Version: 4.

1
Revision Date: 03/08/2024

SAFETY DATA SHEET

1. Identification

Material name: QWIKJOINT UVR

Material: 693HP 5A

Recommended use and restriction on use

Recommended use: Curative
Restrictions on use: Not known.

Manufacturer/Importer/Supplier/Distributor Information
EUCLID CHEMICAL COMPANY
19218 REDWOOD ROAD
CLEVELAND OH 44110
US

Contact person: EH&S Department

Telephone: 216-531-9222
Emergency telephone number: 1-800-424-9300 (US); 1-613-996-6666 (Canada)

2. Hazard(s) identification

Hazard Classification
Health Hazards
Acute toxicity (Inhalation - vapor) Category 4
Acute toxicity (Inhalation - dust and Category 4
mist)
Skin Corrosion/Irritation Category 2
Serious Eye Damage/Eye Irritation Category 2A
Respiratory sensitizer Category 1
Skin sensitizer Category 1
Carcinogenicity Category 2
1.
Specific Target Organ Toxicity - Category 3
Single Exposure
Specific Target Organ Toxicity - Category 2
Repeated Exposure

Target Organs
1. Respiratory tract irritation.

Unknown toxicity - Health

Acute toxicity, oral 13.18 %
Acute toxicity, dermal 13.18 %
Acute toxicity, inhalation, vapor 70.7 %
Acute toxicity, inhalation, dust 70.7 %
or mist

Label Elements
1/14
000000018703
 Version: 4.1
Revision Date: 03/08/2024

Hazard Symbol:

Signal Word: Danger

Hazard Statement: Harmful if inhaled.

Causes skin irritation.
Causes serious eye irritation.
May cause allergy or asthma symptoms or breathing difficulties if inhaled.
May cause an allergic skin reaction.
Suspected of causing cancer.
May cause respiratory irritation.
May cause damage to organs through prolonged or repeated exposure.

Precautionary
Statements

Prevention: Use only outdoors or in a well-ventilated area. Wash thoroughly after

handling. Wear protective gloves/ protective clothing/ eye protection/ face
protection. [In case of inadequate ventilation] wear respiratory protection.
Contaminated work clothing should not be allowed out of the workplace.
Obtain special instructions before use. Do not handle until all safety
precautions have been read and understood. Use personal protective
equipment as required. Do not breathe dust/fume/gas/mist/vapors/spray.

Response: IF INHALED: Remove person to fresh air and keep comfortable for
breathing. If experiencing respiratory symptoms: Call a POISON CENTER
or doctor/ physician. IF IN EYES: Rinse cautiously with water for several
minutes. Remove contact lenses, if present and easy to do. Continue
rinsing. If eye irritation persists: Get medical advice/attention. IF ON SKIN:
Wash with plenty of soap and water. If skin irritation or rash occurs: Get
medical advice/attention. Call a POISON CENTER/doctor if you feel unwell.
Specific treatment (see on this label). Wash contaminated clothing before
reuse.

Storage: Store locked up. Store in a well-ventilated place. Keep container tightly
closed.

Disposal: Dispose of contents/container to an appropriate treatment and disposal

facility in accordance with applicable laws and regulations, and product
characteristics at time of disposal.

Hazard(s) not otherwise None.

classified (HNOC):

3. Composition/information on ingredients

2/14
000000018703
 Version: 4.1
Revision Date: 03/08/2024

Mixtures

Chemical Identity CAS number Content in percent (%)*

4,4'-Methylene bis(phenylisocyanate) 101-68-8 10 - <20%

Diphenylmethane diisocyanate 26447-40-5 10 - <20%
* All concentrations are percent by weight unless ingredient is a gas. Gas concentrations are in percent by volume.

4. First-aid measures
Description of necessary first-aid measures

Inhalation: Call a physician or poison control center immediately. If breathing

stops, provide artificial respiration. Move to fresh air. If breathing is
difficult, give oxygen.

Skin Contact: Get medical attention. Destroy or thoroughly clean contaminated

shoes. Immediately remove contaminated clothing and shoes and
wash skin with soap and plenty of water. If skin irritation or an allergic
skin reaction develops, get medical attention.

Eye contact: Immediately flush with plenty of water for at least 15 minutes. If easy
to do, remove contact lenses. Get medical attention.

