01-06-2025

2401CJA101002250001 JM

PHYSICS

SECTION - I

1) y = 6x2 + . Find

(A)

(B)

(C)

(D) None of these

2) The momentum of a moving particle given by p = t . Net force acting on this particle is defined

by equation . The net force acting on the particle is zero at time:

(A) t = 0

(B)

(C)

(D) None of these

3)

Which of the following is not a unit of time?

(A) microsecond
(B) leap year
(C) lunar month
(D) light year

4) The equation for the acceleration of a hypothetical system is defined as .

2
Acceleration a is measured in m/s , γ is a dimensionless constant, T is temperature in kelvin(K) and
m is mass in kg. Find the SI unit for the Boltzmann constant KB ?

(A) kg.m4.s–4k–1
(B) kg.m2.s–2k–1
(C) kg.m2.s–4.k–2
(D) kg.m2.s–4.k–1

5) Speed of a particle is given by where t is time. Dimensional formula of β is :

(A) T–1
(B) T–2
(C) T
(D) T2

6) The speed (v) of wave on surface of water is given by . The dimensional formula
for a and b respectively. Where λ is the wavelength and ρ is density of water.

0
(A) L1T–2, M1L T–2
(B) LT–2, L–1T2
(C) LT–2, L1T–2
0 0 0
(D) L–1T2,M L T

7) If x = , then :-

(A) The dimension of x and a are the same

(B) The dimension of a and b are not same
(C) x is dimensionless
(D) None of these

8) If y = 3x2 + x + 5, then find value of at x = 1.

(A) 11
(B) 9
(C) 7
(D) 5

9) What is the dimensions of a and b in the relation F = , where F is a force, x is distance

and t is time:

(A) ML1/2 T–2, MLT–4

(B) ML1/2T–1, MLT–4
(C) ML1/2T–2, ML2T–4
(D) Both are dimensionless

10) The approximate value of x where

x = (sin 2°) (cos 2°), is :

(A)

(B) 2
(C) 1

(D)

11) Frequency is the function of density ρ, length λ and tension T. The period of oscillation is
proportional to:-

(A) ρ1/2λ2T –1/2

(B) ρ3/2λ3/2T –1/2
(C) ρ1/2λ3/2T –3/4
(D) ρ1/2λ1/2T3/2

12) The value of universal gravitational constant The value of G in units

of is

(A)
(B)
(C)
(D)

13) If x = at + bt2, where x is metre and t is in hour (hr) then unit of b will be

(A)

(B)

(C) m

(D)

14) If area (A) velocity (v) and density are base units, then the dimensional formula of force can
be represented as

(A)
(B)
(C)
(D)

15)

The potential energy of a particle varies with distance x as where A and B are constants.
The dimensional formula for A × B is

(A) M1 L7/2 T–2

(B) M1 L11/2 T–2
(C) M1 L5/2 T–2
(D) M1 L9/2 T–2

16)

If the resultant of two forces of magnitudes P and Q acting at a point at an angle of 60° is Q, then
P/Q is :-

(A) 1

(B)

(C) 2
(D) 4

17)

A bird moves from point (1, –2) to (4, 2). If the speed of the bird is 10 m/s, then the velocity vector of
the bird is

(A)

(B)

(C)
(D)

18) At what angle should the two force vectors 2F and act so that the resultant force is :-

(A) 37°
(B) 30°
(C) 45°
(D) 60°

19) A man moves towards 3 m north then 4 m towards east and finally 5 m towards 37° south of
west. His displacement from origin is :-

(A) 5√2m
(B) 0m
(C) 1m
(D) 12m

20) Which of the following relations is true for two unit vectors and making an angle θ to each
other?
(A)

(B)

(C)

(D)

SECTION - II

1)

A dust particle oscillates in air with a time period which depends on atmospheric pressure P, density
of air d and energy of particle E. Time period is proportional to (P)a (d)b (E)c. Find the value of (–6a +
2b + 3c).

2)

Three forces (shown in figure) act on a body simultaneously. What will be magnitude (in newton) of
smallest additional force to make net force along North direction.

3)

If and are two non-collinear unit vectors and if , then the value of .

is . Find the value of x.

4)

In the given figure if the angle between and is 5α°. Find the value of α.
5) The farm house shown in figure has rectangular shape and has sides parallel to the chosen x and
y axes. The position vector of corner A is 125 m at 53° and corner C is 100 m at 37° from x axis. Find

the length of the fencing required in meter.

