FRs in car dust were different from AC filter and floor dust, which reflected their wider application as FR and plasticizer in variety of household and commercial products. For toddlers,
A lot of attention has been paid to improving occupational safety and health (OSH) in small scale industries all over the globe. This study describes the outcomes of a preliminary OSH status assessment in small scale industries of motor... more
A lot of attention has been paid to improving occupational safety and health (OSH) in small scale industries all over the globe. This study describes the outcomes of a preliminary OSH status assessment in small scale industries of motor vehicle repair workshops (MVRW) in Jeddah, Kingdom of Saudi Arabia (KSA). An inspection tool composed of 10 OSH elements and 62 items employed walk-through survey, observations and interviews. The mean positive responses for different OSH elements surveyed were as follows; personal protective equipment (PPEs) (43%), emergency preparedness (49%), fire protection (60%), facilities (80%), general workshop safety (43%), housekeeping (17%), chemical exposure (12%), services and maintenance (57%), mechanical handling (81%) and tool safety (63%). However, special concerns were found for OSH elements including; use of PPE's, emergency preparedness, general workshops safety, housekeeping and exposures to chemicals as having safety score less than 50%. OSH elements with lower positive responses at surveyed workshops would be addressed through further monitoring and training of technical and administrative staff. This preliminary survey will form the basis of a more comprehensive study for evaluation of an accurate representative OSH status in small scale industries in KSA.
Professional driving is associated with high rates of occupational musculoskeletal disorders (OMSDs). The objective of this study was to assess the prevalence of OMSDs among drivers and office workers of taxi industry in Jeddah city. A... more
Professional driving is associated with high rates of occupational musculoskeletal disorders (OMSDs). The objective of this study was to assess the prevalence of OMSDs among drivers and office workers of taxi industry in Jeddah city. A detailed custom-made questionnaire was used that included socio-demographic and occupational characteristics of subjects together with OMSDs prevalence rates. In this research, 173 subjects participated of which 70.5% were drivers and 29.5% were office workers. Standard Nordic Questionnaire (SNQ) was used to assess 1-year and 1-week prevalence rates of OMSDs in nine body regions. 1-year and 1-week reported prevalence rates of OMSDs among taxi drivers were 85.3 and 51.6%, while among office workers were 52.9 and 31.4%, respectively. The highest self-reported prevalence rates of OMSDs for taxi drivers were found for the lower back (60.7%) and lowest rates for the elbow (14.8%). Whereas, among office workers, the highest prevalence rates were found for the lower back and knee (29.4%) and lowest rates for feet/ankle (2.0%). The chi-square test found significant correlation between being immigrant (p=0.038), hours of driving per day (p=0.002), number of working days per week (p=0.000) with 1-year prevalence of OMSDs, while job experience (p=0.006), hours of driving per day (p=0.004) and break during work (p=0.029) showed significant correlation with perceived 1-week prevalence of OMSDs among taxi drivers in Jeddah.
This study aims to examine the occupational health and safety (OHS) status in motor vehicle repair workshops (MVRW) industry in the city of Jeddah, Kingdom of Saudi Arabia (KSA). An inspection tool composed of 10 OHS components and 69... more
This study aims to examine the occupational health and safety (OHS) status in motor vehicle repair workshops (MVRW) industry in the city of Jeddah, Kingdom of Saudi Arabia (KSA). An inspection tool composed of 10 OHS components and 69 items was employed through observations, interviews, walk through survey and focused group discussions. The data was collected from local workshops (LWs, N=62) and multinational companies' workshops (CWs, N=11). The mean positive response for OHS components among surveyed LWs and CWs was as follow; personal protective equipment's (PPEs) (28% and 61%), fire protection and emergency management (52% and 91%), provision of facilities (69% and 94%), electric safety (44% and 82%), general workshop safety (43% and 82%), housekeeping (18% and 84%), chemical exposure (16% and 69%), maintenance and services (54% and 86%), manual handling (84% and 100%) and tool safety (58% and 91%), respectively. The overall OHS mean positive response, complying best practices and regulations, of all OHS elements in LWs was 47% which was much lower than 84% positive response for CWs. The impact of OHS on workers' health was also discussed together with recommendations given for further improvement.
The concept of energy from waste is getting popular nowadays across the globe, as being capable of producing multi fuels and value-added products from different fractions of municipal solid waste (MSW). The energy recovery technologies... more
The concept of energy from waste is getting popular nowadays across the globe, as being capable of producing multi fuels and value-added products from different fractions of municipal solid waste (MSW). The energy recovery technologies under this concept are anaerobic digestion (AD), pyrolysis, transesterification, refuse derived fuel (RDF) and incineration. This concept is very relevant to implementation in countries like Saudi Arabia, who wants to cut their dependence on oil. Moreover, the waste to energy becomes the imperative need of the time because of new governmental policy ‘Vision 2030’ that firmly said to produce renewable energy from indigenous sources of waste, wind and solar and due to given situations of Hajj and Umrah with massive amounts of waste generation in a short period. This study focused on two waste to energy technologies, AD and pyrolysis for food (40% of MSW) and plastic (20% of MSW) waste streams respectively. The energy potential of 1409.63 and 5619.80 TJ can be produced if all of the food and plastic waste of the Madinah city are processed through AD and pyrolysis respectively. This is equivalent to 15.64 and 58.81 MW from biogas and pyrolytic oil respectively or total 74.45 MW of continuous electricity supply in Madinah city throughout the whole year. It has been estimated that the development of AD and pyrolysis technologies will also benefit the economy with net savings of around US $63.51 and US $53.45 million respectively, totaling to an annual benefit of US $116.96 million. Therefore, in Saudi Arabia and particularly in Holiest cities of Makkah and Madinah the benefits of waste to energy are several, including the development of renewable-energy, solving MSW problems, new businesses, and job creation and improving environmental and public health.
