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WO2003074632A1 - Procede de fabrication des hydrocarbures liquides - Google Patents

Procede de fabrication des hydrocarbures liquides Download PDF

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Publication number
WO2003074632A1
WO2003074632A1 PCT/RU2002/000545 RU0200545W WO03074632A1 WO 2003074632 A1 WO2003074632 A1 WO 2003074632A1 RU 0200545 W RU0200545 W RU 0200545W WO 03074632 A1 WO03074632 A1 WO 03074632A1
Authority
WO
WIPO (PCT)
Prior art keywords
coal
hydrogen donor
donor solvent
waste
flow
Prior art date
Application number
PCT/RU2002/000545
Other languages
English (en)
Russian (ru)
Inventor
Aleksandr Titov
Original Assignee
Aleksandr Titov
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Aleksandr Titov filed Critical Aleksandr Titov
Priority to EP02803259A priority Critical patent/EP1471129A1/fr
Priority to AU2002365174A priority patent/AU2002365174A1/en
Publication of WO2003074632A1 publication Critical patent/WO2003074632A1/fr

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G1/00—Production of liquid hydrocarbon mixtures from oil-shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal
    • C10G1/04—Production of liquid hydrocarbon mixtures from oil-shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal by extraction
    • C10G1/042—Production of liquid hydrocarbon mixtures from oil-shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal by extraction by the use of hydrogen-donor solvents

Definitions

  • the process of converting coal into liquid products is known by mixing coal with a reagent, which is a mixture of thermally stable hydrocarbons at a high pressure of 188;
  • ned ⁇ s ⁇ a ⁇ am e ⁇ i ⁇ izves ⁇ ny ⁇ s ⁇ s ⁇ b ⁇ v ⁇ n ⁇ si ⁇ sya mn ⁇ g ⁇ s ⁇ adiyn ⁇ s ⁇ , sl ⁇ zhn ⁇ s ⁇ ⁇ e ⁇ n ⁇ l ⁇ gii associated with ne ⁇ b ⁇ dim ⁇ s ⁇ yu is ⁇ lz ⁇ vaniya s ⁇ etsi ⁇ iches ⁇ i ⁇ ⁇ a ⁇ aliza ⁇ v, ⁇ imeneniem vys ⁇ i ⁇ ⁇ em ⁇ e ⁇ a ⁇ u ⁇ and pressure znachi ⁇ elnaya ene ⁇ g ⁇ em ⁇ s ⁇ and ⁇ vyshennaya sebes ⁇ im ⁇ s ⁇ ⁇ luchaemy ⁇ ⁇ du ⁇ v.
  • D ⁇ ugim ned ⁇ s ⁇ a ⁇ m izves ⁇ n ⁇ g ⁇ s ⁇ s ⁇ ba yavlyae ⁇ sya ne ⁇ b ⁇ dim ⁇ s ⁇ is ⁇ lz ⁇ vaniya znachi ⁇ eln ⁇ g ⁇ ⁇ bema v ⁇ dy for vysv ⁇ b ⁇ zhdeniya ⁇ ebuem ⁇ g ⁇ ⁇ liches ⁇ va v ⁇ d ⁇ da, uchas ⁇ vuyuscheg ⁇ in gid ⁇ genizatsii, d ⁇ s ⁇ a ⁇ chn ⁇ vys ⁇ e s ⁇ de ⁇ zhanie ⁇ a ⁇ a in ⁇ du ⁇ a ⁇ ⁇ e ⁇ inga and ⁇ a ⁇ sleds ⁇ vie, znachi ⁇ eln ⁇ e presence v ⁇ dy in leg ⁇ i ⁇ ⁇ a ⁇ tsiya ⁇ ⁇ du ⁇ a.
  • the objective of the invention is the creation of a method that is used to intensify the process of grinding grinding of processed particles and processable products. Increase the yield of gasoline fraction with a boiling temperature of 100-200 ° ⁇ and diesel fraction with a boiling temperature of 200-450 ° ⁇ .
  • P ⁇ s ⁇ avlennaya task ⁇ eshae ⁇ sya ⁇ edl ⁇ zhennym s ⁇ s ⁇ b ⁇ m in ⁇ m zhid ⁇ ie uglev ⁇ d ⁇ dy ⁇ luchayu ⁇ of ⁇ ve ⁇ d ⁇ g ⁇ ⁇ liva and ugle ⁇ dis ⁇ g ⁇ ma ⁇ e ⁇ iala ⁇ e ⁇ m ⁇ me ⁇ aniches ⁇ im ⁇ e ⁇ ing ⁇ m and gid ⁇ genizatsiey ugle ⁇ da in usl ⁇ viya ⁇ nes ⁇ atsi ⁇ na ⁇ n ⁇ g ⁇ ' ⁇ echeniya dvu ⁇ azn ⁇ y sis ⁇ emy "is ⁇ dn ⁇ e sy ⁇ e - v ⁇ d ⁇ d ⁇ d ⁇ n ⁇ ny ⁇ as ⁇ v ⁇ i ⁇ el".
  • Devices and devices that are involved in the processing of devices with modulation (interruption) are subject to any harm to the user.
  • Aviation is a complex non-stationary hydraulic process, associated with secondary physical and chemical processes, such as luminescence, exhaustion; shock waves of pressure, velocity and temperature; microbes and cumulative microbes; gas heating and ionization in a cavitation bubble.
  • the pressure generated by the shock absorbing cavities reaches a value of 10 Pa. This ensures a sufficiently high degree of grinding, the growth of the specific rate of particulate matter and their non-hazardous equipment.
  • the acceleration of the process occurs due to the dispersed distribution of energy in a large number of small volumes (centers of cavitation). In this case, the energy is concentrated in the volume of the order of the size of the cavitated bubbles (0.001-0.01 mm), which results in an intensification of the process.
  • Received suspension on line 3 - is supplied . into reactive apparatus 4 for thermo-mechanical cracking and hydrogenation.
  • Other particles, including ash, line 5 is inserted into the drive (not shown).
  • Raw ⁇ moisture. 80% with a carbon content of 49% for the absolute dry matter and the non-hazardous in-line fuse are supplied through a waste fuse with a free-flowing medium. in the process.
  • the separation of process Upon leaving the process, a gaseous hydrocarbon mixture with a temperature of more than 350 ° C is obtained, after separation, the separation and separation are directed.
  • the yield of liquid products of average fractions of 160-400 ° C is 17% of the original mass of the furnace.
  • a water source and a mixture of fractions with a boiling range of 35-100 ° C are used, which are connected to a dispersing system.
  • Method for use Use brown coal with a moisture content of 55% with a carbon content of 72% for absolute dry matter and adding 80% of the water to the auger. The yield of liquid hydrocarbon products of average fractions of 160-400 ° C makes up 22% of the original mass of coal.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
  • Lenses (AREA)

