TW202123790A - Mask for solder ball array to solve the problem of falling off of a primary electrodeposition layer from a secondary electrodeposition layer, which leads to protrusion damage and the reduction in mounting rate of the conductive solder balls - Google Patents
Mask for solder ball array to solve the problem of falling off of a primary electrodeposition layer from a secondary electrodeposition layer, which leads to protrusion damage and the reduction in mounting rate of the conductive solder balls Download PDFInfo
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Abstract
本發明之課題在於,解決一次電沈積層從形成有遮罩背面之突起部的二次電沈積層脫落而導致突起破損,從而導致導電性焊球之搭載率降低的問題。 本發明之焊球陣列用遮罩1具有對應於特定之陣列圖案之開口部30,藉由將導電性焊球載入上述開口部30,而將上述導電球性焊球搭載於特定位置,且於上述焊球陣列用遮罩1之與被搭載體相對之側,具備藉由在一次電沈積層3上積層二次電沈積層4而形成之突起2,上述突起2之一次電沈積層3具備不易從二次電沈積層4脫落之不易脫落構造。又,上述突起2之一次電沈積層3俯視下為環狀,於上述突起2之一次電沈積層3與二次電沈積層4之界面處具備卡止部11。The subject of the present invention is to solve the problem that the primary electrodeposition layer falls off from the secondary electrodeposition layer on which the protrusions on the back of the mask are formed, which causes the protrusions to be damaged, and thereby leads to a decrease in the loading rate of conductive solder balls. The solder ball array mask 1 of the present invention has openings 30 corresponding to a specific array pattern. By loading conductive solder balls into the opening 30, the conductive solder balls are mounted at specific positions, and On the side of the solder ball array mask 1 opposite to the mounted body, there are provided protrusions 2 formed by laminating a secondary electrodeposition layer 4 on the primary electrodeposition layer 3, and a primary electrodeposition layer 3 of the protrusions 2 It has a structure that does not easily fall off from the secondary electrodeposition layer 4. In addition, the primary electrodeposition layer 3 of the protrusion 2 has a ring shape in a plan view, and a locking portion 11 is provided at the interface between the primary electrodeposition layer 3 and the secondary electrodeposition layer 4 of the protrusion 2.
Description
本發明係關於一種適於排列導電性焊球之焊球陣列用遮罩及其製造方法。The invention relates to a mask for a solder ball array suitable for arranging conductive solder balls and a manufacturing method thereof.
先前以來,於導電性焊球陣列用金屬遮罩(以下,簡稱為遮罩)中,為了防止形成於導電性焊球搭載部之電極上之助焊劑等附著於遮罩,而使用了於基板面側之開口圖案之周邊部形成有凹部之遮罩。作為該凹部之形成方法,揭示有如下之遮罩之製造方法:藉由複數次電鑄法,於一次電沈積層上積層二次電沈積層而形成凸部,並且將未設置一次電沈積層而僅由二次電沈積層形成之部位作為凹部(參照專利文獻1)。Conventionally, in the metal mask for conductive solder ball array (hereinafter referred to as mask), in order to prevent the flux formed on the electrode of the conductive solder ball mounting portion from adhering to the mask, it is used on the substrate A recessed mask is formed on the periphery of the opening pattern on the face side. As a method of forming the recesses, the following method of manufacturing a mask is disclosed: A secondary electrodeposition layer is laminated on the primary electrodeposition layer by a plurality of electroforming methods to form the protrusions, and the primary electrodeposition layer is not provided On the other hand, the portion formed only by the secondary electrodeposition layer is referred to as a recessed portion (refer to Patent Document 1).