Small-scale industries account for a large proportion of jobs and play a vital role in most countries’ economic growth and prosperity. Due to the very low use of personal protective equipment (PPEs), employees are exposed to numerous... more
Small-scale industries account for a large proportion of jobs and play a vital role in most countries’ economic
growth and prosperity. Due to the very low use of personal protective equipment (PPEs), employees
are exposed to numerous physical, chemical, and accidental hazards in small-scale industries. PPEs
are very effective in minimizing occupational injuries, accidents, and other hazards which otherwise
result in substantial manpower and financial losses. The study objective was to assess the availability
and use of PPEs as well as self-reported occupational exposures among workers in surveyed small industries
in Jeddah. The study involved 102 workers from 28 small-scale industries (vehicle repair, welding,
and paint). A survey was conducted to gather data of socio-demographic characteristics, self-reported
occupational exposures, and frequency of PPEs used by workers. The occupational exposures (never
exposed, sometimes exposed and always exposed) were reported in percentages including; noise exposure
(19.6, 73.5 and 6.9%); dust/smoke exposure (9.8, 69.6 and 20.6%); vapors/fumes exposure (11.8, 60.8
and 27.5%); and direct sunlight (43.1, 56.9 and 0%), respectively. The reported use of different PPEs in
descending order was; knee joints mats (50%), welding shields (50%), safety glasses (33.3%), gloves
(27.5%), face masks (26.5%), safety shoes (10.8%) and earplugs/ muffs (8.8%). On the basis of this study
findings, hand hygiene and general OSH awareness like interventions can be developed which will help
in minimizing workplace exposures among small-scale industry workers.
Growing environmental concern and rapid consumption of poor biodegradable mineral oils have triggered the need for the development of eco-friendly biodegradable bio-based oils with low toxicity and excellent lubricating performance. The... more
Growing environmental concern and rapid consumption of poor biodegradable mineral oils have triggered the need for the development of eco-friendly biodegradable bio-based oils with low toxicity and excellent lubricating performance. The study aims to produce and evaluate the performance of date seed (Phoenix dactylifera L.) oil, which is abundantly available in the Middle East region, as an alternative bio-based lubricant. The optimum date seed oil (DSO) yield of 6% was achieved using solvent extraction of date seeds with particle size of 1 mm, hexane solvent to seed ratio of 6:1, and processing time of 18 hours. The physicochemical properties of the DSO were found such as its clear yellow color, density of 0.907 g/cm 3 , iodine value of 13.28 gl 2 /100 g, saponification value of 162.5 mg KOH/g, and acid value of 1.4 mg KOH/g. Moreover, fatty acid composition was analyzed employing quantitative gas chromatography (GC), and the oleic acid (41.1%), linoleic acid (21.4%), and palmitic acid (11.3%) were found to be the major unsaturated fatty acids. The pour and flash points were around-10°C and 140°C, respectively. Thermogravimetric analysis (TGA) revealed that the produced DSO is thermally stable at up to 300°C. The rheological properties such as viscosity (41.62 cSt at 40°C and 8.13 cSt at 100°C) and viscosity index 173 were also assessed. These properties along with tribological properties of the DSO were compared with other bio-based oils and commercial SAE20W40 mineral oil. Overall, the characteristics of the DSO showed good potential to be developed into a bio-based lubricant. Furthermore, its properties can be enhanced by adding suitable additives. The findings of this study will help in developing eco-friendly bio-based industrial lubricants.
Purpose The aim of this work was to investigate the influence of hydroxypropyl methylcellulose (HPMC) on the phase transformation and release profile of carbamazepine-nicotinamide (CBZ-NIC) cocrystal in solution and in sustained release... more
Purpose The aim of this work was to investigate the influence of hydroxypropyl methylcellulose (HPMC) on the phase transformation and release profile of carbamazepine-nicotinamide (CBZ-NIC) cocrystal in solution and in sustained release matrix tablets. Methods The polymorphic transitions of the CBZ-NIC cocrystal and its crystalline properties were examined by differential scanning calorimetry (DSC), X-ray powder diffraction (XRPD), Raman spectroscopy, and scanning electron microscopy (SEM). Results The apparent CBZ solubility and dissolution rate of CBZ-NIC cocrystal were constant in different concentrations of HPMC solutions. In a lower percentage of HPMC in the matrix tablets, the CBZ release profile of the CBZ-NIC cocrystal was nonlinear and declined over time. With an increased HPMC content in the tablets, the CBZ-NIC cocrystal formulation showed a significantly higher CBZ release rate in comparison with the other two formulations of CBZ III and the physical mixture. Conclusions Because of a significantly improved dissolution rate of the CBZ-NIC cocrystal, the rate of CBZ entering into solution is significantly faster than the rate of formation of the CBZ-HPMC soluble complex in solution, leading to a higher supersaturation level of CBZ and subsequently precipitation of CBZ dihydrate.