Abstract

L'invention concerne des procédés de fabrication des hydrocarbures liquides à partir de la tourbe, du pyroschiste, du lignite, de l'houile brune, de l'anthracite, de déchet de charbon et de raffinage, des résidus de plastique et de polymère, des rebuts de caoutchouc industriels etc., et peut être utilisée dans l'industrie houillère et chimique et dans l'industrie pétrolière. Le craquage et hydrogénation du produit de départ sont effectués en présence d'un solvant donneur d'hydrogène et dans les conditions d'écoulement non stationnaire d'un système biphasique 'produit de départ - solvant donneur d'hydrogène' dans un appareil à rotor et à réaction avec de la modulation (interruption) de l'écoulement. En tant que solvant donneur d'hydrogène, on utilise de l'eau et un mélange d'une fraction qui a une température d'ébullition de 35-100 °C avec le résidu de post-fractionnement circulant ayant une température d'ébullition de 450-600 °C et une température de solidification de 20 °C. L'hydrogénation et le craquage thermomécanique sont intensifiés à l'aide des processus de cavitation et par multiples effets secondaires de cavitation. Le procédé permet de simplifier la technologie du processus et d'augmenter le rendement des produits liquides de la meilleure qualité qui peuvent être utilisés en tant que combustibles pour moteur.
PCT/RU2002/000545 2001-12-26 2002-12-23 Procede de fabrication des hydrocarbures liquides WO2003074632A1 (fr)

Priority Applications (2)

Application Number Priority Date Filing Date Title
EP02803259A EP1471129A1 (fr) 2001-12-26 2002-12-23 Procede de fabrication des hydrocarbures liquides
AU2002365174A AU2002365174A1 (en) 2001-12-26 2002-12-23 Method for producing liquid hydrocarbons

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
RU2001135111/04A RU2203924C1 (ru) 2001-12-26 2001-12-26 Способ получения жидких углеводородов
RU2001135111 2001-12-26

Publications (1)

Publication Number Publication Date
WO2003074632A1 true WO2003074632A1 (fr) 2003-09-12

