PRODUCT NAME PAGE

Material Safety Data Sheet LONG #2 Spray (1/ 8 )

SECTION 1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Identity (Trade Name As Used On Label); LONG #2 Spray

Recommended use of the chemical and restrictions on use; Long-termRust-Preventer
Manufacturer Name /Address;
NAMBANG CNA CO., LTD. / 204, Chupalsandan 1-gil, Paengseong-eup, Pyeongtaek-si, GyeongGi-do,
17998, Korea
TEL : 82 31 651 5911~8 FAX : 82 31 691 6441 / 82 31 658 6441

SECTION 2. HAZARD IDENTIFICATION

Hazard Class

Hazard Class Hazard category

Flammable aerosols 1

Flammable gases 1

Gases under pressure Liquefied gas

Flammable liquids 2

Skin corrosion / skin irritation 2

Serious eye damage/eye irritation 2

Sensitization-Skin 1

Aspiration hazard 1

GHS label elements, including precautionary statements

Category Indication

Symbol

Signal word Danger

H222 Extremely flammable aerosol.
H229 Pressurized container: may burst if heated.
H220 Extremely flammable gas.
Hazard statement H280 Contains gas under pressure; may explode if heated.
H225 Highly flammable liquid and vapour.
H315 Causes skin irritation.
H319 Causes serious eye irritation.
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LONG #2 Spray ( 2 / 8 )

H317 May cause an allergic skin reaction.

H304 May be fatal if swallowed and enters airways.
P210 Keep away from heat/sparks/open flames/hot surfaces. No
smoking.
P211 Do not spray on an open flame or other ignition source.
P233 Keep container tightly closed.
P240 Ground/Bond container and receiving equipment.
P241 Use explosion-proof electrical/ventilating/lighting/.../equipment.
P242 Use only non-sparking tools.
Prevention P243 Take precautionary measures against static discharge.
P251 Do not pierce or burn, even after use.
P261 Avoid breathing dust/fume/gas/mist/vapours/spray.
P264 Wash … thoroughly after handling.
P272 Contaminated work clothing should not be allowed out of the
workplace.
P280 Wear protective gloves/protective clothing/eye protection/face
protection.
P301+P310 IF SWALLOWED: Immediately call a POISON CENTER/
doctor/...
P302+P352 IF ON SKIN: Wash with plenty of water/…
P303+P361+P353 IF ON SKIN (or hair): Take off immediately all
Precautionary contaminated clothing. Rinse skin with water/shower.
statements P305+P351+P338 IF IN EYES: Rinse cautiously with water for several
minutes. Remove contact lenses, if present and easy to do. Continue
rinsing.
P321 Specific treatment (see ... on this label)
Response
P331 Do NOT induce vomiting.
P332+P313 If skin irritation occurs: Get medical advice/attention.
P333+P313 If skin irritation or rash occurs: Get medical advice/attention.
P337+P313 If eye irritation persists: Get medical advice/attention.
P362+P364 Take off contaminated clothing and wash it before reuse.
P370+P378 In case of fire: Use ... to extinguish.
P377 Leaking gas fire: Do not extinguish, unless leak can be stopped
safely.
P381 Eliminate all ignition sources if safe to do so.
P403+P235 Store in a well-ventilated place. Keep cool.
P405 Store locked up.
Storage P410+P403 Protect from sunlight. Store in a well-ventilated place.
P410+P412 Protect from sunlight. Do not expose to temperatures
exceeding 50 ºC/122 ºF.
P501 Dispose of contents/container to...… in accordance with
Disposal
local/regional/national/international regulations (to be specified).

Other hazards which do not result in classification : No information found

SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS

CHEMICAL NAME OTHER NAME CAS NUMBER Content (%)

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LONG #2 Spray ( 3 / 8 )

Petrolatum(petroleum) Oxidized, calcium salt - 68425-34-3 1~10

Polybutene - 9003-29-6 0.1~0.2
Sulfonic acids, petroleum, calcium salts - 61789-86-4 1~5
Distillates(petroleum), hydrotreated light - 64742-47-8 1~5
Methylcyclohexane - 108-87-2 1~10
3-Methylhexane - 589-34-4 1~5
2-Methylhexane - 591-76-4 1~5
1,2-Dimethylcyclopentane - 2452-99-5 1~3
1,3-Dimethylcyclopentane - 2453-00-1 1~3
Heptane - 142-82-5 0.1~0.9
Propane - 74-98-6 10~20
Butane - 106-97-8 50~60