Ingestion: Call a POISON CENTER/doctor if you feel unwell. Rinse mouth.

Personal Protection for First- Self-contained breathing apparatus and full protective clothing must
aid Responders: be worn in case of fire.

Most important symptoms/effects, acute and delayed

Symptoms: Prolonged or repeated contact with skin may cause redness, itching,
irritation and eczema/chapping. Respiratory tract irritation.

Hazards: No data available.

Indication of immediate medical attention and special treatment needed

Treatment: Symptoms may be delayed.

5. Fire-fighting measures

General Fire Hazards: No unusual fire or explosion hazards noted.

Suitable (and unsuitable) extinguishing media

Suitable extinguishing Use fire-extinguishing media appropriate for surrounding materials.

media:

Unsuitable extinguishing Do not use water jet as an extinguisher, as this will spread the fire.
media:

Specific hazards arising from During fire, gases hazardous to health may be formed.
the chemical:

3/14
000000018703
 Version: 4.1
Revision Date: 03/08/2024

Special protective equipment and precautions for fire-fighters

Special fire-fighting No data available.

procedures:

Special protective equipment Self-contained breathing apparatus and full protective clothing must be
for fire-fighters: worn in case of fire.

6. Accidental release measures

Personal precautions, Ventilate closed spaces before entering them. Evacuate area. See Section
protective equipment and 8 of the SDS for Personal Protective Equipment. Keep upwind. Keep
emergency procedures: unauthorized personnel away. Do not touch damaged containers or spilled
material unless wearing appropriate protective clothing.

Accidental release measures: In the event of a spill or accidental release, notify relevant authorities in
accordance with all applicable regulations.

Methods and material for Dam and absorb spillages with sand, earth or other non-combustible
containment and cleaning material. Collect spillage in containers, seal securely and deliver for
up: disposal according to local regulations.

Environmental Precautions: Do not contaminate water sources or sewer. Prevent further leakage or
spillage if safe to do so.

7. Handling and storage

Handling

Technical measures (e.g. Local Observe good industrial hygiene practices. Observe occupational exposure
and general ventilation): limits and minimize the risk of inhalation of vapors and mist. Mechanical
ventilation or local exhaust ventilation may be required.

Safe handling advice: Provide adequate ventilation. Wear appropriate personal protective
equipment. Observe good industrial hygiene practices.Do not handle until
all safety precautions have been read and understood. Obtain special
instructions before use. Use personal protective equipment as required.
Avoid contact with eyes. Wash hands thoroughly after handling. Do not
breathe dust/fume/gas/mist/vapors/spray. Avoid contact with skin. Avoid
contact with eyes, skin, and clothing.

Contact avoidance measures: No data available.

Hygiene measures: Observe good industrial hygiene practices. Wash hands before breaks and
immediately after handling the product. Avoid contact with eyes. Wash
contaminated clothing before reuse. Avoid contact with skin. Contaminated
work clothing should not be allowed out of the workplace.

Storage

Safe storage conditions: Store locked up.

Safe packaging materials: No data available.

4/14
000000018703
 Version: 4.1
Revision Date: 03/08/2024

8. Exposure controls/personal protection

Control Parameters
Occupational Exposure Limits
Chemical Identity Type Exposure Limit Values Source

4,4'-Methylene TWA 0.005 ppm US. ACGIH Threshold Limit Values, as

bis(phenylisocyanate) amended (2008)
Ceiling 0.02 ppm 0.2 mg/m3 US. OSHA Table Z-1 Limits for Air
Contaminants (29 CFR 1910.1000), as
amended (02 2006)

Chemical name Type Exposure Limit Values Source

4,4'-Methylene CEILING 0.01 ppm Canada. British Columbia OELs: Table of

bis(phenylisocyanate) Exposure Limits for Chemical Biological
Substances (Workers Compensation Board);
as amended (07 2007)
TWA 0.005 ppm Canada. British Columbia OELs: Table of
Exposure Limits for Chemical Biological
Substances (Workers Compensation Board);
as amended (07 2007)
4,4'-Methylene TWA 0.005 ppm Canada. Ontario OELs. (Control of Exposure to
bis(phenylisocyanate) Biological or Chemical Agents), as amended
(06 2015)
CEV 0.02 ppm Canada. Ontario OELs. (Control of Exposure to
Biological or Chemical Agents), as amended
(06 2015)
4,4'-Methylene TWA 0.005 ppm 0.051 mg/m3 Canada. Quebec OELs. (Ministry of Labor -
bis(phenylisocyanate) Regulation respecting occupational health and
safety), as amended (09 2017)
Diphenylmethane TWA 0.005 ppm Canada. British Columbia OELs: Table of
diisocyanate Exposure Limits for Chemical Biological
Substances (Workers Compensation Board);
as amended (07 2007)
CEILING 0.01 ppm Canada. British Columbia OELs: Table of
Exposure Limits for Chemical Biological
Substances (Workers Compensation Board);
as amended (07 2007)

