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US2196562A - Wetting agent for alkaline mercerizing solutions - Google Patents

Wetting agent for alkaline mercerizing solutions Download PDF

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Publication number
US2196562A
US2196562A US155821A US15582137A US2196562A US 2196562 A US2196562 A US 2196562A US 155821 A US155821 A US 155821A US 15582137 A US15582137 A US 15582137A US 2196562 A US2196562 A US 2196562A
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US
United States
Prior art keywords
mixture
lye
acid
weight
naphthenic
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
US155821A
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English (en)
Inventor
Lier Heinrich
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
FIRM CHEMICAL WORKS
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FIRM CHEMICAL WORKS
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Application granted granted Critical
Publication of US2196562A publication Critical patent/US2196562A/en
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Expired - Lifetime legal-status Critical Current

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Classifications

    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
    • D06M13/325—Amines
    • D06M13/342—Amino-carboxylic acids; Betaines; Aminosulfonic acids; Sulfo-betaines
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/32—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond
    • D06M11/36—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond with oxides, hydroxides or mixed oxides; with salts derived from anions with an amphoteric element-oxygen bond
    • D06M11/38—Oxides or hydroxides of elements of Groups 1 or 11 of the Periodic Table
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
    • D06M13/325—Amines
    • D06M13/335—Amines having an amino group bound to a carbon atom of a six-membered aromatic ring
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
    • D06M13/402—Amides imides, sulfamic acids
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S516/00—Colloid systems and wetting agents; subcombinations thereof; processes of
    • Y10S516/01—Wetting, emulsifying, dispersing, or stabilizing agents
    • Y10S516/03—Organic sulfoxy compound containing
    • Y10S516/04—Protein or carboxylic compound containing
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S516/00—Colloid systems and wetting agents; subcombinations thereof; processes of
    • Y10S516/01—Wetting, emulsifying, dispersing, or stabilizing agents
    • Y10S516/03—Organic sulfoxy compound containing
    • Y10S516/05—Organic amine, amide, or n-base containing
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S516/00—Colloid systems and wetting agents; subcombinations thereof; processes of
    • Y10S516/01—Wetting, emulsifying, dispersing, or stabilizing agents
    • Y10S516/07—Organic amine, amide, or n-base containing

