19-01-2025

1001CJA101016250001 JA

PART-1 : PHYSICS

SECTION-I (i)

1)

Speed (v) of particle is given as

v = Ae ,
–Bt

where t is time, then dimensions of [A] and [B] are respectively:-

(A) LT–1, T–1

(B) L, T–1
(C) T–1, LT–1
(D) LT, T

2)

If and , then the vector whose magnitude is equal to and parallel

to is :

(A)

(B)

(C)
(D)

3) If P represents pressure, C represents the speed of light, and Q represents energy striking a unit
area per sec, where x, y, z are non-zero integers such that (Px Qy Cz) is dimensionless. Find the value
of x, y and z.

(A) x = –1, y = –1, z = +1

(B) x = 1, y = –1, z = 1
(C) x = –1, y = –1, z = –1
(D) x = 1, y = 1, z = 1

4)

In a hypothetical set of units

1 star joule = 103 joule
1 star Newton = 104 Newton
1 star second = 10 second
Then one meter is equivalent to
(A) 100 star meter
(B) 1000 star meter
(C) 10 star meter

(D)
star meter

5) A plumber steps down 2 m out of his truck and walks 100 m east and then 50 m south, and then
takes an elevator to the basement of the building 18 m below street level. If the east, the north and
the upward direction are represented by the positive x, y and z–axes, which one of the following
represents displacement (meters) of the plumber?

(A)
(B)
(C)
(D)

6)

Two vector & lie in a plane, vector lies in a different plane, then ( are non
zero vector) :-

(A) Cannot be zero

(B) Can be zero
(C) Lies in plane of &
(D) None

SECTION-I (ii)

1) Given two vectors . is the angle between . Which of the following

statements is / are correct ?

(A)
is the component of

(B)
is the component of perpendicular to

(C)
is the component of along

(D)
is the component of perpendicular to

2) Select CORRECT statement(s) for three vectors and

(A) The above vectors can form triangle
(B) Component of along is 3.

(C)
makes angle cos–1 with y-axis.
A vector having magnitude twice the vector and anti parallel to vector is
(D)

3) A displacement vector of magnitude 10 m has its initial point at (4, 3)m. The y-component of this
vector has a magnitude of 6 m. The co-ordinates of the final point of the vector may be:

(A) (–4, 9) m
(B) (–4, –3) m
(C) (12, 9) m
(D) (12, –3) m

4) A block placed on x–y plane at origin and is pulled by two forces F1 & F2 where F1 is towards (3,
4)m and F2 towards (4, –3)m. F1 is of magnitude 9 N and F2 is of magnitude 12 N.

(A)
can be expressed as N

(B)
can be expressed as12 N.
(C) can be expressed as
(D) component of along y-axis is zero.

5) Choose the correct option(s) :

(A) 3 non-zero vectors, not in one plane can give a zero resultant.
(B) 4 non-zero vectors not in one plane can give a zero resultant.
(C) Components of a vector must be perpendicular to each other.
Magnitude of rectangular component of a vector is always less than or equal to the magnitude
(D)
of that vector.

6) A particle moves with constant speed v along a regular hexagon ABCDEF in the same order. Then
the magnitude of the average velocity for its motion from A to :

F is
(A)

D is
(B)

C is
(C)
(D) B is v

SECTION-II

1) A star undergoes some mode of oscillation. The frequency ω of oscillation depends upon the
properties of the star such as the density ρ and the radius R. It also depends on gravitational
constant G which appears in Newton's law of universal gravitation. ω depends on density as ω ∝ ρx.
The value of 2x is

2) In a system of units, the unit of velocity be 5 ms–1, the unit of acceleration be 20 ms–2 and the unit
of force be 10N then 80 unit of pressure is equal to ..........pascal

3)

A particle moves in a straight line covers half the distance with speed of 3 m/s. The other half of the
distance is covered in two equal time intervals with speed of 4.5 m/s and 7.5 m/s, respectively. The
average speed of the particle during this motion is

4) Given that force = ; if the dimensions of α is MxLyTz, the value of is.

5) Find if the three vectors are given by

6)

A car moving with constant acceleration covers two successive kilometers in 30 sec and 20 sec

respectively. If the acceleration of car is . Then value of n is

PART-2 : CHEMISTRY

SECTION-I (i)

1) Which set does not shows correct matching :

(A) Cu = [Ar] 3d10 4s1 ; element belongs to 11th group.

