[go: up one dir, main page]

0% found this document useful (0 votes)
70 views8 pages

13.Long#2G (Bulk) (6) (GHS) 영문

Uploaded by

peter.toanthinh
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
Download as PDF, TXT or read online on Scribd
0% found this document useful (0 votes)
70 views8 pages

13.Long#2G (Bulk) (6) (GHS) 영문

Uploaded by

peter.toanthinh
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
Download as PDF, TXT or read online on Scribd
You are on page 1/ 8

PRODUCT NAME PAGE

Material Safety Data Sheet LONG #2G(Bulk) (1/ 8 )

SECTION 1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Identity (Trade Name As Used On Label); LONG #2G(Bulk)


Recommended use of the chemical and restrictions on use; Long-term Rust-Preventer
Manufacturer/Supplier/Distributor Information;
Name; NAMBANG CNA CO., LTD.
Address; / 204, Chupal Sandan 1-gil, Paengseong-eup, Pyeongtaek-si, Gyeonggi-do, 17998 Korea
Emergency phone number; 82 31 651 5911~8

SECTION 2. HAZARDS IDENTIFICATION

HazardᆞRisk Classification

Hazard Class Hazard category

Flammable liquids 2

Skin corrosion/irritation 2

Eye damage/irritation 2

Sensitization-Skin 1

Specific target organ toxicity(Single exposure) 3(Narcotic effects)

Specific target organ toxicity(Repeated exposure) 2

Aspiration hazard 1

Hazardous to the aquatic environment–acute hazard 1


Hazardous to the aquatic environment–Long-term
1
hazard

GHS label elements, including precautionary statements

Category Indication

Symbol

Signal word Danger


H225 Highly flammable liquid and vapour.
H315 Causes skin irritation.
HazardᆞRisk Statement H319 Causes serious eye irritation.
H317 May cause an allergic skin reaction.
H336 May cause drowsiness or dizziness.
PRODUCT NAME PAGE

LONG #2G(Bulk) ( 2 / 8 )

H373 Prolonged or repeated exposure may cause damage to the nerves,


brain and lungs of the body.
H304 May be fatal if swallowed and enters airways.
H400 Very toxic to aquatic organisms.
H410 Very toxic to aquatic life with long lasting effects.
P210 Keep away from heat/sparks/open flames/hot surfaces. No
smoking.
P211 Do not spray on an open flame or other ignition source.
P233 Keep container tightly closed.
P240 Ground/Bond container and receiving equipment.
P241 Use explosion-proof electrical/ventilating/lighting/.../equipment.
P242 Use only non-sparking tools.
P243 Take precautionary measures against static discharge.
Prevention P260 Do not breathe dust/fume/gas/mist/vapours/spray.
P261 Avoid breathing dust/fume/gas/mist/vapours/spray.
P264 Wash …thoroughly after handling.
P271 Use only outdoors or in a well-ventilated area.
P272 Contaminated work clothing should not be allowed out of the
workplace.
P273 Avoid release to the environment.
P280 Wear protective gloves/protective clothing/eye protection/face
protection.
P301+P310 IF SWALLOWED: Immediately call a POISON CENTER/
doctor/...
P302+P352 IF ON SKIN: Wash with plenty of water/…
P303+P361+P353 IF ON SKIN (or hair): Take off immediately all
Precautionary
contaminated clothing. Rinse skin with water/shower.
statements
P304+P340 IF INHALED: Remove person to fresh air and keep
comfortable for breathing.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several
minutes. Remove contact lenses, if present and easy to do. Continue
rinsing.
Response
P312 Call a POISON CENTER/doctor/…/if you feel unwell.
P314 Get medical advice/attention if you feel unwell.
P321 Specific treatment (see ... on this label)
P331 Do NOT induce vomiting.
P332+P313 If skin irritation occurs: Get medical advice/attention.
P333+P313 If skin irritation or rash occurs: Get medical advice/attention.
P337+P313 If eye irritation persists: Get medical advice/attention.
P362+P364 Take off contaminated clothing and wash it before reuse.
P370+P378 In case of fire: Use ... to extinguish.
P391 Collect spillage.
P403+P233 Store in a well-ventilated place. Keep container tightly
closed.
Storage
P403+P235 Store in a well-ventilated place. Keep cool.
P405 Store locked up.
P501 Dispose of contents/container to...… in accordance with
Disposal
local/regional/national/international regulations (to be specified).