又,作為藉由進行複數次電鍍法而形成凸部之遮罩之製造方法,有以下說明之專利文獻2。專利文獻2所記載之遮罩之製造方法係焊球陣列用遮罩之製造方法,其特徵在於,該焊球陣列用遮罩具備遮罩本體及突起,遮罩本體係藉由鍍覆而形成,且形成有供載入之導電性焊球插通之複數個開口部,突起係藉由鍍覆而形成,且部分突出於上述遮罩本體背面之上述開口部以外,上述突起之前端部形成為其外圍邊緣部具有圓度之R形;且該焊球陣列用遮罩之製造方法具備如下步驟:於SUS母材上形成上述突起形成用抗蝕劑層;藉由以使上述突起成為特定高度之方式於SUS母材上進行鍍覆,而形成第一鍍覆層;於第一鍍層之形成結束之後,去除上述突起形成用抗蝕劑層;除去上述突起以外之第一鍍覆層,於SUS母材上留下由第一鍍覆層形成之突起;於上述SUS母材上之上述突起之間形成複數個開口部形成用抗蝕劑層;藉由以使上述遮罩本體成為指定厚度之方式於SUS母材及上述突起上進行鍍覆,而形成第二鍍覆層;於第二鍍覆層之形成結束之後,去除上述複數個開口部形成用抗蝕劑層;以及從上述SUS母材上剝離由第一鍍覆層及第二鍍覆層構成之突起以及遮罩本體之鍍覆層(參照專利文獻2)。
再者,電鑄法與電鍍法只是表達上之不同,技術內容實質上相同。
[先前技術文獻]
[專利文獻]In addition, as a method of manufacturing a mask in which convex portions are formed by performing multiple plating methods, there is
[專利文獻1]日本專利特開2010-247500號公報 [專利文獻2]日本專利特開2017-5053號公報[Patent Document 1] Japanese Patent Laid-Open No. 2010-247500 [Patent Document 2] Japanese Patent Laid-Open No. 2017-5053
[發明所欲解決之問題][The problem to be solved by the invention]
藉由上述專利文獻1或專利文獻2所記載之製造方法,能夠於遮罩背面形成任意形態之突起(以下,亦稱為突起部或凸部)。該突起係於一次電沈積層之上積層二次電沈積層而形成,一次電沈積層係藉由一次電鑄步驟而形成,二次電沈積層係藉由二次電鑄步驟而形成。因此,該等兩個步驟之間存在時間差,於一次電鑄步驟與二次電鑄步驟中,即使完全相同地設定電鑄條件,一次電沈積層與二次電沈積層之間亦會存在邊界。According to the manufacturing method described in
若存在邊界,則於一次電沈積層與二次電沈積層之界面處密接性會降低。即便是為提高界面處之密接性而於一次電鑄步驟之後對一次電沈積層進行了鹽酸處理等化學表面處理,密接性之提高亦存在極限。而且,若於反覆使用遮罩之階段反覆進行清洗操作等,則會出現以下問題:於密接性較低之遮罩中,因對遮罩施加之外力而導致一次電沈積層從形成有突起之二次電沈積層脫落。If there is a boundary, the adhesion at the interface between the primary electrodeposition layer and the secondary electrodeposition layer will decrease. Even if chemical surface treatment such as hydrochloric acid treatment is performed on the primary electrodeposited layer after one electroforming step in order to improve the adhesiveness at the interface, there is a limit to the improvement of the adhesiveness. Moreover, if the cleaning operation is repeated in the stage of repeated use of the mask, the following problem will occur: in the mask with low adhesion, the primary electrodeposited layer is removed from the protrusions formed by the external force on the mask. The secondary electrodeposition layer comes off.
圖10表示於藉由先前技術製造出之遮罩1中,一次電沈積層3從形成有突起2之二次電沈積層4脫落之狀態。圖10(a)表示正常狀態,圖10(b)表示從突起側(遮罩之背面側)施加了外力F之狀態。由於遮罩之厚度薄至數十μm程度,因此,若從突起側施加外力,則遮罩容易變形。其結果,於一次電沈積層之外周部與二次電沈積層之界面處產生間隙,一次電沈積層以被推出之方式脫落。雖然一次電沈積層是否脫落實際上取決於外力之大小,但若反覆使用遮罩,則確認到有相當數量之突起之一次電沈積層發生脫落。FIG. 10 shows a state where the
若一次電沈積層從形成有突起之二次電沈積層脫落,則亦有突起整體之強度降低而導致於遮罩之使用中突起破損的情況。其結果,存在以下問題:形成於導電性焊球搭載部之電極上之助焊劑附著於遮罩,而導致焊球之搭載率降低。If the primary electrodeposition layer falls off from the secondary electrodeposition layer on which the protrusions are formed, the strength of the protrusions as a whole may decrease, which may cause the protrusions to be damaged during use of the mask. As a result, there is a problem in that the flux formed on the electrode of the conductive solder ball mounting portion adheres to the mask, resulting in a decrease in the mounting rate of the solder balls.