An increasing interest in biochar application has opened many multidisciplinary research areas in science. Biochar can be produced by thermochemical conversion of organic biomass in an oxygen-deficient condition. Extensive research has... more
An increasing interest in biochar application has opened many multidisciplinary research areas in science. Biochar can be produced by thermochemical conversion of organic biomass in an oxygen-deficient condition. Extensive research has been conducted on the potential of biochar for agronomic applications, such as soil fertility improvement and carbon sequestration due to its specific mineralogical composition and long-term stability in the soil. Using biochar for environmental remediation has also been recognized recently as a promising area of research for its unique physicochemical characteristics, redox potential, and adsorption capacity. However, the published works are mostly focused only on the agronomic and environmental applications with little information presented to elucidate the different mechanisms involved. This study, therefore, aims to examine the influence of controlling parameters during biochar production, such as pyrolysis temperature, residence time, and types of feedstock on the characteristics of biochar. Various mechanisms explaining the potential of biochar for the environmental and agronomic applications are discussed in detail. The challenges faced in biochar development and its field applications for agronomic and environmental remediation purposes are also highlighted. Finally, recommendations for future research are given on the development of biochar with high redox functional groups and sorption potential as well as on understanding the behavior of biochar under the natural field conditions.
An industrial-scale molasses-based bioethanol production system was modeled and studied by conducting exergy, exergoeconomic, and exergoenvironmental analyses. The entire process was represented by a control volume, and its exergoeconomic... more
An industrial-scale molasses-based bioethanol production system was modeled and studied by conducting exergy, exergoeconomic, and exergoenvironmental analyses. The entire process was represented by a control volume, and its exergoeconomic and exergoenvironmental parameters were determined using the specific exergy costing (SPECO) approach. These exergy-based analyses were carried out to measure the overall exergy dissi-pation, cost, and environmental impact of the bioethanol production process based on actual operational ther-modynamic, economic, and environmental data. Natural gas showed the highest contribution to the total input exergy (61.1%) and total environmental impact rate (56.6%) of the process, while the highest contribution to its total cost rate (75.7%) was from molasses. The exergetic efficiency determined for the process was 35.9%, while the exergy dissipation accounted for 60.8% of its total input exergy. The unit exergoeconomic costs of the fuel and product were determined to be 6.2 and 20.9 USD/GJ, while the unit exergoenvironmental impacts of the fuel and product were 15.5 and 31.5 mPts/GJ, respectively. The exergoeconomic factor of the process was found to be 29.4%, while the exergoenvironmental factor was 0.74%. Overall, natural gas consumption was the most significant exergetic hotspot of the process, and hence more exergetically-sustainable alternatives should be considered to improve the process. Low-cost waste feedstocks need to be utilized to improve the economic viability of the process.
The rapid depletion of fossil fuel resources and climatic changes has triggered the researchers' attention to find an alternative and renewable energy source. Thus, biodiesel has been recognized as a potential alternative to petrodiesel... more
The rapid depletion of fossil fuel resources and climatic changes has triggered the researchers' attention to find an alternative and renewable energy source. Thus, biodiesel has been recognized as a potential alternative to petrodiesel for its biodegradability, non-toxicity, and environment-friendly attributes. In this study, an efficient and recyclable Cu-Ni doped ZrO 2 catalyst was synthesized and used to produce biodiesel from a novel non-edible caper (Capparis spinosa L.) seed oil. The synthesized catalyst was characterized by x-ray diffraction, fourier-transform infrared spectroscopy, scanning electron microscopy, and energy dispersive x-ray analysis. The catalyst was reused in four consecutive transesterification reactions without losing any significant catalytic efficiency. Transesterification reaction conditions were optimized via response surface methodology based on Box-Behnken design for predicting optimum biodiesel yields by drawing 3D surface plots. Maximum biodiesel yield of 90.2% was obtained under optimal operating conditions of 1:6 M ratio of oil to methanol, reaction temperature of 70 • C, reaction time of 1.5 h, and 2.5% catalyst loading. Fourier-transform infrared spectroscopy, gas chromatography mass spectrometry, and nuclear magnetic resonance (1 H and 13 C) analysis confirmed the high quality of biodiesel produced from non-edible caper (Capparis spinosa L.) seed oil. The fuel properties of the produced biodiesel were also found, such as kinematic viscosity (4.17 cS T), density (0.8312 kg/L), flash point (72 • C), acid no (0.21 mgKOH/g) and sulphur content (0.00042 wt%). These properties were matched and are in close agreement with the International Biodiesel Standards of European Union (EU-14214), China GB/T 20,828 (2007), and American (ASTM6751). Thus, non-edible Capparis spinosa L. seed oil and Cu-Ni doped ZrO 2 catalyst appeared to be highly active, stable, and cheap candidates to boost the future biodiesel industry.
The poly deep eutectic solvents (PDESs), a potential substituent to ionic liquids, have emerged as relatively new material and have been successfully applied in catalysis, nanotechnology, and, more importantly, in gas separation. Herein,... more
The poly deep eutectic solvents (PDESs), a potential substituent to ionic liquids, have emerged as relatively new material and have been successfully applied in catalysis, nanotechnology, and, more importantly, in gas separation. Herein, the PDESs were incorporated for the first time in the CO 2 capturing membranes to exploit their inherent advantages in the acid gas capture. The PDESs were synthesized by mixing choline chloride (hydrogen bond acceptor-HBA) and two hydrogen bond donors-HBDs (polyacrylic acid and polyacrylamide) separately in different molar ratios. The physical changes of the resulting homogeneous mixture along with the Fourier Transform Infrared confirmed the successful synthesis of the PDESs. Afterward, these PDESs were impregnated into microporous polyvinylidene fluoride (PVDF) membrane support to fabricate supported liquid membranes (SLMs). The gas performance of the prepared PDES-SLMs was tested under pure and mixed-gas conditions for CO 2 , CH 4 , and N 2. The PDES-SLMs showed a significantly high CO 2 / CH 4 and CO 2 /N 2 selectivities of the order of 55.5 and 60, respectively. To evaluate their practical implication, the SLMs were investigated systematically under different operating conditions such as choline content, temperature, volume fraction of the CO 2 in the feed, and the activation energy required for CO 2 capture. The synthesized SLMs showed exceptional results in both permeability and selectivity viewpoint. The remarkable SLMs gas performance can be ascribed to the basicity, molar free volume, and the H-bonding strength of the synthesized PDESs. The green potential, low cost, and the promising gas separation performance make theses PDESs a favorable alternative to the competing PILs in capturing the greenhouse acid gases.
