25-05-2025

9610WJA801491250008 JA

PART 1 : PHYSICS

SECTION-I

1) A uniform heavy rope is being pulled by a force 100 N, find tension at its mid point :-

(A) 25 N
(B) 50 N
(C) 75 N
(D) 100N

2) In all the given cases blocks are at rest, are in contact and the forces are applied as shown. All the
surfaces are smooth then in which of the following case(s), normal reaction between the two block is
non–zero?

(A)

(B)

(C)

(D)

3) Three blocks a, b and c of masses 10 kg, 10 kg and 20 kg respectively are arranged as shown in
figure. All the surfaces are frictionless and string is inextensible. A constant force F = 20 N is
applied on block ‘a’ as shown. Pulleys and string are light. Part of the string connecting both pulleys
is vertical and part of the strings connecting pulleys with masses a and b are horizontal.

(A) Acceleration of blocks a, b and c is 0.5 m/s2.

(B) Acceleration of block b is 1 m/s2.
(C) Tension in the string is 10 N.
(D) Acceleration of block c is 0.5 m/s2.

4) A cylinder of mass M and radius R is resting on two corner edges A and B as shown in figure. The
normal reaction at the edges A and B are :

(A)
NA =
(B) NB =
NA =
(C)

(D)
NB =

5) A painter is applying force himself to raise him and the box with an acceleration of 5 m/s2 by a
massless rope and pulley arrangement as shown in figure. Mass of painter is 100 kg and that of box

is 50 kg. If , then :

(A) Tension in the rope is 1125 N

(B) Tension in the rope is 2250 N
(C) Force of contact between the painter and the floor is 375 N
(D) None of these

6)

In a new system of units, the unit of mass is 1000 kg (1 metric ton), unit of length is 1000m (1km)
and unit of time is 3600 s(1hr). Select correct statement(s).

(A) The numerical value of 500 m in this new system is 0.5.

(B) The numerical value of 7200 s in this new system is 2.
(C) The numerical value of 1/36 J in this new system is 3.6 × 10–4.
(D) The numerical value of 1/36N in this new system is 0.36.

SECTION-III
1) A body covers one-third of the total distance with speed v1. For the remaining distance, it travels
for half of the time with speed v2 & another half of the time with speed v3. If average speed is

, find n.

2) The position vector of a particle is given as . The time (in sec.) after which
velocity vector and acceleration vector becomes perpendicular to each other is equal to :-

3) The relation 2t = describes the displacement of a particle in one direction where x is in

metre and t is in seconds. Find the displacement when velocity is zero.

4) Forces represented by , and are in equilibrium.The ratio of magnitude of p to

that of q is

5) If two forces vector 2F and act at 5n° so that the resultant force is F. Value of n is :

6) If and , then is equal to

SECTION-II

1) Four blocks of same mass (m= 1kg) connected by cord are pulled by force F=20N on a smooth
horizontal surface. The tension T2(N) will be

2) Two block of masses 1 kg and 2 kg are placed on a horizontal surface and then connected to a
light movable pulley as shown in the figure. A time varying force F=4t N starts acting on the pulley
in the direction shown. Find the time(in second) after which any block will break off from the surface
3) Find magnitude of force (N) exerted by string on pulley

4) A box of mass m is placed on a smooth horizontal platform as shown in the figure. The platform is
made to move in direction 30° above the horizontal with acceleration a so that the contact force
between the box and the platform becomes 3mg/2. Find the magnitude of the acceleration (m/s2).

5)

In a certain system of absolute units the acceleration produced by gravity in a body falling freely is
denoted by 4.9, the kinetic energy of a 20 kg shot moving with velocity 4 metres per second is
denoted by 100, and its momentum by 10. Then find unit of length (in meter). (acceleration due to
gravity = 9.8 m/s2)

6) Natural frequency 'ƒ' of sound wave in an organ pipe depends on 'ℓ' length of tube, 'ρ' density of

air, 'P' pressure of air. Frequency f can be related as f ∝ ℓaPbρc. Then is.

PART 2 : CHEMISTRY

SECTION-I

1) Which of the following statement(s) is/are correct?