又,若一次電沈積層從形成有突起之二次電沈積層脫落,則於載入導電性焊球之遮罩之表面側產生作為脫落痕跡之凹痕,因此,存在導電性焊球被鉤掛在凹痕之邊緣而無法確實地排列導電性焊球之問題。 [解決問題之技術手段]In addition, if the primary electrodeposition layer falls off from the secondary electrodeposition layer on which the protrusions are formed, dents are formed on the surface side of the mask on which the conductive solder balls are loaded as falling traces. Therefore, the conductive solder balls may be hooked. The problem of the conductive solder balls hanging on the edge of the dent and unable to arrange the conductive solder balls reliably. [Technical means to solve the problem]
本發明係一種焊球陣列用遮罩,其特徵在於:具有對應於特定之陣列圖案之開口部,且藉由將導電性焊球載入上述開口部,而將上述導電性焊球搭載於特定位置,且該焊球陣列用遮罩具備複數個一次電沈積層及二次電沈積層:該複數個一次電沈積層隔開形成於上述焊球陣列用遮罩之表面側之複數個部位,該二次電沈積層一體形成於上述一次電沈積層以外之部位及上述一次電沈積層上;於上述焊球陣列用遮罩之與被搭載體相對之側,具有由上述一次電沈積層與上述二次電沈積層形成之突起部,於上述突起部之一次電沈積層與二次電沈積層之界面處具有卡止部,上述突起部之一次電沈積層不易從二次電沈積層脫落。 又,本發明之焊球陣列用遮罩之特徵在於:上述突起部之一次電沈積層於俯視下為環狀,上述卡止部為一次電沈積層之內周面與二次電沈積層之間之界面。 又,本發明之焊球陣列用遮罩之特徵在於:上述卡止部於剖視下為蘑菇狀或大致紡錘狀。 [發明之效果]The present invention is a mask for a solder ball array, which is characterized by having openings corresponding to a specific array pattern, and by loading conductive solder balls into the openings, the conductive solder balls are mounted on the specific Position, and the mask for the solder ball array is provided with a plurality of primary electrodeposition layers and secondary electrodeposition layers: the plurality of primary electrodeposition layers separate a plurality of locations formed on the surface side of the mask for the solder ball array, The secondary electrodeposition layer is integrally formed on the part other than the primary electrodeposition layer and the primary electrodeposition layer; on the side of the solder ball array mask opposite to the mounted body, there is a combination of the primary electrodeposition layer and the The protrusion formed by the secondary electrodeposition layer has a locking part at the interface between the primary electrodeposition layer of the protrusion part and the secondary electrodeposition layer, and the primary electrodeposition layer of the protrusion part is not easy to fall off from the secondary electrodeposition layer . In addition, the mask for a solder ball array of the present invention is characterized in that the primary electrodeposition layer of the protruding portion is ring-shaped in a plan view, and the locking portion is the inner peripheral surface of the primary electrodeposition layer and the secondary electrodeposition layer. Between the interface. In addition, the mask for a solder ball array of the present invention is characterized in that the locking portion is mushroom-shaped or substantially spindle-shaped in a cross-sectional view. [Effects of Invention]
根據本發明之遮罩,能夠提高形成有突起之一次電沈積層與二次電沈積層之界面之密接性,防止一次電沈積層從二次電沈積層脫落。其結果,能夠防止於遮罩使用中突起破損,並且形成於導電性焊球搭載部之電極上之助焊劑不會附著於遮罩上,從而能夠防止導電性焊球之搭載率降低。又,由於不會在載入導電性焊球之遮罩之表面側產生凹痕,因此,能夠順暢且確實地排列導電性焊球。According to the mask of the present invention, the adhesion of the interface between the primary electrodeposition layer and the secondary electrodeposition layer on which protrusions are formed can be improved, and the primary electrodeposition layer can be prevented from falling off from the secondary electrodeposition layer. As a result, the bumps can be prevented from being damaged during use of the mask, and the flux formed on the electrodes of the conductive solder ball mounting portion does not adhere to the mask, thereby preventing the conductive solder ball mounting rate from decreasing. In addition, since dents are not generated on the surface side of the mask loaded with conductive solder balls, the conductive solder balls can be arranged smoothly and reliably.