CHEMISTRY

SECTION - I

1) When 3d orbital is complete, the electron inters to next :

(A) 4s
(B) 5s
(C) 4p
(D) 5p

2) Which of the following orbital is non-axial ?

(A) dxy
(B)
(C)
(D) pz

3) Which of the following has the maximum number of unpaired electrons ?

(A) V3+
(B) Fe3+
(C) Ti3+
(D) Fe2+
4) The quantum number of four electrons are given below :
I. n = 4, ℓ = 2, mℓ = –2, ms = –1/2
II. n = 3, ℓ = 2, mℓ = 1, ms = +1/2
III. n = 4, ℓ = 1, mℓ = 0, ms = +1/2
IV. n = 3, ℓ = 1, mℓ = 0, ms = –1/2
The correct order of their increasing energies will be :

(A) IV < II < III < I

(B) I < III < II < IV
(C) IV < III < II < I
(D) I < II < III < IV

5) Which set of quantum number is not possible ?

(A) n = 3, ℓ = 1, mℓ = –1, ms = +1/2

(B) n = 4, ℓ = 0, mℓ = 0, ms = –1/2
(C) n = 3, ℓ = 2, mℓ = –2, ms = +1/2
(D) n = 4, ℓ = 1, mℓ = –2, ms = –1/2

6) Which quantum number will determine the orientation of various orbital in space?

(A) Principal quantum number

(B) Magnetic quantum number
(C) Azimuthal quantum number
(D) Spin quantum number

7) The sum of maximum number of electron having +1 and –1 value of m in Ti.

(A) 6
(B) 10
(C) 8
(D) 12

8) The isoelectronic set of ions is :

(A) N3–, Li+, Mg2+, O2–

(B) F–, Li+, Na+, Mg2+
(C) Li+, Na+, O2–, F–
(D) N3–, O2–, F–, Na+

9) Which is not anomalous pair of elements in Mendeleev's periodic table ?

(A) Ar & K
(B) Co & Ni
(C) Te & L
(D) Al and Si
10) Total number of orbitals in N-shell of He+ is :

(A) 16
(B) 9
(C) 7
(D) 31

11) Which set of quantum number is not possible for last electron of 17Cl :

(A) n = 3, ℓ = 1, mℓ = –1, ms = –1/2

(B) n = 3, ℓ = 1, mℓ = 0, ms = +1/2
(C) n = 3, ℓ = 0, mℓ = 0, ms = –1/2
(D) n = 3, ℓ = 1, mℓ = +1, ms = +1/2

12) Which is isotone of 8O16 ?

14
(A) 6C
15
(B) 7N
12
(C) 6C
(D) Both (A) and (B)

13) An element has electronic configuration [Ar]4s2, 3d7 the elements belongs to :

(A) IVth period, 8th group

(B) IVth period, 7th group
(C) Vth period, 8th group
(D) None of these

14) The number of electron in Na having m = 0 is :

(A) 7
(B) 8
(C) 11
(D) 6

15) Spin multiplicity of 3d8 is :

(A) 3
(B) 2
(C) 1
(D) 5

16) The spin magnetic moment (µs) for Ni2+ will be :

(A) 2.84 B.M

(B) 1.73 B.M.
(C) 3.78 B.M.
(D) 2 B.M.

17) An element X has three radius named as covalent radius, metallic radius & Vander wall's radius
which option represent correct match of radius :

Column - I Column - II

a. Covalent radius I. 104 pm

b. Metallic radius II. 94 pm

c. Vander wall's radius III. 119 pm

(A) a - I; b - II; c - III
(B) a - II; b - I; c - III
(C) a - II; b - III; c - I
(D) a - I; b - III; c - II

18) Which of the following d-orbital does not have any nodal plane ?

(A)
(B) dxy
(C) dyz
(D)

19) Which of the following ion is largest in size ?

(A) N3–
(B) O2–
(C) P3–
(D) S2–

20) An element Z has its IUPAC name Unniloctium, the element belong to which period and group of
periodic table.

(A) VIth period, 8th group

(B) VIIth period, 8th group
(C) VIIth period, 18th group
(D) VIIth period, 10th group

SECTION - II

1) The total no of exchange pair possible in 3d8 electronic configuration is :

2) Minimum number of electrons having ms = –1/2 in 'Cr' is ______ :

3) The difference between group no & period of element having atomic no 114 is ________.

4) The number of elements in 5th period of long form of periodic table are ______.

