2Prz-Coating & Painting Tech Course@ MBP
2Prz-Coating & Painting Tech Course@ MBP
(shortened version)
CORROSION is the degradation of materials by reaction with
surrounding media through chemical or electrochemical process
Anode Site :
2 Fe (OH)2 + H2O + ½ O2 -> 2 Fe (OH)3
[Iron Hydroxide + Water + Oxygen = Iron
Hydroxide (RUST)]
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Hydrogen Gas
Cathode (+)
e- e -
Cathode (+)
Anode (-)
2 H + + 2 e - H2
[ Acid Solution + Iron Ion = Hydrogen Gas ]
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Rust Grade – A Rust Grade – B Rust Grade – C Rust Grade – D
100% Millscale Millscale + Rust 100% Rust Rust Pits
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(shortened version)
1. USE of CORROSION RESISTANT
MATERIALS
Stainless Steel & Similar Alloys
Galvanized (Metal Coating) Steels
2. PAINT & COATING APPLICATION
Protective Coating / Painting Systems
(Powder/ Liquid)
Anti-Foulings / Other Similar Specialised
Coatings/ Systems
3. CATHODIC PROTECTION SYSTEM
Sacrificial Anode System (Galvanic
Anode)
Impressed Current Protection System
(ICCP – Inert Anode)
4. COMBINATION of PROTECTION SYSTEM
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METAL / ALLOY Potential in VOLTS
(Normally Used in Offshore/ Marine Structures) (Ag/AgCl ref.)
MAGNESIUM / Mg-6Al-3Zn/ ALUMINUM Anode -1.15 to -1.64
Al 5257-H25/ ZINC (MIL-A-18001G) -1.03 to -1.13
ALUMINUM Alloys (5083-0; X7005-T63; 5456-H321) -0.96 to -0.98
ALUMINUM Anode (5Zn)/ ALUMINUM Alloys -0.65 to -0.95
2% Ni CAST IRON/ Cast IRON / Carbon Steel A1010 -0.61 to -0.68 Note:
Seawater Velocity = 7.8 to 13 ft/sec
Hi-Strength, Low-Alloy STEEL/ 430 SS (Active) -0.57 to -0.61 Temperature = 11 to 30 deg C
304 STAINLESS STEEL (Active) / 410 SS (Active) -0.52 to -0.53 Potentials are measured
Versus Silver-Silver Chloride
Ni Resist Type 1/ Tobin BRONZE -0.40 to -0.47 Reference Electrode (SSC)
Yellow BRASS/ COPPER / Admiralty BRASS (24.6 C) -0.36
Saturated Calomel Electrode (SCE) =
Red BRASS/ G BRONZE/ Admiralty BRASS (11.9 C) -0.30 to -0.33 +0.245 Volt
Aluminum BRASS/ 90-10 CUPRONickel (0.82 & 1.4 Fe) -0.28 to -0.29 Silver/ Silver Chloride (SSC) =
+0.25 Volt
70-30 & 90-10 CUPRONICKEL (0.45, 0.51, 1.4 & 1.5 Fe) -0.22 to -0.25 Copper/ Copper Sulfate (CSE) =
430 SS (Passive)/ 70-30 CuproNICKEL (0.51Fe) -0.20 to -0.26 +0.32 Volt
Zinc Electrode = -0.78 Volt
NICKEL 200/ 316 SS (Active)/ INCONEL 600 -0.17 to -0.20
410 SS (Passive)/ PDA TITANIUM/ SILVER -0.13 to -0.15
BI TITANIUM/ 304 SS (Passive)/ HASTELLOY C -0.08 to 0.10
MONEL 400/ 316 SS (Passive) -0.06 to -0.08
PLATINUM +0.26
GRAPHITE +0.25
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# 3 - SURFACE # 5 - GENERIC TYPE # 6 - PAINT
PREPARATION METHOD SELECTION APPLICATION METHOD
# 4 - COATING SYSTEM
1.) Primer Coat # 7 - TOTAL DRY FILM
2.) Intermediate Coat THICKNESS
3.) Finish Coat
# 2 - ENVIRONMENT
topcoat
# 1 - SUBSTRATE
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(shortened version)
RELATIVE HUMIDITY
85% max (40-70%)
Dew point
calculator
STEEL
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ITEM DEFINITION RANGE MAX. LIMIT*
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Barometer/ Thermometer RH & Thermometer
(Wall Mounted) with Probe (Digital)
1a – Sling Psychrometer
or Hygrometer
Sling Hygrometer
(Bacharach Type) Surface Thermometer
with Probe (Digital)
Dew Point Calculator
Dial Surface Thermometer
(Magnetic Backing)
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Dry Bulb
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(shortened version)
1 - OIL & GREASE Suitable DETERGENT + WATER
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5 - MILLSCALE & RUST Abrasive BLAST, Water Jetting, TOOL Cleaning
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SURFACE BLAST CLEANING STANDARD
ISO 8501- 1 and/or SSPC Visual 1
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Old Paint Removal
Rust Removal
Blasting Abrasive
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RUST GRADE STANDARDS
A – Sa 3
B – Sa 3
C – Sa 3 D – Sa 3
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Sa 2 ½ (2.5) – NEAR WHITE METAL BLAST CLEANING GRADE
(SSPC-SP10)
A – Sa 2.5
B – Sa 2.5
D – Sa 2.5
C – Sa 2.5
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Sa 2 – COMMERCIAL BLAST CLEANING GRADE (SSPC-SP6)
A – Sa 2
B – Sa 2
D – Sa 2
C – Sa 2
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Sa 1 – BRUSH-OFF/ SWEEP BLAST CLEANING GRADE (SSPC-SP7)
B – Sa 1
A – Sa 1
C – Sa 1 D – Sa 1
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Usually used for Maintenance & Repair Works or where
Abrasive blast cleaning is restricted .