以下,一面參照圖式一面對用於實施本發明之方式加以說明。於焊球陣列用遮罩中,能夠藉由實施複數次電鑄步驟而於遮罩背面形成突起。先前技術之突起係於一次電沈積層上積層二次電沈積層而形成,但一次電沈積層與二次電沈積層之界面之密接性弱,若反覆使用遮罩,則會導致一次電沈積層從二次電沈積層上脫落。Hereinafter, the method for implementing the present invention will be described with reference to the drawings. In the solder ball array mask, it is possible to form protrusions on the back surface of the mask by performing multiple electroforming steps. The protrusions of the prior art are formed by stacking a secondary electrodeposition layer on the primary electrodeposition layer, but the adhesion between the primary electrodeposition layer and the secondary electrodeposition layer is weak. If the mask is used repeatedly, it will cause the primary electrodeposition. The build-up layer is peeled off from the secondary electrodeposited layer.
因此,本發明之發明人為了提高一次電沈積層與二次電沈積層之界面之密接性而進行了精心研究,為了提高密接性,可以考慮加大界面之面積本身。但是,突起之俯視形狀之尺寸勢必有其侷限,要使構成突起之一次電沈積層之俯視面積增加有其限度。 [實施例1]Therefore, the inventors of the present invention have conducted careful studies to improve the adhesion of the interface between the primary electrodeposition layer and the secondary electrodeposition layer. In order to improve the adhesion, it may be considered to increase the area of the interface itself. However, the size of the top-view shape of the protrusion is bound to have its limitations, and there is a limit to increase the top-view area of the primary electrodeposited layer constituting the protrusion. [Example 1]
圖1係模式性表示實施例1之遮罩1之突起2之放大剖視圖。圖示之突起2係於一次電沈積層3上積層二次電沈積層4而形成,一次電沈積層3於俯視下為環狀。環狀之形態不限於圓形,亦可為橢圓形或卵形、進而為多邊形等,但於本實施例中為圓環形。實際上,由於遮罩大多為其一邊具有數百mm之大小,從而一個遮罩上將形成數千個如圖所示之突起2。FIG. 1 is an enlarged cross-sectional view schematically showing the
若如此般將一次電沈積層3之俯視形狀設為圓環狀,則一次電沈積層3與二次電沈積層4俯視下之界面5之面積於環狀之內側將會減少相當於一次電沈積層3之界面消失之部分,另一方面,由於在一次電沈積層3之環狀之內側亦形成二次電沈積層4,因此於環狀之內側會形成相當於一次電沈積層3之厚度的縱向之環狀界面6,從而界面之面積增加。例如,當於環狀之內徑尺寸與一次電沈積層3之厚度尺寸相等之情況下,界面之面積相對減少部分增加0.75π(2.36)倍。其結果,包括環狀之一次電沈積層3之外周上之界面7在內的一次電沈積層3與二次電沈積層4之界面整體之面積增加。If the shape of the
