Half Yearly Examination SESSION 2015 - 16 Class Xi Subject - Chemistry

HALF YEARLY EXAMINATION
SESSION 2015 16
CLASS XI
SUBJECT CHEMISTRY
Time: 3 Hrs
MM: 70
Instructions
a)
b)
c)
d)
e)
f)
There are 26 questions and all questions are compulsory

Question 1 to 5 carry one mark each
Question 6 to 10 carry two mark each
Question 11 to 22 carry three marks each
Question 23 carry four marks
Question 24 to 26 carry five marks
1. Calculate the number of radial & angular nodes present in 3d

orbital.
2. State Law of Multiple proportion.
3. Write the Vanderwaals equation for real gases.
4. Classify the following as extensive and intensive properties:
Molar Heat Capacity, Temperature, Enthalpy & Volume
5. Find the conjugate base or the species: NH4+ & CH3COOH
6. What do you mean by resonance? Draw resonance structures for
CO32- ion.
Or
a. Define the term dipole moment.
b. Out of NH3 and NF3 which has higher dipole moment and why?
7. What is the wavelength of light emitted when the electron in a
hydrogen atom undergoes transition from an energy level n = 4 to
an energy level with n = 2?
8. a) What do you understand by isoelectronic species?
b) Select the isoelectronic species from the following:
Na+, K+, Mg2+, S2-, Ar
9. a) Indicate the number of unpaired electron in Mn2+ and Cu2+ ion.
b) State Paulis Exclusion principle
10.
The threshold frequency for a metal is 7.0 x 1014 s-1. Calculate
the kinetic energy of an electron emitted when radiation of 1.0 x 1015 -1
s hits the metal.
11.
Explain the following statements
st
a) 1 ionization enthalpy of B is less than that of Be
b) Noble gases show positive electron gain enthalpy

c) Cations are smaller than their parent atoms
12.
Deduce the structure of the following on the basis of VSEPR
Theory:
XeF4, ClF3, SF4
13.
a) Write the expression for the relation of partial pressure to
the mole fraction of a gas.
b) Calculate the volume occupied by 8.8 grams of CO2 at 31.1 o C
and 1 bar pressure (R=0.083 barL K-1 mol-1)
14.
Define Molality. The density of 3M solution of NaCl is 1.25 gm.
Calculate the molality of the solution.
15.
a) What do you understand by anomalous behaviour of 2nd
period elements? Explain with the help of an example.
b) What would be the IUPAC name and symbol for the element with
atomic number 116?
Or
a) Why do the properties of Li resemble with Mg. Explain the
relationship between them with reason?
b) Why electron gain enthalpy of F is less negative than that of Cl?
16.
Calcium carbonate reacts with HCL to give CaCl2 and CO2
according to the reaction
CaCO3(s) + 2HCl (aq) CaCl2 (aq) + CO2 (g) + H2O
What mass of CaCO3 is required to react completely with 25 ml of
0.75M HCl?
17.
A compound contains 4.07 % hydrogen, 24.27% carbon and
the rest is chlorine. Its molar mass is 98.96 gm. What are their
empirical and molecular formulas?
18.
a) For an isolated system
U = 0, what will be
S?
b)The enthalpies of formation CO(g), CO2(g), N2O(g) N2O4(g) Ar-110393,81 & 9.7 kJ/mole-1 respectively. Find the enthalpy of the reaction
N2O4 (g) + 3CO (g) -> N2O (g) + 3CO2 (g)
19.
Give three postulates of Kinetic Theory of gases
20.
What do you understand by the following:
a) Dissociation constant of an acid
b) Buffer solution
c) Solubility Product
21. a) what do you mean by surface tension?
b) What will be the minimum pressure required to compress 300 dm3
of air at 1 bar to 200 dm3 at 30o C.
22. At a certain temperature and a total pressure of 105 Pa, iodine vapours
contain 40 % by volume of atoms:
I2(g)
2I (g)
Calculate Kp for the given equilibrium.

23. As the number of vehicles is increasing the demand for the motor fuel
is increasing. The time is not far off when there may be acute shortage of
crude petroleum and its products. LPG used as domestic fuel is also a
product of crude petroleum. Our government is helpless and has to
increase the price of petroleum products. This will result in the increase in
transportation of the goods of our everyday life and also the petrol
expense to drive vehicles
After reading the above paragraph, answer the following questions
a) Name an alternative fuel which is used in the vehicles these days.
b) In a vehicle petrol or diesel is consumed during the process heat
energy is being converted to which type of work.
c) The problem of shortage of non renewable resources of energy has
become very serious. What are the two suggestions which you can
give as the citizen of India to deal with this problem?
24.
a) On the basis of molecular orbital theory write the configuration of
N2 molecule. Calculate its bond order. Predict its magnetic behaviour.
b) Give any two limitation of Valence bond theory
c) Differentiate between an atomic orbital and molecular orbital
Or
a) What is hybridization? Give any two conditions required for
hybridization of orbitals.
b) Differentiate between sigma and pi bond
c) Although NH3 and H2O have the sane hybridization yet their bond
angles are different. Why?
25.
a)
b)
Calculate the pH of a 1.0 x 10-8 M solution of HCl

What is common ion effect? Assign reason for the following:
i) A solution of NH4Cl in water shows pH less than 7
ii) In qualitative analysis NH4Cl is added before adding NH4OH for

testing Fe3+ & Al3+ ions
Or
a) Calculate the pH of a 0.4 gm of NaOH dissolved in water to give ml

of solution.
b) Equal volumes of 0.002 M solutions of sodium iodate and copper
chlorate are mixed together. Will it lead to precipitation of copper
iodate? (For copper iodate KSP = 7.4 X 10-8)
26.
(a) Derive the de Broglies wave equation.
(b) Calculate the wavelength of de Broglies wave associated with a

proton of kinetic energy 500 eV.
Or
(a) State Heisenbergs Uncertainty principle.

(b) Write an expression for deBroglie equation.
(c) A proton is accelerated to one tenth of velocity of light. If the velocity
can be measured with a precision of + 0.5%. What must be the
uncertainty in its position, (mp=1.675 x 10-27 kg)

Half Yearly Examination SESSION 2015 - 16 Class Xi Subject - Chemistry

Uploaded by

Document Informationclick to expand document information

Copyright:

Available Formats

Half Yearly Examination SESSION 2015 - 16 Class Xi Subject - Chemistry

Uploaded by

Document Information

Original Description:

Original Title

Copyright

Available Formats

Share this document

Share or Embed Document

Sharing Options

Did you find this document useful?

Is this content inappropriate?

Copyright:

Available Formats

Half Yearly Examination SESSION 2015 - 16 Class Xi Subject - Chemistry

Uploaded by

Copyright:

Available Formats

HALF YEARLY EXAMINATION

There are 26 questions and all questions are compulsory

1. Calculate the number of radial & angular nodes present in 3d

b) Noble gases show positive electron gain enthalpy

Calculate Kp for the given equilibrium.

Calculate the pH of a 1.0 x 10-8 M solution of HCl

ii) In qualitative analysis NH4Cl is added before adding NH4OH for

a) Calculate the pH of a 0.4 gm of NaOH dissolved in water to give ml

(a) Derive the de Broglies wave equation.

(b) Calculate the wavelength of de Broglies wave associated with a

(a) State Heisenbergs Uncertainty principle.

You might also like