“THE G- BLOCK ELEMENTS -
b
Jy d-block lemons: SKY amore
yrast cS ener IMO PEHaltimare d orpttal .
3 GTOUP Stow and Period : 4497. 49 Clemente Caviny”
x6 3 4 8 G67 Bq ww
\ p,2sdseries so oT Vcr Nn Fe co Ni ca mM
+ pp oad series OY |, zr Nb Mo 1 Ro Rh PS ra cd
pe 59 series He OW sd
p,eadceies Ac Re Db gg Bh ta Mr DS Rg CH
¥ METS WIS 40 Clemens
gAll AVS MRtdale.
FAL AVS SOWds Oxeopte Mereayy, & oppermicigm Ciqaid) .
¥MOSt Aoandant Giement ih Earthy Crast is Iron CAth) /
KMAIACST SlOmMent — Tungaren WN) — Hignesr MP and BP.
x Highest OS G+S) Shown ’y osmian & Ruthenium.
¥ nignest density — Osmiam & Idiaro - -
# Fowest Aensiey — Scandiany,
% Group Il — Coinage Metal.
* Highest IS — Neraary C1007 KT! Mol) of
# First Man Made clement ~ Teenitiam.
¥comMony KNowN As Transition Clements.
Transition element:
FIMsSO AVE the E1ement in which Contain Parriany Piped or
unpcired cd oybital in ground State or GNY oF ing Tonic | oid
ON Stare . 7
>It ie the trancition sexier From WoTe positive 9 block tO. Mor
DEQAIVE pP bIOCK.
ly scandiom , -
ineks-
cry Messa) asm
Conpaired ©)
sade
Min
=
um on
{ 23d Carpe yo?
zirad® 497
{ no anparred © iy Nong
ionic Stay
ca* : 349 Caps) zno 2 3a -
Sova SPs 7 SUH, CH
“erp lo dd mot hove unpaired | End NS?
I orbital th ground tate @ tds Card’
onic SALE. So, they Gre Caled +P. se0do TRANSIT, PeMene,
OF No-OF transition Glemens in d. block SIEMENS 1S SG C49-4)
| General electronic consigutation:
(& Cm, mgo-2
a Pd ;
* @ip > No-oF Ns and Cn-11d Ss.
Ba 3d series
a) 2 4d s@rieg
O08 Fs Uo 309° S Bas
x pdh >... 4d B97 age j pyate add
eNOS
RROD
e
a8 4s Wah eae
Wis? Spas
s+. BAY go!
gwnicn OF the ADIOwing lone hove Tae no-oF anpaired Ss
J a cde* HE 44 og) Mott dy MNO
3 cd >. AA BoP 2. ad® 5 MO Oe
HEAT SIP GS2 mp dS | eng apem
Moras... aat BS" Ages aanpe=~
Minot. BUPASD ns LB. 5 BOUT 780
Which CF the Atom wil ercnibit ds consigararh IN Qrow
gare. BAQ — b/RO -Dpd De «
SPQe4d®ss' RUSAd®aqr PAs 4db Hor LED AAS:
| NB: Platinam is JE OMI SNe atom which Sschibir da Coneig
cnation in ground srate.
Qeind ho: OF ANPaited & iW ed. DH bs MQ AO
SRS. Adios? > —. aq nse 5 N=0
Atomic and physical prapertico:
Ay Momie stae oy tonic radius: :
= promic Tadius of a black loments are Werallic Yadiag
shay al ave Merole * :
plong O PEricd :
AALS TADIUS OF ETANAtH MErAal ATOND 4 Poy fad FAIOWS A
AeOQUION trend wig dueto,
ge _Nadencharge sige ¥ Ciormal tend)
ada cone ee oy
NO.OF INCL SS F G -S VEPACION t Sige T
cet)
qg
spices “@ as
HPP. Bd%@o% =>. RAVES! nett odin fue
| a 2
Pr* SHd9 2 2
: Bag? ie Bove
ROD... WAS? 5 poss ays ima:a A en
Naience shell 4
ps!