界面面積之增加雖然能夠有效地提高一次電沈積層3與二次電沈積層4之界面之密接性,但是,比增加面積更為重要的是,若將一次電沈積層3之俯視形狀形成為環狀,則即使從突起2側作用外力F,環狀之一次電沈積層3亦被卡止於二次電沈積層4上,從而能夠實現不易脫落之構造。Although the increase of the interface area can effectively improve the adhesion of the interface between the
於圖1所示之遮罩1中,由於遮罩1之厚度薄至數十μm程度,因此,若從突起2側作用外力F,則遮罩1變形,而於一次電沈積層3之外周面與二次電沈積層4之界面7處作用使其產生間隙之力。而且,於一次電沈積層3之外周面與二次電沈積層4之界面7處,實際上亦會產生間隙。另一方面,由於環狀之一次電沈積層3之內周面與二次電沈積層4之間存在界面6,因此,若從突起2側作用外力F,則外力F會在該界面6,成為擴大界面直徑之方向上之推壓力而起作用。因此,即使作用外力F,亦能夠維持一次電沈積層3卡止於與二次電沈積層4之界面6之狀態,無損該界面6處之密接性,從而能夠防止一次電沈積層3從形成有突起2之二次電沈積層4脫落。
[實施例2]In the
圖2係模式性表示實施例2之遮罩1之突起2之放大剖視圖。該實施例中之突起2於剖視下,一次電沈積層3形成為倒蘑菇狀。即,具有將蘑菇狀之傘8與柄9倒置之形狀。因此,即使從突起2側作用外力,亦不會對構成蘑菇狀之傘8之一次電沈積層3與二次電沈積層4之界面作用如使彼此分離之大小之力。假設即使作用較大之力,亦僅在相當於蘑菇狀之柄9之外周之部分之界面7形成微小之間隙,蘑菇狀之傘8之部分卡止於二次電沈積層4。因此,即使從突起2側作用外力,亦能夠維持一次電沈積層3卡止於與二次電沈積層4之卡止部11之狀態,從而能夠防止一次電沈積層3從二次電沈積層4脫落。
[實施例3]FIG. 2 is an enlarged cross-sectional view schematically showing the
圖3係模式性表示實施例3之遮罩1之突起2之放大剖視圖。該實施例中之突起2於剖視下,一次電沈積層3被形成為大致紡錘狀。此處,所謂大致紡錘狀係指圓柱狀之中間部之直徑粗,而兩端之直徑逐漸變細之形狀。剖視下一次電沈積層3形成為大致紡錘狀之突起2發揮與實施例2相同之作用效果。即,即使從突起2側作用外力,亦僅在相當於大致紡錘狀之一次電沈積層3之外周之部分之界面7產生微小之間隙,一次電沈積層3之最大直徑部分卡止於與二次電沈積層之卡止部11。因此,即使從突起2側作用外力,亦能夠維持一次電沈積層3卡止於與二次電沈積層4之卡止部11之狀態,從而能夠防止一次電沈積層3從二次電沈積層4脫落。
[製造方法之說明]3 is an enlarged cross-sectional view schematically showing the
基於圖4所示之步驟,依次對本發明之實施例1之焊球陣列用遮罩之製造方法進行說明。Based on the steps shown in FIG. 4, the manufacturing method of the solder ball array mask of the first embodiment of the present invention will be sequentially described.
如圖4(a)所示,準備母模20,並且於該母模20之表面上形成光阻膜21。母模20只要為具有導電性者則可為任意,於本實施例中使用了SUS(Stainless Steel,不鏽鋼)材。接下來,如圖4(b)所示,於光阻膜21上,利用眾所周知之方法將一次圖案抗蝕劑膜22曝光。As shown in FIG. 4(a), a
如圖4(c)所示,對描繪有一次圖案之一次圖案抗蝕劑膜22進行顯影並乾燥,將一次圖案抗蝕劑膜22形成於母模20上。如圖5所示,至此為止之步驟中所形成之一次圖案抗蝕劑膜22之俯視形狀由中心部之圓形抗蝕劑及與其形成為同心狀之環狀抗蝕劑所構成。此處,一次圖案抗蝕劑膜22可將負型之感光性乾膜抗蝕劑膜按照特定高度層壓一片或數片而形成。As shown in FIG. 4( c ), the primary pattern resist
將形成有一次圖案抗蝕劑膜22之母模20放置於在特定條件下所製備之電鑄槽中,且如圖4(d)所示,將電沈積金屬電鑄於母模20之未被一次圖案抗蝕劑膜22覆蓋之表面上直至與一次圖案抗蝕劑膜22之高度相同之程度,從而形成一次電沈積層3。可使用Ni作為電沈積金屬而形成一次電沈積層3。接下來,如圖4(e)所示,去除一次圖案抗蝕劑膜22。The
如圖4(f)所示,去除作為遮罩不需要之廢棄電沈積層23等。如圖6所示,至此為止之步驟中所形成之一次電沈積層3之俯視形狀為圓環狀。As shown in FIG. 4(f), the waste electrodeposited
