[go: up one dir, main page]

WO2000017406A2 - Procede d'extraction de plomb dans des matieres premieres contenant du plomb - Google Patents

Procede d'extraction de plomb dans des matieres premieres contenant du plomb Download PDF

Info

Publication number
WO2000017406A2
WO2000017406A2 PCT/RU1999/000335 RU9900335W WO0017406A2 WO 2000017406 A2 WO2000017406 A2 WO 2000017406A2 RU 9900335 W RU9900335 W RU 9900335W WO 0017406 A2 WO0017406 A2 WO 0017406A2
Authority
WO
WIPO (PCT)
Prior art keywords
lead
potassium
κaliya
potassium hydroxide
solution
Prior art date
Application number
PCT/RU1999/000335
Other languages
English (en)
Russian (ru)
Other versions
WO2000017406A3 (fr
Inventor
Nikolai Vladimirovich Khodov
Oleg Konstantinovich Kuznetsov
Original Assignee
Nikolai Vladimirovich Khodov
Oleg Konstantinovich Kuznetsov
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Nikolai Vladimirovich Khodov, Oleg Konstantinovich Kuznetsov filed Critical Nikolai Vladimirovich Khodov
Priority to AU60124/99A priority Critical patent/AU6012499A/en
Publication of WO2000017406A2 publication Critical patent/WO2000017406A2/fr
Publication of WO2000017406A3 publication Critical patent/WO2000017406A3/fr

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B7/00—Working up raw materials other than ores, e.g. scrap, to produce non-ferrous metals and compounds thereof; Methods of a general interest or applied to the winning of more than two metals
    • C22B7/006—Wet processes
    • C22B7/008—Wet processes by an alkaline or ammoniacal leaching
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B13/00—Obtaining lead
    • C22B13/02—Obtaining lead by dry processes
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B13/00—Obtaining lead
    • C22B13/04—Obtaining lead by wet processes
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P10/00—Technologies related to metal processing
    • Y02P10/20—Recycling