Forest harvesting activities on peatlands have long been associated with nutrient leaching and deterioration of downstream water quality. This study aims to assess the effect of grass seeding practice on harvested blanket peatlands to... more
Forest harvesting activities on peatlands have long been associated with nutrient leaching and deterioration of downstream water quality. This study aims to assess the effect of grass seeding practice on harvested blanket peatlands to immobilize N and reduce its export to water courses. First, a plot-scale field experiment was conducted by seeding with two grass species (Holcus lanatus and Agrostis capillaris) to study the N uptake potential from a harvested area. Secondly, a simulated rainfall experiment was conducted to study the effect of these grasses on reducing N leaching from surface peat using laboratory flume approach. In the end, the role of seeded grasses in removing N from nutrient-rich throughflow water was assessed using simulated overland flow experiment. The results showed that the seeded grasses had the potential to uptake over 30 kg ha −1 of N in the first year after seeding on harvested peatlands, whereas it takes over 2.5 years to establish the same level of N uptake by natural re-vegetation (non-grassed). In the simulated rainfall experiment, the inorganic N (NH 4 +-N and NO 3 −-N) leaching in surface runoff from grassed flumes was 72% lower (453 mg m −2) than non-grassed flumes (1643 mg m −2). In the simulated overland flow experiment , the N retention by grassed flumes was significantly higher (98%) as compared to non-grassed flumes (70%) in the simulated overland flow experiment. Comparatively higher concentrations of NH 4 +-N and NO 3 −-N in soil porewaters of non-grassed flumes suggest that this N retention by non-grassed flumes is less sustainable and is likely to be leached in runoff in subsequent flow events. The results from all three experiments in this study suggest that seeded grasses are a major sink of N on harvested blanket peatland forests. Immobilization of N onsite using the grass seeding and mini-buffer practice could be an efficient and a feasible mean of reducing N export from harvested blanket peatland forests in order to protect the sensitive water courses. However, the sustainability of retention and immobilization of N by grasses needs to be studied further in long-term field-scale experiments on multiple peatland sites.

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Millions of Muslims from all over the world visit the Holy Cities of Saudi Arabia: Makkah and Madinah every year to perform Hajj and Umrah. The rapid growth in urbanization and the local population of Makkah city along with an ever... more
Millions of Muslims from all over the world visit the Holy Cities of Saudi Arabia: Makkah and Madinah every year to perform Hajj and Umrah. The rapid growth in urbanization and the local population of Makkah city along with an ever increasing number of visitors result in huge municipal solid waste (MSW) generation every year. Most of this waste is currently dumped into landfill sites without any treatment, thus causing environmental and health issues. For example, on average around 2.4 thousand tons of waste is dumped into Makkah city’s landfill sites every day that increases to around 3.1 and 4.6 thousand tons per day during Ramadan and Hajj periods, respectively. Around 23% on average of this waste is a plastic waste in the form of plastic bottles, water cups, food plates and shopping bags (Abdul Aziz et al. 2007). A pilot scale catalytic pyrolysis process has been used to convert plastic waste into liquid fuel at Center of Excellence in Environmental Studies (CEES) of King Abdulaziz University, Jeddah. The produced liquid fuel has been found to have a high energy value of around 40 MJ/Kg, the viscosity of 0.9 mm2/s, the density of 0.92 g/cm3, the flash point of 30°C, pour point of -18°C and freezing point of -64°C, characteristics similar to conventional diesel. Thus the produced liquid fuel has the potential to be used in several energy-related applications such as electricity generation, transportation fuel, and heating purposes. It has been estimated that the plastic waste in Makkah city in 2016 could produce around 87.91 MW of electricity with net revenue of 297.52 million SAR. This is projected to increase up to around 172.80 MW of electricity and a total net revenue of 584.83 million SAR by 2040.