如圖4(g)所示,於一次電沈積層3及母模20之表面上形成光阻膜25。該光阻膜25係將負型之感光性乾膜抗蝕劑膜按照特定高度層壓一片或數片而形成。接下來,如圖4(h)所示,於光阻膜25上藉由眾所周知之方法將二次圖案抗蝕劑膜26曝光。As shown in FIG. 4(g), a
如圖4(i)所示,藉由對描繪有二次圖案之二次圖案抗蝕劑膜26進行顯影且去除未曝光部分,而於母模20上形成二次圖案抗蝕劑膜26。As shown in FIG. 4(i), the secondary pattern resist
如圖4(j)所示,於形成在母模20上之一次電沈積層3之表面上以及母模20之未被二次圖案抗蝕劑膜26覆蓋之表面上電鑄作為與一次電沈積層3相同材料之Ni,而形成二次電沈積層4。於至此為止之步驟中,藉由二次電沈積層4所形成之突起2之俯視形狀為如圖7所示般之圓環狀。但是,於圓環狀之一次電沈積層3之內徑較小且二次電沈積層4之厚度較厚之情況下,電沈積層亦形成於突起2之中央部,從而在外觀上亦難以被識別為環狀之突起。接下來,如圖4(k)所示,去除二次圖案抗蝕劑膜26,形成用於排列導電性焊球之開口部30。As shown in FIG. 4(j), electroforming is performed on the surface of the
然後,如圖4(l)所示,將一體化之一次電沈積層3及二次電沈積層4從母模20剝離,則能夠得到焊球陣列用遮罩1。依據藉由如上方法所製造之焊球陣列用遮罩1,即使從突起側作用外力F,亦能夠維持一次電沈積層3卡止於二次電沈積層4之狀態,從而能夠防止一次電沈積層3從二次電沈積層4脫落。Then, as shown in FIG. 4(1), the integrated
接下來,基於圖8,對本發明之實施例2之焊球陣列用遮罩1之製造方法進行說明。實施例2之焊球陣列用遮罩1之製造方法與圖4所示之實施例1之焊球陣列用遮罩1之製造方法基本相同。因此,在圖8中,僅對與圖4中不同之步驟進行說明。Next, based on FIG. 8, the manufacturing method of the
圖8(a)(b)(c)所示之步驟分別對應於實施例1之圖4(d)(e)(f)所示之步驟。再者,圖4(d)(e)(f)為模式性放大剖視圖,但由於對實施例2需要進一步放大而進行說明,因此,圖8(a)(b)(c)作為僅表示圖4(d)(e)(f)所示之右半部分之模式性放大剖視圖。The steps shown in Fig. 8(a)(b)(c) correspond to the steps shown in Fig. 4(d)(e)(f) of
於形成一次電沈積層3之步驟中,如圖8(a)所示,將形成有一次圖案抗蝕劑膜22之母模20放置於在特定條件下所製備之電鑄槽中,並以超越一次圖案抗蝕劑膜22之厚度之方式進行電沈積。以此方式,於一次電沈積層3上形成所謂之懸突(overhang)並將其作為卡止部11。懸突量可藉由電鑄步驟之時間來控制。接下來,如圖8(b)所示,去除一次圖案抗蝕劑膜22。In the step of forming the
如圖8(c)所示,去除作為遮罩不需要之廢棄電沈積層23等。至此為止之步驟中所形成之一次電沈積層3之剖視圖形狀為倒蘑菇狀。As shown in FIG. 8(c), the waste electrodeposited
接下來,基於圖9所示之步驟,對本發明之實施例3之焊球陣列用遮罩1之製造方法進行說明。實施例3之焊球陣列用遮罩1之製造方法與圖4所示之實施例1之焊球陣列用遮罩1之製造方法基本相同。因此,在圖9中,僅對與圖4中不同之步驟進行說明。Next, based on the steps shown in FIG. 9, the manufacturing method of the solder
圖9(a)(b)(c)(d)(e)(f)所示之步驟分別對應於實施例1之圖4(b)(c)(d)(e)(f)(j)所示之步驟。再者,與表示實施例2之圖8同樣地,圖9(a)(b)(c)(d)(e)(f)作為僅表示圖4(b)(c)(d)(e)(f)(j)中所示之右半部分之模式性放大剖視圖。The steps shown in Figure 9(a)(b)(c)(d)(e)(f) correspond to Figure 4(b)(c)(d)(e)(f)(j) in Example 1. ) Shows the steps. In addition, as shown in Fig. 8 of Example 2, Fig. 9(a)(b)(c)(d)(e)(f) is only shown in Fig. 4(b)(c)(d)(e ) A schematic enlarged cross-sectional view of the right half shown in (f)(j).