(A) An atomic orbital is a 3-dimensional picture of movement of an electron inside an atom

(B) An atomic orbital is the wave function ψ for an electron in an atom.
From the values of ψ at different points within an atom, it is possible to predict the region
(C)
around the nucleus where electron will most probably be found.
The total probability of finding the electron in a given volume can be calculated by the sum of
(D)
all the products of ψ and the corresponding volume elements

2) Which of the following statement(s) is/are correct about following plot?

(A) This orbital wave function is associated with one radial node
(B) This orbital wave function is associated with zero radial node
(C) Radial node is at 0.2 nm
(D) This orbital wave function is associated with zero angular node

3) In a H-like sample electrons make transition from 4th excited state to 2nd state then

(A) 10 different spectral lines are observed

(B) 6 different spectral lines are observed
(C) number of lines belonging to the balmer series is 3
(D) Number of lines belonging to paschen series is 2.

4) The sum of IE1 and IE2 , IE3 and IE4 for element P and Q are given below :
IE1 + IE2 IE3 + IE4
(P) 2.45 8.82
(Q) 2.85 6.11
Then according to the given information the correct statement(s) is/are

(A) P2+ is more stable than Q2+

(B) Q2+ is less stable than P2+
(C) P4+ is more stable than Q4+
(D) Stability of both P4+ and Q4+ is same

5) Which of the following orders of atomic / Ionic radius is/are correct ?

(A) B < Ga < Aℓ

(B) Sc > Cu < Zn
(C) C < O < N
(D) Al+3 < Al+2 < Al+1

6) Which of the following is correct order of EA.

(A) N < C < O < F

(B) F > Cl > Br > I
(C) Cl > F > Br > I
(D) C < N < O < F
 SECTION-III

1) Total number of elements which have less IE1 than that of 'N'. Be, B, C, F, P, He

2) Atomic number of Ag is 47. In the same group the atomic numbers of elements placed above and
below Ag in long form of periodic table will be x and y respectively. Give the value of (x + y)/12.

3) What volume of a liquid (in L) will contain 10mole ? Molar mass of liquid is 280 g/mol and its
density is 1.4 g/mL.

4) In an atom, the total number of electrons having quantum numbers n = 4, & is

5) 92 g mixture of CaCO3 and MgCO3 heated strongly in an open vessel. After complete
decomposition of the carbonates it was found that the weight of residue left behind is 48 g. If the

mass of MgCO3 in the mixture is x gm, the value of is.

6) Number of spectral lines when e– jumps from 3rd shell to 1st shell:

SECTION-II

1) Given the first and second ionization potentials of helium (He) are 24.58 eV and 54.4 eV
respectively. Calculate the energy (kJ) erquired to produce one mole of He2+ ions.
1 eV = 96.49 kJ mol-1

2) Stopping potential [V volts] is plotted against frequency of light used [υ]. Find work function (eV).

(h = 6.62 × 10–34 J × s)

3) Flourine reacts with uranium to produce uranium hexafluoride, UF6, as represented by this
equation U(s) + 3F2(g) → UF6(g) If no. of fluorine molecules are required to produce 7.04 mg of
uranium hexafluoride, UF6, from an excess of uranium is y × 1019 then value of y is ? The molar
mass of UF6 is 352 gm/mol.
(NA = 6.022 × 1023)

4) Calculate mass of (H3PO4) phosphoric acid (in gm) required to obtain 53.4g pyrophosphoric acid
(H4P2O7) [H4P2O7 = 178] [H3PO4 = 98] 2H3PO4 → H4P2O7 + H2O
5) How many pairs are, in which first species has lower ionisation energy than second species.
(i) N and O (ii) Br and K (iii) Be and B (iv) I and I– (v) Li and Li+ (vi) O and S (vii) Ba and
Sr

6) How many of the following trend of ionisation energy is CORRECT ?

1. I.E1 : 0 > F > N
2. I.E1 : Mg > Al > Na
3. I. E1 : Li+ > Be > B
4. I.E1 : Al > Si > Mg
5. I.E1 : Na > Ne > Mg

PART 3 : MATHEMATICS

SECTION-I

1) a, b, c ∈ R, a ≠ 0 and the quadratic equation ax2 + bx + c = 0 has no real roots, then

(A) c(a + b + c) > 0

(B) a(a + b + c) > 0
(C) b(a + b + c) > 0
(D) c(a + b + c) < 0

2) If the quadratic equation x2 + 2ax + b(a – 1) = 0 has real roots for all real values of a, and b is an
integer, then which of the following is correct ?