Definitions

  • the invention relates to non-ferrous metals, in particular, to the method of extracting lead from lead-containing raw materials.
  • the indicated method of extracting lead from lead concentrate is very expensive due to the inadequate increase of the profitability of the ⁇ aib ⁇ lee bliz ⁇ im ⁇ ⁇ e ⁇ niches ⁇ y suschn ⁇ s ⁇ i yavlyae ⁇ sya s ⁇ s ⁇ b ( ⁇ , ⁇ , 0588235), in order to reduce ⁇ m za ⁇ a ⁇ on ⁇ egene ⁇ atsiyu gid ⁇ sida ⁇ lav ⁇ u s ⁇ svints ⁇ vym ⁇ ntsen ⁇ a ⁇ m vedu ⁇ in ⁇ isli ⁇ elny ⁇ usl ⁇ viya ⁇ , ⁇ duvaya v ⁇ zdu ⁇ che ⁇ ez ⁇ as ⁇ lav, ⁇ i e ⁇ m in ⁇ as ⁇ lave ⁇ b ⁇ azue ⁇ sya ⁇ eimusches ⁇ venn ⁇ sul ⁇ a ⁇ na ⁇ iya.
  • the process is reacting:
  • metal lead separates the alloy, which directly contains excess hydroxide, sodium sulfide, zinc sulfide and sodium hydroxide.
  • the suspension is filtered and obtained by a basic aqueous solution, which is contained, in the main. hydrated hydroxide and solid garden.
  • the reactive hydroxide discharges the sodium vapor, and the resulting hydroxide melt discharges into the reaction zone.
  • ⁇ ve ⁇ dy ⁇ sad ⁇ ⁇ dve ⁇ gayu ⁇ ⁇ e ⁇ atsii v ⁇ g ⁇ v ⁇ dn ⁇ g ⁇ v ⁇ tselachivaniya and ⁇ luchayu ⁇ sus ⁇ enziyu, ⁇ uyu ⁇ il ⁇ uyu ⁇ and ⁇ luchayu ⁇ ⁇ e ⁇ , ⁇ eds ⁇ avlyayuschy s ⁇ b ⁇ y ⁇ ve ⁇ dye chas ⁇ itsy sul ⁇ id ⁇ v tsin ⁇ a, copper and iron and ⁇ us ⁇ y ⁇ dy with ads ⁇ bi ⁇ vannym on i ⁇ ⁇ ve ⁇ n ⁇ s ⁇ i ⁇ as ⁇ v ⁇ m sulfonic
  • the aforementioned product is electrically processed and processed, and the sulfuric acid is released from the process and is clicked on, and the appliance is operated on. After washing and receiving the solution of the sulphate of the country, it is transferred to the operation of the leaching process.
  • P ⁇ s ⁇ avlennaya task ⁇ eshae ⁇ sya ⁇ em, ch ⁇ s ⁇ s ⁇ be in lead extraction from svinetss ⁇ de ⁇ zhascheg ⁇ s ⁇ ya, s ⁇ de ⁇ zhascheg ⁇ lead sul ⁇ idy, tsin ⁇ a, copper, iron and ⁇ us ⁇ uyu ⁇ du, v ⁇ lyuchayuschem ⁇ lav ⁇ u svints ⁇ v ⁇ g ⁇ ⁇ ntsen ⁇ a ⁇ a gid ⁇ sid ⁇ m with alkaline l ⁇ chn ⁇ g ⁇ me ⁇ alla ⁇ i ⁇ em ⁇ e ⁇ a ⁇ u ⁇ e 600 - 700 ° C ⁇ isu ⁇ s ⁇ vii ⁇ isli ⁇ elya, ⁇ dele- of me ⁇ alliches ⁇ g ⁇ lead ⁇ schel ⁇ chn ⁇ g ⁇ ⁇ as ⁇ lava and vyv ⁇ d lead from ⁇ ea ⁇ tsi ⁇ n
  • the rate of filtration of the water treatment unit is 25–30%; it is equal to 0,01 m 3 / m 2 • hour, and potassium hydroxide (50 - 52%) is 0, 3 m 3 / m : - hour, and Respectively, at 30 times the area of filtration.
  • Disasters (pulp) of the Ministry of Internal Affairs are not filtered out (50 - 52%).
  • ⁇ and the generation ⁇ 6 - 8 (for example 1, 0 - 1, 1) the sum of all the above listed impurities does not exceed 0, 001 - 0, 0005 mg / dm 3 .
  • the yield of the gvdruxide kalida on the smelter is 0, 7 - 1, 25 of the weight of the percentage.
  • the alloy promotes the first stage of the water treatment in combination with the liquid phase phase (1.1, -1, 0): 1, 0.
  • the resulting suspension containing ⁇ , ⁇ 2 8 ⁇ 4 , ⁇ 2 ⁇ 3 and empty, is filtered.
  • Zhid ⁇ aya ⁇ aza s ⁇ de ⁇ zhi ⁇ in ⁇ sn ⁇ vn ⁇ m, gid ⁇ sid ⁇ aliya ⁇ ntsen ⁇ atsiey with 50 - 52%, and in ⁇ ve ⁇ duyu ⁇ azu ⁇ e ⁇ e ⁇ dya ⁇ s ⁇ de ⁇ z haschie not lead ⁇ s ⁇ a ⁇ i ⁇ ntsen ⁇ a ⁇ a, and sul ⁇ a ⁇ ⁇ a ⁇ b ⁇ na ⁇ ⁇ aliya, ⁇ s ⁇ a ⁇ i schel ⁇ chn ⁇ g ⁇ ⁇ as ⁇ v ⁇ a, za- ⁇ vachennye ⁇ sad ⁇ m.
  • ⁇ delennaya ⁇ ⁇ as ⁇ v ⁇ a gvd ⁇ sida ⁇ aliya ⁇ ve ⁇ daya ⁇ aza ⁇ d- ve ⁇ gae ⁇ sya ⁇ myv ⁇ e on ⁇ il ⁇ e ⁇ gid ⁇ sida ⁇ aliya, ⁇ i e ⁇ m ⁇ myvn ⁇ y ⁇ as ⁇ v ⁇ na ⁇ avlyayu ⁇ leaching is ⁇ dn ⁇ g ⁇ schel ⁇ chn ⁇ g ⁇ ⁇ as ⁇ lava and ⁇ ve ⁇ dy ⁇ my- ⁇ y ⁇ s ⁇ a ⁇ na ⁇ avlyayu ⁇ on v ⁇ uyu s ⁇ adiyu leaching.
  • a large-scale recovery of sulphate is used. Leaching is carried out at a temperature of 80 - 90 ° C in order to create conditions for the maximum possible saturation of the potassium sulfate solution. After the dissolution of all the components, in the main, the sulphate and the potassium hydroxide, in the suspension add sulfuric acid in the amount of - 8. At the same time, the entire potassium chloride is sold in the potassium sulfate, and a number of other potassium, tobacco, zinc, lead, and mineral are excreted.
  • Suspension Filt- It rinses out of the liquid phase in a known manner, such as cooling and crystallization, consumes a potassium sulfate, which is a valuable product, and is discharged.
  • the lower and upper borders ⁇ distribute the increase in the volume of the specified mixed substances in al
  • FIG. 1 An indicative flow chart of the proposed method for recovering lead from lead-containing material is shown in FIG. All of the potassium hydroxide excreted from the process in the VVD is equivalent to the quantity of sulfate and calcium, the amount of calcium is compensated by a 50% reduction in the concentration of calcium. This product is combined with the waste from the first stage of leaching of the alkaline melt and is fed to the extraction.
  • the intentional use of the invention may be used to extract lead from lead-containing raw materials derived from lead sulphide.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Manufacturing & Machinery (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Environmental & Geological Engineering (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Geology (AREA)
  • Manufacture And Refinement Of Metals (AREA)
  • Nitrogen And Oxygen Or Sulfur-Condensed Heterocyclic Ring Systems (AREA)