Needle Gun
Peening Hammer
Power Jig
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Power Steel Brush
Scraper
Needle Gun
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Power Grinder
Grinder Disc
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St 3 – POWER TOOL CLEANING GRADE (SSPC-SP3)
A – St 3 B – St 3
D – St 3
C – St 3
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St 2 – HAND OR MANUAL TOOL CLEANING GRADE (SSPC-SP2)
A – St 2 B – St 2
D – St 2
C – St 2
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Fl – FLAME CLEANING GRADE
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ISO 8501-1 SSPC (Steel DESCRIPTION
Structure Painting
Council)
Sa 1 SP 7 Brush-Off or Sweep Blast Cleaning
Grade
- SP 1 Solvent Cleaning
Note : Indicative closest/nearest equivalent only between SSPC with ISO. Refer
to actual pictorial standards and detailed description. Both standards are viewed
without magnification.
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SURFACE TYPE Sa 2.5 / SP 10 Sa 3 / SP 5
Near White Metal White Metal
New Steel Kilogram Meter2 / Kilogram/ Meter2 /
Rust Grades A & B / Meter2 Man- Meter2 Man-
Hour Hour
SMOOTH 40 9 60 6
NORMAL 45 8 65 5.5
COMPLICATED 60 6 80 4.5
Note: Capacity = Kilogram per Square Meter & Consumption = Square Meter per Man
Hour. Indicative values only using mineral grit abrasives.
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WATER JETTING (NACE/ SSPC-SP12) – process by which water at a
pressure higher than 70 MPa (700 Bar; 10,000 psi) is forced through a
nozzle for the purpose of cleaning a surface (NOTE: but cannot
create a profile).
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ISO 8503 – 1:1988
Note: Grit create sharp & angular profile while shot create dimpled & rounded
Profile. High profiles result to increase in primer consumption known as
DEAD VOLUME due to increased surface area & porosity.
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180
160 0
140
25
120
100 50
80 75
60 100
40 125
20
150
0
Rugotest ISO Keane- 175
No. 3 8503G Tator 200
25 – 180 microns 25 – 150 microns G/S
35 – 140 / 10 – 100 microns
Note : Rugotest No. 3 – Swiss origin (Ra), ISO 8503 G (Grit) & Keane
Tator - US origin G/S (Grit & Shot), both are Rz values.
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1 – Rugotest No. 3 Comparator
2 – Keane-Tator G/S Comparator
3 – ISO 8503G Comparator
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2 – Compare the Surface Roughness felt on a
new blast cleaned steel (biting sensation)
against with the comparator corresponding
1 – Using a fingernail, feel the Surface Roughness using the fingernail. Repeat the
Roughness created on a new blast cleaned steps 2-3 times until a closest comparison
steel (biting sensation). Ensure to cover all or similarity is achieved.
surfaces and make at least 2-3 times feel.
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Step 1 – TESTEX Replica Tape – Take surface
Profile imprint on the blast cleaned surface
using a TESTEX replica tape by affixing on the
surface and by rubbing using a plastic pointer
with rounded end or pencil rubber eraser.
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BRESLE’ Method Field Test Kit
1 – Bresle Sampler Extraction Cell
2 – Syringes
3 – Distilled Water (with Zero
Conductivity)
4 – Pocket Conductivity Meter (Digital)
5 – Steel Surface Dial Thermometer
(with Magnetic back)
6 – Blast Cleaned Steel Surface
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Step 4
Step 3 Open a bottle of the
Step 1 Remove the entrapped Distilled water and
Step 2
Carefully open a air inside the cell fill in the syringe
Carefully affix the
BRESLE sampler cell using the syringe to approx. 25 ml.
