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TWI869438B - Solder ball array mask - Google Patents

Solder ball array mask Download PDF

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Publication number
TWI869438B
TWI869438B TW109128786A TW109128786A TWI869438B TW I869438 B TWI869438 B TW I869438B TW 109128786 A TW109128786 A TW 109128786A TW 109128786 A TW109128786 A TW 109128786A TW I869438 B TWI869438 B TW I869438B
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Taiwan
Prior art keywords
electrodeposition layer
primary
mask
solder ball
layer
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TW109128786A
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Chinese (zh)
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TW202123790A (en
Inventor
武田久司
露木賢一
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日商雅典股份有限公司
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Priority claimed from JP2019224242A external-priority patent/JP6713154B1/en
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Publication of TW202123790A publication Critical patent/TW202123790A/en
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Abstract

本發明之課題在於,解決一次電沈積層從形成有遮罩背面之突起部的二次電沈積層脫落而導致突起破損,從而導致導電性焊球之搭載率降低的問題。 本發明之焊球陣列用遮罩1具有對應於特定之陣列圖案之開口部30,藉由將導電性焊球載入上述開口部30,而將上述導電球性焊球搭載於特定位置,且於上述焊球陣列用遮罩1之與被搭載體相對之側,具備藉由在一次電沈積層3上積層二次電沈積層4而形成之突起2,上述突起2之一次電沈積層3具備不易從二次電沈積層4脫落之不易脫落構造。又,上述突起2之一次電沈積層3俯視下為環狀,於上述突起2之一次電沈積層3與二次電沈積層4之界面處具備卡止部11。The subject of the present invention is to solve the problem that the primary electrodeposition layer falls off from the secondary electrodeposition layer having the protrusion formed on the back of the mask, resulting in damage to the protrusion, thereby reducing the loading rate of the conductive solder ball. The solder ball array mask 1 of the present invention has an opening 30 corresponding to a specific array pattern, and the conductive solder ball is loaded at a specific position by loading the conductive solder ball into the above-mentioned opening 30. In addition, on the side of the solder ball array mask 1 opposite to the loaded body, there is a protrusion 2 formed by stacking the secondary electrodeposition layer 4 on the primary electrodeposition layer 3, and the primary electrodeposition layer 3 of the above protrusion 2 has a non-detachable structure that is not easy to fall off from the secondary electrodeposition layer 4. Furthermore, the primary electrodeposition layer 3 of the protrusion 2 is ring-shaped in a plan view, and a stopper 11 is provided at the interface between the primary electrodeposition layer 3 of the protrusion 2 and the secondary electrodeposition layer 4.

Description

焊球陣列用遮罩Solder ball array mask

本發明係關於一種適於排列導電性焊球之焊球陣列用遮罩及其製造方法。The present invention relates to a solder ball array mask suitable for arranging conductive solder balls and a manufacturing method thereof.

先前以來,於導電性焊球陣列用金屬遮罩(以下,簡稱為遮罩)中,為了防止形成於導電性焊球搭載部之電極上之助焊劑等附著於遮罩,而使用了於基板面側之開口圖案之周邊部形成有凹部之遮罩。作為該凹部之形成方法,揭示有如下之遮罩之製造方法:藉由複數次電鑄法,於一次電沈積層上積層二次電沈積層而形成凸部,並且將未設置一次電沈積層而僅由二次電沈積層形成之部位作為凹部(參照專利文獻1)。Conventionally, in a metal mask for a conductive solder ball array (hereinafter referred to as a mask), a mask having a recess formed on the periphery of an opening pattern on the substrate surface is used in order to prevent the flux formed on the electrode of the conductive solder ball mounting portion from adhering to the mask. As a method for forming the recess, a mask manufacturing method is disclosed as follows: a secondary electrodeposition layer is deposited on a primary electrodeposition layer by multiple electrocasting processes to form a convex portion, and a portion formed only by the secondary electrodeposition layer without the primary electrodeposition layer is used as a recess (see Patent Document 1).

又,作為藉由進行複數次電鍍法而形成凸部之遮罩之製造方法,有以下說明之專利文獻2。專利文獻2所記載之遮罩之製造方法係焊球陣列用遮罩之製造方法,其特徵在於,該焊球陣列用遮罩具備遮罩本體及突起,遮罩本體係藉由鍍覆而形成,且形成有供載入之導電性焊球插通之複數個開口部,突起係藉由鍍覆而形成,且部分突出於上述遮罩本體背面之上述開口部以外,上述突起之前端部形成為其外圍邊緣部具有圓度之R形;且該焊球陣列用遮罩之製造方法具備如下步驟:於SUS母材上形成上述突起形成用抗蝕劑層;藉由以使上述突起成為特定高度之方式於SUS母材上進行鍍覆,而形成第一鍍覆層;於第一鍍層之形成結束之後,去除上述突起形成用抗蝕劑層;除去上述突起以外之第一鍍覆層,於SUS母材上留下由第一鍍覆層形成之突起;於上述SUS母材上之上述突起之間形成複數個開口部形成用抗蝕劑層;藉由以使上述遮罩本體成為指定厚度之方式於SUS母材及上述突起上進行鍍覆,而形成第二鍍覆層;於第二鍍覆層之形成結束之後,去除上述複數個開口部形成用抗蝕劑層;以及從上述SUS母材上剝離由第一鍍覆層及第二鍍覆層構成之突起以及遮罩本體之鍍覆層(參照專利文獻2)。 再者,電鑄法與電鍍法只是表達上之不同,技術內容實質上相同。 [先前技術文獻] [專利文獻]In addition, as a method for manufacturing a mask in which a protrusion is formed by performing a plurality of electroplating processes, there is patent document 2 described below. The method for manufacturing a mask described in Patent Document 2 is a method for manufacturing a mask for a solder ball array, and is characterized in that the mask for a solder ball array comprises a mask body and protrusions, the mask body is formed by plating, and has a plurality of openings for inserting conductive solder balls to be loaded, the protrusions are formed by plating, and partially protrude beyond the openings on the back of the mask body, and the front end of the protrusions is formed into an R-shape with a rounded outer edge; and the method for manufacturing a mask for a solder ball array comprises the following steps: forming an anti-etching agent layer for forming the protrusions on a SUS base material; plating the SUS base material in such a manner that the protrusions have a specific height, thereby forming a first plating layer; After the formation of the first coating is completed, the anti-etching agent layer for forming the protrusion is removed; the first coating layer other than the protrusion is removed, and the protrusion formed by the first coating layer is left on the SUS base material; a plurality of anti-etching agent layers for forming openings are formed between the protrusions on the SUS base material; by making the mask body become a specified thickness The method of coating the SUS base material and the protrusions in a manner of degree to form a second coating layer; after the formation of the second coating layer is completed, the plurality of anti-etching agent layers for forming the openings are removed; and the coating layer of the protrusions and the mask body formed by the first coating layer and the second coating layer is peeled off from the SUS base material (refer to patent document 2). Furthermore, the electrocasting method and the electroplating method are only different in expression, and the technical contents are substantially the same. [Prior technical document] [Patent document]