(A) Greatest value of b is 4

(B) No such value of b is possible
(C) Least value of b is 0
(D) b can be any integer

3) In which of the following options, A ≠ B :

(A) A = {x : x + 2 = 3}, B = {x : x ∈ ℕ and is less than 2}

(B) A = {x : x ∈ ℕ and 3x – 1 < 2}, B = {x : x ∈ W and 3x – 1 < 2}
(C) A = {x : x ∈ ℕ and is prime factor of 36}, B = {1, 2, 3, 4, 6, 9, 12}
(D) A = {x : x ∈ I and x2 < 4}, B = {x : x ∈ R and x2 – 3x + 2 = 0}

4) Which of the following options are incorrect

(A) {2,3,4,5} and {3,6} are disjoint sets

(B) {a, e, i, o, u} and {a, b, c, d} are disjoint sets
(C) {2,6,10,14} and {3,7,11,15} are disjoint sets
(D) {2,6,10} and {3,7,11} are disjoint sets
5) If A ⊆ B then which of the following option(s) is/are correct ?

(A) A' ⊆ B'

(B) B' ⊆ A'
(C) A ∩ B' = ϕ
(D) A' ∩ B = ϕ

6) In a survey it was found that 21 people liked product A, 26 liked product B and 29 liked product
C. If 14 people liked products A and B. 12 people liked products C and A, 14 people liked products B
and C and 8 liked all the three products. Which of the following are correct?

(A) 11 people like C only

(B) 6 people like B only
(C) 15 people like exactly two products
(D) 20 people like exactly one product

SECTION-III

1) If α and β are roots of x2 – 21x + 4 = 0 and are roots of px2 + qx + 2 = 0, then value of of
(26p + q) is

2) Number of integral values of x simultaneously satisfying the system of inequalities

and is

3) Let P(x) be a cubic polynomial and α, β, γ are roots of equation P(x) = 0. If

, then the value of is equal to

4) If A = {5, 10}, B = (5, 10), C = (5, 10], D = [5, 10), E = [5, 10], then how many of the following
statements are incorrect ?
(i) n(A) + n(B) = 6 (ii) B = {6,7,8,9}
(iii) C = {6,7,8,9,10} (iv) n(C) + n(D) + n(E) = 16

5) If A and B are two sets such that n(A) = 150,

n(B) = 250 and n(A ∪ B) = 300. Then is

6) If , then the value of 12A is equal to

 SECTION-II

1) If x be a real number such that x3 + 4x = 8 then the value of expression x7 + 64x2 is

2) Let a, b, c and d be four roots of the equation x4 – 10x3 + 37x2 – 60x + 32 = 0.

, where p and q are co-prime numbers, then find the value of (p + q).

3) If = where a and b are natural number find (a + b).

4) If are roots of x2 – 2x + 4 = 0; then is equal to ?

5) The sum of value of 'a' so that x2 – 11x + a = 0 and x2 – 14x + 2a = 0 have a common root.

6) Quadratic Equation , have equal roots, then the value of

 ANSWER KEYS

PART 1 : PHYSICS

SECTION-I

Q. 1 2 3 4 5 6
A. B A,B,C B,C B,C A,C A,B,C,D

SECTION-III

Q. 7 8 9 10 11 12
A. 3 2 0 1 9 1

SECTION-II

Q. 13 14 15 16 17 18
A. 10.00 5.00 200.00 10.00 0.02 0.25

PART 2 : CHEMISTRY

SECTION-I

Q. 19 20 21 22 23 24
A. A,C,D A,D B,C,D A,B A,B,D A,C

SECTION-III

Q. 25 26 27 28 29 30
A. 4 9 2 6 6 3

SECTION-II

Q. 31 32 33 34 35 36
A. 7620.78 0.41 3.61 58.80 2.00 2.00

PART 3 : MATHEMATICS

SECTION-I

Q. 37 38 39 40 41 42
A. A,B A,C B,C,D A,B B,C A,B,D

SECTION-III

Q. 43 44 45 46 47 48
A. 9 1 7 4 1 2
 SECTION-II

Q. 49 50 51 52 53 54
A. 128.00 7.00 8.00 32.00 24.00 35.00
 SOLUTIONS

PART 1 : PHYSICS

1) 100 = Ma

&T=

2)

3)

ac = 0

20 – T = 10 × 1 ⇒ T = 10 N

4)

For equilibrium NA cos 60° + NB cos 30° = Mg

and Na sin 60° = NB sin 30°

On solving NB = NA ; NA =
5) For painter ;
.......(1)
For the system ;
.....(2)
where ; M = 50 kg

and ; R = 375 N.

