Atmic uce
Bohr' Tinciple (Postulatof Shruclwe
of Hydhogen atonm and yduogen Llke akom
1) Fixst posulakeh
Hee
F Fe
(ze).e Lciruak orbit
Hydhog en ike aBom
21 Second poaiulae
Angula monmentum_of e in
thein spedffc orbit _wiu be inlegral multiple
of h Anqula ei n
mentum o thin
Specitc rbit wiU bequantibed.
mv,r nh uhene ms 12,3,4-
2
* De Bsoqlie explanation toY quantsaton o anqua
momentum ofelectron in heispecihte rbit
nd2Y
PauhcdoW a L e
and
m a t H e
2T
P or bito
A
2-7 antisahon a anquaH momentum o
e nUb Speitic0rbile
mh= mVnYn
Hig Cngy
pbheton
3 Thad bostulake
Lowe dcuel
Uhen eleciron junp om any qhe enegy
leuel to any Lo We onegy Jeuel then
adtale ( petphholon of enegY
To deteumine obital yadius ot olectTon Jun its
bile £or hydhogenike atom
mv 2e) e
4co.
2e) Ce d)
4com
m n
27
Vn
n (2ee
Tm
K C2eHe) m,v To
Ze mm
emn
*
m nCreQses Hhen j s dpo in crens0,
fo hydrogen atom
0 53nA
Foy 1t Ovect
Y 0-53 A Qo= %, Bohr adi
Fov Dxait
212 A
ain
Axea T* =T (0:53h)
A n
*Velocity af electran in m" orbit o huduaaen
ike Qta
mV,Vn= nh ez 2
2TT
n mh 2 Eoh ,
Nm
Vn2-18 XID° 2 m
Vn m
xmo5n V.2xio 2.Xlo": m
mxo S3
V,
V 22X1K
F o ydcen atom
Vn 22X1O
n 2 2 XI0 m/s
For rbit at faydxogtn-
V1 2-2xIo m/a
Vm 2.-2 Xo o r helium
V3 2:2x (o°
4.qxt o m
*Ta deleumine Rinetic enekgy eleclromnm
orbit Ads for hydrogen ike atom!
mv
m
me
3- 6 ev)x z ric
2
m, k
for Hydnogen akom
* 136 ev
8
fox 99ound stote me
K= 136 ev
# Ta deteumiane Potential ene-gy ele cton
Lnn orbit fo Hydogen like atom
O -2e)e_
Un
2e mez
22
4E7 (272ev)
met
for Pyduogern atom 21
Un me
m2
24-2ev
tor 9ownd State m= i
n 23 2 eV:|
Gaph
Un 2
O
n u
T o deleumine total enegy o electron un
th orbit fox Hyadsuogen like atom
En Kt Un
En me z2 me z
En met
En-t36) | 2
En L m
.,ET
-t
for Hydrogen atom 2 1
En -met
8
136 t2
ev
to 9round tate
E -13.6 ev
To deleumine Ionisation eregy o elechrom b-
o r b i t tor ydoqen ike atom LE
Ent E = 0
En E me
X
22
2
/ me
E (136ev)2 tiky
E
for o 9 e n atom 2 1
E: me
&2 13:6ev h2
for 9round state
E 13.6 ev
T tck- E K -E
ITT
He
Z2
m-2
E 136)ev
E ((86ev
Tonisatton Potential ot electrom in n
orbit t o hpdsagen Jike atom V:):
obit
V z vett =13-6X2velt
*Magnettc ttield produced at centre. due to
Yeoluion eLeckrn m m onbit
obit
lex Vn
6
) 8 2
roblen I an electrom eelw ingnd
orbit i n hydnoqen. atom then maqneic
field Produ ce a t t » Centreis B NOw
Now Same electron i s allow ed to
rwolng in 2d orblt Hhen ind mew
mageHc field
6 32
Soution-
(
B2 na
B
gaia T o a enengy electrm n n0rbtr
Em me (R- R: c)x z2
RC me =3.6 ev LRy dbeng
enegy
R Met
mLRydberg
109 x to
Constant
0 m
LR CM° LT°]P Dimenpion
when electron Jump om Quny Pugher engy
devel to any Joue r e hHhen
Leuel e n 1t
it
adtate a poton
e
E
Radiatn
E] Jump Photon 2
Hence enegY o adi aled pthoton is giuen a
Av E
hv E-Ef
Av--
RA.C( -(R:h-C/
Rc2 2 freg. a radiakon
Produ ced
A
Rz
Cwauel
R
NrumbH
Aydbe eg
Fox udrogen atom
R
Emiasim Speckwn fox Hydagen atom
n yr es)
N
NB
P e.s)
m:6
v
0 s (es)
Ks No
/-fundSeve 4 es)
IIICo-seies RRdtie
Ey (Brakett seies m n: d es)
N-S p.kadiaion
(es chen seies L n2 (bt excited r l a t )
1.Sl ev.