[專利文獻1]日本專利特開2010-247500號公報 [專利文獻2]日本專利特開2017-5053號公報[Patent document 1] Japanese Patent Publication No. 2010-247500 [Patent document 2] Japanese Patent Publication No. 2017-5053

[發明所欲解決之問題][The problem the invention is trying to solve]

藉由上述專利文獻1或專利文獻2所記載之製造方法,能夠於遮罩背面形成任意形態之突起(以下,亦稱為突起部或凸部)。該突起係於一次電沈積層之上積層二次電沈積層而形成,一次電沈積層係藉由一次電鑄步驟而形成,二次電沈積層係藉由二次電鑄步驟而形成。因此,該等兩個步驟之間存在時間差,於一次電鑄步驟與二次電鑄步驟中,即使完全相同地設定電鑄條件,一次電沈積層與二次電沈積層之間亦會存在邊界。By the manufacturing method described in the above-mentioned patent document 1 or patent document 2, a protrusion (hereinafter also referred to as a protrusion or a convex portion) of any shape can be formed on the back of the mask. The protrusion is formed by stacking a secondary electrodeposition layer on the primary electrodeposition layer. The primary electrodeposition layer is formed by a primary electrocasting step, and the secondary electrodeposition layer is formed by a secondary electrocasting step. Therefore, there is a time difference between the two steps. In the primary electrocasting step and the secondary electrocasting step, even if the electrocasting conditions are set exactly the same, there will be a boundary between the primary electrodeposition layer and the secondary electrodeposition layer.

若存在邊界,則於一次電沈積層與二次電沈積層之界面處密接性會降低。即便是為提高界面處之密接性而於一次電鑄步驟之後對一次電沈積層進行了鹽酸處理等化學表面處理,密接性之提高亦存在極限。而且,若於反覆使用遮罩之階段反覆進行清洗操作等,則會出現以下問題:於密接性較低之遮罩中,因對遮罩施加之外力而導致一次電沈積層從形成有突起之二次電沈積層脫落。If there is a boundary, the adhesion at the interface between the primary electrodeposited layer and the secondary electrodeposited layer will be reduced. Even if the primary electrodeposited layer is subjected to chemical surface treatment such as hydrochloric acid treatment after the primary electrocasting step to improve the adhesion at the interface, there is a limit to the improvement of adhesion. In addition, if cleaning operations are repeatedly performed during the stage of repeated use of the mask, the following problem will occur: in the mask with low adhesion, the primary electrodeposited layer will fall off from the secondary electrodeposited layer with protrusions due to external force applied to the mask.

圖10表示於藉由先前技術製造出之遮罩1中,一次電沈積層3從形成有突起2之二次電沈積層4脫落之狀態。圖10(a)表示正常狀態,圖10(b)表示從突起側(遮罩之背面側)施加了外力F之狀態。由於遮罩之厚度薄至數十μm程度,因此,若從突起側施加外力,則遮罩容易變形。其結果,於一次電沈積層之外周部與二次電沈積層之界面處產生間隙,一次電沈積層以被推出之方式脫落。雖然一次電沈積層是否脫落實際上取決於外力之大小,但若反覆使用遮罩,則確認到有相當數量之突起之一次電沈積層發生脫落。FIG10 shows a state in which a primary electrodeposition layer 3 is peeled off from a secondary electrodeposition layer 4 having a protrusion 2 formed thereon in a mask 1 manufactured by the prior art. FIG10(a) shows a normal state, and FIG10(b) shows a state in which an external force F is applied from the protrusion side (the back side of the mask). Since the thickness of the mask is as thin as tens of μm, if an external force is applied from the protrusion side, the mask is easily deformed. As a result, a gap is generated at the interface between the outer periphery of the primary electrodeposition layer and the secondary electrodeposition layer, and the primary electrodeposition layer is peeled off in a pushed-out manner. Although whether the primary electrodeposition layer falls off actually depends on the size of the external force, if the mask is used repeatedly, it is confirmed that a considerable amount of the primary electrodeposition layer with protrusions falls off.

若一次電沈積層從形成有突起之二次電沈積層脫落,則亦有突起整體之強度降低而導致於遮罩之使用中突起破損的情況。其結果,存在以下問題:形成於導電性焊球搭載部之電極上之助焊劑附著於遮罩,而導致焊球之搭載率降低。If the primary electrodeposition layer falls off from the secondary electrodeposition layer on which the protrusions are formed, the strength of the protrusions as a whole may be reduced, resulting in the protrusions being damaged during use of the mask. As a result, there is a problem that the flux formed on the electrode of the conductive solder ball loading portion adheres to the mask, resulting in a reduction in the solder ball loading rate.

又,若一次電沈積層從形成有突起之二次電沈積層脫落,則於載入導電性焊球之遮罩之表面側產生作為脫落痕跡之凹痕,因此,存在導電性焊球被鉤掛在凹痕之邊緣而無法確實地排列導電性焊球之問題。 [解決問題之技術手段]Furthermore, if the primary electrodeposition layer falls off from the secondary electrodeposition layer formed with the protrusions, a dent as a mark of the detachment is generated on the surface side of the mask on which the conductive solder balls are loaded, and therefore there is a problem that the conductive solder balls are hooked on the edge of the dent and cannot be accurately arranged. [Technical means for solving the problem]