Chemical name Type Exposure Limit Values Source

4,4'-Methylene CEILING 0.01 ppm Canada. British Columbia OELs: Table of

bis(phenylisocyanate) Exposure Limits for Chemical Biological
Substances (Workers Compensation Board);
as amended (07 2007)
TWA 0.005 ppm Canada. British Columbia OELs: Table of
Exposure Limits for Chemical Biological
Substances (Workers Compensation Board);
as amended (07 2007)
4,4'-Methylene TWA 0.005 ppm Canada. Ontario OELs. (Control of Exposure to
bis(phenylisocyanate) Biological or Chemical Agents), as amended
(06 2015)
CEV 0.02 ppm Canada. Ontario OELs. (Control of Exposure to
Biological or Chemical Agents), as amended
(06 2015)

5/14
000000018703
 Version: 4.1
Revision Date: 03/08/2024

4,4'-Methylene TWA 0.005 ppm 0.051 mg/m3 Canada. Quebec OELs. (Ministry of Labor -
bis(phenylisocyanate) Regulation respecting occupational health and
safety), as amended (09 2017)
Diphenylmethane TWA 0.005 ppm Canada. British Columbia OELs: Table of
diisocyanate Exposure Limits for Chemical Biological
Substances (Workers Compensation Board);
as amended (07 2007)
CEILING 0.01 ppm Canada. British Columbia OELs: Table of
Exposure Limits for Chemical Biological
Substances (Workers Compensation Board);
as amended (07 2007)

Appropriate Engineering Observe good industrial hygiene practices. Observe occupational exposure
Controls limits and minimize the risk of inhalation of vapors and mist. Mechanical
ventilation or local exhaust ventilation may be required.

Individual protection measures, such as personal protective equipment

Eye/face protection: Wear safety glasses with side shields (or goggles).

Skin Protection
Hand Protection: Additional Information: Use suitable protective gloves if risk of skin contact.

Skin and Body Protection: Wear chemical-resistant gloves, footwear, and protective clothing
appropriate for the risk of exposure. Contact health and safety professional
or manufacturer for specific information.

Respiratory Protection: If engineering controls do not maintain airborne concentrations below

recommended exposure limits (where applicable) or to an acceptable level
(in countries where exposure limits have not been established), an
approved respirator must be worn. Air-purifying respirator with an
appropriate, government approved (where applicable), air-purifying filter,
cartridge or canister. Contact health and safety professional or
manufacturer for specific information.

Hygiene measures: Observe good industrial hygiene practices. Wash hands before breaks and
immediately after handling the product. Avoid contact with eyes. Wash
contaminated clothing before reuse. Avoid contact with skin. Contaminated
work clothing should not be allowed out of the workplace.

9. Physical and chemical properties

Appearance
Physical state: liquid
Form: liquid
Color: Colorless
Odor: Mild
Odor threshold: No data available.
pH: No data available.
Melting point/freezing point: No data available.
Initial boiling point and boiling range: No data available.

6/14
000000018703
 Version: 4.1
Revision Date: 03/08/2024

Flash Point: 163 °C 325 °F(Setaflash Closed Cup)

Evaporation rate: Slower than Ether
Flammability (solid, gas): No
Upper/lower limit on flammability or explosive limits
Flammability limit - upper (%): No data available.
Flammability limit - lower (%): No data available.
Explosive limit - upper: No data available.
Explosive limit - lower: No data available.
Vapor pressure: No data available.
Vapor density: Vapors are heavier than air and may travel along the floor and
in the bottom of containers.
Relative density: 1.05
Solubility(ies)
Solubility in water: Practically Insoluble
Solubility (other): No data available.
Partition coefficient (n-octanol/water): No data available.

