TW235906B - - Google Patents
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- Publication number
- TW235906B TW235906B TW82101879A TW82101879A TW235906B TW 235906 B TW235906 B TW 235906B TW 82101879 A TW82101879 A TW 82101879A TW 82101879 A TW82101879 A TW 82101879A TW 235906 B TW235906 B TW 235906B
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- TW
- Taiwan
- Prior art keywords
- combustion
- extrudate
- wrapping
- patent application
- composite member
- Prior art date
Links
- 239000000463 material Substances 0.000 claims abstract description 119
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- 238000005520 cutting process Methods 0.000 claims abstract description 9
- 238000002485 combustion reaction Methods 0.000 claims description 29
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- 238000001125 extrusion Methods 0.000 claims description 10
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- 235000013399 edible fruits Nutrition 0.000 claims description 2
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- 238000003825 pressing Methods 0.000 claims 2
- 239000000446 fuel Substances 0.000 abstract description 35
- 235000019504 cigarettes Nutrition 0.000 abstract description 34
- 239000010410 layer Substances 0.000 description 60
- 241000208125 Nicotiana Species 0.000 description 45
- 235000002637 Nicotiana tabacum Nutrition 0.000 description 45
- 239000000123 paper Substances 0.000 description 43
- 239000000779 smoke Substances 0.000 description 30
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 22
- 239000000853 adhesive Substances 0.000 description 9
- 230000001070 adhesive effect Effects 0.000 description 9
- 239000001814 pectin Substances 0.000 description 9
- 235000010987 pectin Nutrition 0.000 description 9
- 229920001277 pectin Polymers 0.000 description 9
- 239000000758 substrate Substances 0.000 description 9
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 8
- 230000008569 process Effects 0.000 description 7
- 241000233866 Fungi Species 0.000 description 6
- 239000003365 glass fiber Substances 0.000 description 6
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- 239000003795 chemical substances by application Substances 0.000 description 5
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- 239000000796 flavoring agent Substances 0.000 description 5
- 230000001939 inductive effect Effects 0.000 description 5
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 4
- 244000025254 Cannabis sativa Species 0.000 description 4
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 4
- 230000004888 barrier function Effects 0.000 description 4
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- 229910052742 iron Inorganic materials 0.000 description 4
- 238000012545 processing Methods 0.000 description 4
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 3
- 241000605422 Asparagus asparagoides Species 0.000 description 3
- 238000009826 distribution Methods 0.000 description 3
- 238000001035 drying Methods 0.000 description 3
- 239000000835 fiber Substances 0.000 description 3
- 239000011121 hardwood Substances 0.000 description 3
- 238000009413 insulation Methods 0.000 description 3