本發明係一種焊球陣列用遮罩,其特徵在於:具有對應於特定之陣列圖案之開口部,且藉由將導電性焊球載入上述開口部,而將上述導電性焊球搭載於特定位置,且該焊球陣列用遮罩具備複數個一次電沈積層及二次電沈積層:該複數個一次電沈積層隔開形成於上述焊球陣列用遮罩之表面側之複數個部位,該二次電沈積層一體形成於上述一次電沈積層以外之部位及上述一次電沈積層上;於上述焊球陣列用遮罩之與被搭載體相對之側,具有由上述一次電沈積層與上述二次電沈積層形成之突起部,於上述突起部之一次電沈積層與二次電沈積層之界面處具有卡止部,上述突起部之一次電沈積層不易從二次電沈積層脫落。 又,本發明之焊球陣列用遮罩之特徵在於:上述突起部之一次電沈積層於俯視下為環狀,上述卡止部為一次電沈積層之內周面與二次電沈積層之間之界面。 又,本發明之焊球陣列用遮罩之特徵在於:上述卡止部於剖視下為蘑菇狀或大致紡錘狀。 [發明之效果]The present invention is a solder ball array mask, which is characterized in that: it has an opening corresponding to a specific array pattern, and by loading the conductive solder ball into the opening, the conductive solder ball is placed at a specific position, and the solder ball array mask has a plurality of primary electrodeposition layers and a secondary electrodeposition layer: the plurality of primary electrodeposition layers are separated and formed at a plurality of locations on the surface side of the solder ball array mask, and the secondary electrodeposition layers are separated and formed at a plurality of locations on the surface side of the solder ball array mask. The secondary electrodeposition layer is integrally formed on a portion other than the primary electrodeposition layer and on the primary electrodeposition layer; the side of the solder ball array mask opposite to the carrier body has a protrusion formed by the primary electrodeposition layer and the secondary electrodeposition layer, and a stopper is provided at the interface between the primary electrodeposition layer and the secondary electrodeposition layer of the protrusion, so that the primary electrodeposition layer of the protrusion is not easy to fall off from the secondary electrodeposition layer. In addition, the solder ball array mask of the present invention is characterized in that the primary electrodeposition layer of the protrusion is annular in a plan view, and the stopper is the interface between the inner peripheral surface of the primary electrodeposition layer and the secondary electrodeposition layer. Furthermore, the solder ball array mask of the present invention is characterized in that the above-mentioned locking portion is mushroom-shaped or roughly hammer-shaped in cross-section. [Effect of the invention]

根據本發明之遮罩,能夠提高形成有突起之一次電沈積層與二次電沈積層之界面之密接性,防止一次電沈積層從二次電沈積層脫落。其結果,能夠防止於遮罩使用中突起破損,並且形成於導電性焊球搭載部之電極上之助焊劑不會附著於遮罩上,從而能夠防止導電性焊球之搭載率降低。又,由於不會在載入導電性焊球之遮罩之表面側產生凹痕,因此,能夠順暢且確實地排列導電性焊球。According to the mask of the present invention, the adhesion of the interface between the primary electrodeposition layer formed with the protrusion and the secondary electrodeposition layer can be improved, and the primary electrodeposition layer can be prevented from falling off from the secondary electrodeposition layer. As a result, the protrusion can be prevented from being damaged during the use of the mask, and the flux formed on the electrode of the conductive solder ball loading part will not adhere to the mask, thereby preventing the conductive solder ball loading rate from being reduced. In addition, since no dents are generated on the surface side of the mask where the conductive solder ball is loaded, the conductive solder ball can be arranged smoothly and reliably.

以下,一面參照圖式一面對用於實施本發明之方式加以說明。於焊球陣列用遮罩中,能夠藉由實施複數次電鑄步驟而於遮罩背面形成突起。先前技術之突起係於一次電沈積層上積層二次電沈積層而形成,但一次電沈積層與二次電沈積層之界面之密接性弱,若反覆使用遮罩,則會導致一次電沈積層從二次電沈積層上脫落。The following is a description of the method for implementing the present invention with reference to the drawings. In a solder ball array mask, a protrusion can be formed on the back of the mask by performing multiple electroplating steps. The protrusion of the prior art is formed by stacking a secondary electroplating layer on a primary electroplating layer, but the interface between the primary electroplating layer and the secondary electroplating layer has weak adhesion. If the mask is used repeatedly, the primary electroplating layer will fall off from the secondary electroplating layer.

因此,本發明之發明人為了提高一次電沈積層與二次電沈積層之界面之密接性而進行了精心研究,為了提高密接性,可以考慮加大界面之面積本身。但是,突起之俯視形狀之尺寸勢必有其侷限,要使構成突起之一次電沈積層之俯視面積增加有其限度。 [實施例1]Therefore, the inventors of the present invention have conducted careful research to improve the adhesion of the interface between the primary electrodeposition layer and the secondary electrodeposition layer. In order to improve the adhesion, it is possible to consider increasing the area of the interface itself. However, the size of the top view shape of the protrusion must have its limitations, and there is a limit to increasing the top view area of the primary electrodeposition layer constituting the protrusion. [Example 1]

圖1係模式性表示實施例1之遮罩1之突起2之放大剖視圖。圖示之突起2係於一次電沈積層3上積層二次電沈積層4而形成,一次電沈積層3於俯視下為環狀。環狀之形態不限於圓形,亦可為橢圓形或卵形、進而為多邊形等,但於本實施例中為圓環形。實際上,由於遮罩大多為其一邊具有數百mm之大小,從而一個遮罩上將形成數千個如圖所示之突起2。FIG. 1 is an enlarged cross-sectional view schematically showing a protrusion 2 of a mask 1 of Example 1. The protrusion 2 shown in the figure is formed by stacking a secondary electrodeposition layer 4 on a primary electrodeposition layer 3, and the primary electrodeposition layer 3 is ring-shaped when viewed from above. The shape of the ring is not limited to a circle, and can also be an ellipse or an egg, or even a polygon, but in this embodiment it is a ring. In practice, since most masks have a size of several hundred mm on one side, thousands of protrusions 2 as shown in the figure will be formed on one mask.