實施例3之焊球陣列用遮罩1之製造方法之特徵為將一次圖案抗蝕劑膜22曝光之步驟。曝光可使用市售之雷射光束曝光裝置進行,但以與雷射光束之標準能量相比為過剩能量之強度進行照射。如此,由於母模中使用SUS材料,且表面經鏡面拋光,因此,過剩之能量會於母模之表面伴有光暈而反射。其結果,如圖9(a)所示,一次圖案抗蝕劑膜22之與母模相接之側被固化為裙擺狀。The manufacturing method of the
接下來,如圖9(b)所示,對描繪有一次圖案之一次圖案抗蝕劑膜22進行顯影、乾燥,將一次圖案抗蝕劑膜22形成於母模20上,如圖9(c)所示,將形成有一次圖案抗蝕劑膜22之母模20放入以特定條件建浴而成之電鑄槽中,於母模20之未被一次圖案抗蝕劑膜22覆蓋之表面電鑄電沈積金屬直至與一次圖案抗蝕劑膜22之高度相同之程度,從而形成一次電沈積層3。Next, as shown in FIG. 9(b), the primary pattern resist
進而,如圖9(d)所示,去除一次圖案抗蝕劑膜22,如圖9(e)所示,去除不需要作為遮罩之廢棄電沈積層23等。然後,在經過與圖4(g)(h)(i)同樣之步驟之後,如圖9(f)所示,於一次電沈積層3及母模20之表面上電鑄與一次電沈積層3相同材料之Ni,形成二次電沈積層4。以此方式,能夠形成剖視圖形狀為大致紡錘狀之一次電沈積層3。
[脫落試驗之結果]Furthermore, as shown in FIG. 9(d), the pattern resist
對於實施例1,製作了以下三種類型之遮罩試樣,且使用具有3 mm之刺入型端子之測力計,進行了從遮罩之突起側施加30秒之100 N之外力之脫落試驗。關於遮罩試樣,遮罩之總厚度(一次電沈積層與二次電沈積層之合計厚度)分別設為45 μm、80 μm、120 μm,突起之高度分別設為25 μm、50 μm、60 μm,突起之俯視下之直徑為約200 μm。試驗結果為,所有突起均未發生脫落。For Example 1, the following three types of mask samples were made and used The dynamometer with a 3 mm piercing terminal was tested by applying a force of 100 N from the projection side of the shield for 30 seconds. Regarding the mask sample, the total thickness of the mask (the total thickness of the primary electrodeposition layer and the secondary electrodeposition layer) was set to 45 μm, 80 μm, and 120 μm, respectively, and the protrusion height was set to 25 μm, 50 μm, and 60 μm, the diameter of the protrusion in plan view is about 200 μm. As a result of the test, none of the protrusions fell off.
對於實施例2及實施例3亦與實施例1同樣地,製作了以下三種類型之遮罩試樣,且使用具有3 mm之刺入型端子之測力計,進行了從遮罩之突起側施加30秒之100 N之外力之脫落試驗。關於遮罩試樣,遮罩之總厚度(一次電沈積層與二次電沈積層之總厚度)分別設為45 μm、80 μm、120 μm,突起之高度分別設為25 μm、50 μm、60 μm,並且突起之俯視下之直徑為約200 μm。試驗結果為,所有突起均未發生脫落。For Example 2 and Example 3, in the same way as Example 1, the following three types of mask samples were made and used The dynamometer with a 3 mm piercing terminal was tested by applying a force of 100 N from the projection side of the shield for 30 seconds. Regarding the mask sample, the total thickness of the mask (the total thickness of the primary electrodeposition layer and the secondary electrodeposition layer) is set to 45 μm, 80 μm, and 120 μm, respectively, and the height of the protrusions is set to 25 μm, 50 μm, 60 μm, and the diameter of the protrusion in plan view is about 200 μm. As a result of the test, none of the protrusions fell off.
為了進行比較,對先前技術之遮罩之突起亦進行了與上述實施例相同之脫落試驗,其結果發現三種類型之突起均多半發生脫落。根據該等試驗結果可確認,本發明之遮罩之一次電沈積層與二次電沈積層之界面之密接性提高。For comparison, the projections of the mask of the prior art were also subjected to the same fall-off test as in the above-mentioned embodiment. As a result, it was found that most of the three types of projections fell off. According to these test results, it can be confirmed that the adhesion of the interface between the primary electrodeposition layer and the secondary electrodeposition layer of the mask of the present invention is improved.