SECTION 4. FIRST AID PROCEDURES

Eye contact; Check for and remove any contact lenses. Immediately flush eyes with plenty of water for
at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical attention immediately.
Skin contact; In case of contact, immediately flush skin with plenty of water for at least 15 minutes while
removing contaminated clothing and shoes. Wash clothing before reuse. Clean shoes thoroughly before
reuse. Get medical attention immediately.
Inhalation; Move exposed person to fresh air. If not breathing, if breathing is irregular or if respiratory
arrest occurs, provide artificial respiration or oxygen by trained personnel. Loosen tight clothing such as
a collar, tie, belt or waistband. Get medical attention immediately.
Ingestion; Call medical doctor or poison control center immediately. Wash out mouth with water. Do not
induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an
unconscious person. Get medical attention immediately.
Indication of immediate medical attention and notes for physician; Consult a physician. Show this safety
data sheet to the doctor in attendance.

SECTION 5. FIRE-FIGHTING MEASURES

Suitable (and unsuitable) extinguishing media; Use water spray to keep fire exposed containers cool. If
substance does ignite, use CO2, dry chemical or foam.
Specific hazards arising from the chemical (e.g. nature of any hazardous combustion products); No
information found
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Special protective equipment and precautions for fire fighters; In the event of a fire, wear full protective
clothing and NIOSH-approved self-contained breathing apparatus with full face-piece operated in the
pressure demand or other positive pressure mode. Combustion by-products include phosgene and
hydrogen chloride gases. Structural firefighters' clothing provides only limited protection to the
combustion products of this material.

SECTION 6. ACCIDENTAL RELEASE MEASURES

Personal precautions, protective equipment and emergency procedures; No action shall be taken involving
any personal risk or without suitable training. Evacuate surrounding areas. Keep unnecessary and
unprotected personnel from entering. Do not touch or walk through spilled material. Shut off all ignition
sources. No flares, smoking or flames in hazard area. Do not breathe vapor or mist. Provide adequate
ventilation. Wear appropriate respirator when ventilation is inadequate. Put on appropriate personal
protective equipment (see section 8).
Environmental precautions and protective procedures; Avoid dispersal of spilled material and runoff and
contact with soil, waterways, drains and sewers. Inform the relevant authorities if the product has caused
environmental pollution (sewers, waterways, soil or air).
Methods and materials for containment and cleaning up; Stop leak if without risk. Move containers from
spill area. Approach release from upwind. Prevent entry into sewers, water courses, basements or
confined areas. Contain and collect spillage with non-combustible, absorbent material e.g. sand, earth,
vermiculite or diatomaceous earth and place in container for disposal according to local regulations (see
section 13). Use spark-proof tools and explosion-proof equipment. Dispose of via a licensed waste
disposal contractor. Contaminated absorbent material may pose the same hazard as the spilled product.
Note: see section 1 for emergency contact information and section 13 for waste disposal. Dilute with
water and mop up if water-soluble or absorb with an inert dry material and place in an appropriate waste
disposal container.

SECTION 7. HANDLING AND STORAGE

Precautions for safe handling; Vapors may form explosive mixtures with air. Do not smoke. Take
precautionary measures against static discharges. All equipment used when handling the product must
be grounded. Use only in area provided with appropriate exhaust ventilation. Wear personal protective
equipment. Avoid prolonged exposure. Wash thoroughly after handling. DO NOT handle, store or open
near an open flame, sources of heat or sources of ignition. Protect material from direct sunlight. Use
non-sparking tools and explosion-proof equipment.
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LONG #2 Spray ( 5 / 8 )

Conditions for safe storage (including any incompatibilities); Store in cool place. Store in a well-ventilated
place. Keep container tightly closed. Keep away from heat, sparks and open flame. Outside or detached
storage preferred. The pressure in sealed containers can increase under the influence of heat. This
material can accumulate static charge which may cause spark and become an ignition source. Prevent
electrostatic charge build-up by using common bonding and grounding techniques. Keep in an area
equipped with sprinklers. Keep out of the reach of children. Keep from contact with oxidizing materials.