- 239000000843 powder Substances 0.000 description 3
- 238000002360 preparation method Methods 0.000 description 3
- 239000011734 sodium Substances 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 3
- 238000012360 testing method Methods 0.000 description 3
- 238000012546 transfer Methods 0.000 description 3
- DCXYFEDJOCDNAF-UHFFFAOYSA-N Asparagine Natural products OC(=O)C(N)CC(N)=O DCXYFEDJOCDNAF-UHFFFAOYSA-N 0.000 description 2
- 108010011485 Aspartame Proteins 0.000 description 2
- 229930091371 Fructose Natural products 0.000 description 2
- RFSUNEUAIZKAJO-ARQDHWQXSA-N Fructose Chemical compound OC[C@H]1O[C@](O)(CO)[C@@H](O)[C@@H]1O RFSUNEUAIZKAJO-ARQDHWQXSA-N 0.000 description 2
- 239000005715 Fructose Substances 0.000 description 2
- DHMQDGOQFOQNFH-UHFFFAOYSA-N Glycine Chemical compound NCC(O)=O DHMQDGOQFOQNFH-UHFFFAOYSA-N 0.000 description 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 2
- ONIBWKKTOPOVIA-BYPYZUCNSA-N L-Proline Chemical compound OC(=O)[C@@H]1CCCN1 ONIBWKKTOPOVIA-BYPYZUCNSA-N 0.000 description 2
- 229910002651 NO3 Inorganic materials 0.000 description 2
- NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 description 2
- 239000004743 Polypropylene Substances 0.000 description 2
- ONIBWKKTOPOVIA-UHFFFAOYSA-N Proline Natural products OC(=O)C1CCCN1 ONIBWKKTOPOVIA-UHFFFAOYSA-N 0.000 description 2
- 229920001131 Pulp (paper) Polymers 0.000 description 2
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 2
- 239000002956 ash Substances 0.000 description 2
- 235000009582 asparagine Nutrition 0.000 description 2
- 229960001230 asparagine Drugs 0.000 description 2
- IAOZJIPTCAWIRG-QWRGUYRKSA-N aspartame Chemical compound OC(=O)C[C@H](N)C(=O)N[C@H](C(=O)OC)CC1=CC=CC=C1 IAOZJIPTCAWIRG-QWRGUYRKSA-N 0.000 description 2
- 239000000605 aspartame Substances 0.000 description 2
- 235000010357 aspartame Nutrition 0.000 description 2
- 229960003438 aspartame Drugs 0.000 description 2
- 230000005540 biological transmission Effects 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 238000005336 cracking Methods 0.000 description 2
- 230000003111 delayed effect Effects 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 239000000284 extract Substances 0.000 description 2
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- 235000011187 glycerol Nutrition 0.000 description 2
- 230000006872 improvement Effects 0.000 description 2
- 239000004615 ingredient Substances 0.000 description 2
- 239000012212 insulator Substances 0.000 description 2
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 2
- 238000012423 maintenance Methods 0.000 description 2
- 229910052757 nitrogen Inorganic materials 0.000 description 2
- 229910052762 osmium Inorganic materials 0.000 description 2
- SYQBFIAQOQZEGI-UHFFFAOYSA-N osmium atom Chemical compound [Os] SYQBFIAQOQZEGI-UHFFFAOYSA-N 0.000 description 2
- -1 polyethylene Polymers 0.000 description 2
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- 229910052708 sodium Inorganic materials 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- 241000894007 species Species 0.000 description 2
- 235000013599 spices Nutrition 0.000 description 2