6)

For any physical quantity; numerical value × unit = constant

For (A) n1u1 = n2u2

⇒ (500)

= = 0.5

For (B)

For (C)

=
= 3.6 × 10–4

For (D)

= = 0.36

7)

t' =

vavg =

vavg =
8)

(2t – 8) × 2 + 2t × 2 = 0
t = 2 sec

9)
or
or ....(1)
2
or 2x = 4(t – 2)

Now
∴ t=2
since velocity is 0 at t = 2 sec.
substituting t = 2 in equation (1),
x=0

10) For equilibrium

p = –3 & q = 3

11) =

n=9

12) &

13)
...(i)

...(ii)
 14) On 1kg, at moment of breaking from surface

15)
Resultant force on pulley =

= 200 Newton

16)

a=g

17) 4.9 LT–2 = 9.8 ms–2

100 ML2T–2 = kgm2s–2

–1 –1
10 MLT = 20 × 4 kg ms

18) [f] = [L]a[MT–2L–1]b[ML–3]c = [T–1]

[T]–1 = [L]a – b – 3c[M]b + c[T]–2b

b=

c=
a = –1

PART 2 : CHEMISTRY
19) (A) Picture of an electron cannot be captured. Orbital is a 3-dimensional graph (or function
called “wave function”)
(C) From the values of | ψ |2 (probability density) at different points within an atom, it is
possible to predict the region around the nucleus where electron will most probably be found.
(D) The total probability of finding the electron in a given volume can be calculated by the sum
of all the products of | ψ |2 (probability density) and the corresponding volume elements.

20) At 0.2 nm, wave function has a negative value. This is orbital wave function of 2s orbital.

Hence, zero angular node. (At 0.1 nm nearly)

21) For transition between n = 5 to n = 2

No. of spectral lines = 3 + 2 + 1 = 6
Balmer Paschen Brackett
5→2 5→3 5→4
4→2 4→3
3→2

22) Sum of IE1, and IE2 is lower for element P.

Sum of first four IE is lower for element Q.

23) C > N > O

24)

EA ⇒ Cl > F,
N<C

25)

Be, B, C and P have less IE1 than N

26)

Atomic number of Cu is 29 = x
Atomic number of Au is 79 = y
x + y = 108

= = 9.
27) Wt. of 10 mole =

Volume of 2800 gm liquid = 2000 mL = 2L.

28) n = 4, ,
1 2 3

since
∴ Total no. of

29)

CaCO3(s) —→ CaO(s) + CO2(g)

a mol —→ a mol
MgCO3(s) —→ MgO(s) + CO2(g)
b mol —→ b mol
92 g 48 g
7 × 100 a + 84 b + 92
25 × 56a + 40g = 48
7 × 25a + 147 b = 161

b= mol

Mass of MgCO3 = mol × 84 g/mol = 42 g.

30) No. of spectral lines = =

31) He2+ = 24.58 eV + 54.4 eV = 78.98 eV

78.98 × 96.49 kJ mol-1 = 7620.78

32)
∵ stopping potential Þ V = KE (in eV)
∵ E = ϕ + KE
⇒ hu = ϕ + KE(in eV)
From graph it is clear that at frequency (υ) = 1 × 1014 Hz,
stopping potential i.e., kinetic energy is zero
 Hence,
hυ = ϕ
6.62 × 10–34 × 1 × 1014 = ϕ
⇒ ϕ = 6.62 × 10–20 J

33) U + 3F2 → UF6

7.04 mg = 7.04 × 10–3 gm

moles of

molecules of F2 =
= 3.61 × 1019

34) 2H3PO4 H4P2O7 + H2O

53.4 gm

mass = 0.6 × 98
= 58.80 0.3 moles

35) Theory (v), (vii)

36)

(3) & (2) is correct.