Research Interests:
The current electricity demand of the Kingdom of Saudi Arabia (KSA) is around 55 GW, which is projected to reach up to 120 GW by 2032. This energy is mainly produced from fossil fuels, posing a serious risk to human health and... more
The current electricity demand of the Kingdom of Saudi Arabia (KSA) is around 55 GW, which is projected to reach up to 120 GW by 2032. This energy is mainly produced from fossil fuels, posing a serious risk to human health and environment. Moving towards a sustainable model, KSA government has initiated a plan called the King Abdullah City of Atomic and Renewable Energy (KACARE) to utilize the indigenous renewable energy resources to generate a further 54 GW energy from solar, wind, nuclear, geothermal and waste-to-energy (WTE). The arid nature of the KSA increases the importance of water in daily life and makes the country the third-largest per capita water user worldwide. About 12 thousand industries are working in different sectors, which produce large quantities of wastes and waste sludge on a daily basis. It has been estimated that 2.4 and 0.77 billion m3/ year of municipal and industrial wastewater respectively are produced in KSA, totaling to 3.17 billion m3/ year. Therefore, there is a huge potential of producing bioenergy and bioproducts, if this wastewater is treated in algae biorefinery. Algae as a ‘natural chemical factory’ has gained significant attention to produce several energy carriers, including starches for alcohols, lipids for diesel fuel, and bio-hydrogen (H2) for fuel cells and valuable materials and chemicals. Considerable progress has been made in recent years to optimize the production of energy and value-added products by utilizing algae under algae biorefinery concept. The biorefinery is a multi-process and multi-product system, similar to a petroleum refinery. It utilizes various feedstock to produce useful materials, chemicals, and bioenergy in the form of fuel, power, and heat in an integrated system. Algae contain natural oils, carbohydrates, and proteins for the production of biodiesel, ethanol, and H2. The leftover or residues of algae after oil extraction can be digested anaerobically to produce methane (CH4) as an energy carrier. Furthermore, the AD digestate can be a source of animal feed and organic fertilizer. Although, theoretically algae can produce various fuels, an array of valuable materials and capture carbon emissions, but in practice, profitable algal biofuel production has proven to be quite challenging. Most of these challenges lie in algae production methods, including a selection of suitable algae strain, its cultivation, harvesting, and extraction of value-added materials for energy and bioproducts along with their conversion pathways. The aim of this paper is to review the potential of algae biorefinery in KSA for the treatment of wastewater and production of bioenergy and bioproducts.
Research Interests:
Sorghum Bagasse in recent years has emerged as a promising feedstock for production of biofuel and value-added products following various biological conversion pathways. However, adequate conservation is critical for utilizing sorghum... more
Sorghum Bagasse in recent years has emerged as a promising feedstock for production of biofuel and value-added products following various biological conversion pathways. However, adequate conservation is critical for utilizing sorghum bagasse as raw material for fuel and fiber around the year in biofuels plants. The biomass conservation using drying method depends on different parameters such as energy efficiency, heat integration, emission control and dryer performance. The pressure drop phenomenon in drying systems for biomass conservation has been reported in few studies only. Therefore, this study aims to investigate the pressure drop as a function of airflow velocity and construct Shedd’s curves for energy sorghum bagasse with an ambition to develop large-scale drying systems for biomass conservation. The bagasse was obtained by extracting the juice from the harvested sorghum and passing it through a juicing machine. The bagasse was manually chopped and stored on a wooden platform having 2.44 m2 area in a 55-gallon drum at a depth of 0.57 m. A fan equipped with a regulator to control variable speed was attached to the plenum, having the ability to generate airflow up to 2.15 ms-1. The airflow velocities (0.24 to 1.32 ms-1) caused pressure drop (9.96 to 346.23 Pa) across the empty drum. Similarly, the pressure drop in the drum containing sorghum bagasse ranged from 19.92 to 263.25 Pa due to airflow velocities ranging from 0.043 to 0.799 ms-1, respectively. Pressure drop increased with increasing airflow velocity, and was similar to the pressure drop values for ear and shelled corn, reported in ASABE standards. Shedd’s curves for sorghum bagasse samples were developed; these curves could be used for designing large-scale aeration systems for chopped energy sorghum.
Research Interests:
Every year, millions of Muslims gather in the Kingdom of Saudi Arabia (KSA) for worship, i.e. Hajj (Pilgrimage) and Umrah. The Makkah city landfills receive about 2.4 thousand tons of municipal solid waste (MSW) every day. While, these... more
Every year, millions of Muslims gather in the Kingdom of Saudi Arabia (KSA) for worship, i.e. Hajj (Pilgrimage) and Umrah. The Makkah city landfills receive about 2.4 thousand tons of municipal solid waste (MSW) every day. While, these quantities become 3.1 and 4.6 thousand tons per day during the Ramadan and Hajj respectively. All of the collected MSW is disposed to landfill sites untreated, which results in
greenhouse gas (GHG) emissions as well as water and soil contamination. The government considers reuse and recycling as optimum techniques for waste management following source reduction. However, the current waste recycling has been carried out mostly by informal sectors and only few recyclable materials such as paper, cardboard, metals and plastics are recycled (10-15% of total waste). The waste pickers or waste scavengers take the recyclables from the waste bins, containers and dumpsites. There is an immediate need to develop public-private partnership (PPP) to improve MSW management system in Makkah city including waste reuse and recycling. It is theoretically estimated that only by recycling glass, metals, aluminium and cardboard, climate will be saved from 5.6 thousand tons emission of methane
(CH4); a major source of GHG emissions and 140.1 thousand Mt.CO2 eq. of global warming potential (GWP) with carbon credit revenue of worth 67.6 million SAR. Similarly by recycling above-mentioned recyclables, a net revenue of 113 million SAR will be added to the national economy every year only from Makkah city. Moreover,
technically, the waste recycling does not require high-skill labour, complex technology and thus can be easily carried out in any urban areas like Makkah city.