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- 238000003892 spreading Methods 0.000 description 2
- 239000000080 wetting agent Substances 0.000 description 2
- ZWAYGPMHTBGKIW-BYPYZUCNSA-N (2s)-2-aminobutanedial Chemical compound O=C[C@@H](N)CC=O ZWAYGPMHTBGKIW-BYPYZUCNSA-N 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 235000013162 Cocos nucifera Nutrition 0.000 description 1
- 244000060011 Cocos nucifera Species 0.000 description 1
- 102100029158 Consortin Human genes 0.000 description 1
- LEVWYRKDKASIDU-QWWZWVQMSA-N D-cystine Chemical compound OC(=O)[C@H](N)CSSC[C@@H](N)C(O)=O LEVWYRKDKASIDU-QWWZWVQMSA-N 0.000 description 1
- PQUCIEFHOVEZAU-UHFFFAOYSA-N Diammonium sulfite Chemical compound [NH4+].[NH4+].[O-]S([O-])=O PQUCIEFHOVEZAU-UHFFFAOYSA-N 0.000 description 1
- 108010016626 Dipeptides Proteins 0.000 description 1
- 229910052693 Europium Inorganic materials 0.000 description 1
- 208000001836 Firesetting Behavior Diseases 0.000 description 1
- 235000002918 Fraxinus excelsior Nutrition 0.000 description 1
- WHUUTDBJXJRKMK-UHFFFAOYSA-N Glutamic acid Natural products OC(=O)C(N)CCC(O)=O WHUUTDBJXJRKMK-UHFFFAOYSA-N 0.000 description 1
- 239000004471 Glycine Substances 0.000 description 1
- 240000004670 Glycyrrhiza echinata Species 0.000 description 1
- 235000001453 Glycyrrhiza echinata Nutrition 0.000 description 1
- 235000006200 Glycyrrhiza glabra Nutrition 0.000 description 1
- 235000017382 Glycyrrhiza lepidota Nutrition 0.000 description 1
- 101000771062 Homo sapiens Consortin Proteins 0.000 description 1
- QNAYBMKLOCPYGJ-REOHCLBHSA-N L-alanine Chemical compound C[C@H](N)C(O)=O QNAYBMKLOCPYGJ-REOHCLBHSA-N 0.000 description 1
- DCXYFEDJOCDNAF-REOHCLBHSA-N L-asparagine Chemical compound OC(=O)[C@@H](N)CC(N)=O DCXYFEDJOCDNAF-REOHCLBHSA-N 0.000 description 1
- WHUUTDBJXJRKMK-VKHMYHEASA-N L-glutamic acid Chemical compound OC(=O)[C@@H](N)CCC(O)=O WHUUTDBJXJRKMK-VKHMYHEASA-N 0.000 description 1
- ZDXPYRJPNDTMRX-VKHMYHEASA-N L-glutamine Chemical compound OC(=O)[C@@H](N)CCC(N)=O ZDXPYRJPNDTMRX-VKHMYHEASA-N 0.000 description 1
- COLNVLDHVKWLRT-QMMMGPOBSA-N L-phenylalanine Chemical compound OC(=O)[C@@H](N)CC1=CC=CC=C1 COLNVLDHVKWLRT-QMMMGPOBSA-N 0.000 description 1
- 235000014676 Phragmites communis Nutrition 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- RAHZWNYVWXNFOC-UHFFFAOYSA-N Sulphur dioxide Chemical compound O=S=O RAHZWNYVWXNFOC-UHFFFAOYSA-N 0.000 description 1
- 235000009470 Theobroma cacao Nutrition 0.000 description 1
- 244000299461 Theobroma cacao Species 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 230000004913 activation Effects 0.000 description 1
- 235000004279 alanine Nutrition 0.000 description 1
- 229960003767 alanine Drugs 0.000 description 1
- 150000001371 alpha-amino acids Chemical class 0.000 description 1
- 235000008206 alpha-amino acids Nutrition 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 235000001014 amino acid Nutrition 0.000 description 1
- 229940024606 amino acid Drugs 0.000 description 1
- 150000001413 amino acids Chemical class 0.000 description 1
- 229910021529 ammonia Inorganic materials 0.000 description 1
- 239000000728 ammonium alginate Substances 0.000 description 1
- 235000010407 ammonium alginate Nutrition 0.000 description 1