5) The value of zeff for 3d electron of 24Cr is _________.

MATHEMATICS

SECTION - I

1) If a set contains m elements and another set contains n elements. If 144 is the sum of number
of subsets of both sets then (m, n) can be

(A) 4, 6
(B) 7, 2
(C) 7, 4
(D) 8, 2

2) If a, b, c ∈ R and a2 + b2 + c2 – 2a + 2b + 2c + 3 = 0 then value of 2a – 3b + 4c is

(A) -1
(B) 0
(C) 1
(D) 2

3) A survey shows that 73% of the persons working in an office like coffee, whereas 65% like tea. If x
denotes the percentage of them, who like both coffee and tea, then x cannot be:

(A) 63
(B) 38
(C) 54
(D) 36

4) Let X and Y be two sets.

Statement-1 : X ∩ (Y ∪ X)' = ϕ
Statement-2 : If X ∪ Y has m elements and X ∩ Y has n elements then symmetric difference X Δ Y
has m-n elements.

(A) Both the statements are true.

(B) Statement-I is true, but Statement-II is false.
(C) Statement-I is false, but Statement-II is true.
(D) Both the statements are false.

5) If A and B are two sets containing 5 and 7 elements respectively, then maximum and minimum
number of elements in A ∪ B respectively are –

(A) 7,5
(B) 12,5
(C) 7,0
(D) 12, 7

6) Find the values of a and b so that the polynomial x3 – ax2 – 13x + b has (x – 1) and (x + 3) as
factors.

(A) a = 3, b = –15
(B) a = –3, b = 15
(C) a = 3, b = 15
(D) a = –3, b = –15

7) A survey of 500 television viewers produced the given information : 285 watch football, 195 watch
hockey, 115 watch cricket, 45 watch football and cricket, 70 watch football and hockey, 50 watch
cricket and hockey, 50 do not watch any of the three games. How many watch exactly one of the
three games?

(A) 225
(B) 325
(C) 425
(D) None of these

8) Which of the following is not equal to A – B ?

(A) A – (A ∩ B)
(B) (A ∪ B) – (A ∩ B)
(C) A ∩ Bc
(D) none of these

9) If , then

(A)
(B) N
(C)
(D)

10) If , then what is equal to?

(A) X
(B) Y
(C) N
(D) A null set
11) If A = {1, 3, 5, 7, 11, 13, 15, 17, 19, 21}
B = {2, 4, 6, ....., 22}
U is universal set, then A' ∪ ((A ∪ B) ∩ B') is -

(A) U
(B) A'
(C) A ∩ B
(D) A

12) then x =

(A) 2
(B) 1
(C)
(D) –1

13) If n(A) = 20, n(P(B)) = 225 and n(A ∪ B) = 35 then n(A ∩ B) is (where n(X) represent number of
elements in set X and P(X) represents power set of X)

(A) 10
(B) 20
(C) 5
(D) 15

14) Consider a number N = 21P53Q4 (where P & Q represent digit of number N). Find the number
of ordered pairs (P, Q) so that the number N is divisible by 44.

(A) 1
(B) 2
(C) 3
(D) 4

15) Suppose a and b are constants such that (x3 + bx2 - 7x + 9) (x2 + ax + 5) = x5 + 13x4 + 38x3 -

22x2 + 37x + 45

(A) a = 8 and b = 5
(B) a = 6 and b = 4
(C) a = 3 and b = 6
(D) a = 10 and b = 20

16) P(x) is a polynomial of degree 5 with leading coefficient unity such that
P(1) = 1, P(2) = 4, P(3) = 9, P(4) = 16, P(5) = 25.
The constant term in the expression of P(x) is:

(A) 110
(B) –100
(C) –120
(D) 24

17) If , then the value of is :

(A) 0
(B) 1
(C) 2
(D) –1

18) If A = (–2, 5], B = [0, 7) and C = (3, 10], then which one of the following is correct option -

(A) (A ∪ B) – C = [–2, 3)
(B) A – (B ∩ C) = [–2, 3]
(C) A – (B ∪ C) = (–2, 0)
(D) (A ∩ B) – C = [0, 3)

19) If and , then the value of x2 + y2 is equal to

(A) 40
(B) 50
(C) 98
(D) 100

20) A polynomial P(x) of third degree vanishes when x = 1 and x = – 2. This polynomial has values 4
and 28 when x = – 1 and x = 2 respectively. If the polynomial P(x) is divided by (x + 3), the
remainder is :