Research Interests:
The concept of the waste biorefinery is known as one of the several energy recovery technologies capable of producing multi-products in the form of biofuels and value-added products treating different fractions of municipal solid waste... more
The concept of the waste biorefinery is known as one of the several energy recovery technologies capable of producing multi-products in the form of biofuels and value-added products treating different fractions of municipal solid waste (MSW). The conversion technologies such as anaerobic digestion (AD), pyrolysis, transesterification, incineration treat food, plastic, meat, and lignocellulosic wastes to produce liquid, gaseous and solid biofuels. Makkah city landfills receive about 2750 tons of waste every day. While during the Ramadan and Hajj seasons, these quantities become 3000 tons and 4706 tons per day respectively. More than 2.5 million animals were sold for slaughtering in 2014 Hajj, and their blood and organic solid waste were disposed of untreated. Similarly, around 2.1 million plastic Zam-Zam cups were wasted every day during the 2014 Ramadan time. In the first three days of 2014's Ramadan, 5000 tons of food was wasted only in Makkah municipality. Collectively, about 3853 tons of waste were generated each day during 2014 Hajj and Ramadan. The waste from Al-Haram and Al-Masha’ir (Mina, Muzdalifah and Arafat) and their surroundings was mainly composed of organics (up to 68.5%). There is no waste-to-energy facility existing in Saudi Arabia. The waste biorefinery in Makkah will divert up to 94% of MSW from landfill to biorefinery. The energy potential of 2171.47 TJ and 8852.66 TJ can be produced if all of the food and plastic waste of the Makkah city are processed through AD and pyrolysis respectively. The development of AD and pyrolysis under waste biorefinery will also benefit the economy with gross savings of 405 and 565.7 million SR respectively, totalling to an annual profit of 970.7 million SR. Therefore, the benefits of waste biorefinery in Makkah city and other parts of the Saudi Arabia are numerous including the development of renewable-energy science and research, solving solid waste problems, new businesses and job creation opportunities and minimizing environmental pollution.
Research Interests:
The energy consumption in Saudi Arabia has increased significantly in recent years due to a rapidly growing population and economic development. The current peak demand of electrcity is 55 GW and it is projected to become 120 GW in the... more
The energy consumption in Saudi Arabia has increased significantly in recent years due to a rapidly growing population and economic development. The current peak demand of electrcity is 55 GW and it is projected to become 120 GW in the year 2032. Fossil fuels are the only choice to meet the energy requirements. The government plans to double its energy generating capacity by 2020, of which around 85% will come from renewable resources. Natural zeolites are found abundantly in Saudi Arabia and have a significant role in the energy generation applications. Natural zeolites samples have been collected from the Jabal Shama occurrence near Jeddah city. All of the samples showed the standard zeolite group of alumina-silicate minerals with the presence of other elements such as Na, Mg and K etc. A highly crystalline structure is found in natural zeolites, which is critical when using in the energy applications as a process catalyst. However, there is a need of special milling and purification process to achieve homogeneous particle morphology and sizes in a range of sub-micron to nano-meter without impurities. This will significantly increase the surface area and pore volume of natural zeolites, thus improving their properties as a process catalyst and optimizer. The aim of this paper is to investigate the potential and utilization of naturally occurring zeolites in Saudi Arabia for pyrolysis of waste plastic to fuel oil.
Research Interests:
The energy demand and waste generation have increased significantly in the developing world in the last few decades with rapid urbanization and population growth. The adequate treatment of the waste or sustainable waste management is... more
The energy demand and waste generation have increased significantly in the developing world in the last few decades with rapid urbanization and population growth. The adequate treatment of the waste or sustainable waste management is essential not only from a sanitation point of view but also due to its economic and environmental values including its potential contribution to energy generation in the developing countries. Many of the developed nations have adopted the approach and strategies of the integrated waste management system (Figure 1) to maximize the waste-based revenues in the form of energy, fuels, heat, recyclables, value-added products, and chemicals along with more jobs and business opportunities. As a result, waste is no longer seen as refuse or discarded material, but an asset or resource to reduce not only the landfill volumes but also the dependency on fossil fuels by generating clean fuels.
Research Interests:
Renewable Energy, Wind Energy, Energy, Bioenergy, Water and wastewater treatment, and 38 more
The Sustainable Development Goals (SDGs) established by the United Nations provide a comprehensive framework for a brighter tomorrow, encompassing crucial aspects such as renewable energy, clean water and sanitation, and responsible... more
The Sustainable Development Goals (SDGs) established by the United Nations provide a comprehensive framework for a brighter tomorrow, encompassing crucial aspects such as renewable energy, clean water and sanitation, and responsible consumption. However, accomplishing these goals requires dedicated efforts over an extended period. An innovative
and effective solution to waste management and energy issues is the emergence of waste biorefineries. These advanced systems not only provide sustainable waste management and energy solutions, but they also have the potential to reduce poverty and hunger while supporting global economic growth initiatives.

As our world faces critical environmental concerns, such as climate change and serious health issues, a major shift in our production and consumption paradigms seems inevitable. One solution to achieve that would be extending waste-oriented biorefineries, converting waste into energy, power, and useful products in a circular economy context. In light of the above, this Research Topic focuses on the role of waste biorefineries in meeting the SDGs, where respected scientists share their insights on waste biorefineries’ status, advancements, and prospects. Through their contributions, readers can explore how these innovative systems can play a vital role in achieving SDGs, tackling pressing environmental and health issues, and creating a better future. The accepted articles in this Research Topic are categorized under the sections of (1) Technological innovations and advancements in biorefineries, (2) Biomass sourcing, characterization, and valorization, and (3) Sustainable systems, economic growth, and policy implications based on the relevancy of their Research Topic and aims.
The world is facing severe environmental challenges, including increasing consumption of fossil-based energy and its consequent devastative impact, i.e. global warming and climate change. Biofuels are promising alternatives to fossil... more
The world is facing severe environmental challenges, including increasing consumption of fossil-based energy and its consequent devastative impact, i.e. global warming and climate change. Biofuels are promising alternatives to fossil fuels with tremendous environmental and socio-economic benefits. There has been a considerable deal of research and development carried out on the production of biofuels in the last 2 decades. However, there is still a huge potential for achieving more
cost-effective and efficient biofuel production processes through the application of nanotechnology. The exceptional properties of nanomaterials (nanocatalysts) such as high surface area, catalytic
performance, crystallinity, durability, energy storage capacity, etc. offer great potential for optimizing biofuel production systems. Nanocatalysts could also serve recovery, reusability, and recycling purposes.