PART 3 : MATHEMATICS

37) ax2 + bx + c = 0 has no real roots

So the sign of ax2 + bx + c will be either positive
or negative will depend on sign of a
If a is positive then the expression is positive
If a is negative then the expression is negative
so a(a + b + c) > 0 {put x =1 in the expression}
when x = 0 then the expression has the same sign as c
so c(a + b + c) > 0{put x = 1 in the expression}

38) For real roots 4a2 – 4b(a – 1) ≥ 0

⇒ a2 – ba + b ≥ 0
Now for above inequality to hold for all values of a, b2 – 4b ≤ 0.
or 0 ≤ b ≤ 4.

39)

(A) A = {x : x + 2 = 3}
A = {1}
B = {x : x ∈ ℕ and is less than 2}
B = {1}
A=B
(B) A = {x : x ∈ ℕ and 3x – 1 < 2}
3x – 1 < 2 ⇒ x < 1
A=ϕ
B = {x : x ∈ W and 3x – 1 < 2}
3x – 1 < 2
x<1
B = {0}
A≠B
(C) A = {x : x ∈ ℕ and is prime factor of 36}
A = {2, 3}
B = {1, 2, 3, 4, 6, 9, 12}
A≠B
(D) A = {x : x ∈ I and x2 ≤ 4}
⇒ x2 – 4 ≤ 0
⇒ (x – 2)(x + 2) ≤ 0
⇒ x ∈ [–2, 2]
A = {–2, –1, 0, 1, 2}
B = {x : x ∈ ℝ and x2 – 3x + 2 = 0}
⇒ x2 – 3x + 2 = 0
⇒ (x – 2)(x – 1) = 0
⇒ x = 1, 2
B = {1, 2}
A≠B
Option B, C, D are correct

40)

(A) {2,3,4,5} and {3,6} have one element common which is ‘3’ therefore they are not disjoint
sets.
(B) {a, e ,i, o, u} and {a, b, c, d} have one element common which is ‘a’ therefore they are not
disjoint sets.
(C) {2,6,10,14} and {3,7,11,15} have no element in common therefore they are disjoint sets.
(D) {2,6,10} and {3,7,11} have no element in common therefore they are disjoint sets.
41) (A)

(B)

(C)

(D)
∵ option B,C are correct

42)

Let, no. of people liking product A = n(A) = 21

no. of people liking product B = n(B) = 26
no. of people liking product C = n(C) = 29
given, n(A∩B)=14,n(B∩C)=14,n(A∩C)=12,n(A∩B∩C)=8.

⇒ no. of people liking C only = 11

no. of people liking B only = 6
no. of people liking exactly one product = 3 + 6 + 11 = 20
no. of people liking exactly two products = 4 + 6 + 6 = 16.

43)
αβ = 4
then we get
∴ required equation 4x2 – 95x + 2 = 0

44)
......(1)

⇒
x ∈ (–∞, 1) ..........(2)
Taking intersection of (1) and (2)

x ∈ (–1, 1)

45) Let P(x) = k(x – α)(x – β)(x – γ)

put , &x=0

46)

A={5, 10}, B=(5, 10), c =(5, 10]

D=[5, 10), E=[5, 10]
n(A)=2
In B there is infinite number of elements.
Same is true for C, D and E.
So all four are incorrect.

47)

n(A) = 150, n(B) = 250, n(A ∪ B) = 300

n(A ∪ B) = n(A) + n(B) – n(A ∩ B)
⇒ 300 = 150 + 250 – n(A ∩ B)
n(A ∩ B) = 100
n(A – B) = 50
n(B – A) = 150

Then,
48)

Let

x=3

y = 3, –2 (reject)
12A = 2

49) x3 + 4x = 8

50) (x2 – 5x + 10)(x2 –5x + 2) + 12 = 0

(x2 – 5x + 10)(x2 –5x + 10 – 8) + 12 = 0
x2 – 5x + 10 = 2, 6

∴
∴ p+q=7

51) =

= =

= =
a = 6; b = 2 ⇒ a + b = 8

52)

= 64 – 32 = 32

53)
Given equation are x2 – 11x + a = 0 …....... (i)
x2 –14x + 2a = 0 ......… (ii)
Multiplying equation (i) by 2 and then subtracting, we get x2 – 8x = 0 ⇒ x = 0, 8
If x = 0, a = 0 If x = 8, a = 24
Sum of values of a = 24 + 0 = 24

54) D = 0