COMPARTMENT 2

Chemistry QP

Grade - XI
SECTION _ A
Q.1) The number of atoms present in one mole of an element is equal to Avogadro 1
number. Which of the following elements contains the greatest number of
atoms?
(a) 4g He (b) 46g Na (c) 0.40g Ca (d) 12g He
Q.2) If the density of a solution is 3.12 g mL1, the mass of 1.5 mL solution in 1
significant figures is________

(a) 4.7 g
(b) 4680 x 10-3 g
(c) 4.680 g
(d) 46.80 g

Q.3) Total number of orbitals associated with third shell will be _______. 1
(a) 2
(b) 4
(c) 9
(d) 3
Q.4) Two atoms are said to be isobars if 1
(a) they have same atomic number but different mass number.
(b) they have same number of electrons but different number of neutrons.
(c) they are same number of neutrons but different number of electrons.
(d) Sum of the number of protons and neutrons is same but the number of
protons is different.
Q.5) The first ionization enthalpies of Na, Mg, Al and Si are in the order 1
(a) Na < Al< Mg < Si
(b) Na>Mg>Al>Si
(c) Na < Mg < Al < Si
(d) Na > Mg > Al < Si
Q.6) Which of the following elements has the maximum negative electron gain 1
enthalpy?
(a) Bromine
(b) Chlorine
(c) Fluorine
(d) Iodine
Q.7) Enthalpy of sublimation of a substance is equal to 1
(a) enthalpy of fusion + enthalpy of vapourisation
(b) enthalpy of fusion
(c) enthalpy of vapourisation
 (d) twice the enthalpy of vapourisation.
Q.8) Which of the following is not correct? 1
(a) ∆G is zero for a reversible reaction.
(b) ∆G is positive for a spontaneous reaction
(c) ∆G is negative tor a spontaneous reaction
(d) ∆G is positive for a non-spontaneous reaction.
Q.9) The pH of neutral water at 25°C is 7.0. As the temperature increases, 1
ionization of water increases, however, the concentration of H+ ions and
OH– ions are equal. What will be the pH of pure water at 60°C?
(a) Equal to 7.0
(b) Greater than 7.0
(c) Less than 7.0
(d) Equal to zero
Q.10) Hydrogen bonds are formed in many compounds e.g., H20, HF, NH3. The 1
boiling point of such compounds depends to a large extent on the strength of
hydrogen bond and the number of hydrogen bonds: The correct decreasing
order of the boiling points of above compounds is
(a) HF>H2O>NH3
(b) H2O>HF>NH3
(c) NH3>HF>H2O
(d) NH3>H2O>HF
Q.11) Identify disproportionation reaction 1
(a) CH4 + 2O2 → CO2 + 2H2O
(b) CH4 + 4Cl2 → CCl4 + 4HCl
(c) 2KCIO3 →2KCl + 3O2
(d) 2NO2 + 2OH― → NO2 + NO―3 + H2O
Q.12) Which of the following is the correct IUPAC name? 1
(a) 3-Ethyl-4,4-dimethylheptane
(b) 4,4-Dimethyl-3-ethylheptane
(c) 5-Ethyl-4,4-dimethylheptane
(d) 4,4-Bis(methyl)-3-ethylheptane
Q.13) The IUPAC name of CH3CH2COCH2C(CH3)2CH2COOH is 1
(a) 3,3-dimethyl 3-oxo heptanone
(b) 3,3-dimethyl 3-oxo heptanoic acid
(c) 3,3-dimethyl 5-oxo heptanoic acid
(d) 5,5-dimethyl 5-oxo heptanoic acid
Q.14) Which of the following alkenes on ozonolysis gives an aldehyde and a ketone? 1
(a) CH3CH=CHCH3
(b) CH2=CHCH2CH3
(c) CH3C(CH3)=C(CH3)CH3
(d) CH2=C(CH3)2
Q.15) Nitration of benzene is 1
a) Electrophilic addition
b) Electrophilic substitution
c) Nucleophilic addition
d) Nucleophilic substitution
 ASSERTION –REASONING QUESTIONS
In each of the following questions, a statement of Assertion (A) is given
followed by a corresponding statement of Reason (R) just below it. Of the
statements, mark the correct answer as –
a. If both assertion and reason are true, and reason is the true explanation of
the assertion.
b. If both assertion and reason are true, but reason is not the true explanation
of the assertion.
c. If assertion is true, but reason is false.
d. If both assertion and reason are false.
Q.16) Assertion: Electron gain enthalpy of fluorine is higher than chlorine 1
Reason : due to small size of fluorine
Q.17) Assertion – The dipole moment helps to predict whether a molecule is polar or 1
non-polar.
Reason – The dipole moment is only due to difference in electronegativity of
covalently bonded atoms
Q.18) Assertion: Salt bridge maintains electrical neutrality in the solutions in two 1
half cells and it also acts as internal circuit of an electrochemical cell.
Reason: Concentration of ions does not change in two electrolytes.
SECTION – B
Q.19) Explain the following name reaction – 2
a) Wurtz reaction b) Friedel craft alkylation
Q.20) Calculate the volume of CO2 gas released when 5 g of CaCO3 decomposes at STP? 2
(Atomic mass of Ca = 40)
Q.21) Calculate the wave length of an electron moving with a velocity of 2.05 x 107 2
m/s.
Q.22) Calculate the standard enthalpy of formation of CH3OH(l) from the data 2
CH3OH(l) +3/2O2 (g) → CO2(g) +2H2O ∆cH0 = -726 kJ/mol
C(graphite) + O2(g) → CO2 (g) ∆cH0 = - 393 kJ/mol
H2(g) + ½ O2(g)→ H2O(l) ∆fH0 = -286 kJ/mol