(A) –32
(B) 100
(C) 32
(D) 0

SECTION - II

1)

Let
and x is prime number greater than 2}
and then number of elements in is
2) In a survey, 100 teenagers were interviewed to know their preferences for arrange marriage
(AM), love marriage (LM), remain single (RS), and the collected data were as following
n(AM ∩ LM ∩ RS) = 10, n(AM ∩ LM) = 20
n(LM ∩ RS) = 30, n(AM ∩ RS) = 25
n(only AM) = 25, n(only LM) = 5, n(only RS) = 8 and some of them did not respond,
then number of correct statements from the following is-
(i) n(AM) = 47
(ii) n(LM) = 45
(iii) n(RS) = 53
(iv) n(AM ∪ LM ∪ RS) = 100

3) If + = 1, then total number of possible ordered pair of positive integer (x, y) is -

4) If polynomial Ax3 + 4x2 + Bx + 5 leaves same remainder, when divided by x – 1 and x + 2

respectively then value of 3A + B is equal to

5) If can be expressed as , (a, b, c, d ∈ ) then find the value of a3 + b3 + c3 + d3 is

equal to
 ANSWER KEYS

PHYSICS

SECTION - I

Q. 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20
A. A B D C A A C C A A A A D B B C D C B B

SECTION - II

Q. 21 22 23 24 25
A. 7.00 6.00 2.00 3.00 90.00

CHEMISTRY

SECTION - I

Q. 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45
A. C A B A D B B D D A C D D A A A B D C B

SECTION - II

Q. 46 47 48 49 50
A. 13.00 9.00 7.00 18.00 4.60

MATHEMATICS

SECTION - I

Q. 51 52 53 54 55 56 57 58 59 60 61 62 63 64 65 66 67 68 69 70
A. C C D A D C B B C B A A A D A C A C C A

SECTION - II

Q. 71 72 73 74 75
A. 3.00 2.00 6.00 4.00 32.00
 SOLUTIONS

PHYSICS

3)

4.5 × 10–6 Parsec = 1.5 × 10–5 light year

1 Parsec = light year

4)

5) Power of any number should be dimensionless.

0 0 0
βt = M L T
0 0
β = M L T–1

6)

∴ [a] =
0
and [b] = L2T–2 × ML–3 × L ⇒ [b] = M1L T–2

7) sin θ is dimensionless

8)

At x = 1, =7

9)

10) x = (sin2°) (cos2°)

x (sin2°) (1) = sin

11)

Period of oscillation
t ∝ ρa λb Tc
T ∝ [ML–3] ∝ [L]b[MLT–2]c
0 0
M L T1 ∝ Ma+c L–3a+b+c T–2c
Comparing powers of M, L and T
a + c = 0, –3a + b + c = 0, –2c = 1

t ∝ ρ1/2 λ2 T–1/2

12)

13) x = at + bt2
x = bt2
m = (b) hr2

14)
F = KAa vb qc
=
F=
=
So, F = A v2 q1
1

F = Av2q

15)

Here, x2 has the dimensions of L2, B = [L2]

Also, or

18)
R2 = A2 + B2 + 2ABcosθ

20)

21)

T = k[P]x[d]y[E]z = k[ML–1T–2]x[ML–3]y[ML2T–2]z
0 0
M L T1 = k[M]x + y + z[L]–x – 3y + 2z[T]–2x–2z
on comparing
x+y+z=0 ......(i)
–x – 3y + 2z = 0 ......(ii)
–2x – 2z = 1 ......(iii)

22)
To have resultant along north, force towards west should be cancelled.

23)

a1 = a2 = 1
and
Now
 24)
5α = 15
α=3

25)
AD = 125 sin53° – 100sin37°
= 40m
Also, BC = 40
AB = 100cos37° – 125cos55°
= 5m = CD
so, fencing required = 2(AB + AD)
= 2(40 + 5) = 90

CHEMISTRY

26) 4p orbital is just filled after complete filled of 3d orbital

27) dxy is non-axial orbital

28) Fe3+ has 5 number of unpaired electrons

29) Energy of orbital is given by (n + 1) rule higher the value of (n + 1); higher the energy so
Correct order is : IV < II < III < I

30) n = 4, ℓ = 1, mℓ = –1, 0, +1, ms = +1/2 or –1/2

So mℓ = –2 is not possible

31) Magnetic quantum number determines the orientation of various orbital in space