This Research Topic is designed to attract the state-of-the-art recent developments in fabrication, modification, and optimization of advanced nanocatalysts and nanostructured materials for biofuel production processes (Figure 1). This Frontiers Research Topic has attracted and compiled 12 top quality research and review articles. The articles have been written by researchers and academics working in institutions at different countries across the world including Australia, China, Egypt,
Greece, India, Iran, Malaysia, Netherlands, Pakistan, Saudi Arabia and South Korea. The editorial team of this research topic is very grateful to all the authors for their excellent contributions and making the research topic successful.
Energy recovery from waste resources holds a significant role in the sustainable waste management hierarchy to support the concept of circular economies and to mitigate the challenges of waste originated problems of sanitation,... more
Energy recovery from waste resources holds a significant role in the sustainable waste management hierarchy to support the concept of circular economies and to mitigate the challenges of waste originated problems of sanitation, environment, and public health. Today, waste disposal to landfills is the most widely used methodology, particularly in developing countries, because of limited budgets and lack of efficient
infrastructure and facilities to maintain efficient and practical global standards. As a consequence, the dump-sites or non-sanitary landfills have become the significant sources of greenhouse gases emissions, soil and water contamination, unpleasant odors, leachate, and disease spreading vectors, flies, and rodents. However, waste can be utilized to produce a range of potential products such as energy, fuels and value-added products under waste biorefineries.

A holistic and quantitative view, such as waste biorefinery, on waste management must be linked to the actual country, taking into account its socio-economic situation, local waste sources, and composition, as well as the available markets for the recovered energy and products. Therefore, it is critical to understand that solutions cannot be just copied from one region to the others. In fact, all waste handling, transportation, and treatment can represent a burden to the cities’ environment and macro and
micro economics, except for the benefits obtained from recovered materials and energy. Equally significant is a clear and quantitative understanding of the industrial, and public potential of utilizing recovered materials and energy in the markets as these can be reached without exacerbating the environmental issues using excessive transport.

The book explores new advancements and discoveries on the development of emerging waste-to-energy technologies, practical implementation, and lessons learned from sustainable waste management practices under waste biorefinery concept, which will accelerate the growth of circular economies in the world. The articles presented in this book have been written by expert researchers and academics working in institutions at different countries across the world including Germany,
Greece, Japan, South Korea, China, Saudi Arabia, Pakistan, Indonesia, Malaysia, Iran, and India. The research articles have been arranged into three main subject categories; 1) Resource recovery from waste, 2) Waste to energy technologies and 3) Waste biorefineries. This book will serve as an important resource for research students, academics, industry, policy makers, and government agencies working in the field of integrated waste management, energy and resource recovery, waste to energy technologies, waste biorefineries etc. The editorial team of this book is very grateful to all the authors for their excellent contributions and making the book
successful.
Energy crisis, solid waste management, ever-increasing CO2 and methane levels, unemployment, deforestation, increased energy generation cost, and depleting fossil fuels are some current challenges faced by developing countries. The biogas... more
Energy crisis, solid waste management, ever-increasing CO2 and methane levels, unemployment, deforestation, increased energy generation cost, and depleting fossil fuels are some current challenges faced by developing countries. The biogas production is a sustainable, lenient, and affordable approach to address these issues. This chapter focuses on the history of biogas digesters and their evolution, feasible techniques for biogas production, and methods to enhance biogas quality. It highlights the advantages and limitations of fixed dome digester, floating drum digester, and plug flow digester. Organic waste such as animal dung, food waste, agricultural waste, municipal solid waste, industrial waste, and sewage sludge can be used as feedstock to produce biogas in digesters. Acetic acid produced from glucose and water in acetogenesis process is transformed into methane and by-products through methanogenesis. The efficient production of
biogas is carried out by a complex microbial process in which an appropriate environment is necessary for the multiplication of microbes and their proper functioning. Biogas generated at low temperatures using psychrophilic enzymes has a low methane content; however, other factors such as pH, oxygen content, and salt concentration also affect microbial activities and hence the quality of the biogas. The electrical energy produced by biogas from agricultural waste feedstock
is carbon zero. In Asia, biogas production is the need of the time and will
not only contribute towards a low carbon economy but also will address the longstanding issue of deforestation and environmental pollution. If increasing energy demands of a growing population in Asia and Africa are addressed through this renewable approach, then it will enhance the energy security and environment integrity of these two continents.
Hydrogen (H2) has emerged as a promising alternative fuel that can be produced from renewable resources including organic waste through biological processes. In the Kingdom of Saudi Arabia (KSA), the annual generation rate of municipal... more
Hydrogen (H2) has emerged as a promising alternative fuel that can be
produced from renewable resources including organic waste through biological processes. In the Kingdom of Saudi Arabia (KSA), the annual generation rate of municipal solid waste (MSW) is around 15 million tons
that average around 1.4 kg per capita per day. Similalry, a significant
amount of industrial and agricultural waste is generated every year in
KSA. Most of these wastes are disposed in landfills or dumpsites after
partial segregation and recycling and without material or energy recovery. This causes environmental pollution and release of greenhouse gas (GHG) emissions along with public health problems. Therefore, the scope of producing renewable H 2 energy from domestic and industrial waste sources is promising in KSA, as no waste-to-energy (WTE) facility exists. This chapter reviews the biological and chemical ways of H2 production from waste sources and availability of waste resources in KSA.