Q.23) What is the conjugate acid/base pair of the following - 2

a) SO42- b)H3O+
Q.24) Explain the mechanism of acylation of Benzene. 2
Q.25) With the help of molecular orbital diagram find the bond order and magnetic 2
nature of O2―.
SECTION – C
Q.26) a) Identify the type of isomerism exhibited by 3
i) propanal and propanone ii) butanol and butan-2-ol
b) What is the order of stability of 1o, 2o and 3o carbocations.
Q.27) Find the empirical and molecular formula of a compound which contains 3
 4.07% of hydrogen, 24.27% of carbon and 71.6% of chlorine. Its molecular
mass is 98.96 g.
Q.28) Electrons are emitted with zero velocity from a metal surface when it is 3
exposed to a radiation of wavelength 6800 Å. Calculate the threshold
frequency.
Q.29) Define entropy. In which of the following entropy decreases / increases. 3
i) CO2(g) → CO2(s)
ii) A liquid crystallizes into a solid.
iii) H2(g) + Cl2(g) → 2HCl (l)
iv) 2NaHCO3(s) → Na2CO3 (s) + CO2 + H2O

Q.30) Balance the following reaction (show detailed steps) 3

I― + MnO4― → Mn2+ +I2 (in basic medium)
SETION - D
Q.31) Carbon is tetravalent and shows sp, sp2, and sp3 hybridisation in its compound. 4
Compounds of carbon and hydrogen known as hydrocarbon are covalent
compound.
Structural formulae of six different compounds (A to F) are given.
A) CH3CH=CHCH3
B) CH3CH2COCH3
C) CH2=CHCH2CH3
D) CH3CH2CH(OH)CH3
E) CH3CH2CH2CH2CHO
F) CH3CH2OCH2CH3
a) Which of these are functional isomers?
b) Draw the bond line structure of E.
c) Which of these compound exhibit metamerism?
d) Which one among these would exhibit geometrical isomerism?
Q.32) In the modern periodic table, elements are arranged in order of increasing 2+1+1
atomic numbers which is related to the electronic configuration. Depending
upon the type of orbitals receiving the last electron, the elements in the
periodic table have been divided into four blocks, viz, s, p, d and f. The
modern periodic table consists of 7 periods and 18 groups. Each period begins
with the filling of a new energy shell. In accordance with the Aufbau principle,
the seven periods (1 to 7) have 2, 8, 8, 18, 18, 32 and 32 elements respectively.
The seventh period is still incomplete. To avoid the periodic table being too
long, the two series of f-block elements, called lanthanoids and actinoids are
 placed at the bottom of the main body of the periodic table.
a) How does ionisation enthalpy vary along the period and down
the group and give reason?
b) Name an element which has highest electronegativity.
c) Name a metal which shows +7 oxidation state and belongs to 4th
period.
SECTION - E
Q.33) a) Draw the structure of (i) PF5 (ii) XeF6 (iii) BrF5 5
b) Distinguish between sigma and pi bond.(Any two points)
OR
(a) Give the shapes of following covalent molecules using VSEPR theory.
(i) ClF3
(ii) NF3
(b) Explain the geometry and hybridisation of PCl5 molecule.
Q.34) a) At 450K, Kp = 2.0 x1010 bar for the given reaction at equilibrium. 5
2SO2(g) + O2(g) → 2SO3(g)
What is Kc at this temperature?
b) Calculate the pH of a solution whose [H+] = 0.01
Q.35) a) Explain the following with example-
i) Decarboxylation
ii) Aromatisation
iii) dehydrohalogenation
b) How will you convert –
i) Benzene into benzyl chloride
ii) but2ene into ethanal