若如此般將一次電沈積層3之俯視形狀設為圓環狀,則一次電沈積層3與二次電沈積層4俯視下之界面5之面積於環狀之內側將會減少相當於一次電沈積層3之界面消失之部分,另一方面,由於在一次電沈積層3之環狀之內側亦形成二次電沈積層4,因此於環狀之內側會形成相當於一次電沈積層3之厚度的縱向之環狀界面6,從而界面之面積增加。例如,當於環狀之內徑尺寸與一次電沈積層3之厚度尺寸相等之情況下,界面之面積相對減少部分增加0.75π(2.36)倍。其結果,包括環狀之一次電沈積層3之外周上之界面7在內的一次電沈積層3與二次電沈積層4之界面整體之面積增加。If the top view shape of the primary electrodeposition layer 3 is set to a circular ring shape in this way, the area of the interface 5 between the primary electrodeposition layer 3 and the secondary electrodeposition layer 4 in the top view will be reduced on the inner side of the ring by an amount equivalent to the disappearance of the interface of the primary electrodeposition layer 3. On the other hand, since the secondary electrodeposition layer 4 is also formed on the inner side of the ring of the primary electrodeposition layer 3, a longitudinal ring-shaped interface 6 equivalent to the thickness of the primary electrodeposition layer 3 will be formed on the inner side of the ring, thereby increasing the area of the interface. For example, when the inner diameter of the ring is equal to the thickness of the primary electrodeposition layer 3, the area of the interface is relatively reduced by 0.75π (2.36) times. As a result, the overall area of the interface between the primary electrodeposition layer 3 and the secondary electrodeposition layer 4, including the interface 7 on the outer periphery of the ring-shaped primary electrodeposition layer 3, is increased.

界面面積之增加雖然能夠有效地提高一次電沈積層3與二次電沈積層4之界面之密接性,但是,比增加面積更為重要的是,若將一次電沈積層3之俯視形狀形成為環狀,則即使從突起2側作用外力F,環狀之一次電沈積層3亦被卡止於二次電沈積層4上,從而能夠實現不易脫落之構造。Although the increase in interface area can effectively improve the adhesion of the interface between the primary electrodeposition layer 3 and the secondary electrodeposition layer 4, what is more important than increasing the area is that if the top view shape of the primary electrodeposition layer 3 is formed into a ring shape, then even if an external force F acts from the side of the protrusion 2, the ring-shaped primary electrodeposition layer 3 will be stuck on the secondary electrodeposition layer 4, thereby realizing a structure that is not easy to fall off.

於圖1所示之遮罩1中,由於遮罩1之厚度薄至數十μm程度,因此,若從突起2側作用外力F,則遮罩1變形,而於一次電沈積層3之外周面與二次電沈積層4之界面7處作用使其產生間隙之力。而且,於一次電沈積層3之外周面與二次電沈積層4之界面7處,實際上亦會產生間隙。另一方面,由於環狀之一次電沈積層3之內周面與二次電沈積層4之間存在界面6,因此,若從突起2側作用外力F,則外力F會在該界面6,成為擴大界面直徑之方向上之推壓力而起作用。因此,即使作用外力F,亦能夠維持一次電沈積層3卡止於與二次電沈積層4之界面6之狀態,無損該界面6處之密接性,從而能夠防止一次電沈積層3從形成有突起2之二次電沈積層4脫落。 [實施例2]In the mask 1 shown in FIG. 1 , since the thickness of the mask 1 is as thin as several tens of μm, if an external force F is applied from the side of the protrusion 2, the mask 1 is deformed, and a force to generate a gap is applied at the interface 7 between the outer peripheral surface of the primary electrodeposition layer 3 and the secondary electrodeposition layer 4. Moreover, a gap is actually generated at the interface 7 between the outer peripheral surface of the primary electrodeposition layer 3 and the secondary electrodeposition layer 4. On the other hand, since there is an interface 6 between the inner peripheral surface of the annular primary electrodeposition layer 3 and the secondary electrodeposition layer 4, if an external force F is applied from the side of the protrusion 2, the external force F acts on the interface 6 as a pushing force in a direction of expanding the diameter of the interface. Therefore, even if an external force F is applied, the primary electrodeposition layer 3 can be kept stuck at the interface 6 with the secondary electrodeposition layer 4 without damaging the adhesion at the interface 6, thereby preventing the primary electrodeposition layer 3 from falling off from the secondary electrodeposition layer 4 formed with the protrusion 2. [Example 2]

圖2係模式性表示實施例2之遮罩1之突起2之放大剖視圖。該實施例中之突起2於剖視下,一次電沈積層3形成為倒蘑菇狀。即,具有將蘑菇狀之傘8與柄9倒置之形狀。因此,即使從突起2側作用外力,亦不會對構成蘑菇狀之傘8之一次電沈積層3與二次電沈積層4之界面作用如使彼此分離之大小之力。假設即使作用較大之力,亦僅在相當於蘑菇狀之柄9之外周之部分之界面7形成微小之間隙,蘑菇狀之傘8之部分卡止於二次電沈積層4。因此,即使從突起2側作用外力,亦能夠維持一次電沈積層3卡止於與二次電沈積層4之卡止部11之狀態,從而能夠防止一次電沈積層3從二次電沈積層4脫落。 [實施例3]FIG2 is an enlarged cross-sectional view schematically showing the protrusion 2 of the mask 1 of Example 2. In the protrusion 2 of this example, the primary electrodeposition layer 3 is formed into an inverted mushroom shape when viewed in cross section. That is, it has a shape in which the mushroom-shaped umbrella 8 and the handle 9 are inverted. Therefore, even if an external force is applied from the side of the protrusion 2, a force of a magnitude that separates the primary electrodeposition layer 3 and the secondary electrodeposition layer 4 constituting the mushroom-shaped umbrella 8 will not be applied to the interface. Even if a relatively large force is applied, only a tiny gap will be formed at the interface 7 corresponding to the outer periphery of the mushroom-shaped handle 9, and part of the mushroom-shaped umbrella 8 will be stuck to the secondary electrodeposition layer 4. Therefore, even if an external force acts from the side of the protrusion 2, the primary electrodeposition layer 3 can be kept stuck in the stopper 11 of the secondary electrodeposition layer 4, thereby preventing the primary electrodeposition layer 3 from falling off from the secondary electrodeposition layer 4. [Example 3]