- KPGABFJTMYCRHJ-YZOKENDUSA-N ammonium alginate Chemical compound [NH4+].[NH4+].O1[C@@H](C([O-])=O)[C@@H](OC)[C@H](O)[C@H](O)[C@@H]1O[C@@H]1[C@@H](C([O-])=O)O[C@@H](O)[C@@H](O)[C@H]1O KPGABFJTMYCRHJ-YZOKENDUSA-N 0.000 description 1
- LFVGISIMTYGQHF-UHFFFAOYSA-N ammonium dihydrogen phosphate Chemical compound [NH4+].OP(O)([O-])=O LFVGISIMTYGQHF-UHFFFAOYSA-N 0.000 description 1
- 229910000148 ammonium phosphate Inorganic materials 0.000 description 1
- ZRIUUUJAJJNDSS-UHFFFAOYSA-N ammonium phosphates Chemical compound [NH4+].[NH4+].[NH4+].[O-]P([O-])([O-])=O ZRIUUUJAJJNDSS-UHFFFAOYSA-N 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 125000000613 asparagine group Chemical group N[C@@H](CC(N)=O)C(=O)* 0.000 description 1
- 239000012298 atmosphere Substances 0.000 description 1
- 229910052788 barium Inorganic materials 0.000 description 1
- DSAJWYNOEDNPEQ-UHFFFAOYSA-N barium atom Chemical compound [Ba] DSAJWYNOEDNPEQ-UHFFFAOYSA-N 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 230000008033 biological extinction Effects 0.000 description 1
- 239000004202 carbamide Substances 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 241001233037 catfish Species 0.000 description 1
- 239000000919 ceramic Substances 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 235000019506 cigar Nutrition 0.000 description 1
- 239000003818 cinder Substances 0.000 description 1
- 210000000078 claw Anatomy 0.000 description 1
- 230000006835 compression Effects 0.000 description 1
- 238000007906 compression Methods 0.000 description 1
- 230000002079 cooperative effect Effects 0.000 description 1
- 229960003067 cystine Drugs 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- MNNHAPBLZZVQHP-UHFFFAOYSA-N diammonium hydrogen phosphate Chemical compound [NH4+].[NH4+].OP([O-])([O-])=O MNNHAPBLZZVQHP-UHFFFAOYSA-N 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- OGPBJKLSAFTDLK-UHFFFAOYSA-N europium atom Chemical compound [Eu] OGPBJKLSAFTDLK-UHFFFAOYSA-N 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 235000013355 food flavoring agent Nutrition 0.000 description 1
- 239000003205 fragrance Substances 0.000 description 1
- 238000002309 gasification Methods 0.000 description 1
- 235000013922 glutamic acid Nutrition 0.000 description 1
- 239000004220 glutamic acid Substances 0.000 description 1
- ZDXPYRJPNDTMRX-UHFFFAOYSA-N glutamine Natural products OC(=O)C(N)CCC(N)=O ZDXPYRJPNDTMRX-UHFFFAOYSA-N 0.000 description 1
- 229960002743 glutamine Drugs 0.000 description 1
- 229960002449 glycine Drugs 0.000 description 1
- 150000002337 glycosamines Chemical class 0.000 description 1
- 230000005484 gravity Effects 0.000 description 1
- 230000020169 heat generation Effects 0.000 description 1
- 230000033444 hydroxylation Effects 0.000 description 1
- 238000005805 hydroxylation reaction Methods 0.000 description 1
- 238000002347 injection Methods 0.000 description 1
- 239000007924 injection Substances 0.000 description 1
- 238000012966 insertion method Methods 0.000 description 1
- 238000009434 installation Methods 0.000 description 1
- 239000012774 insulation material Substances 0.000 description 1
- 239000011229 interlayer Substances 0.000 description 1