Family

ID=20254893

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/RU2002/000545 WO2003074632A1 (fr) 2001-12-26 2002-12-23 Procede de fabrication des hydrocarbures liquides

Country Status (6)

Country Link
EP (1) EP1471129A1 (fr)
AU (1) AU2002365174A1 (fr)
LT (1) LT5078B (fr)
PL (1) PL371514A1 (fr)
RU (1) RU2203924C1 (fr)
WO (1) WO2003074632A1 (fr)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2010094697A1 (fr) 2009-02-17 2010-08-26 Bergen Teknologioverføring As Liquéfaction de lignine avec des composants gazeux
US8911617B2 (en) 2005-12-16 2014-12-16 Petrobeam, Inc. Self-sustaining cracking of hydrocarbons
US20210171920A1 (en) * 2015-10-29 2021-06-10 Temple University-Of The Commonwealth System Of Higher Education Modification of 3' Terminal Ends of Nucleic Acids by DNA Polymerase Theta

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
RU2280673C1 (ru) * 2004-12-24 2006-07-27 Учреждение Институт органического синтеза Уральского отделения Российской академии наук Способ ожижения бурых углей
EP2134812A1 (fr) * 2006-11-20 2009-12-23 Christian Koch Mélangeur à chambre à haute capacité pour suspensions catalytiques huileuses
RU2345118C1 (ru) * 2007-04-17 2009-01-27 Общество с ограниченной ответственностью Научно-производственный центр "КЛАСС" Способ получения жидкого топлива из торфа
RU2376340C1 (ru) * 2008-07-16 2009-12-20 Владимир Андреевич Золотухин Способ подготовки углеводородного сырья для дальнейшей углубленной переработки

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4250015A (en) * 1978-12-18 1981-02-10 The United States Of America As Represented By The United States Department Of Energy Mechanochemical hydrogenation of coal
WO1983003841A1 (fr) * 1982-05-04 1983-11-10 Nederlandse Centrale Organisatie Voor Toegepast- N Procede et dispositif permettant de preparer un hydrocarbure fluide produit a partir du charbon
RU2131903C1 (ru) * 1994-09-12 1999-06-20 Термтек А/С Способ термомеханического крекинга и гидрогенизации углеводородов

Family Cites Families (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
SU355867A2 (fr) 1971-03-29 1974-07-25
US4081351A (en) 1976-09-02 1978-03-28 Mobil Oil Corporation Conversion of coal into motor fuel
DE2943537A1 (de) * 1979-10-27 1981-05-07 Hermann Berstorff Maschinenbau Gmbh, 3000 Hannover Verfahren und anlage zur umwandlung von kohle mit wasserstoff in kohlenwasserstoffe
DE3038842C2 (de) 1980-10-15 1986-06-19 Bergwerksverband Gmbh, 4300 Essen Verfahren zur Steigerung der Kohleölgewinnung bei der Kohlehydrierung
JPS5835247A (ja) 1981-08-26 1983-03-01 Mitsubishi Electric Corp 内燃機関の制御装置

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4250015A (en) * 1978-12-18 1981-02-10 The United States Of America As Represented By The United States Department Of Energy Mechanochemical hydrogenation of coal
WO1983003841A1 (fr) * 1982-05-04 1983-11-10 Nederlandse Centrale Organisatie Voor Toegepast- N Procede et dispositif permettant de preparer un hydrocarbure fluide produit a partir du charbon
RU2131903C1 (ru) * 1994-09-12 1999-06-20 Термтек А/С Способ термомеханического крекинга и гидрогенизации углеводородов

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US8911617B2 (en) 2005-12-16 2014-12-16 Petrobeam, Inc. Self-sustaining cracking of hydrocarbons
WO2010094697A1 (fr) 2009-02-17 2010-08-26 Bergen Teknologioverføring As Liquéfaction de lignine avec des composants gazeux
US20210171920A1 (en) * 2015-10-29 2021-06-10 Temple University-Of The Commonwealth System Of Higher Education Modification of 3' Terminal Ends of Nucleic Acids by DNA Polymerase Theta
US11993791B2 (en) * 2015-10-29 2024-05-28 Temple University-Of The Commonwealth System Of Higher Education Modification of 3′ terminal ends of nucleic acids by DNA polymerase theta

Also Published As

Publication number Publication date
PL371514A1 (en) 2005-06-27
LT2002012A (en) 2003-07-25
EP1471129A1 (fr) 2004-10-27
RU2203924C1 (ru) 2003-05-10
LT5078B (lt) 2003-12-29
AU2002365174A1 (en) 2003-09-16

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