圖3係模式性表示實施例3之遮罩1之突起2之放大剖視圖。該實施例中之突起2於剖視下,一次電沈積層3被形成為大致紡錘狀。此處,所謂大致紡錘狀係指圓柱狀之中間部之直徑粗,而兩端之直徑逐漸變細之形狀。剖視下一次電沈積層3形成為大致紡錘狀之突起2發揮與實施例2相同之作用效果。即,即使從突起2側作用外力,亦僅在相當於大致紡錘狀之一次電沈積層3之外周之部分之界面7產生微小之間隙,一次電沈積層3之最大直徑部分卡止於與二次電沈積層之卡止部11。因此,即使從突起2側作用外力,亦能夠維持一次電沈積層3卡止於與二次電沈積層4之卡止部11之狀態,從而能夠防止一次電沈積層3從二次電沈積層4脫落。 [製造方法之說明]FIG3 is an enlarged cross-sectional view schematically showing the protrusion 2 of the mask 1 of Example 3. In the protrusion 2 of this example, the primary electrodeposition layer 3 is formed into a roughly spun hammer shape under cross-sectional view. Here, the so-called roughly spun hammer shape refers to a shape in which the diameter of the middle part of the cylinder is thick and the diameters of both ends gradually become thinner. The protrusion 2 in which the primary electrodeposition layer 3 is formed into a roughly spun hammer shape under cross-sectional view exerts the same effect as that of Example 2. That is, even if an external force is applied from the side of the protrusion 2, only a tiny gap is generated at the interface 7 of the portion corresponding to the outer periphery of the roughly spun-hammer-shaped primary electrodeposition layer 3, and the maximum diameter portion of the primary electrodeposition layer 3 is stuck at the stop portion 11 with the secondary electrodeposition layer. Therefore, even if an external force is applied from the side of the protrusion 2, the primary electrodeposition layer 3 can be kept stuck at the stop portion 11 with the secondary electrodeposition layer 4, thereby preventing the primary electrodeposition layer 3 from falling off from the secondary electrodeposition layer 4. [Explanation of the manufacturing method]

基於圖4所示之步驟,依次對本發明之實施例1之焊球陣列用遮罩之製造方法進行說明。Based on the steps shown in FIG. 4 , the manufacturing method of the solder ball array mask of the first embodiment of the present invention is described in sequence.

如圖4(a)所示,準備母模20,並且於該母模20之表面上形成光阻膜21。母模20只要為具有導電性者則可為任意,於本實施例中使用了SUS(Stainless Steel,不鏽鋼)材。接下來,如圖4(b)所示,於光阻膜21上,利用眾所周知之方法將一次圖案抗蝕劑膜22曝光。As shown in FIG4(a), a master mold 20 is prepared, and a photoresist film 21 is formed on the surface of the master mold 20. The master mold 20 can be any material as long as it has conductivity, and in this embodiment, SUS (Stainless Steel) is used. Next, as shown in FIG4(b), a primary pattern resist film 22 is exposed on the photoresist film 21 using a well-known method.

如圖4(c)所示,對描繪有一次圖案之一次圖案抗蝕劑膜22進行顯影並乾燥,將一次圖案抗蝕劑膜22形成於母模20上。如圖5所示,至此為止之步驟中所形成之一次圖案抗蝕劑膜22之俯視形狀由中心部之圓形抗蝕劑及與其形成為同心狀之環狀抗蝕劑所構成。此處,一次圖案抗蝕劑膜22可將負型之感光性乾膜抗蝕劑膜按照特定高度層壓一片或數片而形成。As shown in FIG4(c), the primary pattern resist film 22 having the primary pattern drawn thereon is developed and dried, and the primary pattern resist film 22 is formed on the master mold 20. As shown in FIG5, the top view of the primary pattern resist film 22 formed in the steps up to this point is composed of a circular resist in the center and an annular resist formed concentrically therewith. Here, the primary pattern resist film 22 can be formed by laminating one or more sheets of a negative photosensitive dry film resist film at a specific height.

將形成有一次圖案抗蝕劑膜22之母模20放置於在特定條件下所製備之電鑄槽中,且如圖4(d)所示,將電沈積金屬電鑄於母模20之未被一次圖案抗蝕劑膜22覆蓋之表面上直至與一次圖案抗蝕劑膜22之高度相同之程度,從而形成一次電沈積層3。可使用Ni作為電沈積金屬而形成一次電沈積層3。接下來,如圖4(e)所示,去除一次圖案抗蝕劑膜22。The master mold 20 formed with the primary pattern resist film 22 is placed in an electrocasting tank prepared under specific conditions, and as shown in FIG4(d), the electro-deposited metal is electro-casted on the surface of the master mold 20 not covered by the primary pattern resist film 22 until the height is the same as the primary pattern resist film 22, thereby forming a primary electro-deposited layer 3. Ni can be used as the electro-deposited metal to form the primary electro-deposited layer 3. Next, as shown in FIG4(e), the primary pattern resist film 22 is removed.

如圖4(f)所示,去除作為遮罩不需要之廢棄電沈積層23等。如圖6所示,至此為止之步驟中所形成之一次電沈積層3之俯視形狀為圓環狀。As shown in Fig. 4(f), the waste electro-deposition layer 23 which is not needed as a mask is removed. As shown in Fig. 6, the primary electro-deposition layer 3 formed in the steps up to this point has a ring shape in top view.

如圖4(g)所示,於一次電沈積層3及母模20之表面上形成光阻膜25。該光阻膜25係將負型之感光性乾膜抗蝕劑膜按照特定高度層壓一片或數片而形成。接下來,如圖4(h)所示,於光阻膜25上藉由眾所周知之方法將二次圖案抗蝕劑膜26曝光。As shown in FIG4(g), a photoresist film 25 is formed on the surface of the primary electrodeposition layer 3 and the master mold 20. The photoresist film 25 is formed by laminating one or more sheets of a negative photosensitive dry film resist film at a specific height. Next, as shown in FIG4(h), a secondary pattern resist film 26 is exposed on the photoresist film 25 by a well-known method.

如圖4(i)所示,藉由對描繪有二次圖案之二次圖案抗蝕劑膜26進行顯影且去除未曝光部分,而於母模20上形成二次圖案抗蝕劑膜26。As shown in FIG. 4( i ), a secondary pattern resist film 26 is formed on the master mold 20 by developing the secondary pattern resist film 26 having the secondary pattern and removing the unexposed portion.