Other hazards which do not result in classification : No information found


PRODUCT NAME PAGE

LONG #2G(Bulk) ( 3 / 8 )

SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS

CHEMICAL NAME OTHER NAME CAS NUMBER Content (%)


Sulfonic acids, petroleum, calcium salts - 61789-86-4 1~5
Distillates(Petroleum), Hydrotreated light - 64742-47-8 1~5
Hydrogenated heavy paraffin refined oil (petroleum) - 64742-54-7 1~10
Solvent naphtha (petroleum), hard aromatic compounds - 64742-95-6 1~5
Methylcyclohexane - 108-87-2 25~35
3-Methylhexane - 589-34-4 10~20
2-Methylhexane - 591-76-4 10~20
1,2-Dimethylcyclopentane - 2452-99-5 1~10
1,3-Dimethylcyclopentane - 2453-00-1 1~10
Heptane - 142-82-5 1~5
Polybutene - 9003-29-6 0.01~0.05

SECTION 4. FIRST AID MEASURES

Eye contact; Immediately flush eyes with plenty of water for at least 15 minutes. Remove contact
lenses, if present and easy to do. Continue rinsing. Get medical attention if irritation develops and
persists.
Skin contact; Immediately flush skin with plenty of water. Get medical attention if irritation develops and
persists. For minor skin contact, avoid spreading material on unaffected skin. Wash clothing separately
before reuse. Take off immediately all contaminated clothing.
Inhalation; Move to fresh air. Oxygen or artificial respiration if needed. Call a physician if symptoms
develop or persist.
Ingestion; Keep respiratory tract clear. Do NOT induce vomiting. Do not give milk or alcoholic beverages.
Never give anything by mouth to an unconscious person. Take victim immediately to hospital.
Indication of immediate medical attention and notes for physician; Consult a physician. Show this safety
data sheet to the doctor in attendance

SECTION 5. FIRE-FIGHTING MEASURES

Suitable (and unsuitable) extinguishing media; Use water spray to keep fire exposed containers cool. If
substance does ignite, use CO2, dry chemical or foam.
PRODUCT NAME PAGE

LONG #2G(Bulk) ( 4 / 8 )

Specific hazards arising from the chemical (e.g. nature of any hazardous combustion products); No
information found
Special protective equipment and precautions for fire fighters; In the event of a fire, wear full protective
clothing and NIOSH-approved self-contained breathing apparatus with full face-piece operated in the
pressure demand or other positive pressure mode. Combustion by-products include phosgene and
hydrogen chloride gases. Structural firefighters' clothing provides only limited protection to the
combustion products of this material.

SECTION 6. ACCIDENTAL RELEASE MEASURES

Personal precautions, protective equipment and emergency procedures; Use personal protective
equipment. Ensure adequate ventilation. Remove all sources of ignition. Evacuate personnel to safe
areas. Beware of vapors accumulating to form explosive concentrations. Vapors can accumulate in low
areas.
Environmental precautions and protective procedures; Prevent product from entering drains. Prevent
further leakage or spillage if safe to do so. If the product contaminates rivers and lakes or drains inform
respective authorities.
Methods and materials for containment and cleaning up; Contain spillage, and then collect with non-
combustible absorbent material, (e.g. sand, earth, diatomaceous earth, vermiculite) and place in
container for disposal according to local /national regulations(see section 13).

SECTION 7. HANDLING AND STORAGE

Precautions for safe handling; Do not get in eyes or on skin or clothing. Do not breathe vapor or mist.
Do not ingest. Use only with adequate ventilation. Wear appropriate respirator when ventilation is
inadequate. Do not enter storage areas and confined spaces unless adequately ventilated. Keep in the
original container or an approved alternative made from a compatible material, kept tightly closed when
not in use. Store and use away from heat, sparks, open flame or any other ignition source. Use
explosion-proof electrical (ventilating, lighting and material handling) equipment. Use non-sparking tools.
Take precautionary measures against electrostatic discharges. To avoid fire or explosion, dissipate static
electricity during transfer by grounding and bonding containers and equipment before transferring
material. Empty containers retain product residue and can be hazardous. Do not reuse container.
Conditions for safe storage (including any incompatibilities); Store in accordance with local regulations.
Store in a segregated and approved area. Store in original container, protected from direct sunlight.
Eliminate all ignition sources. Separate from oxidizing materials. Keep container tightly closed and sealed
PRODUCT NAME PAGE

LONG #2G(Bulk) ( 5 / 8 )

until ready for use. Containers that have been opened must be carefully resealed and kept upright to
prevent leakage.