BRESLE sampler cell
& remove backing. create vacuum.
on blast cleaned
steel surfaces.
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Step 7
Transfer the extracted
Step 5 water into the clean
Conductivity Meter Step 8
Inject & fill-in with 3.5 ml Step 6
sampling cup. Measure out the
of distilled water into Carefully extract the conductivity of the
the cell with the syringe. distilled water from extract with the
Massage lightly the cell the cell with the Conductivity Meter.
to stir for 1-2 minutes. syringe. Ensure that Record & run a blank.
same volume is
extracted.
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Conductivity, Equiv. Equiv. NaCl Remarks
mS/m* @ 20 oC Chloride microgram /
microgram / cm2 @ 20oC
cm2 @ 20oC Temperature of Correction
Water, oC Factor
0.50 0.70 1.00 mS = Micro 15.0 1.10
Siemens
17.5 1.05
1.00 1.30 2.10
20.0 1.00
2.00 2.60 4.20 22.5 0.95
3.00 3.90 6.20 25.0 0.90
4.00 5.20 8.30
5.00 6.50 10.40 NOTE:
5.30 7.00 11.20 Always run a blank test with the distilled
water used for salt extraction & check
5.50 7.20 11.40 Maximum both water temperature & conductivity
Limit
6.00 7.80 12.50
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(shortened version)
THICKNESS
THINNER
TEMPERATURE
TIME
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1 – BINDER or RESIN 2 - SOLVENTS
PROVIDES :
PROVIDES : Dissolution of Binders
Generic Classification Application Properties
Volume Solids Evaporation Rate (Drying Time)
Adhesion & Cohesion Flash Point
Anti-Corrosion Properties
Chemical Resistance Examples : Xylene, Methyl Iso-
Abrasion / Mechanical Resistance Butyl Ketone, Isopropyl Alcohol
PROVIDES :
PROVIDES : Economy
Color Application Properties
Opacity or Hiding Power Mechanical Strength
Volume Solids Gloss Control
Anti-Corrosion Properties Rheology & Viscosity
Fouling Protection Fouling Protection
Anti-Corrosion Properties
Examples : Titanium Dioxide, Zinc
Phosphate, Iron Oxide, Cuprous Oxide Examples: Dolomite, Chalk, Bauxite,
(except Lead and Chromates) Silica Flume, Cuprous Oxide
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PROVIDES
Special properties with
regard to manufacture,
5 - ADDITIVE application and storage
1. PRE-MIXING
2. GRINDING/
DISPERSION
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3. FINAL MIXING
4. QUALITY CONTROL
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(shortened version)
•Oxidatively Curing
Asphalt, Tar
and
Bitumen Drying Oil
Chlorinated Rubber Alkyd
Vinyl Modified Alkyd
Acrylic
Epoxy
Polyurethane
Polysiloxane
Oxiarane Ester
Emulsion
Latex/ Dispersion
Waterborne Zinc Silicate
Silicone
•Chemically Curing
•Physically Drying
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PHYSICALLY DRYING CHEMICALLY CURING*
BITUMEN/ ASPHALT/ COAL TAR – Spin- DRYING OILS / OLEORESINOUS - Natural oils are
offs from petrochemical plant or triglycerides such as tung oil combined with other
petroleum cut backs. resins.
ACRYLIC – Polymeric derivatives of ALKYDS, MODIFIED ALKYDS - Reaction product of
acrylic & meth-acrylic acid. a polybasic acid, polyhydric alcohol and a
monobasic fatty acid or oil.
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PHYSICALLY DRYING CHEMICALLY CURING*
Common Properties – Solvent Borne Common Properties – Solvent Borne
THERMOPLASTIC - dry film property to NON-THERMOPLASTIC – not affected when
soften when exposed at temp. above 35 deg exposed at temp above 35 deg. C but has
C & hardens as temp. cools off. specific dry service temp resistance.
REVERSIBLE – dry film property to soften/ IRREVERSIBLE – When fully cured, the film
dissolves when wiped with its thinner. cannot be affected by thinner/ solvent.