如圖4(j)所示,於形成在母模20上之一次電沈積層3之表面上以及母模20之未被二次圖案抗蝕劑膜26覆蓋之表面上電鑄作為與一次電沈積層3相同材料之Ni,而形成二次電沈積層4。於至此為止之步驟中,藉由二次電沈積層4所形成之突起2之俯視形狀為如圖7所示般之圓環狀。但是,於圓環狀之一次電沈積層3之內徑較小且二次電沈積層4之厚度較厚之情況下,電沈積層亦形成於突起2之中央部,從而在外觀上亦難以被識別為環狀之突起。接下來,如圖4(k)所示,去除二次圖案抗蝕劑膜26,形成用於排列導電性焊球之開口部30。As shown in FIG4(j), Ni, which is the same material as the primary electrodeposition layer 3, is electrocast on the surface of the primary electrodeposition layer 3 formed on the master mold 20 and on the surface of the master mold 20 not covered by the secondary pattern anti-etching agent film 26 to form the secondary electrodeposition layer 4. In the steps up to this point, the top view shape of the protrusion 2 formed by the secondary electrodeposition layer 4 is an annular shape as shown in FIG7. However, in the case where the inner diameter of the annular primary electrodeposition layer 3 is small and the thickness of the secondary electrodeposition layer 4 is thick, the electrodeposition layer is also formed in the center of the protrusion 2, so that it is difficult to be recognized as an annular protrusion in appearance. Next, as shown in FIG. 4( k ), the secondary pattern resist film 26 is removed to form an opening 30 for arranging the conductive solder balls.

然後,如圖4(l)所示,將一體化之一次電沈積層3及二次電沈積層4從母模20剝離,則能夠得到焊球陣列用遮罩1。依據藉由如上方法所製造之焊球陣列用遮罩1,即使從突起側作用外力F,亦能夠維持一次電沈積層3卡止於二次電沈積層4之狀態,從而能夠防止一次電沈積層3從二次電沈積層4脫落。Then, as shown in FIG4(l), the integrated primary electrodeposition layer 3 and the secondary electrodeposition layer 4 are peeled off from the master mold 20, and the solder ball array mask 1 can be obtained. According to the solder ball array mask 1 manufactured by the above method, even if an external force F acts from the protrusion side, the primary electrodeposition layer 3 can be kept stuck to the secondary electrodeposition layer 4, thereby preventing the primary electrodeposition layer 3 from falling off from the secondary electrodeposition layer 4.

接下來,基於圖8,對本發明之實施例2之焊球陣列用遮罩1之製造方法進行說明。實施例2之焊球陣列用遮罩1之製造方法與圖4所示之實施例1之焊球陣列用遮罩1之製造方法基本相同。因此,在圖8中,僅對與圖4中不同之步驟進行說明。Next, the manufacturing method of the solder ball array mask 1 of the embodiment 2 of the present invention is described based on FIG8. The manufacturing method of the solder ball array mask 1 of the embodiment 2 is basically the same as the manufacturing method of the solder ball array mask 1 of the embodiment 1 shown in FIG4. Therefore, in FIG8, only the steps different from those in FIG4 are described.

圖8(a)(b)(c)所示之步驟分別對應於實施例1之圖4(d)(e)(f)所示之步驟。再者,圖4(d)(e)(f)為模式性放大剖視圖,但由於對實施例2需要進一步放大而進行說明,因此,圖8(a)(b)(c)作為僅表示圖4(d)(e)(f)所示之右半部分之模式性放大剖視圖。The steps shown in Fig. 8(a)(b)(c) correspond to the steps shown in Fig. 4(d)(e)(f) of Example 1. Fig. 4(d)(e)(f) is a schematic enlarged cross-sectional view, but since it is necessary to further enlarge the cross-sectional view for explaining Example 2, Fig. 8(a)(b)(c) is a schematic enlarged cross-sectional view showing only the right half shown in Fig. 4(d)(e)(f).

於形成一次電沈積層3之步驟中,如圖8(a)所示,將形成有一次圖案抗蝕劑膜22之母模20放置於在特定條件下所製備之電鑄槽中,並以超越一次圖案抗蝕劑膜22之厚度之方式進行電沈積。以此方式,於一次電沈積層3上形成所謂之懸突(overhang)並將其作為卡止部11。懸突量可藉由電鑄步驟之時間來控制。接下來,如圖8(b)所示,去除一次圖案抗蝕劑膜22。In the step of forming the primary electro-deposition layer 3, as shown in FIG8(a), the master mold 20 formed with the primary pattern anti-etching agent film 22 is placed in an electro-casting tank prepared under specific conditions, and electro-deposition is performed in a manner that exceeds the thickness of the primary pattern anti-etching agent film 22. In this way, a so-called overhang is formed on the primary electro-deposition layer 3 and serves as a stopper 11. The amount of overhang can be controlled by the time of the electro-casting step. Next, as shown in FIG8(b), the primary pattern anti-etching agent film 22 is removed.

如圖8(c)所示,去除作為遮罩不需要之廢棄電沈積層23等。至此為止之步驟中所形成之一次電沈積層3之剖視圖形狀為倒蘑菇狀。As shown in Fig. 8(c), the waste electrodeposition layer 23 which is not needed as a mask is removed. The cross-sectional shape of the primary electrodeposition layer 3 formed in the steps up to this point is an inverted mushroom shape.

接下來,基於圖9所示之步驟,對本發明之實施例3之焊球陣列用遮罩1之製造方法進行說明。實施例3之焊球陣列用遮罩1之製造方法與圖4所示之實施例1之焊球陣列用遮罩1之製造方法基本相同。因此,在圖9中,僅對與圖4中不同之步驟進行說明。Next, the manufacturing method of the solder ball array mask 1 of the embodiment 3 of the present invention is described based on the steps shown in FIG9. The manufacturing method of the solder ball array mask 1 of the embodiment 3 is basically the same as the manufacturing method of the solder ball array mask 1 of the embodiment 1 shown in FIG4. Therefore, in FIG9, only the steps different from those in FIG4 are described.

圖9(a)(b)(c)(d)(e)(f)所示之步驟分別對應於實施例1之圖4(b)(c)(d)(e)(f)(j)所示之步驟。再者,與表示實施例2之圖8同樣地,圖9(a)(b)(c)(d)(e)(f)作為僅表示圖4(b)(c)(d)(e)(f)(j)中所示之右半部分之模式性放大剖視圖。The steps shown in FIG. 9(a)(b)(c)(d)(e)(f) respectively correspond to the steps shown in FIG. 4(b)(c)(d)(e)(f)(j) of Example 1. Moreover, similarly to FIG. 8 showing Example 2, FIG. 9(a)(b)(c)(d)(e)(f) is a schematic enlarged cross-sectional view showing only the right half shown in FIG. 4(b)(c)(d)(e)(f)(j).