Definitions

  • alkaline lyes of at least 15 B. for example mercerizing lyes
  • ramified aliphatic acids such aliphatic acids are meant the carbon chain of which is ramified or branched.
  • the amides coming into question are those made from naphthenic acids or any naphthenic acid fractions or from the ramified aliphatic carboxylic acids, in any known manner by means -of ammonia or monoor polyvalent aliphatic or cycloaliphatic amines which may eventually still contain one or more hydroxyl groups.
  • alkali-stable, highly sulphonated oils for example highly sulphonated castor oil
  • phenols as for example the cresols, especially metaand para-cresol, cresol mixtures, xylenols, xylenol mixtures, cresol-xylenol mix- 4 tures, ethyl phenols, propyl phenols, methylethyl phenols, methyl-propyl phenols as for example Carvacrol, phenols from wood-tar, tar phenols as mentioned in the British Patent No.
  • auxiliary emulsifiers are suitable as auxiliary emulsifiers; the initial members of the homologous series of the aliphatic and the aromatic benzeneand phenolsulphonic acids, for example butane-, pentane-, isopentane-sulphonic acids, xylol-, cymenesulphonic acids, butyl-phenolsulphonic acids, the acid sulphuric acid esters of straight-chained or ramified alcohols with 4 to 10 C atoms, the acid sulphuric acid esters of etheralcohols with one or more etheric oxygen bridges as well as the true ether-sulphonic acids obtainable from these esters by reaction with sodium sulphite, further the glucoside-like derivatives from sugars and normal ramified aliphatic alcohols or ether-alcohols.
  • the initial members of the homologous series of the aliphatic and the aromatic benzeneand phenolsulphonic acids for example
  • Ready prepared mixtures of the acid amides with the dispersing auxiliary substances are best adapted for carrying out the process.
  • the ingredients and proportion of the mixture it is possible to adapt the mixture to given conditions as regards lye concentration, lye temperature and resistance to wetting of the material to be treated, in such a way that clear, highly active lyes are obtained, which changes not at all or hardly at all in action, which are outstandingly adapted for carrying out alkalizations of all kinds, for examplev raw mercerization.
  • the presentinvention comprises a process for increasing the wetting-out power of alkaline lyes of more than 15 31%., consisting in adding to said lyes at least one amide of an aliphatic carboxylic acid selected from the class consisting of naphthenic and ramified aliphatic acids and at least one dispersing agent which is soluble and stable in alkaline solutions.
  • Another object of the invention consists in improved alkaline lyes of more than 15 B., containing at least one amide of an aliphatic carboxylic acid selected from the class consisting of naphthenic and ramified aliphatic acids and at least one dispersing agent which is soluble andstable in alkaline solutions.
  • the present invention comprises mixtures consisting of 40-1 per cent of at least one amide of an aliphatic carboxylic acid selected from the class consisting of naphthenic and ramified aliphatic acids and of 60-99 per cent of at least one dispersing agent which is soluble and limited to the details of the following examples.
  • Dry raw fabrics are slowly and unevenly wetted through by the naphthenic acid containing lye, but are immediately and quite uniformly Wetted through by the naphtheic acid amide containing lye, so that they rapidly sink down and strongly shrink.
  • the raw fabrics become wetted through uniformly in a moment and sink down in the lye within 10-30 seconds.
  • EXAMPLE 5 A mercerizing lye of 35 B. which contains 1.14% by weight of a mixture of by weight of technical cresol-xylenol mixture and of 15% by weight of naphthenic acid-di-n-propylamide (prepared from naphthenic acid chloride and difraction boiling between about 120-160" C. at a pressure of 8 mm. of mercury, by means of phosphorus trichloride) and contains 6.65% of nitrogen, is added to a mercerizing lye of 35 B. A clear liquid is obtained which after 24 hours open storage does not change either in it's character or its good action.
  • Raw fabrics become wetted through uniformly the moment they are laid on the lye and sink down within 8-9 seconds.
  • EXAMPLE 8 A mixture of 90 parts by weight of an approximately 65% aqueous solution of the sodium salt of the acid sulphuric acid ester of ethyleneglycol-monobutyl-ether and parts by weight of a mixture of naphthenic acid amides prepared by reaction, with ammonia, of the naphthenic acid chloride mixture from a technical naphthenic acid fraction of the acid number of about 280, is added in a proportion of 1.5% by volume to a caustic soda lye of 28 B. A clear liquid is obtained, the extraordinarily effective action of which is by far not reached by similar use alone of the acid sulphuric acid ester.
  • the shrinking of a dry Mako raw pearl yarn amounts after but seconds action to 21.8% of the original length, while in a comparative lye to which only 1.5% by volume of the sulphuric acid ester solution has been added, it only amounts to 15.0%.
  • EXAMPLE 9 A mixture of 95% by weight of technical high boiling xylenol mixture and 5% by weight of the reaction product of one molecule of ethyleneoxide and one equivalent part of the naphthenic acid amide mixture named in Example 8, when added in the proportion of 1.5% by volumeto a caustic soda lye of 30 B., yields a clear solution which immediately uniformly wets through raw twist fabrics and raw, undesized poplin, so that the fabrics sink down within about 8-11 seconds.