- 239000002655 kraft paper Substances 0.000 description 1
- 238000003475 lamination Methods 0.000 description 1
- 229940010454 licorice Drugs 0.000 description 1
- 238000011068 loading method Methods 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 239000003595 mist Substances 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 238000013021 overheating Methods 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 230000002093 peripheral effect Effects 0.000 description 1
- COLNVLDHVKWLRT-UHFFFAOYSA-N phenylalanine Natural products OC(=O)C(N)CC1=CC=CC=C1 COLNVLDHVKWLRT-UHFFFAOYSA-N 0.000 description 1
- 238000001637 plasma atomic emission spectroscopy Methods 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 229910052573 porcelain Inorganic materials 0.000 description 1
- 238000000197 pyrolysis Methods 0.000 description 1
- 150000003856 quaternary ammonium compounds Chemical class 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 230000001172 regenerating effect Effects 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 239000010802 sludge Substances 0.000 description 1
- 229910000029 sodium carbonate Inorganic materials 0.000 description 1
- 239000001509 sodium citrate Substances 0.000 description 1
- NLJMYIDDQXHKNR-UHFFFAOYSA-K sodium citrate Chemical compound O.O.[Na+].[Na+].[Na+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O NLJMYIDDQXHKNR-UHFFFAOYSA-K 0.000 description 1
- GCLGEJMYGQKIIW-UHFFFAOYSA-H sodium hexametaphosphate Chemical compound [Na]OP1(=O)OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])O1 GCLGEJMYGQKIIW-UHFFFAOYSA-H 0.000 description 1
- 239000011343 solid material Substances 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 230000003238 somatosensory effect Effects 0.000 description 1
- 235000000346 sugar Nutrition 0.000 description 1
- 239000000454 talc Substances 0.000 description 1
- 229910052623 talc Inorganic materials 0.000 description 1
- 229940098465 tincture Drugs 0.000 description 1
- 235000013311 vegetables Nutrition 0.000 description 1
- 238000009423 ventilation Methods 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
- A24B—MANUFACTURE OR PREPARATION OF TOBACCO FOR SMOKING OR CHEWING; TOBACCO; SNUFF
- A24B15/00—Chemical features or treatment of tobacco; Tobacco substitutes, e.g. in liquid form
- A24B15/10—Chemical features of tobacco products or tobacco substitutes
- A24B15/16—Chemical features of tobacco products or tobacco substitutes of tobacco substitutes
- A24B15/165—Chemical features of tobacco products or tobacco substitutes of tobacco substitutes comprising as heat source a carbon fuel or an oxidized or thermally degraded carbonaceous fuel, e.g. carbohydrates, cellulosic material
-
- A—HUMAN NECESSITIES
- A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
- A24B—MANUFACTURE OR PREPARATION OF TOBACCO FOR SMOKING OR CHEWING; TOBACCO; SNUFF
- A24B15/00—Chemical features or treatment of tobacco; Tobacco substitutes, e.g. in liquid form
-
- A—HUMAN NECESSITIES
- A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
- A24D—CIGARS; CIGARETTES; TOBACCO SMOKE FILTERS; MOUTHPIECES FOR CIGARS OR CIGARETTES; MANUFACTURE OF TOBACCO SMOKE FILTERS OR MOUTHPIECES