SECTION 8. EXPOSURE CONTROLS / PERSONAL PROTECTION

Control parameters (e.g. occupational exposure limit values, biological limit values);
Methylcyclohexane : TWA 400 ppm
Heptane : TWA 400 ppm, STEL 500 ppm
Engineering controls; Use only with adequate ventilation. Use process enclosures, local exhaust
ventilation or other engineering controls to keep worker exposure to airborne contaminants below any
recommended or statutory limits. The engineering controls also need to keep gas, vapor or dust
concentrations below any lower explosive limits. Use explosion-proof ventilation equipment.
Personal protective equipment;
- Eye / face protection; Safety eyewear complying with an approved standard should be used when a
risk assessment indicates this is necessary to avoid exposure to liquid splashes, mists or dusts.
Recommended: splash goggles.
- Skin protection; Personal protective equipment for the body should be selected based on the task
being performed and the risks involved and should be approved by a specialist before handling this
product.
Recommended: lab coat.
- Respiratory protection; Use a properly fitted, air-purifying or air-fed respirator complying with an
approved standard if a risk assessment indicates this is necessary. Respirator selection must be based
on known or anticipated exposure levels, the hazards of the product and the safe working limits of the
selected respirator.

SECTION 9. PHYSICAL / CHEMICAL CHARACTERISTICS

Appearance; Dark green viscous liquid


Odor; Oil odor
Odour threshold; No information found
Ph; No information found
Melting point/freezing point; No information found
Initial boiling point and boiling range; >91℃
Flash point; Liquid; >-4℃
Evaporation rate; No information found
PRODUCT NAME PAGE

LONG #2G(Bulk) ( 6 / 8 )

Flammability (solid, gas); No information found


Upper/lower flammability or explosive limits; Methylcyclohexane; 6.7 / 1.2 %
Vapour pressure; No information found
Vapour density; No information found
Specific Gravity (H2O = 1); 0.75 ± 0.05
Relative density; No information found
Solubility(ies); Insoluble
Partition coefficient; n-octanol/water; Methylcyclohexane 3.61
Auto-ignition temperature; No information found
Decomposition temperature; No information found
Viscosity; No information found
Molecular Weight; No information found

SECTION 10. STABILITY AND REACTIVITY

Chemical stability and possibility of hazardous reactions; Stable under ordinary conditions of use and
storage
Conditions to avoid (e.g. static discharge, shock or vibration, etc); Heat, flame, ignition sources, light,
moisture, incompatibles.
Incompatability (Materials to Avoid); Oxidizing agent, base, metal, alkali metal, lithium
Hazardous Decomposition Products; carbon oxide

SECTION 11. TOXICOLOGICAL INFORMATION

- Methylcyclohexane -
Information on the likely routes of exposure; No information found
Acute toxicity
- Oral; No information found
- Dermal; LD50> 2000 ㎎ / ㎏ Species: Guinea pig (OECD Guideline 402) ※ Source: ECHA
- Inhalation; LC50> 26.3 ㎎ / ℓ 1 hr Species: Mouse Source: ECHA
Skin corrosion/irritation; No information found
Serious eye damage/irritation; No information found
Respiratory or skin sensitization; No information found
Germ cell mutagenicity; No information found
Carcinogenicity; No information found
PRODUCT NAME PAGE

LONG #2G(Bulk) ( 7 / 8 )

Reproductive toxicity; No information found


Specific target organ toxicity (single exposure); No information found
Specific target organ toxicity (repeated exposure); No information found
Aspiration hazard; No information found

SECTION 12. ECOLOGICAL INFORMATION

Aquatic and terrestrial ecotoxicity; No information found


Persistence and degradability; No information found
Bioaccumulative potential; No information found
Mobility in soil; No information found
Other adverse effects; No information found

SECTION 13. DISPOSAL CONSIDERATION

Whatever cannot be saved for recovery or recycling should be managed in an appropriate and approved
waste disposal facility. Processing, use or contamination of this product may change the waste
management options. State and local disposal regulations may differ from federal disposal regulations.
Dispose of container and unused contents in accordance with federal, state and local requirements.

SECTION 14. TRANSPORT INFORMATION

Proper Shipping Name; FLAMMABLE LIQUID N.O.S (CONTAINS METHYLCYCLOHEXANE, HEPTANES)


Class No; 3
UN-NUMBER; 1993
Packing group; II

SECTION 15. REGULATORY INFORMATION

Follow all regulation in your country

SECTION 16. OTHER INFORMATION

Issuing date; 2005.11.28


Revision number and date; 2020.07.23.
PRODUCT NAME PAGE

LONG #2G(Bulk) ( 8 / 8 )

Others; This information has been faithfully prepared on the basis of various knowledge and information
and is not to guarantee the quality of this product. Also, this information can be changed without prior
notice in accordance with introduction of new knowledge and test results, etc. For inquiries, please
contact us or the place of product purchase.

You might also like