+ tah uy
74s
Cero inet # TPR? PR
Nucleus) onital) o =, FR
“i © pete
ck Metal
Resort: Both ‘QS Ord
Inner d aha) are pa
Wieipating i in meratic
inne and Cn-nd Ss ane Valenes So,
‘a 4 Wigh Penevorion ighe oF. comparatie "
NE SRI ESN YG OAZP ates on somal eveTBALSTTETENCS of
bale ghee Oya ee i vaso : 4s ES)
MBs SKCMNO: OF Ghipatred To.charcinesshra= 4 < H40-5
4 ; ne ao! “dest > High NBS
Se> Tid Mn= gn>V>e1>CU9 FEE D=Ni , ; ne wh a
ma Top, : x a ov al Sore > LOWOTHRS
gS | es Gp 4 ----- PP : Sy Bog Ngaiat Simnedeny_ zine
a 2d ese “Te 8) Caan ovbtials ?
s———— 40,0 Gyan | PbIOcK
eee Bd > 4d>30 |
re £40630
bitta to Foch Votallic ond Ae= qeungsten
3% andest element -in A oo) {ayo to Tigh MBS
Hand: @p et C1 < MO SEE ise
ox <2 MeTCANG CS0sTiquid)
@ cee © oH MAS -
% gortesr, element in d_bIo
+, Sart: GP las ZN >>
Spe
Cored ns® \ Corandsnng?
emcoption,
Re >Os
BAB obitals WeR
Jas Stable CMEg4}
Ti>Mn
# Highest MP. Gp:6 > cr
Gp:2 > zN> Cd hg
/% Most volatile tort > 12 “
Cepy)
i. hig: Riquid (te v high te
SOWNBS Cine)
Qbrrange Ysing Order.or MP+
Q Mn, fo, RE 62
3? NPxcige = MnZTO Mp we.
MP Wicks = SC>FY/7 Ca Uitide & patios
1
Yo Fey KOHUS . nD OM t
> 98 ROOFS
Ay ca, bas fa
A HLOMISALTON Enthaipgs /
Bie is The min Amount oF ENErQy Tequhed to bIeak Ante!
meratic Crystal into Merol atoms.
Meg > Mg)
PR
£> AgW (ave Sends)
= CORO g,
2 °.
Seo
expirmdGignesr Aart th
5) Catalytic Propeng :
amansition metals can act as catalyst in soverd!
due 19 They
Can Show Variable 08. Lb Free Ss on Meral surpace
4 comparatively stat size = Hence, high lonio charge
Fans .ltis
> Availability OF _Incomplere oy VACA A OYbitAIs cose
KEQ! > Raber MACs: FS
> Coynreaer PIOCESS : V_IG
> Qerwald Process: Rh/ PA/Pr CHNos)
> Hydrogenation Toon: NIP PA Pr
> WACKET PIOCESS! PACT o— zeigen nara Catalyst * qiol4 + AICCaHe)s Mains
Cpoiymenisatn)
> witkinaon caralyst + FAW CPPA
> Decomposition oF Kelos ! MNOS ©
6) Magnetic, properties:
€\p anpaired Ovbhals > Paramnagnetic
AIF AL orbhals Paired = Diamagneric
Paramagheriem « unpaired ©
Spin Ong Forma,
y
33 NI
Pe Ovbital .] MM
Pawar | oO © ~Cofamagnericd
p aida A Vixs - 8 BM) Wg
ae, de 2 are 2I
Lhas.a |] 5 9x4 = 9-8 BM Z
Is asyas |g Vax5 ‘seem / 8
Ib as 5 {axe = 4am | &
j ExT =5-4RM
=? ene: 3d 4s° 95 m=5 5 MM-5.QRM
| Racts 3 Rutt: adage 4 ad 7 BS! 5 RUST Ad;
m=8 ; MM=5-40M CPare)
= "cdala S aot : adie a2 & AdP 5s N<0 Cola)
7 Nisog > NiO4 2 dB 492 => aqe 5 =2 3) BMM~28BM
DMM = 5-8 BM 5 The lon. wil bo; .
a) ROM PAA — NIDA ayant”
> N— 5 ng fs
CF
Magnetic morient = afqanay, = EM): NO-OF CINPahads
poet 9 BAS net a5 gqtd ar sat x @adt
aaa n=0 ND ae
gealeutate MM oF ivatent fon th aq-goin ; Ite zA-4e. -
Hose DSB V 4-4 By dy 713 BM
51-48 5 GPS P55
Pd > 4d” BS
pao? @ 4dS 5 N=9 5 MM ~9-g OM
9 catcaiare MM oF trivalent ion in aq-sin j Its <=19
agra; Pos
Aa > ....50" 682 >. Bde ge!
4 ROS ABATE 5 M=o 5 MMH O-8 OM
OMm of Fe** ic 5.9 BM, Find the Value of
ae no Os w4
> Fe > Bds 497
Fee > SIF 5M=5 7 MM=5-9 BM
Ord
T)CGIOUIE OF. Spectral propend:
* Transirion Metals ane fis COMPOUNAS Gre coloured fh AQuEd
son anon end
er is due to d= trangicion
Gd-d transition : Excitation of S FIOM lowe) Energy,
d arbiral to higher energy d-orbital
KpCCoIding tO CFSE. warer ges as weak (igand
Sdz
aN
abs om
ROS
.o<8 |
VoyTist sd!