(B) Fe = [Ar] 3d6 ; element belongs to 8th group.
(C) Pd = [Kr] 4d10 ; element belongs to 10th group.
1 2 rd
(D) 89Ac = [Rn]6d 7s ; element belongs to 3 group

2) Give the correct initial T for true & F for false statement
(I) For 3d subshell of Mn+2 spin multiplicity value is 4
(II) 18 elements are present in 5th period of long form periodic table
(III) Mn+4 magnetic moment value is same as that of Cr+3
(IV) General valence shell electronic configuration for p-block elements is ns2np1-6

(A) FFTF
(B) FTTT
(C) F F T T
(D) F T T F

3) Calculate difference in Zeff value of Na+ and F–.

(A) 1
(B) 0.7
(C) 2
(D) 0

4) Which of the following set is isoelectronic?

(A) Si4– , P3– , S–

–
(B) H2S , HCl , HS
(C) , ,
(D) C4– , N3– , F– , Na

5) Maximum value of n + ℓ + m for the last unpaired electron in an element present in 17th group
and 3rd period in periodic table

(A) 4
(B) 5
(C) 6
(D) 7

6) Which set contain all the atoms with (n – 1)d10 ns2 np3 configuration :-

(A) Nitrogen , Phosphorous , Arsenic

(B) Phosphorous , Arsenic , Antimony
(C) Nihonium , Antimony , Arsenic
(D) Arsenic , Antimony , Moscovium

SECTION-I (ii)

1) Which rule(s) is/are violated if an element's configuration is written as :

(A) Aufbau rule

(B) Pauli's rule
(C) Hund's rule
(D) No rule is violated

2) Select the correct order of radii :-

(A) Al > Al3+

(B) N3– > F–
(C) Al < Ga
(D) Sc > Zn

3) The sum of maximum number of electrons having ℓ × m = –1 and ℓ × m = –4 in Ga are equal to

the

(A) Number of s-electrons in Aluminium atom

(B) Number of p-electrons in Sulphur atom
(C) Number of d-electrons in Cobalt atom
(D) Total number of electron in Nitrogen atom

4) Two elements have set of quantum numbers of their last filled subshell of valence shell as follows
:
'X' → n = 4 ℓ = 1
'Y' → n = 5 ℓ = 2
Then which statement is CORRECT?

(A) Element 'Y' has greater atomic number than atomic number of element 'X'
(B) Element 'X' has 10 electrons in 'd' subshell
(C) Element 'X' is not a transition element
(D) Atomic size of element 'Y' must be equal to the atomic size of element 'X'

5) Among the following is INCORRECT about the quantum numbers.

(A) The value of spin quantum number depends upon the principle quantum number.
(B) The value of azimuthal quantum number depends upon magnetic quantum number.
The energy of the orbitals of a particular subshell is different (in the absence of external
(C)
electric and magnetic field.)
(D) Energy order : 1s < 2s < 2p < 3s < 3p < 4s < 3d < 4p as per (n + ℓ) rule.

6) If IUPAC name of an element is "unununium" then correct statement regarding element is :

(A) It is a inner transition element

(B) It belongs to 8th period in periodic table
(C) It is transition element
(D) It is p-block element

SECTION-II
1) How many of the following are correct set of four quantum numbers :-

(a) n = 3, ℓ = 2, mℓ = 1, ms = – (b) n = 2, ℓ = 2, mℓ = 1, ms = +

(c) n = 4, ℓ = 3, mℓ = –4, ms = + (d) n = 3, ℓ = 1, mℓ = 2, ms = +

(e) n =1, ℓ = 0, mℓ = 0, ms = + (f) n = 1, ℓ = 0, mℓ = 0, ms = –

(g) n =2, ℓ = 0, mℓ = 0, ms = + (h) n = 5, ℓ = 1, mℓ = 0, ms = +

2)

Number of diamagnetic species among the following :-

V+4 , Cu+ , Sc+3, Ti+2, Cr+3, Mn+4, F–

3) If x : maximum number of degenerated orbitals in 3rd shell of He

y : number of empty orbital in outermost occupied shell of Ne atom
then value of (x + y) will be?

4) Sum of nodal planes of , dxy , px , s , orbitals.

5) Find total number of species having radius less than Be.

Sr , C , N , Li , F , O , Mg , Ca , Be+ , Be+2 , B+ , Be– , H–

6) In Lothar Meyer curve, if number of elements occupying ascending part of curve from the given
list is equal to x and number of elements occupying the descending part of curve from the given list
are y, then calculate (y – x).
Li, F, Be, Na, Br, Cs, Ca, Cl, Mg, I, Ba, Rb, Sr

PART-3 : MATHEMATICS

SECTION-I (i)

1) Value of is equal to

(A) x2
(B) xy
(C) y3
(D) x4
2) The shaded region in the figure is

(A)
(B)
(C)
(D)