Abstract

Cette invention concerne un procédé d'extraction de plomb qui consiste à envoyer de l'hydroxyde de potassium en fusion, des matières premières contenant du plomb et un gaz contenant de l'oxygène dans une zone de réaction à une température de 600 à 700° C. Le plomb est extrait de la zone de réaction et l'on effectue une première lixiviation aqueuse permettant d'obtenir une suspension qui consiste en un mélange comprenant des particules solides de sulfate de potassium, de carbonate de potassium, de sulfures de zinc, de cuivre, de fer et de roches stériles, ainsi qu'une solution aqueuse comprenant essentiellement de l'hydroxyde de potassium. On filtre ensuite la suspension et l'on obtient une solution contenant essentiellement de l'hydroxyde de potassium et des résidus solides. La solution d'hydroxyde de potassium est ensuite soumise à une évaporation, et l'hydroxyde de potassium en fusion ainsi obtenu est envoyé vers la zone de réaction. Après la première étape de lixiviation et de rinçage, les résidus solides sont soumis à une seconde lixiviation aqueuse où l'on introduit une solution inverse et de l'acide sulfurique tout en maintenant le pH entre 6 et 8. On obtient ainsi une suspension que l'on filtre de manière à obtenir un pain que l'on rince à l'eau et que l'on retire du processus. On retire ensuite les cristaux de sulfate de potassium de la solution aqueuse et saturée de sulfate de potassium, lesdits cristaux étant retirés du processus. La solution mère résultant de la cristallisation du sulfate de potassium est ensuite associée à l'eau de rinçage du pain, puis soumise à une seconde lixiviation.
PCT/RU1999/000335 1998-09-23 1999-09-14 Procede d'extraction de plomb dans des matieres premieres contenant du plomb WO2000017406A2 (fr)

Priority Applications (1)

Application Number Priority Date Filing Date Title
AU60124/99A AU6012499A (en) 1998-09-23 1999-09-14 Method for extracting lead from lead-containing raw materials

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
RU98117450 1998-09-23
RU98117450A RU2131474C1 (ru) 1998-09-23 1998-09-23 Способ извлечения свинца из свинецсодержащего сырья

Publications (2)

Publication Number Publication Date
WO2000017406A2 true WO2000017406A2 (fr) 2000-03-30
WO2000017406A3 WO2000017406A3 (fr) 2000-05-25

Family

ID=20210609

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/RU1999/000335 WO2000017406A2 (fr) 1998-09-23 1999-09-14 Procede d'extraction de plomb dans des matieres premieres contenant du plomb

Country Status (3)

Country Link
AU (1) AU6012499A (fr)
RU (1) RU2131474C1 (fr)
WO (1) WO2000017406A2 (fr)

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105907986B (zh) * 2016-06-29 2018-08-14 江西铜业集团公司 一种分银渣中铅的提取方法
CN112501451B (zh) * 2020-11-13 2022-09-13 桐乡市思远环保科技有限公司 一种采用溶剂萃取电积工艺生产金属铅的方法
CN113061736B (zh) * 2021-03-30 2022-03-22 攀钢集团攀枝花钢铁研究院有限公司 烧结机头灰中钾、铅、铁的分离方法