He CUSO4 XXX Hod
Cogos Soin > Blog > Leacsod«] Soe
@
os a-d wonsith _q? ie
ae poani
snoonpaneas OSS Lear ae
dia no d-d nansity
No d-d transition ‘ess
chiess
Dwhich oF she Forowing pairs are civless
ane ,cost by zn, THe CVA, OT BFA Var
wnat sgas 5 Qos sds 5 za: 3de soe use
Cae 2 3g 5 cgay sada 5 RATE SIE pub
Dwhien oF the FNowing Mdiecsle Te Chea in GAUCOUS Solty
ACUSA BHACla © Fads, dance
Fut: sq 7 ger ado % FOR SdH zn ssh y
63'S ponpe
GV +2 3 Violet ve
MOS y= = Grean cham bs Cg > co 5 BILE fink % ‘
oS Co SBWOF PINK Sorc)
V4*= Blue Bh. i NEelagoasham sons
Or > crt BIE Burley g F NOt STSSH
9 OM Cras > Vigor 2 Ls CU S BlUw EOE Hage
L vin Mn 5 Pink Poragal-oo PBS
MITE Wns => Vig\er esl eitmss
* long with d-d transition, chr fe due to,
& Rigand to meral choige transter
EQ: Kno, — PUIpe Kactad7 — NANQeS wed
ve 9. ° °
, anos Sa NZ
ae
Fy wom. SO
USS poe S'Green ser
Fo* 3 Yo}Ow
oad
TPHricca 6 Mor char aot a
IQS wWOnstey
eq: FOG TPO CONDI rene
Ly polatisarn OF large Preval
ee eh ae
QELNIA CF
EQ? Ciel — Pink,
g) Formation OF complerea:
= transition Meral can Form tai
pation COMpounds
Siwis Wew,
RTHSG, SHOW VATAe oS
le High Tonic Chaige
fe ANATOLIY OF _Incomplere and Vacant a Orbital
SEQ: LPr (Nts g@lal , LeoCometha)
gy tonfearion Enthatpg:
2 plong a period,
Along A period follows irregular
trend, itis _duete, a
LS leregalarity in aromic sige,
to rregalay Slectronic consigaratiod ,
[> Esschange nergy
*xors
AS NO: OF ComMplesr Salt C Ca0Td!|
comparommaly energy dinrerence oF as and ad.50, exckation
oe wit yokes, Place, and, © 7 loss in exchange energy. ef
a gnesr le In Sad SSTiessS ZN
stable ec > sd 4s"
Ls High loss In Gaachange Cneigy,
Ls Rigih Nacleat Charge.
oy {i aisle Re ay
SR NEST IPT ae rei Fe
oT in 3d SETIES > ' 29 .
HX Mighest Ie wransirion Meral in qousesh te Se > nighest 1@ > Pia
Fe Tey t
He OF Mn & go) DENS ey? @>arcd
wae oeaba wn ___9FS s
BONS SA PETC, “Wghest cemsig =a SOIISS acm
NE, <18a zn
o
Carqurerneemgge CPS KSRCN NSGMTY serait re
si Nal 4D
ay ciae + CNN > FS) SRIONG_A period; eB
©
ty pe, —H, pot —B2> Fret one a wast Seay dersigt” SOS
Bde 4s zds4s! ads cerable) Density y,
b cao —B4 > gye Bey quar A> COS Nidco>FE>MNSCr> ZVI Tisse — NAPErod
Gy He yg LO gat EE ne = [Sccno's } Dense CSA)
Bdb402 WONBE sqe gr DOWAIE sig Hidhale sqa Ad Somos “
|g, SSrabIe Cunsrabie) Corable) unstable) Bd (ee save } Density M
D whieh oF the Following is Ineonecr. Mes M
sosmnionn alrdign
*LOWSt density : Seandian
Ary oscidarion Stare: _
as x KTransition Merale Can show Variable Oacidation arare due to
None oF these COMPANADIO Chergy PiFreverae Herween AE and Cn-1)d ort
> tenor Ti < lear Zh H ich.