K m-seies TRadialion
/Balmex setes
LSetRadalim (ground ptete).
3-6 e yman peies
K- seies
(Uv. Ra diahion)
Ageu Concept
is albo knowm
c Tt Jime o an entes
tirst menbero Hhat seuies Cund iit
alway poduce a adi'ntion a waueten
maxtmm wauelenqth and minimum equeny
C Last dine aany 3eLtesJA also encwm as
sules Jimit and i t always oduce
a minmuum wavelëgth and maximun
adiaon
reguen c
- --
Aqain
Eox yduqen auam
E m2
Poton
R(-¢):
d R(4)
3 3 X|O - "m
3XIo7
1330XIO m
A 13 30 A
ultraviotet Yadiation
C Fo Hudegen atom
La
E A
phe ton
SX 10
E m2
c 2 Xo*
72XIC
R ) A20o A
visible
A
O L and out J a i o o wavelenoth adidton
produed by a mémbR Jemian euies
and 6enies Jtmit a Balméi seutes
n2
L
- =}
AL 3R:
OLLe End sut wauelength o adiatrm produce&
due to d- excitation oyyduoqen
electromatom:
m
es eS
m2
R2
e T
5. 33 x 1o
3R 5330 XI6
S330 A
Que Find out a ralio o minimum uJavelengH
and maximam wuelha-h of yodiothon
produ ce d By braket
m.4 R
R() )
RR A 16
A 400(10 16
9P
photaun nd Les 2S
(h271)
(-1)
2
Rz
.Rz
Rc[n-*
Ln-(m
aN-I
-1 n
2m
yRc2
- RC RC2
A
Ec-EA hc
Ec FBhe
E-En hCAu)
QueeiE
-2E
-f-|-
-E-(26) -Ac 4EE
n2 to n:1
H9
A Zy
ALSAy
2 Rz
(
+To deleumiinu total numbe o possible spectrum ines
when electren de-ex cited Brem any high levol
ad
. N n-n +1)(nh)
2
M N= n - 1
to
Aaaint A n any f
N-(-n t1) ("i-hE)
LC L electrev dee- erited m m3 do
Youd
gYound
hen fnd eut Possi ble nube
Spectrunm lv poduce,
s3
me2 N (m)
ne 2.
a(3-) N3
eleckson
d-extfted uom n# to gfsund
Letel fhen
fhen ind eut possible mwnben o
Speckrum PAoduce
: 4-
4u-)
2-X
Ag aia
Nedeus o Qny tem
OUnd Neu Le
Nucdeus
an d
nd A N+P : Nt Z*mwmbe
9umen.
Z Atemia numb
atom s
Bgain Radius mucleo) of any
dlebendubon ma bamunbore A
RA3
R R A'
R f12 XrolSmekr) a '3
uLRS
Kar
T2
Te RTe 7
Ral 2
Pre
Fre RAL