實施例3之焊球陣列用遮罩1之製造方法之特徵為將一次圖案抗蝕劑膜22曝光之步驟。曝光可使用市售之雷射光束曝光裝置進行,但以與雷射光束之標準能量相比為過剩能量之強度進行照射。如此,由於母模中使用SUS材料,且表面經鏡面拋光,因此,過剩之能量會於母模之表面伴有光暈而反射。其結果,如圖9(a)所示,一次圖案抗蝕劑膜22之與母模相接之側被固化為裙擺狀。The manufacturing method of the solder ball array mask 1 of Example 3 is characterized by the step of exposing the primary pattern anti-etching agent film 22. The exposure can be performed using a commercially available laser beam exposure device, but the irradiation is performed with an intensity that is excess energy compared to the standard energy of the laser beam. In this way, since SUS material is used in the master mold and the surface is mirror-polished, the excess energy will be reflected on the surface of the master mold with halo. As a result, as shown in Figure 9(a), the side of the primary pattern anti-etching agent film 22 that is in contact with the master mold is solidified into a skirt shape.

接下來,如圖9(b)所示,對描繪有一次圖案之一次圖案抗蝕劑膜22進行顯影、乾燥,將一次圖案抗蝕劑膜22形成於母模20上,如圖9(c)所示,將形成有一次圖案抗蝕劑膜22之母模20放入以特定條件建浴而成之電鑄槽中,於母模20之未被一次圖案抗蝕劑膜22覆蓋之表面電鑄電沈積金屬直至與一次圖案抗蝕劑膜22之高度相同之程度,從而形成一次電沈積層3。Next, as shown in FIG9(b), the primary pattern anti-etching agent film 22 having the primary pattern is developed and dried to form the primary pattern anti-etching agent film 22 on the master mold 20. As shown in FIG9(c), the master mold 20 having the primary pattern anti-etching agent film 22 is placed in an electro-casting tank formed by a bath under specific conditions, and metal is electro-cast and deposited on the surface of the master mold 20 not covered by the primary pattern anti-etching agent film 22 until the height is the same as that of the primary pattern anti-etching agent film 22, thereby forming a primary electrodeposition layer 3.

進而,如圖9(d)所示,去除一次圖案抗蝕劑膜22,如圖9(e)所示,去除不需要作為遮罩之廢棄電沈積層23等。然後,在經過與圖4(g)(h)(i)同樣之步驟之後,如圖9(f)所示,於一次電沈積層3及母模20之表面上電鑄與一次電沈積層3相同材料之Ni,形成二次電沈積層4。以此方式,能夠形成剖視圖形狀為大致紡錘狀之一次電沈積層3。 [脫落試驗之結果]Furthermore, as shown in FIG9(d), the primary pattern anti-etching agent film 22 is removed, and as shown in FIG9(e), the waste electrodeposition layer 23 that is not needed as a mask is removed. Then, after the same steps as FIG4(g)(h)(i), as shown in FIG9(f), Ni of the same material as the primary electrodeposition layer 3 is electroplated on the surface of the primary electrodeposition layer 3 and the master mold 20 to form a secondary electrodeposition layer 4. In this way, a primary electrodeposition layer 3 having a cross-sectional shape that is roughly a spinning hammer shape can be formed. [Results of the peeling test]

對於實施例1,製作了以下三種類型之遮罩試樣,且使用具有3 mm之刺入型端子之測力計,進行了從遮罩之突起側施加30秒之100 N之外力之脫落試驗。關於遮罩試樣,遮罩之總厚度(一次電沈積層與二次電沈積層之合計厚度)分別設為45 μm、80 μm、120 μm,突起之高度分別設為25 μm、50 μm、60 μm,突起之俯視下之直徑為約200 μm。試驗結果為,所有突起均未發生脫落。For Example 1, the following three types of mask samples were prepared, and the The dynamometer of the 3 mm piercing terminal was used to perform a detachment test by applying an external force of 100 N for 30 seconds from the protruding side of the mask. For the mask samples, the total thickness of the mask (the combined thickness of the primary electrodeposition layer and the secondary electrodeposition layer) was set to 45 μm, 80 μm, and 120 μm, respectively, the height of the protrusion was set to 25 μm, 50 μm, and 60 μm, respectively, and the diameter of the protrusion when viewed from above was about 200 μm. The test results showed that none of the protrusions fell off.

對於實施例2及實施例3亦與實施例1同樣地,製作了以下三種類型之遮罩試樣,且使用具有3 mm之刺入型端子之測力計,進行了從遮罩之突起側施加30秒之100 N之外力之脫落試驗。關於遮罩試樣,遮罩之總厚度(一次電沈積層與二次電沈積層之總厚度)分別設為45 μm、80 μm、120 μm,突起之高度分別設為25 μm、50 μm、60 μm,並且突起之俯視下之直徑為約200 μm。試驗結果為,所有突起均未發生脫落。For Example 2 and Example 3, the following three types of mask samples were prepared in the same manner as Example 1, and the following three types of mask samples were prepared using The dynamometer of the 3 mm piercing terminal was used to perform a detachment test by applying an external force of 100 N for 30 seconds from the protruding side of the mask. For the mask samples, the total thickness of the mask (total thickness of the primary electrodeposition layer and the secondary electrodeposition layer) was set to 45 μm, 80 μm, and 120 μm, respectively, the height of the protrusion was set to 25 μm, 50 μm, and 60 μm, respectively, and the diameter of the protrusion when viewed from above was about 200 μm. The test results showed that none of the protrusions fell off.

為了進行比較,對先前技術之遮罩之突起亦進行了與上述實施例相同之脫落試驗,其結果發現三種類型之突起均多半發生脫落。根據該等試驗結果可確認,本發明之遮罩之一次電沈積層與二次電沈積層之界面之密接性提高。For comparison, the protrusions of the prior art mask were also subjected to the same peeling test as in the above embodiment, and the results showed that most of the three types of protrusions fell off. Based on these test results, it can be confirmed that the interface adhesion between the primary electrodeposition layer and the secondary electrodeposition layer of the mask of the present invention is improved.