Sin ig ee ee i “| xoovidation Stare,
ops apa aps CP ee GR Iy CoN Cr (SD) Fe Co Ni Co ZH i
O) IE, OF FE > le, OF MN
DDE a OF CU > leg OF MN ran
O's OF Ti > leg orzo
sonmond Core
4 Check ata NE
se WT froor aes Ct My S84! eq Zn ts { 6 oaks 480
5 : ost ley -\@® BOSD, ° or
a ae a for Mo} to seems] 44 SS SOeoe Recah
' y a * MAIS Yoni:
Yn, ey ME Wo} Re ance
" ble os
La AS Bddadoad” By
+ Inner F SBT SEM
Sd >4d> Bd W >>Md>Cr LEER ey eei
al
transition MEVal FOESN't oh, S
9 which oF the Frolowing
N ee (
Se a ©) woth add a) ca
XI) Fd dick os dirrerence ba *
% [No-oF degenerate Gymral 7 Ssechange snerayt
EQ: Fos a eae as
414141
3d
41111
v
% Hignest o¢ oF metal can be Ie stabiised by wery
mone in their respective group.
FAS GDT So crd® ne? 5 Highest os = 47
Sone es GA
SOs Wn" | ccabiteg, 4 7
Ads qo? ig
Bd: Ret Re™ > ToT >IT les ot
‘Good on ost
MOTT pgs SM te
CHigh xen)
eras 4 gee ISMN, gy 4s
oa 48 a5
Good OA: KNNOg > KaCI207 5 Voom
*
DUC tO _hi
GP8 > Gp-nds ne2
$e Moos > Woe
x08 oF MENA In MeIal conoongle B Selo, due w ayneraic
ep ect CT ACIA Chatacre@y) cord 7 tech DetrMEMI), BAEKE dD3p-
49) AVOD Formation: oy Denagecm BissS . go, balance eassieG
; Beg GRE
> NOMOAENOUS MHIRIGIS’ Containing DOF MoYe FHOrdl ator
© Tgp abAS ORT 72 @gote
ify IF the metal chonid hove,
* Almost similar sige gine APFOTEN 415%)
* Airnosr Sicvilan Metallic BOnd Screnath.
A Pirnese cipsiiay lonic ChaTgE
# TZN = Brose
% CU + SN Bronge / Bell Meral » 4a
# CQ TZN ASN => GUN MEIa
CF CO + ZN-+Ni~ Qeiman silver
ron mera! Carer
* OTC S creat Chon WRG Aiton)
* FET CA WN. > Fungaren sree)
e* FE + CYAN > Stainless greg) Neesc)
* FE + Ni > IVT (High tensile errength)
* Fe th > Mischmeral 1 Fe and Rg dogs for for
SN), COR”), . : ANOY dae to high dir
OX FO + NANT -EC0 5} AlNies renee their merck
Crast © bond srrength and of
Sbondant) BE Chg ie Weak bat Fei
on ‘SrroTNg)- ASO Wand Zn
# Merl + Ng = Metal amalgam Ceionid Alloy) See dor A
v + astais weak eq Natigs ZO-Kg oy
Weakmeratic boned ©:
Cs Bock &2h),
Hacicay choige, FE Can:
t show. +6)
43) Intereritial compounds:i i
~ Stra Siged Grom The HNLBL ETE Soranouinte hs
Lrstiial veids of meratiic Cras! :
Wrereritial compounds , . _
> w soy Gre porn HOLSTON FNEC at Gg
% the bord fe, Neither fanle NOT COValEn,”
Cragr an attracrive — NILE og
Into NN & Chemicaly inert ae
Noi ¥* Does Nor Boog 1a OF Yerinke mon, |
EQ? Miia + Voss tron. .
Fea gg 1 Md yas!
> Properties,
* Hardness Hardiness oF come borides = Diamond
* eral sratiita, | imergeiial > Rave Tera!
* Mp @ OP . «
* Density, *
%* Ductile ae
HF Mateaple PEE MEXal > Inovsririal
‘nerstitia)),
43) crystal Rartice: :
soi
phigh tonsile strangth, nigh ter]
MAL Stabilitg.and theg have apeciric eTYystal ldtrice ‘eke
> Group S-a 1 NOP CHERagonal aude clo.
é ‘ se pack) ektaciune|
> Soup B-s Boe C Body Conrered CUbieelogepackd
> Group 1-3 : HOP Cexeepr FE CBE, Mn Enid)
SrOUP Fy 19,1! CCP Couple close pack) :
> Group 19+ Nil
TTOACLAN SCR nee) cSrandara Redaction
jn solution: ’
e
a ™ ba
oO Pag re M cag
Dot
or
ih Arua!