SECTION 8. EXPOSURE CONTROLS / PERSONAL PROTECTION

Control parameters (e.g. occupational exposure limit values, biological limit values);
Distillates(petroleum), hydrotreated light; TWA 200 ㎎/㎥ (skin)
Methylcyclohexane); TWA 400 ppm
Engineering controls; Good general ventilation (typically 10 air changes per hour) should be used.
Ventilation rates should be matched to conditions. If applicable, use process enclosures, local exhaust
ventilation,or other engineering controls to maintain airborne levels below recommended exposure limits.
If exposure limits have not been established, maintain airborne levels to an acceptable level. Explosion-
proof general and local exhaust ventilation.
Personal protective equipment;
- Eye / face protection; Safety eyewear complying with an approved standard should be used when a
risk assessment indicates this is necessary to avoid exposure to liquid splashes, mists or dusts.
Recommended: splash goggles.
- Skin protection; Personal protective equipment for the body should be selected based on the task being
performed and the risks involved and should be approved by a specialist before handling this product.
Recommended: lab coat.
- Respiratory protection; Use a properly fitted, air-purifying or air-fed respirator complying with an
approved standard if a risk assessment indicates this is necessary. Respirator selection must be based
on known or anticipated exposure levels, the hazards of the product and the safe working limits of the
selected respirator.

SECTION 9. PHYSICAL / CHEMICAL CHARACTERISTICS

Appearance; Dark brown opaque

Odor; Oil odor
Odour threshold; No information found
Ph; No information found
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LONG #2 Spray ( 6 / 8 )

Melting point/freezing point; No information found

Initial boiling point and boiling range; Liquid; >35℃
Flash point; ; <-105℃(c.c.)(Propane) / Liquid; >-18℃
Evaporation rate; No information found
Flammability (solid, gas); No information found
Upper/lower flammability or explosive limits; 9.5 / 2.1 %(Propane)
Vapour pressure; No information found
Vapour density; No information found
Specific Gravity (H2O = 1); 0.77 ± 0.05
Relative density; No information found
Solubility(ies); Insoluble
Partition coefficient; n-octanol/water; Methylcyclohexane 3.88
Auto-ignition temperature; No information found
Decomposition temperature; No information found
Viscosity; No information found
Molecular Weight; No information found

SECTION 10. STABILITY AND REACTIVITY

Chemical stability and possibility of hazardous reactions; Stable under ordinary conditions of use and
storage
Conditions to avoid (e.g. static discharge, shock or vibration, etc); Heat, flames and sparks. Incompatible
materials.
Incompatability (Materials to Avoid); Strong oxidizing agents.
Hazardous Decomposition Products; carbon oxide

SECTION 11. TOXICOLOGICAL INFORMATION

- Polybutene -
Information on the likely routes of exposure; No information found
Acute toxicity
- Oral; LD50 >34600 ㎎/㎏ Rat
- Dermal; LD50 >10250 ㎎/㎏ Rabbit
- Inhalation; Vapor LC50 >0.85 ㎎/ℓ Rat
Skin corrosion/irritation; No information found
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LONG #2 Spray ( 7 / 8 )

Serious eye damage/irritation; No information found

Respiratory or skin sensitization; No information found
Germ cell mutagenicity; No information found
Carcinogenicity; No information found
Reproductive toxicity; No information found
Specific target organ toxicity (single exposure); No information found
Specific target organ toxicity (repeated exposure); No information found
Aspiration hazard; No information found

SECTION 12. ECOLOGICAL INFORMATION

Aquatic and terrestrial ecotoxicity; No information found

Persistence and degradability; No information found
Bioaccumulative potential; No information found
Mobility in soil; No information found
Other adverse effects; No information found

SECTION 13. DISPOSAL CONSIDERATION

Whatever cannot be saved for recovery or recycling should be managed in an appropriate and approved
waste disposal facility. Processing, use or contamination of this product may change the waste
management options. State and local disposal regulations may differ from federal disposal regulations.
Dispose of container and unused contents in accordance with federal, state and local requirements.

SECTION 14. TRANSPORT INFORMATION

Proper Shipping Name; Aerosols

Class No 2.1
UN-NUMBER; 1950

SECTION 15. REGULATORY INFORMATION

Follow all regulation in your country.

SECTION 16. OTHER INFORMATION

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LONG #2 Spray ( 8 / 8 )

Issuing date; 1996.06.12

Revision number and date; 2018.12.10
Others; This information has been faithfully prepared on the basis of various knowledge and information
and is not to guarantee the quality of this product. Also, this information can be changed without prior
notice in accordance with introduction of new knowledge and test results, etc. For inquiries, please
contact us or the place of product purchase.