Auto-ignition temperature: No data available.

Decomposition temperature: No data available.
Viscosity: No data available.

10. Stability and reactivity

Reactivity: No data available.

Chemical Stability: Material is stable under normal conditions.

Possibility of hazardous No data available.

reactions:

Conditions to avoid: Avoid heat or contamination.

Incompatible Materials: Alcohols. Amines. Strong acids. Strong bases. Water, moisture.

Hazardous Decomposition Thermal decomposition or combustion may liberate carbon oxides and
Products: other toxic gases or vapors.

11. Toxicological information

Information on likely routes of exposure

Inhalation: In high concentrations, vapors, fumes or mists may irritate nose, throat and
mucus membranes.

Skin Contact: Causes skin irritation. May cause an allergic skin reaction.

Eye contact: Causes serious eye irritation.

Ingestion: May be ingested by accident. Ingestion may cause irritation and malaise.

Symptoms related to the physical, chemical and toxicological characteristics

7/14
000000018703
 Version: 4.1
Revision Date: 03/08/2024

Inhalation: No data available.

Skin Contact: No data available.

Eye contact: No data available.

Ingestion: No data available.

Information on toxicological effects

Acute toxicity (list all possible routes of exposure)

Oral
Product: Not classified for acute toxicity based on available data.

Specified substance(s):
4,4'-Methylene LD 50 (Rat): > 31,600 mg/kg
bis(phenylisocyanate)

Dermal
Product: Not classified for acute toxicity based on available data.

Inhalation
Product: ATEmix: 11 mg/l
ATEmix : 1.5 mg/l

Repeated dose toxicity

Product: No data available.

Skin Corrosion/Irritation
Product: No data available.

Specified substance(s):
4,4'-Methylene in vivo (Rabbit): Irritating , 24 - 72 h
bis(phenylisocyanate)

Serious Eye Damage/Eye Irritation

Product: No data available.

Respiratory or Skin Sensitization

Product: May cause allergy or asthma symptoms or breathing difficulties if inhaled.
May cause sensitization by inhalation.

Carcinogenicity
Product: Suspected of causing cancer.

8/14
000000018703
 Version: 4.1
Revision Date: 03/08/2024

IARC Monographs on the Evaluation of Carcinogenic Risks to Humans:

No carcinogenic components identified

US. National Toxicology Program (NTP) Report on Carcinogens:

No carcinogenic components identified

US. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1053), as amended:

No carcinogenic components identified

Germ Cell Mutagenicity

In vitro
Product: No data available.

In vivo
Product: No data available.

Reproductive toxicity
Product: No data available.

Specific Target Organ Toxicity - Single Exposure

Product: No data available.

Specific Target Organ Toxicity - Repeated Exposure

Product: No data available.

Target Organs
Specific Target Organ Toxicity - Single Exposure: Respiratory tract irritation.

Aspiration Hazard
Product: No data available.

Other effects: No data available.

12. Ecological information

Ecotoxicity:

Acute hazards to the aquatic environment:

Fish
Product: No data available.

Specified substance(s):
4,4'-Methylene LC 0 (Oryzias latipes, 96 h): > 3,000 mg/l Experimental result, Key study
bis(phenylisocyanate)

Aquatic Invertebrates
9/14
000000018703
 Version: 4.1
Revision Date: 03/08/2024

Product: No data available.

Chronic hazards to the aquatic environment:

Fish
Product: No data available.

Aquatic Invertebrates
Product: No data available.

Specified substance(s):
4,4'-Methylene NOAEL (Daphnia magna): >= 10 mg/l read-across based on grouping of
bis(phenylisocyanate) substances (category approach) Read-across based on grouping of
substances (category approach), Key study

Toxicity to Aquatic Plants

Product: No data available.

Persistence and Degradability

Biodegradation
Product: No data available.

BOD/COD Ratio
Product: No data available.

Bioaccumulative potential
Bioconcentration Factor (BCF)
Product: No data available.

Specified substance(s):
4,4'-Methylene Cyprinus carpio, Bioconcentration Factor (BCF): 200 Aquatic sediment
bis(phenylisocyanate) Experimental result, Key study

Partition Coefficient n-octanol / water (log Kow)

Product: No data available.

Specified substance(s):
4,4'-Methylene Log Kow: 5.22
bis(phenylisocyanate)

Mobility in soil: No data available.