Porenrial | staldifry oF Metal {el
By Hess’ s law, |T2 = Aan + Ahgd H + 29
sw
we oH
® Ey yar = Ve
wus _Ssin
CRA)
Ble LS.
ot] AQ
EST SE an ESSENCE IIe
RY vel
EF =-Ve AG = 4ve
Teqn ie Mon spomanecas
Oxdn is spomanecag
wet
staple
TEL abihitg to loss HOF ten in con
BAWY WY any t
TY
aE
Meet edt
con
Mewar 7 WS
2 —4ve AG’=-ve
TEAn ie sponraneous
Ordy is NON spontaneous
Mat
Stable7 i erailed by
~cxapiy OF THERA! fon in-sOI is CONT by
K crandard Reduction porencial CSR
* Ygartacion enthatipg Ct)
Standard Reduction parenta
oscicn
| oF meral CEM)
| Mey SSL, yor
cag) \
cen Stable
riod FOMOWS gh y
¥ SRP value oF transition Mert along 4 PSF ce,
| Pregalan trend, due to, stats:
mreauiatitg in, cane enxnotpy 4
b trreogatarieg in 12
b Inregulavitg in Ohya #,
+O.ccondi
© ongmtiongnitlgy
. ody - 0 flow 11
Stabe co CHS 4y)
moa,
Inable to, disp}
Oke 1H Aron
Aciq
U+OHL van
e
“ey Nn
ay tT Monel > Nelo
RA wx 2° vo\Ue
Tiove
x ENAUE OF Cats tye,
com Iea = 40-34 y
tt} Awl Tete -EPvatac
Bhs age I
SBS cat ES Qgar
sate Nok
a
get = Ao + TE) + 2e9
\«
High 12:
a Fo VAWE OF ZN is. Lye,
Foxntt}an = —O-1¢ v
znio Move RA than Fe
Tey
“Oat e+ Te, 4 By + Aah
1 bow ban Sy ant 28, cnet
BAP 4s) Sdio
in 42 gg . tone)
aN
4 Zn Nave di Conriganation
SRP NOG OF ES ystsqiod t
M coy > M3
coup cag
erable)
RE sg — _ .
Ey ry yar OSTN | Fused nae, = —8
e ~S: Sev (wer io'moie stanie
Sel Ss OA shan MS In soln
* ES Mor O8dn yer
cs ee ea oe fa
Fost] Fens = Stable
is son RPL —eP value
eo ay RRS CTOFS Tt Sy at
ay
Eve = AWE Cus je move erable Ahan MP)
@ ca)
yar Ned, gas
Mn'> CF > ZN> FE > COPNI DCH # tobility Ti
can aq) (Sratie)‘OR HES Nae
OR? COB* > WN 3ty FO™
we POT VET See yey 7 :
TE PS Aah T+ lent + Shodt
wo oO ec
G high Bon _
& yor Sat, yt ey
aq? cand
33 ad? a
Stable Unstable : tag
|B hor pest, A? = tQ3 sidhle
Fee _ "sein Foot lew
saF sd6 Feet —— > feat
stabe
sirable
Which ic Strangest RA-
A) Fee OF Crot
osxin
= FO SA pose
ads 305
Cea - NE
Fe™ is mote arable
faq
than Fes+
ca@
“Cre is move RA thon feo
Seed Gy st
33
yet
a4
EGA — “Ve
a
ens
~
9c Om =
> cas eyet en enat
ee Ave ee = -ve
Zn More RA than ca
er
ig MOIe Noble tran At
ey
eevee ss
* 34
VION Me yin
esher Vc PNW = ave
WPHOVE RB than Net:
yout 7 MTS Stable han Cut due to, concted by see
n ye
b wigh hyd ation 7
Entnalpy . So ES, ‘eu feu Ne
+
aw Ce Ss 5
tale aaa
cur shone’ sixed _
Angad W4
Avya Wh change
©
Eroaat/eat = TNe
Ee 2 vaxiaom
9c0s —> cua sou
aa undergoes dispropanti-)
at or onadion segcrn,
Set ,
4g) Stability OF Orcide |hale /oxcacide:
¥ Highest Os OF Meta) eschibked th its Hustides and ox}
des Only due to,
b eq ae Nigh NE GON and Have small clae-
b heir bond is“errective.