3) In fig, ABCD is a parallelogram, AL ⊥ CD and AM ⊥ BC. If AB = 12 cm, AD = 8 cm and AL = 6

cm, then AM =

(A) 15 cm
(B) 9 cm
(C) 10 cm
(D) None of these

4) Number of positive integral solutions of the equation , is

(A) 2
(B) 8
(C) 7
(D) 5

5) If n(A) = 20, n(P(B)) = 225 and n(A ∪ B) = 35 then n(A ∩ B) is (where n(X) represent number of
elements in set X and P(X) represents power set of X)

(A) 10
(B) 20
(C) 5
(D) 15

6) Number of –ve integral values of x satisfying are

(A) 2
(B) 3
(C) infinite
(D) 1

SECTION-I (ii)

1) Consider the equation , where x ≥ 5

(A) Two solutions are twin prime

(B) Two solutions are coprime
(C) All natural solutions
(D) Sum of integral solutions is 11

2) Let A = {x ; x ∈ R and (x2 – 12)2x = (x2 + 2x)2x }, then A have

(A) all non-positive integer

(B) sum of all elements in A is –7
(C) product of all elements in A is 0
(D) n(A) = 3

3) If x2 – 1 is one factor of x5 + x4 + 3x3 + ax + b, then which of the following is/are correct ?

(A) a2 + b2 > 12
(B) a2 + b2 < 18
(C) a > b
(D) a2 > b2

4) Which of the following is simplifies to a prime number ?

(A)

(B)

(C)

(D)

5) Let
Then the value of

lies in the interval

(A) (0,40)
(B) [10,30]
(C) [15,40]
(D) [0,10]

6) Let P(x) be a polynomial which leaves remainder 4x + 6 when divided by x2 – 1 and the
remainder 4 + 6x when divided by . Which of the following is/are false ?

(A) If P(x) is divided by x + 1, remainder is 2

(B) If P(x) is divided by , remainder is 5x + 7
(C) If P(x) is divided by x – 1, remainder is –2
(D) If P(x) is divided by x – 3, remainder is 20

SECTION-II

1) If value of the expression is p then value of is

2) If , then value of is :

3) From first 100 natural numbers, number of numbers which are divisible by 2 but not by 3, is

4) If A and B are two sets and U is the universal set such that n(U) = 700, n(A) = 200, n(B) = 300
and n(A ∩ B) = 100, then n(A' ∩ B'). (where n(X) denotes the cardinal number of set X) is

5) Number of integral values of x satisfying is/are

6) If x, y and z are real numbers such that x2 + y2 + 2z2 – 4x + 2z – 2yz + 5 = 0, then value of z ÷ y +
x is
 ANSWER KEYS

PART-1 : PHYSICS

SECTION-I (i)

Q. 1 2 3 4 5 6
A. A B B C C A

SECTION-I (ii)

Q. 7 8 9 10 11 12
A. A,B A,C,D A,B,C,D B,C,D B,D A,C,D

SECTION-II

Q. 13 14 15 16 17 18
A. 1.00 512.00 4.00 0.50 15.00 4.00

PART-2 : CHEMISTRY

SECTION-I (i)

Q. 19 20 21 22 23 24
A. B B C B B D

SECTION-I (ii)

Q. 25 26 27 28 29 30
A. A,C A,B,D C,D A,B,C A,B,C C

SECTION-II

Q. 31 32 33 34 35 36
A. 5.00 3.00 5.00 5.00 7.00 1.00

PART-3 : MATHEMATICS

SECTION-I (i)

Q. 37 38 39 40 41 42
A. A D B D A B

SECTION-I (ii)

Q. 43 44 45 46 47 48
A. B,C,D B,D A,B,D B,D A,B,C C,D
 SECTION-II

Q. 49 50 51 52 53 54
A. 0.25 0.00 34.00 300.00 3.00 3.00
 SOLUTIONS

PART-1 : PHYSICS

1)
0 0 0
[e–Bt] = M L T
∴ [v] = [A] = LT–1
And Bt is exponent
0 0 0
∴ [Bt] = M L T
∴ B = T–1

2)

Required vector =

3)

PxQyCz = 1
0 0 0
[ML–1T–2]x[MT–3]y[LT–1]z = M L T

4) L ∝ EaFbTc
L = (ML2T–2)a (M1L1T–2)bTc
L = Ma+b L2a+b T–2a–2b+c
a+b=0
2a + b = 1
–2a – 2b + c = 0
2a – a = 1
a=1
b = –1 and c = 0
∴ L = EaFbTc = E1F–1 or length = energy/force
(1 star meter) = (1 star joule)1 (1 star N)–1
= (103) (104)–1 [(Joule)1 (N)–1]
1 star meter = 10 –1 m
∴1 m = 10 star meter
5)

6)

Theoritcial

7)

Component of along is cos for being the angle between the vectors.