Other adverse effects: No data available.

13. Disposal considerations

Disposal methods: Dispose of waste at an appropriate treatment and disposal facility in

accordance with applicable laws and regulations, and product
characteristics at time of disposal.
10/14
000000018703
 Version: 4.1
Revision Date: 03/08/2024

Contaminated Packaging: No data available.

14. Transport information

TDG:

Not Regulated

CFR / DOT:

Not Regulated

IMDG:

Not Regulated

Further Information:
The above shipping description may not be accurate for all container sizes and all modes of transportation.
Please refer to Bill of Lading.

15. Regulatory information

US Federal Regulations
TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D)
None present or none present in regulated quantities.

US. Toxic Substances Control Act (TSCA) Section 5(a)(2) Proposed Significant New Use Rules
(SNURs) (40 CFR 721, Subpt E)
None present or none present in regulated quantities.

US. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1053), as amended

None present or none present in regulated quantities.

CERCLA Hazardous Substance List (40 CFR 302.4):

Chemical Identity Reportable quantity
4,4'-Methylene 5000 lbs.
bis(phenylisocyanate)

Superfund Amendments and Reauthorization Act of 1986 (SARA)

Hazard categories
Immediate (Acute) Health Hazards
Delayed (Chronic) Health Hazard
Acute toxicity (any route or exposure)
Skin Corrosion or Irritation
Serious eye damage or eye irritation
Respiratory or Skin Sensitization
Carcinogenicity
Specific target organ toxicity (single or repeated exposure)

11/14
000000018703
 Version: 4.1
Revision Date: 03/08/2024

US. EPCRA (SARA Title III) Section 304 Extremely Hazardous Substances Reporting Quantities and
the Comprehensive Environmental Response, Compensation, and Liability Act (CERCLA) Hazardous
Substances

US. EPCRA (SARA Title III Section 313 Toxic Chemical Release Inventory (TRI) Reporting
Chemical Identity % by weight
4,4'-Methylene 1.0%
bis(phenylisocyanate)

Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR 68.130)
None present or none present in regulated quantities.

Clean Water Act Section 311 Hazardous Substances (40 CFR 117.3)
None present or none present in regulated quantities.

US State Regulations

US. California Proposition 65

No ingredient requiring a warning under CA Prop 65.

International regulations

Montreal protocol
Not applicable

Stockholm convention
Not applicable

Rotterdam convention
Not applicable

Kyoto protocol
Not applicable

VOC: When appropriately mixed with the other part, product has a VOC less water and exempt solvent of:
< 5 g/l

Regulatory VOC (less water and : 0 g/l

exempt solvent)
VOC Method 310 : 0.00 %

12/14
000000018703
 Version: 4.1
Revision Date: 03/08/2024

Inventory Status:
Australia AICS: All components in this product are
listed on or exempt from the
Inventory.

Canada DSL Inventory List: All components in this product are

listed on or exempt from the
Inventory.

EC Inventory: One or more components in this

product are not listed on or exempt
from the Inventory.

Japan (ENCS) List: One or more components in this

product are not listed on or exempt
from the Inventory.

China Inv. Existing Chemical All components in this product are

Substances: listed on or exempt from the
Inventory.

Korea Existing Chemicals Inv. (KECI): All components in this product are
listed on or exempt from the
Inventory.

Canada NDSL Inventory: One or more components in this

product are not listed on or exempt
from the Inventory.

Philippines PICCS: All components in this product are

listed on or exempt from the
Inventory.

US TSCA Inventory: All components in this product are

listed on or exempt from the
Inventory.

New Zealand Inventory of Chemicals: All components in this product are

listed on or exempt from the
Inventory.

Japan ISHL Listing: One or more components in this

product are not listed on or exempt
from the Inventory.

Japan Pharmacopoeia Listing: One or more components in this

product are not listed on or exempt
from the Inventory.

13/14
000000018703
 Version: 4.1
Revision Date: 03/08/2024

16.Other information, including date of preparation or last revision

Revision Date: 03/08/2024

Version #: 4.1

Further Information: No data available.

Disclaimer: For Industrial Use Only. Keep out of Reach of Children. The hazard
information herein is offered solely for the consideration of the user, subject
to their own investigation of compliance with applicable regulations, including
the safe use of the product under every foreseeable condition.

14/14
000000018703