M-F/IO
tonic bod covalent bord |
Tonic bond serengthad Adatticn td sige YEE d BOT AguT
et
BRS Cah A aanice®) CAI. Donat.
ed by ou Sn:
Highest og OF Meral if More Sta)aleIPle bong ye
Foutine, pecause Onggen cat cae)
Metal, ee
oo M=O
i M—F 7 aq w
ae Toa as MN oO1 sy MNOSE
} MNES
°
Does mor ex nee
@® Mn
FIN
f Oo)
@ ~~
Sho
© :
High Qp-2p sepalsion
high Sroricerrect
44
_ MX) yt * VPs,
* Neahest oxcidarn y stebiligeg®
+4 ‘Store can srabiit— yy
iS ; Ton Red by X40 Vad,) PY F&O
+6
CrRe 5
onl is \ FLO ™n eh foo
Cig 05, M904
> Ne5 ts _emice , bur Vols / Veg dogs not omice,
~ a ‘ 3
Velp omoacids |:
OR + Ho ——> voolg y cits
NBI5 oR Wo
NOBIS at gy dl
S>BNOtHET Fegtanes oF
os
420 4a . 32, 2
FQ: NOly ,VBIg Goeier bur VEo d0es nor soigt
Flanide b: their ingrabiting Wn Lowel
gerentinoer OF BseaTeaneigy
a ©
s ue
ze Vac cops) ah SO
‘i y
+9, ta, 4
«MNO < Mnoa < Mnad7
idle marane = Yoon ett, CaP
peidic NGS > Voos e Uno <\a05
Ont teric hove 1 Here
ae Fe tee ou ‘BP thon covalent |
ORF Vo05 lOnic > Covalent
Note oF Oxide:
Basic y
weidiet
Rasict
Ceasic)
FEO, CUO
40
ERCOpr,
+ AB
THO , Cin02 Nog- Nost
v og) neces
Mphoreric | >
# VO > covalent a
9
Dae 0 ~ GY
OSS ge ee Bo sen ened
OSS MNT oy =F Green'catoat due to BNET
Ceigand meral chare trons|| Misoed oxide:
FO 304 2 FEO K&FOIS
*Cosd4 co & an |
* vngoa ! Mog + find t —
KoCrg0, . :
% Propared From’ Iton chromate Crecrace)
+3
: LF80 + A102)
Preparation: 46 sdi0
i + Fea!
1 podthog + Nagcos +02 =? Nastros 3
ae. kann CayooT Sodiam Chiomate:
Mon chrome “Se covoes
as
4 Nagero4 + OH* —— > Nagcied4
: sadam dicmornare
TNaa@tads OKC) ——5!kae¥9 04
i * Porossiam dichromate
NB! KaoTAOr 2 Prepared tough Nast1e07 HecIAs© g9-
dium dichtomate fe More salable than KeCTa07-
Dichsormare
~
crno4
* — chiomatre
ChO4°7 kesoronce
roseibie
- s
° » ATS OPT Oy
I QT 3 91 opq Sd
a \) Terrahedral
So 9 tS 5 3d? dia
#1 Cro bonds are
to RMOD
KMIRO«,
PTEPATES FTOTN Meng y CPyrolusite)
preparation ‘ _
by MNda * KOH + Oo EN
*
by koMNOs + ONT ——_ KyNog Cunoa7) + NOD
} PRorassiar permanganare
Kono Cros)
Porassiam manganare
INDUSTRIAL PREPARATION
CABORATORY PREPRRANON
b wn®* -+ Sodg” —Had_, KMNO 4
Perordidefcuiphate lon
va o4 Oo
* 4& 4v 3 Op?
Manganate lon Terranedial
OT Apq — Wy @
wntS = sade
Pana , MM (158M
Green duet |
ot 7 -d transition
*® mo g® o a note
Permanganare lyn | Ag 21005
Mn Terrahedial
TN ST 9 Opq—3dqC5)]
: 0 6:0 |
MntT = 3q°
dig, NM=O
Parple coloay duero,
suey
Yellow Slay due
2aaivatent. C4)ppm ca [DE PpTEPeTHIES OF Khinggy :
a . AS ¥ a
( ® Biewtortae Cores ) 5 : , at 7 DOTK _PAIPIS OMI Needle tke crgarattine ood’,
L SOR eo 2 e% SZ 2 eating We EAR OM)
c7 We? YJ 0 ee T Le + |4.0n NEIING fe decomposes to FoI Kannds (Paiple
Of ar XQ _ ° 7 ° greend
-§7 aps ep3 SO 0
AHS CTO Dongs AE SALtivaeg omidising action:
nat
GAT > 4: Op_ - 3dq
ers 3 pig , we ThE SH
4] ¥09. .
Prop Stange sed due to ANON : a Mn+ \enees
> kolI9O7 is an grange Ciystatine solid.
wis less soludie in water. ym = 4
1 > Mp > er0k
> on Heating ; ir decampases to Fo Kaci 4 Corange NB?