Also . So choice (1) is correct.

The vector is perpendicular to the vector .

So the other resolved component is .

8) , ,
,

so
, hence, component = 0

9) The displacement can be in any direction.

 ⇒ y = 9, y = –3
2
100 = (x – 4) + 36
x – 4 = ±8; x = 12
x = –4
So x = 12 or –4
x = 9 or –3

10) direction vector = 9

12) For A to F, ;

For A to D, ;

For A to C, ;

For A to B, =v

13) w ∝ ρxRyGz
0 0
M L T–1 = (ML3)xLy(M–1L3T–2)z
x–z=0
–3x + y + 3z = 0
–2z = –1

z=
14) Pressure Vx ay Fz
[ML–1T–2] = [LT–1]x [LT–2]y [MLT–2]z
1=z
–1 = x + y + z
–2 = –x – 2y – 2z
⇒ x = –4 ; y = 2, z = 1
P ∝ V–4 a2 F1
80 Pa' = x Pa

x=

15)

Vavg = 4 m/s

16)

= M2L–2T–2
x=2
y=–2
z = –2

17)
= 3 + 18 – 6 = 15

18)
 ⇒ 6u + 90 a = 200 ....(i)

⇒ u + 40a = 50 ....(ii)
Solving (i) & (ii) we get a = 2/3 m/s2

PART-2 : CHEMISTRY

31) a, e, f, g, h

32)

(Sc+3 , F– , Cu+)

PART-3 : MATHEMATICS

37)

38) Shaded region is A ∩ (B ∪ C)′ = A – (B ∪ C)

39)
∵ CP = AL = 6 cm
∵ BC = AD = 8 cm

* Area of ΔABC = AB × CP = ×12 × 6 = 36

* Area of ΔABC = AM × BC = × AM × 8 = 4AM

∴ 4AM = 36
⇒

40) Simplify the equation to the form xy + 42 = 9y, then

y is a positive integer implies that 9 – x is a positive divisor of 42, so
9 – x = 1,2,3,6,7 i.e. x = 8,7,6,3,2
Correspondingly, y = 42,21,14,7,6. By checking, the five solutions satisfy the original equation,
so the answer is 5.

41) Given n(P(B)) = 225

⇒ B has 25 elements
i.e. n(B) = 25
Now n(A ∪ B) = n(A) + n(B) – n(A ∩ B)
⇒ n(A ∩ B) = 20 + 25 – 35 = 10

42)
x ∈ [–7, –6] ∪ {–2} ∪ [1, 3] ∪ (7, ∞)

43)
x–5=1⇒x=6
x–5=0⇒x=5

, no solutions
So only possible values of x are 5 and 6

44) Case - I
2x = 0 ⇒ x = 0
but x = 0 does not satisfy given equation
Case - II
x2 – 12 = x2 + 2x ≠ 0
⇒ 2x = –12 ⇒ x = –6
Case - III
x2 – 12 = –(x2 + 2x)
⇒ 2x2 + 2x – 12 = 0
⇒ x2 + x – 6 = 0
⇒ (x + 3)(x – 2) = 0
⇒ x = – 3, 2 (both value accepted as power is even)

45) x5 + x4 + 3x3 + ax + b = Q(x)(x + 1)(x – 1) put x = 1 : a + b = –5

put x = –1 : a – b = –3
∴ a = –4 & b = –1

46) (B)
(C)

(D)

47)

value of the given expression .

48)

p(–1) = 2
p(x) = (x – 3) (x – 1) q(x) + 4 + 6x
p(1) = 10
p(3) = 22
p(x) = (x – 3) (x + 1) q(x) + Ax + B
p(3) = 3A + B = 22
p(–1) = –A + B = 2
Subtracting 4A = 20
A=5
B=7
Remainder = 5x + 7

49)

=0

50) or

or
51) Number of numbers divisible by (2) = 50
Number of numbers divisible by both 2 and 3 = 16
Number of numbers divisible by 2 but not 3 = 34

52) We have, A' ∩ B' = (A ∪ B)'

∴ n(A' ∩ B') = n((A ∪ B)' ) = n(U) – n(A ∪ B)
= n(U) – [n(A) + n(B) – n(A ∩ B)]
= 700 – (200 +300 – 100) = 300.

53)
applying componendo and dividendo

is a solution

Final solution x = 0, 3, 8
No. of integral values = 3

54) x2 – 4x + 4 + y2 + z2 – 2yz + z2 + 2z + 1 = 0
(x – 2)2 + (y – z)2 + (z + 1)2 = 0
⇒ x = 2, y = z, z = –1
∴ (–1) ÷ (–1) + 2
1+2=3