以上,基於實施例對本發明進行了說明,但是本發明並不限於上述之實施例。例如,於上述實施例1中,將形成突起之一次電沈積層之俯視形狀設定為單圓環,但環之形態不限於單環之形態,亦可為多環之形態。又,於上述實施例中,對設置廢棄電沈積層之遮罩之製造方法進行了說明,但當然亦可應用於未設置廢棄電沈積層之遮罩之製造方法。 [產業上之可利用性]Above, the present invention has been described based on the embodiments, but the present invention is not limited to the above-mentioned embodiments. For example, in the above-mentioned Example 1, the top view shape of the primary electrodeposited layer forming the protrusions is set to a single circular ring, but the form of the ring is not limited to the form of a single ring, and may be a form of multiple rings. In addition, in the above-mentioned embodiment, the manufacturing method of the mask provided with the waste electrodeposition layer has been described, but of course it can also be applied to the manufacturing method of the mask without the waste electrodeposition layer. [Industrial availability]
本發明之焊球陣列用遮罩可適用於將導電性焊球排列於基板等,本發明之製造方法能夠用於製造可防止一次電沈積層從形成遮罩之突起之二次電沈積層脫落之焊球陣列用遮罩。The mask for the solder ball array of the present invention is suitable for arranging conductive solder balls on a substrate, etc., and the manufacturing method of the present invention can be used for manufacturing a secondary electrodeposition layer that prevents the primary electrodeposition layer from falling off the protrusion forming the mask Mask for the solder ball array.
1:焊球陣列用遮罩(遮罩)
2:突起部(突起)
3:一次電沈積層
4:二次電沈積層
5,6,7:界面
8:傘
9:柄
11:卡止部
20:母模
21:光阻膜
22:一次圖案抗蝕劑膜
23:廢棄電沈積層
25:光阻膜
26:二次圖案抗蝕劑膜
30:開口部
F:外力1: Mask for solder ball array (mask)
2: Protruding part (protrusion)
3: Primary electrodeposition layer
4:
圖1係模式性表示實施例1之遮罩之突起之放大剖視圖。 圖2係模式性表示實施例2之遮罩之突起之放大剖視圖。 圖3係模式性表示實施例3之遮罩之突起之放大剖視圖。 圖4(a)~(l)係表示實施例1之遮罩之製造方法之步驟說明圖。 圖5係圖4(c)之A-A箭頭方向觀察之俯視圖。 圖6係圖4(f)之B-B箭頭方向觀察之俯視圖。 圖7係圖4(j)之C-C箭頭方向觀察之俯視圖。 圖8(a)~(c)係表示實施例2之遮罩之製造方法之步驟說明圖。 圖9(a)~(f)係表示實施例3之遮罩之製造方法之步驟說明圖。 圖10(a)、(b)係模式性表示先前技術之遮罩之突起之放大剖視圖。FIG. 1 is an enlarged cross-sectional view schematically showing the protrusion of the mask of Example 1. FIG. FIG. 2 is an enlarged cross-sectional view schematically showing the protrusion of the mask of Example 2. FIG. FIG. 3 is an enlarged cross-sectional view schematically showing the protrusion of the mask of Example 3. FIG. 4(a) to (l) are explanatory diagrams showing the steps of the manufacturing method of the mask of the first embodiment. Fig. 5 is a plan view viewed from the direction of arrow A-A in Fig. 4(c). Fig. 6 is a plan view viewed from the direction of arrow B-B in Fig. 4(f). Fig. 7 is a top view of Fig. 4(j) viewed from the direction of arrow C-C. 8(a) to (c) are explanatory diagrams showing the steps of the manufacturing method of the mask of the second embodiment. 9(a) to (f) are explanatory diagrams showing the steps of the manufacturing method of the mask of the third embodiment. Fig. 10 (a) and (b) are enlarged cross-sectional views schematically showing the protrusions of the mask of the prior art.
1:焊球陣列用遮罩(遮罩)1: Mask for solder ball array (mask)
2:突起部(突起)2: Protruding part (protrusion)
3:一次電沈積層3: Primary electrodeposition layer
4:二次電沈積層4: Secondary electrodeposition layer
5:界面5: interface
6:界面6: Interface
7:界面7: Interface
F:外力F: External force
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JP2021093476A (en) | 2021-06-17 |
TWI869438B (en) | 2025-01-11 |
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