‘© Yellow)
| Oxcidising action + ‘
crtS 4 ge —_tedn_, gy a
1S = Reidfe median
7 C101 4 GST + A HY > oer2t 40
a ee
Me = 2x6
+J-Ve.0¢ —> 9
9 — rower +veos
Lower +e Os ——> Higher +ve og
FQ: > KMnog + Qo — Ls pnt ee NSO 4
FQ: cr 904 Mt
5 , > kt + ot - 3M
> KoC1207 +909 —H erst + 9037 > 3%a ee Se = _ yon
7 * . MN Alkaline soln oF nectral medians
2 as
> KoO%9 O7 + HNO, ——_, e134 + NOs” Green
aa :
Mnog + se” ——> Mn4*
Y oF Cos) 3
SES SEAS Sa TT7 {MreyConvey
Se ChTOMALE and Aichrorare ions I" "Abi
with suftable. pit -
ros EE e103
3 0H7 orange.
Yeitos 7 / PH >E 508 4
USeS OF KoO19 94! 7
> God Of ip Volumetric Analysis - ~
> of in leather industrg .
— Preparations oF Mang asocoMpound .
GSD Cradare tony)
‘san
oN
3x03 8042
Y20,
ee
g MONQAINAS And Perma)
pie with SuitabIe PR.
Ht eH cg
nganare. Ions .are interconvend.
wno4?”
Green
ses OF KNNg, +
G00 SA my Volumetric Analyste
> Bleaching OF Sik, Corton, ete.
> Heccloarisarion oF ails.
> Disinrecrant in water
>in VQ CON.
MNO4™
PY 5a 50H Parpie
AY Me doe 16 ies Oxidising
character> 5 pica .
Past S emerin antipenatrimare FP
> Also known as Inner transition CONES -
Cantnanoid Benes ranjon’ ran Baa tag
onttoraa Prasgatymin, Premetign | Fare | THERM TM Yb
*Cormonty known as Rare earth gemens.
* AI ATE siverg white metal
* common os is 43 3
_® Radioactive tantnancid: Pr Cpromethtund
)¥ Steel hard Metal: Sm samarium)
Electronic conrigaration: Ti tue
sins piace a
Exe] ar 5qent go
tos cy -
— | ~ Ap act ag?
4f 45q4602 ap lH tgs
*orners, ;
Lxe] 4e=°S got
ne,
ty Gast = apt
S sm = Lxel] 4eS e928
s Ba
6 a > Cxe] ae%es2
a BS
by tyst
W
=~ [xe] ae*
34
Atomic ot tonic Radius:
THE $-BLOCK eheMeENTS FT
Reringid Series
BICAEINOM ty
inom PKG ANE) Beveswom £1
he 2h Pa UND RG BiG OR ee
fel “thoniany Wonton Auronton Wrlow ' Coliromntas
gp Oe Nadioactive ements.
y REOVIEST NALGTANY Geeaving element ie Uranium . Elem-
ers CFTC) CHANG ane cated rane chaniim Siemens
apt are Merals.
KCOMMON Oe |
Electtonic Coneigavation ;
+3.
3 GEC > CN=9) FAH Capa o* pst Cm=period)
ean Pra:7
TRn1 BF BAS AQ2. | Len] BEI !S Se? Ae
eee OM-----------
ee ss
Soe BF? ed! Io? Bred! Ts?
BEN gqi jaa
BF! Gd! 4% tas Bdlec?
Breed Teo he > gate?
boms* omer
Tend BF eee 5
es
ty qn2? > ten) oF
a
tp oo = Ten] pr 1s :
a8 a
a
“Atomic ar lanic tadiug: ©
am Ss pend BET TIS?
8Consequently .
* Bromic radius / onic radius: Rast >COs > =. >SIF*> oH
* Mromic Tadius of 4d =Bd series = zrAt = Rat
* Basic chayacrer , Cisotation is dificate) 7
BME Y ACI AS
RaCoWg) > Cecons)> ----- > LACOWs ~
sige ~ Basic
SE Rasigg
% Racowds » Gd Conds, CUCOHs, YCOND: lL
> LACOHIS > GACONIs > KU COHs > VCOHad ise
yori ey
COGUVER ANA Magneric Property! IS
% go Para gy
Nounpaired eo red No UNnpaired CF
via due to Dio
citless #-F transition golguriess =
Esxcepr: @d3+ > chiess
% Max Paamagneriom tice > Nd" veadioniom
HP caleutare Magnerie mornent oF Gd2*.