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Classification of Hempel Paints
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Classification of Hempel Paints
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Classification of Hempel Paints
Example :
Hempatex Enamel 56360
5 ---- Top Coat
6 ---- Physically drying
3 6 ---- Serial Number
0 ---- Standard Formula
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Classification of Hempel Paints
Colour Numbers:
1st digit series
00000 Transparent
10000 White
10010 – 19980 Whitish , Grey
19990 Black
20010 - 29990 Yellow , Cream , Buff
30010 - 39990 Blue , Violet
40010 - 49990 Green
50010 - 59990 Red, Orange , Pink
60010 – 69990 Brown
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Classification of Hempel Paints
Hempel Product Name composed of :
A Family name + Optional Proper Name + Quality
Number
# 4 - COATING SYSTEM
1.) Primer Coat # 7 - TOTAL DRY FILM
2.) Intermediate Coat THICKNESS
3.) Finish Coat
FT
D
# 2 - ENVIRONMENT
FINISH COAT
INTERMEDIATE
PRIMER
STEEL
# 1 - SUBSTRATE
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Method BRUSH
Application By Hand
Characteristics Good Penetration
Ideal for Stripe Coating
Typical Applicable DFT 40 Microns/ 1.6 Mils Touch-Up Stripe Coating
Application Rate 100 sq. Meter / 8 hrs.
Stripe coating brush
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STRIPE COATING by BRUSH
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Method ROLLER
Application By Hand
Characteristics Less Good Penetration
Gives Uneven, Porous Film
Lower Applicable DFT than Brush 30 to 40 Microns / 1.2 to 1.6 Mils
Application Rate 200 – 300 sq. meters/ 8 - hours
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Method CONVENTIONAL AIR SPRAY
Characteristics Supply Air directly feed from Compressor for atomization
(30 – 60 psi)
Spray Gun features 3 adjustments knobs.
Requires more thinning (e.g. 25% by Volume minimum).
Best for excellent finishing paint job but creates too much
spray dusts.
Application Rate 200 – 400 square meters per 8 - hours
Spray Guns – suction/ gravity feed Air cap & spray mists
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Airless Spray Pump Set-Up
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Airless Spray Paint Application
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(shortened version)
Gauge
125 100 75 50 25
WET PAINT
STEEL
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DFT GAGE READINGS Figure A1 - Part of Structure
Spot 1 Spot 2
Approx 2 m W
1.5”(4 cm)
Spot 3
Spot 4 Spot 5
Approx 5 m L
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(shortened version)
Volume Solids - VS Thickness Units:
Micron = 0.001 mm.
Wet Film Thickness
Mil = 0.001 inch
VS = DFT 1 Mil = 25.4 Microns
WFT
DFT(µm) x 100
VS (%) =
WFT(µm)
Dry Film
Thickness
Theoretical Spreading Rate - (TSR)
1 ltr
DFT (Micron)
DFT(Micron)
DFT
12/06/25 = Dry Film Thickness - WFT = Wet Film Thickness 74
Theoretical Consumption - (TC)
A(m2)
TC(ltr) =
TSR(m2/ltr)
= DFT(Micron) x A(m2)
VS(%) x 10
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Practical or Actual Consumption (PC or AC)
PC or AC (ltr) = A (m2) x CF
TSR (m2/ltr)
10 0.90 1.11
20 0.80 1.25
30 0.70 1.40
35 0.65 1.53
40 0.60 1.66
50 0.50 2.00
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DEAD VOLUME – DV (Primer)
Note: Applicable only for 1st coat applied directly over blasted
surfaces (e.g. primer).
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VOLUME SOLIDS AFTER THINNING
Where:
% VS – Volume Solids
% Thinner – Thinning volume
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(shortened version)
PAINT FIM DEFECT
is defined as any deviation from a continuous
COHESIVE and well ADHERING film.
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Paint Defect – “ALLIGATORING”
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Paint Defect – BLISTERING
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Paint Defect – BLUSHING / “AMINE BLOOM”
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Paint Defect – CHALKING
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Paint Defect – CHECKING
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Paint Defect – CRACKING
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Paint Defect – CRATERING
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Paint Defect – DELAMINATION / FLAKING
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Paint Defect – EMBEDDED DUST, DIRT, SAND
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Paint Defect – FISH EYES
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Paint Defect – “MUDCRACKING”
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Paint Defect – “ORANGE PEEL”
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Paint Defect – PINHOLES OR “HOLIDAYS”
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Paint Defect – RUNS & SAGS OR “CURTAIN”
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Paint Defect – WRINKLING OR WRINKLES
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Paint Defect – “BRUSH MARK”
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SOLVENT IMPROPER COATING SALT
SOLVENT IMPROPER COATING EXUDATION OF SALT
RETENTION APPLICATION EXUDATION OF CONTAMINATION
RETENTION APPLICATION COMPONENTS CONTAMINATION
COMPONENTS
EG. TARS, OILS, ETC.
EG. TARS, OILS, ETC.
OSMOSIS OSMOSIS
OSMOSIS
OSMOSIS POROSITY
POROSITY
BLISTERING
BLISTERING
CATHODIC
CATHODICDISBONDMENT
DISBONDMENT
LOSS
LOSS OFADHESION
OF ADHESION
CORROSION
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(shortened version)