  • a still higher effect is obtained with a mixture of 10 parts of the liquid or solid part of the above named naphthenic acid amide with 90 parts of a technical xylenol' mixture.
  • Raw, undesized pieces of poplin are immediately uniformly wetted through in the first lye, so that they sink downwithin 17-24 seconds, while in a similar lye free from naphthenic acid amide they are only wetted non-uniformly and sink down only after about 1% minutes.
  • EXAMPLE 12 18 grams of a mixture of 90% by weight of N-di-(cr' -dioxypropyl) aniline (prepared from 1 molecule of aniline and 2 molecules of glycide) and of 10% by weight of the mixture of amides prepared from a high-boiling technical naphthenic acid fraction of the acid number 259, are added per litre to a caustic soda lye of 25 B. After short stirring a clear liquid is obtained in which a raw Mako pearl yarn 3/2 shrinks for 18% after 15 seconds and for 20.8% after seconds, in respect of its original length.
  • EXAMPLE 13 93% by weight of isoamylglucoside and 7% by weight of the naphthenic acid amide named in Example 12 are mixed together and 18 grams thereof are added per litre to a caustic soda lye of 28 B. or 18 grams thereof per litre to a caustic potash lye of 32 B.; clear liquids of good wetting and penetrating powers on raw yarns and fabrics are thereby obtained.
  • EXAMPLE 14 1.5% by volume of a mixture of 96% by weight of the 40% aqueous solution of technical sodium cymene sulphonate and of 4% by weight of the naphthenic acid amide mixture named in Example 12, is added to a caustic soda lye of 25 B. at 30 C.
  • the clear lye has a high wetting and penetrating power on raw fab ics and yarns.
  • a Mako raw pearl yarn 3/2 undergoes a shrinkage of 15.6% of the original length after but 15 seconds action as compared with that of only 11.3% in a lye to which 1.5% by volume of the plain solution of the sodium cymene sulphonate has been added.
  • Mercerizing lyes of more than 15 B. conaining at least one amide, free from basic :roups and sulphonic acid groups of an aliphatic :arboxylic acid selected from the class consistng of naphthenic and branched-chain aliphatic :arboxylic acids having at least 5 carbon atoms Lnd at least one dispersing agent which is solu- )le and stable in alkaline solutions.
  • Mercerizing lyes of more than 15 B. conaining 0.5 to 2 per cent of a mixture consistng of 40-1 per cent of the mixture of amidem ree from basic groups and sulfonic acid groups, repared from naphthenic acids of theacid numier of 230-280 and of 60-99 per cent of a techiical monochlorocresol mixture.
  • compositions of matter consisting of 40-1 per cent of at least one amide, free from basic groups and sulfonic acid groups of an aliphatic carboxylic acid selected from the class consisting of naphthenic and branched-chain aliphatic carboxylic acids having at least 5 carbon atoms and of 60-99 per cent of at least one dispersing agent which is soluble and stable in alkaline solutions, said mixtures being valuable products for increasing the Wetting-out power of mercerising lyes of more than 15 B.
  • compositions of matter consisting of 40-1 per cent of at least one amide, free from basic groups and sulfonic acid groups of a naphthenic acid and of 60-99 per cent of at least one dispersing agent which is soluble and stable in alkaline solutions, said mixtures being valuable products for increasing the wetting-out power of mercerizing lyes of more than 15 B.
  • compositions of matter consisting of 40-1 per cent of the mixture of amides, free from basic groups and sulfonic acid groups, prepared from naphthenic acids of the acid number of 230-280 and of 60-99 per cent of a technical xylenol mixture.
  • compositions of matter consisting of 40-1 per cent of the mixture of amides, free from basic groups and sulfonic acid groups, prepared from naphthenic acids of the acid number 2130-280 and of 60-99 per cent of a technical monochlorocresol mixture.
  • compositions of matter consisting of 40-1 per cent of the mixture of amldesyfree from basic groups and sulfonic acid groups, prepared from naphthenic acids of the'acid number of 230-280 and of 60-99 per cent of the sulphuric acid ester of ethylenegly-.

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  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
  • Chemical And Physical Treatments For Wood And The Like (AREA)
  • Curing Cements, Concrete, And Artificial Stone (AREA)
  • Chemical Or Physical Treatment Of Fibers (AREA)
US155821A 1936-08-03 1937-07-26 Wetting agent for alkaline mercerizing solutions Expired - Lifetime US2196562A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CH491048X 1936-08-03

Publications (1)

Publication Number Publication Date
US2196562A true US2196562A (en) 1940-04-09

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Family Applications (1)

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US155821A Expired - Lifetime US2196562A (en) 1936-08-03 1937-07-26 Wetting agent for alkaline mercerizing solutions

Country Status (5)

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US (1) US2196562A (de)
CH (1) CH191827A (de)
DE (1) DE725793C (de)
FR (1) FR825107A (de)
GB (1) GB491048A (de)

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Publication number Publication date
CH191827A (de) 1937-07-15
DE725793C (de) 1942-09-30
FR825107A (fr) 1938-02-24
GB491048A (en) 1938-08-25

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