a5-q BM ») 4-9 EM Oeqew 47-9 eM
> 6d3t 3 4—7 ;
‘No-oF Gnpaired C= 71 = MMe 1-9. By
Oscidation stare:
* COMMON and atable ag ig +5,
* pe ;
Ma
we)
-9.9 <> -g.ay
aways -Vve SRP
Seer inweree TOW er BP gl aR Te BF
ce To-of ar oS Ms FSS Have a er Ss 1; Bees Hane
ag! Poor/ Negligible se 7 SEY 5 Saaible oe; ge wyciae W
“Rettacty blu Nucleus And . Retinoic eanuracticn
Nalence shel t siae 4 = fanthandid cont ey congeaNOnelg,
le
=? C835, => 4F' Contoured)
om
Pa >. ACRE SW > > erst) 7
BASIC = ACCOHI|> ThoWs >... > ErCoH)s.
ar ——————> pr
node:n-) > Nodew-1 5
> Bls4 {
_NO-OF node 4 Sey Retraction + |
gactinoid Contraction is greater sro Cement to Clem!
ent than lanthanoid contraction due to ce oF BF fe om
aliey than 4F Cie; 5F > negligiple and 4e > emall oe)
ealoureg and Magnetic Propertg: |
Q which oF the Folowing ton is chess 9
meet ower gras? dame
Citlese Bo,a9
Borda |
firor and last |
DeDwnn emmy
Oy Mes) Cinay
SUS4 => 4PM = coloutless
* Magneric Moment =n
oseidation crate’:
_ time Goagai
CE, PT NA, MH, BY okt —Rinaga..
a ‘only in Oxides , Moo,
Ee yatyyat = TNS
3%
Mas __a8dn_, wyst
caqy : (aay
I + Goad of & +
Good of setae),
0 Ve saan Z >
Poetcesy 7 AN TaN :
So, always M4 ig MOTE stable.ace
Fst war = Ve
we)
wat osan yar
y
Goad RA
Chemical Properties:
a s tp" Ce) is oneidan,
Hark BNon.) Nea sMnge,Lnges—-
f06 es r ccontides)
a3 eters
thos, e Het From diare adi
s
Basic ko. ot with acids hy
alkatineoun 6? My, A
tera) ox-8
Ides and Wareckies
*.Ahe Chemical properties oF kn
\P_ = SOO KT! MHOh
(Sa =t000 KT! Mol
CHINES FOF
¥% sm, EA, Ty, Yos Nd 9 +2 the sormath OF this ion
caqy cea) Egat Is strony
Agent
= Ruminiot
Ke oF KN Aatcium Che Cartier MEMbers ave quire
i ‘reactive similar to calcium,
with’ Tsing arornic Number 4).
Applications of d and + block Slements:
S Fe and sreet: Most imp Consrraiction mareriat
S Feo + En Mischmeral + Bater making cused in Ma-
Bie 7 Oe : asad alloys), p-————>
Coraces OF Stace $,¢1, AI, ca, eI.)
duce ahen and
1 VSdlachhy
Yor CHE Is vedcicrgg|
PUR MOVES g 7 : 7”
a = -ov csmoll Vz cost 1s NOE Wan Cea iy solation
EOOcpt § EPpy st Jey y ‘Voriatn), ta ea "
» RY sr contiguraty go, Ces
ur
cag) ‘OY does Nor erxcist in golution
am Pa UND Pu pm om Bk Cro oF
AS 45 43 45 43 4s 4 4s +3
Ge) +4 44 44 ta 44 $4 44
nant 75 4H +m
a NQNESe OS OF F-Hlack Is +7 chown by Atinolds .
mw ACLINIAS can FoI JANge NO.OF Os than lanthancids:
HECIUSES COMPATADIE | slight nergy dirFevENnce blw
49,84 and BF Orbiral.
chemical Properties; .
xbcrincids One highly Tedtive bur they are Tadfoactive
a XXX
ANCON) s + No Bncows Tho
me
ApRiications oF @ and -# block Clements:
bb Mixed Oxides QF Fanthancids + caralyerin petroleum
S BUSPAR a ea
cracking ond Etovision Screougs agg HOTS).
ZNENile}
1 Nnoas th Dig COL. (Batrerg Indaserg ISO FEAAICESLs Ager Coliver Bromide? : PHorod"s
Ly eu s+areel > coppel UK ans -
phic Industty .
Copecta Vighit—san,
| Propertigg
9 -
G aga nickel 3 SET OK Coin / SIINET coin :
+s Ranthanside : Producth oF alloy Ste
elo Foy plates on
Coest Single Use)
EK
%
Bi