35) No. of orbitals in N-shell (n = 4) is (4)2 = 16

 36) 17C – 1s2, 2s2, 2p6, 3s1, 3p5
for last e– the possible of quantum number are
n = 3, ℓ = 1, mℓ = –1 or +1, ms = +1/2 or –1/2
n = 3, ℓ = 0 is not possible for last electron of 3p-subshell

37) 8O16 ⇒ Number of neutron = 8,

14
6C & 7N15 both have number of neutron = 8

38) Period – IVth

group no – 9

39) 11Na – 1s2, 2s2, 2p6, 3s1 the number is having m = 0 is equal to 7

43) has no. nodal plane it has only nodal surface.

th th
45) Unniloctium – 108 belongs to VII period & 8 group

46)

No. of exchange pair =

for spinning up is, no. of exchange pair =

for spinning down electrons ______ =

So, sum = 10 + 3 = 13

47) 24Cr – 1s2, 2s2, 2p6, 3s2, 3p6, 4s1, 3d5

So, minimum number of electrons having ms = –1/2 = 9.0

50) ⇒ 24Cr – 1s2, 2s2, 2p6, 3s2, 3p6, 3d5, 4s1

σ3d = 4 × 0.35 + 18 × 1 = 1.40 + 18 = 19.40
So, zeff for 3d electron = 24 – 19.40 = 4.60

MATHEMATICS

52)

a2 – 2a + 1 + b2 + 2b + 1 + c2 + 2c + 1 = 0
⇒ 2a – 3b + 4c = 2(1) – 3(–1) + 4(–1) = 5 – 4 = 1

53)

Ans. (4)
C person like coffee
T person like Tea
n(C) = 73
n(T) = 65
n(C T) 100
n(C) + n(T) – n (C T) 100

73 + 65 – x 100
x 38
73 – x 0 x 73
65 – x 0 x 65

54)

X ∩ (Y ∪ X)' = X ∩ (Y' ∩ X') = X ∩ X' ∩ Y' = ϕ

⇒ Statement – 1 true.
X Δ Y = (X – Y) ∪ (Y – X) = (X ∪ Y) – (X ∩ Y)
⇒ number of element in X Δ Y = m–n.
⇒ Statement-2 is true.

55)

n(A ∪ B)= n(A)+n(B)–n(A ∩ B)

0 ≤ n(A ∩ B) ≤ 5
7 ≤ n(A ∪ B) ≤ 12

59)
[ 5 and 7 are relatively prime numbers ]

60)
X = {0, 9, 54, .....}
Y = {0, 9, 18, 27,.....}

61) (A ∪ B) ∩ B' = A
⇒ A' ∪ ((A ∪ B) ∩ B') = A' ∪ A = U

62)
x2–x–2 = 0
(x–2) (x+1) = 0
x = 2 or x = –1 (not possible)

63) Given n(P(B)) = 225

⇒ B has 25 elements
i.e. n(B) = 25
Now n(A ∪ B) = n(A) + n(B) – n(A ∩ B)
⇒ n(A ∩ B) = 20 + 25 – 35 = 10

67)
squaring both side ⇒

⇒ ⇒
⇒ 0

68) (A ∪ B) – C = (–2, 3]
A – (B ∩ C) = (–2, 3]
A – (B ∪ C) = (–2, 0)
(A ∩ B) – C = [0, 3]

71)

A = {1, 2, 3, 4, 5}
B = {3, 5, 7} U = {1, 2, 3, 4, 5, 6, 7, 8, 9, 10}
C = {5, 10}

= 10 – 7 = 3

72) n(A ∪ B ∪ C) = n(A) + n(B) + n(C)

–n(A ∩ B) – n(B ∩ C) – n(C ∩ A)
+ n(A ∩ B ∩ C)

73)

4y + 5x = xy
xy – 5x – 4y = 0

(x – 4)(y – 5) = 20

Now 20 can be split in following ways

1 × 20 ⇒ (x, y) = (5, 25)

20 × 1 ⇒ (x, y) = (24, 6)

4 × 5 ⇒ (x, y) = (8, 10)

5 × 4 ⇒ (x, y) = (9, 9)

10 × 2 ⇒ (x, y) = (14, 7)

2 × 10 ⇒ (x, y) = (6, 15)

Hence, total number of possible ordered pair of positive integer (x, y) is 6.

74)

P(x) = Ax3 + 4x2 + Bx + 5

P(1) = P(-2)
A + B + 9 = -8A - 2B + 21
9A + 3B = 12
3A+B=4

75)