- A24D1/00—Cigars; Cigarettes
- A24D1/22—Cigarettes with integrated combustible heat sources, e.g. with carbonaceous heat sources
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
- B29C48/25—Component parts, details or accessories; Auxiliary operations
- B29C48/92—Measuring, controlling or regulating
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C2948/00—Indexing scheme relating to extrusion moulding
- B29C2948/92—Measuring, controlling or regulating
- B29C2948/92009—Measured parameter
- B29C2948/92085—Velocity
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C2948/00—Indexing scheme relating to extrusion moulding
- B29C2948/92—Measuring, controlling or regulating
- B29C2948/92323—Location or phase of measurement
- B29C2948/92438—Conveying, transporting or storage of articles
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C2948/00—Indexing scheme relating to extrusion moulding
- B29C2948/92—Measuring, controlling or regulating
- B29C2948/92504—Controlled parameter
- B29C2948/9258—Velocity
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C2948/00—Indexing scheme relating to extrusion moulding
- B29C2948/92—Measuring, controlling or regulating
- B29C2948/92504—Controlled parameter
- B29C2948/9258—Velocity
- B29C2948/9259—Angular velocity
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C2948/00—Indexing scheme relating to extrusion moulding
- B29C2948/92—Measuring, controlling or regulating
- B29C2948/92504—Controlled parameter
- B29C2948/9258—Velocity
- B29C2948/926—Flow or feed rate
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C2948/00—Indexing scheme relating to extrusion moulding
- B29C2948/92—Measuring, controlling or regulating
- B29C2948/92504—Controlled parameter
- B29C2948/92609—Dimensions
- B29C2948/92638—Length
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C2948/00—Indexing scheme relating to extrusion moulding
- B29C2948/92—Measuring, controlling or regulating
- B29C2948/92819—Location or phase of control
- B29C2948/92933—Conveying, transporting or storage of articles
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Molecular Biology (AREA)
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Manufacture Of Tobacco Products (AREA)
- Cigarettes, Filters, And Manufacturing Of Filters (AREA)
- Solid Fuels And Fuel-Associated Substances (AREA)
- Manufacturing Of Cigar And Cigarette Tobacco (AREA)
- Fixed Capacitors And Capacitor Manufacturing Machines (AREA)
- Preparation Of Compounds By Using Micro-Organisms (AREA)
Description
235906 Λ6 B6 五、發明説明(1.) 發明之領域. 本發明係關於吸煙物品諸如香煙,尤指供吸煙物品 之助燃成份,包括有根據本發明所製成之助燃成份之吸 煙物品諸如香煙,以及製造此等成份及物品之方法及設 備。 發明夕背暑 雪茄及煙斗為流行形式之煙草吸煙物品。多年來人 們曾建議很多吸煙製品及吸煙物品,作為對此等流行形 式煙草吸煙物品之改良,或作為其替代物。改良吸煙物 品之實例有美國專利 4,793,365號 ,4,771,795號, 4 ,756,318號,4,714,082號,及 4,708, 151 號中所說明 之香煙及煙斗,其通常包含一燃料元件,一實際單獨之 煙霧産生裝置,及一單獨之口端件。 在參考併入之歐洲專利公布0174645(A2)及0212234 (A2)號,掲示若干替代形成之吸煙物品,其一般包括有 (1)煙蓀産生心,包含一燃料元件用以産生熱以供傳輪 裝…’........……訂::............線 <請先閲讀背面之注意事項再塡寫本頁) 管绝 套之 - 件 2)元 <料 ’燃 料嬈 材圍 成一 形括 蓀包 煙為 之佳 料較 材管 味套 香 -草心 煙該 有接 含外 可套 1 外 至或 經濟部中央標準局員工消没合泎社印製 為 一 含 替 3 一 代Η含 或 包 ,曰心 料罾生 任 材t産 及 草 霧 煙’煙 含料 -之材常 材熱通 成绝 。 形之件 孩心端 煙生口 繞産之 圍锈件 一 煙元 及個嘴 ,整濾 料繞含 材圍包 熱一可 適 度 尺 張 纸 CN 準 tr 家 a % 釐 公 235906 A6 B6 經濟部中央標準局員工消费合作社印製 五、發明説明(2.) 