Research Interests:
Plastic usage in daily life has increased from 5 to 100 million tons per year since the 1950s due to their light-weight, non-corrosive nature, durability and cheap price. Plastic products consist mainly of polyethylene (PE), polystyrene... more
Plastic usage in daily life has increased from 5 to 100 million tons per year since the 1950s due to their light-weight, non-corrosive nature, durability and cheap price. Plastic products consist mainly of polyethylene (PE), polystyrene (PS), polypropylene (PP) and polyvinyl chloride (PVC) type plastics. The disposal of plastic waste causes environmental and operational burden to landfills. Conventional mechanical recycling methods such as sorting, grinding, washing and extrusion can recycle only 15–20 % of all plastic waste. The use of open or uncontrolled incineration or combustion of plastic waste has resulted in air and waterborne pollutants. Recently, pyrolysis technology with catalytic reforming is being used to convert plastic waste into liquid oil and char as energy and value-added products. Pyrolysis is one of the tertiary recycling techniques in which plastic polymers are broken down into smaller organic molecules (monomers) in the absence of oxygen at elevated temperatures (>400 °C). Use of catalysts such as aluminum oxides, natural and synthetic zeolites, fly ash, calcium hydroxide, and red mud can improve the yield and quality of liquid oil. The pyrolysis yield depends on a number of parameters such as temperature, heating rate, moisture contents, retention time, type of plastic and particle size. A yield of up to 80 % of liquid oil by weight can be achieved from plastic waste. The produced liquid oil has similar characteristics to conventional diesel; density (0.8 kg/m3), viscosity (up to 2.96 mm2/s), cloud point (−18 °C), flash point (30.5 °C) and energy content (41.58 MJ/kg). Char produced from pyrolysis can be activated at standard conditions to be used in wastewater treatment, heavy metals removal, and smoke and odor removal. The produced gases from pyrolysis are hydrogen (H2), carbon monoxide (CO) and carbon dioxide (CO2) and can be used as energy carriers. This chapter reviews the challenges and, perspectives of pyrolysis technology for production of energy and value-added products from waste plastics.
Research Interests:
Energy recovery from waste resources holds a significant role in the sustainable waste management hierarchy to support the concept of circular economies and to mitigate the challenges of waste originated problems of sanitation,... more
Energy recovery from waste resources holds a significant role in the sustainable waste management hierarchy to support the concept of circular economies and to mitigate the challenges of waste originated problems of sanitation, environment, and public health. Today, waste disposal to landfills is the most widely used methodology, particularly in developing countries, because of limited budgets and lack of efficient infrastructure and facilities to maintain efficient and practical global standards. As a consequence, the dump-sites or non-sanitary landfills have become the significant sources of greenhouse gases emissions, soil and water contamination, unpleasant odors, leachate, and disease spreading vectors, flies, and rodents. However, waste can be a potential source of energy, fuels, and value-added products, if appropriately and wisely managed.
Research Interests:
The landfill disposal of the massive amount of food waste without treatment and resource recovery is resulting in several public and environmental health concerns. Several technologies have emerged for the conversion of food waste to... more
The landfill disposal of the massive amount of food waste without treatment and resource recovery is resulting in several public and environmental health concerns. Several technologies have emerged for the conversion of food waste to lactic acid, ethanol, biogas, biohydrogen and volatile fatty acids (VFAs) as value-added products. Food waste is a rich source of essential components such as protein, carbohydrate, oil, mineral, and fat that can be converted to many value-added products as mentioned above. The conversion of food waste to fermentation products such as organic acids, gases, and alcohols requires precise control and optimization of operational conditions, including pretreatment, pH, temperature, and microbes. Therefore, the fermentation technologies for food waste are still developing to solve the technical challenges of pretreatment such as the process economics, reactor design and infrastructure cost and lack of homogeneity in the results of laboratory and large-scale plants. A potential way forward is to optimize the fermentation process conditions along with implementing the strategies to integrate different waste treatment technologies to produce high-quality and cost-effective value-added products at commercial scale.
Research Interests:
Addressing the contemporary waste management is seeing a shift towards energy production while managing waste sustainably. Consequently, waste treatment through gasification is slowly taking over the waste incineration with multiple... more
Addressing the contemporary waste management is seeing a shift towards energy production while managing waste sustainably. Consequently, waste treatment through gasification is slowly taking over the waste incineration with multiple benefits, including simultaneous waste management and energy production while reducing landfill volumes and displacing conventional fossil fuels. Only in the UK, there are around 14 commercial plants built to operate on gasification technology. These include fixed bed and fluidized bed gasification reactors. Ultra-clean tar free gasification of waste is now the best available technique and has experienced a significant shift from two-stage gasification and combustion towards a one-stage system for gasification and syngas cleaning. Nowadays in gasification sector, more companies are developing commercial plants with tar cracking and syngas cleaning. Moreover, gasification can be a practical scheme when applying ultra-clean syngas for a gas turbine with heat recovery by steam cycle for district heating and cooling (DHC) systems. This chapter aims to examine the recent trends in gasification-based waste-to-energy technologies. Furthermore, types of gasification technologies, their challenges and future perspectives in various applications are highlighted in detail.
Research Interests:
Environmental Engineering, Chemical Engineering, Environmental Science, Chemistry, Analytical Chemistry, and 101 more
Research Interests:
Environmental Engineering, Chemical Engineering, Environmental Science, Energy Economics, Environmental Economics, and 97 more