以上,基於實施例對本發明進行了說明,但是本發明並不限於上述之實施例。例如,於上述實施例1中,將形成突起之一次電沈積層之俯視形狀設定為單圓環,但環之形態不限於單環之形態,亦可為多環之形態。又,於上述實施例中,對設置廢棄電沈積層之遮罩之製造方法進行了說明,但當然亦可應用於未設置廢棄電沈積層之遮罩之製造方法。 [產業上之可利用性]The present invention has been described above based on the embodiments, but the present invention is not limited to the above embodiments. For example, in the above embodiment 1, the top view shape of the primary electro-deposition layer forming the protrusion is set to a single circular ring, but the shape of the ring is not limited to the single ring shape, and can also be a multi-ring shape. In addition, in the above embodiment, the manufacturing method of the mask with the waste electro-deposition layer is described, but of course it can also be applied to the manufacturing method of the mask without the waste electro-deposition layer. [Industrial Applicability]

本發明之焊球陣列用遮罩可適用於將導電性焊球排列於基板等,本發明之製造方法能夠用於製造可防止一次電沈積層從形成遮罩之突起之二次電沈積層脫落之焊球陣列用遮罩。The solder ball array mask of the present invention can be applied to arranging conductive solder balls on a substrate, etc. The manufacturing method of the present invention can be used to manufacture a solder ball array mask that can prevent a primary electrodeposition layer from falling off from a secondary electrodeposition layer that forms a protrusion of the mask.

1:焊球陣列用遮罩(遮罩) 2:突起部(突起) 3:一次電沈積層 4:二次電沈積層 5,6,7:界面 8:傘 9:柄 11:卡止部 20:母模 21:光阻膜 22:一次圖案抗蝕劑膜 23:廢棄電沈積層 25:光阻膜 26:二次圖案抗蝕劑膜 30:開口部 F:外力1: Mask for solder ball array (mask) 2: Protrusion (protrusion) 3: Primary electro-deposition layer 4: Secondary electro-deposition layer 5,6,7: Interface 8: Umbrella 9: Handle 11: Stopper 20: Mother mold 21: Photoresist film 22: Primary pattern anti-etching agent film 23: Waste electro-deposition layer 25: Photoresist film 26: Secondary pattern anti-etching agent film 30: Opening F: External force

圖1係模式性表示實施例1之遮罩之突起之放大剖視圖。 圖2係模式性表示實施例2之遮罩之突起之放大剖視圖。 圖3係模式性表示實施例3之遮罩之突起之放大剖視圖。 圖4(a)~(l)係表示實施例1之遮罩之製造方法之步驟說明圖。 圖5係圖4(c)之A-A箭頭方向觀察之俯視圖。 圖6係圖4(f)之B-B箭頭方向觀察之俯視圖。 圖7係圖4(j)之C-C箭頭方向觀察之俯視圖。 圖8(a)~(c)係表示實施例2之遮罩之製造方法之步驟說明圖。 圖9(a)~(f)係表示實施例3之遮罩之製造方法之步驟說明圖。 圖10(a)、(b)係模式性表示先前技術之遮罩之突起之放大剖視圖。FIG. 1 is an enlarged cross-sectional view schematically showing the protrusion of the mask of Example 1. FIG. 2 is an enlarged cross-sectional view schematically showing the protrusion of the mask of Example 2. FIG. 3 is an enlarged cross-sectional view schematically showing the protrusion of the mask of Example 3. FIG. 4(a) to (l) are step-illustrating views showing the method for manufacturing the mask of Example 1. FIG. 5 is a top view observed in the direction of the arrow A-A of FIG. 4(c). FIG. 6 is a top view observed in the direction of the arrow B-B of FIG. 4(f). FIG. 7 is a top view observed in the direction of the arrow C-C of FIG. 4(j). FIG. 8(a) to (c) are step-illustrating views showing the method for manufacturing the mask of Example 2. FIG. 9(a) to (f) are step-illustrating views showing the method for manufacturing the mask of Example 3. 10(a) and (b) are enlarged cross-sectional views schematically showing protrusions of a mask in the prior art.

1:焊球陣列用遮罩(遮罩)1: Mask for solder ball array (mask)

2:突起部(突起)2: Protrusion (protrusion)

3:一次電沈積層3: Primary Electrodeposition Layer

4:二次電沈積層4: Secondary electrodeposition layer

5:界面5: Interface

6:界面6: Interface

7:界面7: Interface

F:外力F: External force

Claims (3)

一種焊球陣列用遮罩,其特徵在於:具有對應於特定之陣列圖案之開口部,且藉由將導電性焊球載入上述開口部,而將上述導電性焊球搭載於特定位置,且該焊球陣列用遮罩具備複數個一次電沈積層及二次電沈積層,該複數個一次電沈積層隔開形成於上述焊球陣列用遮罩之表面側之複數個部位,該二次電沈積層一體形成於上述一次電沈積層以外之部位及上述一次電沈積層上,於上述焊球陣列用遮罩之與被搭載體相對之側,具有由上述一次電沈積層與上述二次電沈積層形成之突起部,於上述突起部之一次電沈積層與二次電沈積層之界面處具有卡止部。 A solder ball array mask is characterized in that: it has an opening corresponding to a specific array pattern, and by loading a conductive solder ball into the opening, the conductive solder ball is placed at a specific position, and the solder ball array mask has a plurality of primary electrodeposition layers and a secondary electrodeposition layer, and the plurality of primary electrodeposition layers are separated and formed on the surface of the solder ball array mask. The secondary electrodeposition layer is integrally formed on a portion other than the primary electrodeposition layer and on the primary electrodeposition layer. On the side of the solder ball array mask opposite to the mounted body, there is a protrusion formed by the primary electrodeposition layer and the secondary electrodeposition layer, and a stopper is provided at the interface between the primary electrodeposition layer and the secondary electrodeposition layer of the protrusion. 如請求項1之焊球陣列用遮罩,其中上述突起部之一次電沈積層於俯視下為環狀,上述卡止部為第一電沈積層之內周面與二次電沈積層之間之界面。 As in claim 1, the mask for solder ball array, wherein the primary electro-deposition layer of the protrusion is annular in plan view, and the stopper is the interface between the inner peripheral surface of the first electro-deposition layer and the secondary electro-deposition layer. 如請求項1之焊球陣列用遮罩,其中上述卡止部於剖視下為蘑菇狀或大致紡錘狀。 As in claim 1, the solder ball array mask, wherein the above-mentioned stopper is mushroom-shaped or roughly hammer-shaped in cross-section.
TW109128786A 2019-12-12 2020-08-24 Solder ball array mask TWI869438B (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP2019224242A JP6713154B1 (en) 2019-12-12 2019-12-12 Ball array mask
JP2019-224242 2019-12-12

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Publication Number Publication Date
TW202123790A TW202123790A (en) 2021-06-16
TWI869438B true TWI869438B (en) 2025-01-11

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