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4164416A (en) * 1976-12-20 1979-08-14 Rockwell International Corporation Metal recovery process
SU1486532A1 (ru) * 1987-08-18 1989-06-15 Gnii Tsvetnykh Metallov Способ переработки свинецсодёржащих сульфидных концентратов
SU1523581A1 (ru) * 1988-04-22 1989-11-23 Государственный научно-исследовательский институт цветных металлов Способ переработки сульфидных свинцовых концентратов
US5356455A (en) * 1992-09-14 1994-10-18 Nikolai Vladimirovich Khodov Process for recovering lead from lead-containing raw materials

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4164416A (en) * 1976-12-20 1979-08-14 Rockwell International Corporation Metal recovery process
SU1486532A1 (ru) * 1987-08-18 1989-06-15 Gnii Tsvetnykh Metallov Способ переработки свинецсодёржащих сульфидных концентратов
SU1523581A1 (ru) * 1988-04-22 1989-11-23 Государственный научно-исследовательский институт цветных металлов Способ переработки сульфидных свинцовых концентратов
US5356455A (en) * 1992-09-14 1994-10-18 Nikolai Vladimirovich Khodov Process for recovering lead from lead-containing raw materials

Also Published As

Publication number Publication date
RU2131474C1 (ru) 1999-06-10
AU6012499A (en) 2000-04-10
WO2000017406A3 (fr) 2000-05-25

Similar Documents

Publication Publication Date Title
US5039428A (en) Waste water treatment process using improved recycle of high density sludge
US5102556A (en) Method for rendering ferric hydroxide sludges recyclable
CN101838736B (zh) 湿法炼锌系统净液钴渣中有价金属的湿法分离方法
CN101717868B (zh) 从含铟镓蒸馏废酸中综合回收铟镓方法
CN103781923A (zh) 用于纯化氧化锌的方法
CN101743332B (zh) 从含有铟的氧化锌和/或溶液制备纯金属铟的方法
US4150976A (en) Method for the recovery of metallic copper
EP0124213A1 (fr) Procédé d'extraction
CN101603125B (zh) 一种镍液净化除杂的方法
CA1039064A (fr) Obtention du plomb et de l'argent a meme leurs sulfures
JP5512482B2 (ja) 亜鉛めっき廃液からの亜鉛の分離回収方法
US4124459A (en) Process for removing mercury from brine sludges
GB1595407A (en) Method of eliminating the influence of surfactants on the separation properties in liquid extraction systems
AU2012212381B2 (en) Precipitation of zinc from solution
US4579721A (en) Process for recovering metals from waste
WO2000017406A2 (fr) Procede d'extraction de plomb dans des matieres premieres contenant du plomb
CN104651618A (zh) 一种从含锡碲铋溶液中分离元素的方法
CN100376698C (zh) 含锰材料的湿法冶金改进工艺
KR19980076556A (ko) 다이아몬드 공구스크랩으로부터 유가금속의 회수방법
CN114350945B (zh) 一种铀钼矿湿法冶炼钼反萃取三相物分离、回收方法
CN104561563A (zh) 一种铟富集渣还原预浸工艺及其装置
CN114133059A (zh) 一种铜冶炼烟气洗涤污酸的净化方法
JP3632226B2 (ja) 金属含有排水の処理方法
JP4044068B2 (ja) 重金属類を含有する物質の処理方法
CN1571853B (zh) 处理硅酸锌精矿或硅酸锌矿以及硫化锌煅烧精矿的联合方法

Legal Events

Date Code Title Description
AK Designated states

Kind code of ref document: A2

Designated state(s): AT AU BG BR CA CN CZ DE DK FI GB IL IN JP KR MN MX NO PL SE SI SK TR UA US UZ YU

AL Designated countries for regional patents

Kind code of ref document: A2

Designated state(s): AM AZ BY KG KZ MD RU TJ TM AT BE CH CY DE DK ES FI FR GB GR IE IT LU MC NL PT SE

121 Ep: the epo has been informed by wipo that ep was designated in this application
AK Designated states

Kind code of ref document: A3

Designated state(s): AT AU BG BR CA CN CZ DE DK FI GB IL IN JP KR MN MX NO PL SE SI SK TR UA US UZ YU

AL Designated countries for regional patents

Kind code of ref document: A3

Designated state(s): AM AZ BY KG KZ MD RU TJ TM AT BE CH CY DE DK ES FI FR GB GR IE IT LU MC NL PT SE

DFPE Request for preliminary examination filed prior to expiration of 19th month from priority date (pct application filed before 20040101)
REG Reference to national code

Ref country code: DE

Ref legal event code: 8642

122 Ep: pct application non-entry in european phase