有煙蓀産生材料而在一端有一燃料元件之包套。 在授予Whife等人之美國專利5, 129 ,133號.掲示一 種擠製之香煙,其中將一種含磺材料擠壓於一包捲之煙 蓀産生材料周圍,致使含碩材料及煙霧産生材料隨其間 之阻擋層縱向共同延伸。或則,煙霧産生材料可外接含 硪材料,而在其間有一阻措層。 在本發明之前,在製迪利用含碩燃料而有單獨煙霧 産生裝置之香煙及其他吸煙物品時,通常必要首先單獨 形成含磺燃料元件,然後以正確方向將所形成之燃料插 入香煙结構。一般為製成一含水之硝糊或含碩材料,將 其擠壓通過一希望剖面形狀之模具,將擠壓之糊固化成 一自支撐含磺插塞,並將固化之擠壓物切成希望長度之 燃料元件,而藉以形成燃料元件。 將此等燃料元件裝入香煙或其他吸煙物品,為一複 雜之過程,需要使燃料元件定向,將已定向之燃料元件 進给至一將會使燃料元件與實際單獨煙菝産生裝置结合 之裝置,一般為將已定向之燃料元件插入一中空金屬管 之開口端.此管含有一帶有煙孩形成材料之基匾。然後 一般為必須使结合之燃料/煙菝産生器定向,進给至一插 入结構,並插人香煙结構之其餘部份。請見例如美國專 利4,8 9 3 , 6 3 7號,此專利説明用以製造吸煙物品之成份之 設備及方法。此專利說明一種用以製造一有可取下支承 -4 -
本纸張尺度適用fa國家揉_灰—(c N S)甲4規格(210 X 2 9 7公梦I ..................................................................^......................-可...................^ ί請先閱讀背面之注意事項再填寫本頁) 235906 A6 B6 經濟部中央標準局员工消1Ϊ-合泎社印來 五、發明説明(3.) 構件之套管或外套之方法,其中使用一種新穎形成裝置 ,以一種供高速生産之連鑕方式,以一種可壓縮及彈性 材料外接較佳為中空管之該支承構件。吸煙裝置之形成 ,包括在除去可取下支承構件時,燃料元件/煙霧産生 器之插入套管或外套。 本發明提供方法,用以連绩形成助燃成份,其包含 一套管或外·套,外接一擠壓之助燃组成,以供使用於吸 煙物品,例如香煙型式吸煙物品。 本發明另提供新穎之助燃成份,以及製造此等助燃 成份之設備,解決很多之製造複雜性,並提供改良之吸 煙物品。 發明之槪沭 ' 根據本發明,供吸煙物品之助燃成份為連接擠壓一 種组成以形成預先選擇之形狀,以一層材料外接該連績 擠壓之组成以形成一包捲棒或複合構件,較佳為將助燃 元件拈接至該層材料,並將所獲得之複合構件切成預定 之長度,以供用於组合吸煙物品所形成。較佳為,外接 助燃元件之該層材料作用使助燃元件保持在助燃成份中 。該固持層較佳為包含一種可壓缩彈性材料,諸如一種 锇維绝熱材料。外接之材料宜為包含多層,例如一層绝 熱材料,諸如玻璃纖維,一層含有煙之香味源之材料, 本纸張尺度適闵中西家標準(CNS)甲4規格丨210x 297公釐丨 ...........................'...........·.............. t::丨-玎 :….^ <請先閱讀背面之注意事項再填寫本頁) 235906 Λ6 B6 經濟部中央標準局员工消没合作社印製 五、發明説明(4 ) 諸如煙草或煙草紙或含有煙草提出物或香料之其他材料 。如果希望,任何另加之諸層可予外接另一绝熱層。較 佳為以组或其他適當材料外包外接之(諸)層,以便於 處理及界定一外徑。例如,可在'切斷步驟前,使用各種 香煙紙連缠外包外接之諸層。 在本發明之前,將助燃元件直接擠壓成助燃成份, 由於若干原因而被認為不切合實際。一項原因為助燃组 成在擠壓時具有很小之结構完整性,因此非常不可能倖 免於必要製造過程之菝酷處理。由擠製之固有待性産生 另一問題。擠壓機由於通過模具之材料混合,流變之變 化,而在輸出速率上有很大改變。然而型式為組合供吸 煙物品之助燃成份之機器,需要固定之材料供給,以供 始终一貫之輸出。其他問題包括完成成份之结構完整性 ,將直助燃擠入外接層被認為産生脱落問題。換言之, 在點燃前或其後,助燃元件本身均可能自(諸)外接層 脱落。 現經發現,可在一種有效率之製造過程中直接擠壓 助燃元件及製造助燃元件,並提供一助燃成份,助燃元 件在其中粘接至外接之固持材料層,因而防止脱落問題 Ο 在本發明之較佳實施例,所形成之成份包含一细長 濟製之助燃元件,被一較佳爲以可壓縮彈性材料所形成之固 …:...................................................…::裝......................訂…:-------------線 (請先閲讀背面之注意事項再填寫本頁)
本紙張尺度適用中國闼家標準TtXSTTTC^TTTO X 297公货I Λ6 B6 235906 五、發明説明(5.) 持層所外接並粘接至此層,該回持層外接紙包捲材料或 類似材料。本文中所稱之”粘箸”或”粘接”,指固持 層中之材料予以拈接或粘附至擠製的助燃元件之外表面, 其方式為致使固持材料,助燃元件,或造成拈附或粘接 之作甩劑,其某一部份必須斷開或破碎,俥使材料與擠 壓物分開。 在某些較佳實施例,擠壓助燃元件包含一種可用作 燃料之含磺材料,較佳為包含硪糊,粘料及水,有或没 有其他香料或材料,隨後予以乾燥,以形成助燃元件。 在某些較佳實施例,助燃元件也包含煙草或者煙草 源或其他香味源。例如,助燃元件可包含以重量計,最 多約20%煙草,以重量計,較佳約為5%至15% ,以將 煙草煙味給予所獲得之吸煙製品。 可壓縮彈性固持層較佳為使用繼雒材料,以網片之 形式形成,其寬度足以包捲於擠壓组成周圍,而厚度足 以提供該成份之希望外徑。 在有些較佳贲施例,利用多層之彈性層。持別較佳 為助燃元件外接一層絶熱材料,玻璃锇維,此層複外接 一層煙草紙,此層再外接另一層玻璃纖維之實施例。 較佳為,包捲棒另外接一外紙狀包捲材料,形成一 複合構件,以提供該成份之預定外徑。 有各種因素有肋於本發明之成功。本發明之一較佳 -7 一 本紙張尺度適用中1國家標幕_「CN ST—甲4規格—(210 X 2 9 7公犛丨 装:.....................訂....................線 ί請先閱讀背面之注意事項再填寫本頁) 绶濟部中央標準局員工消费合作社印製 235906 A6 B6 五、發明説明(6.) 方面·為控制擠壓為助燃元件之含硝淤漿之水份含置。 含碩淤漿之水份含量,經發現依擠壓情況及燃料混合物 之组成而定,應保持約在20%舆45%之間,較佳為約在 34%與40%之間,以獲得一棰淤漿,其流變特性允許擠 壓,但仍允許如下述處理擠壓物,以産一種凝集之助燃 元件。 供最佳可擠壓性所應保持之含水置,其範圍在若干 程度上依用以形成擠壓物之擠壓機及模具之出口溫度而 定。例如,活塞式擠壓機雖然不連缠,但會在較低溫度 擠壓,因此在助燃组成可用較低水份含量。不過,連鏔 螺旋或擠壓機會在較高溫度,例如攝氏50 — 80°産生擠 壓物。在此等情形,當擠壓物退出楔具時,大部份水便 閃蒸排出助燃组成。擠壓物由於此種蒸發而冷卻,最後 之擠壓物可能水份含量太少,而不允許製造作業上之進 —步處理。故在此等情況應使用較高之初始溫度。 本發明之另一較佳方面,為利用擠壓物由擠壓機之 ........::::…:................................................裝訂:’:------------線 (請先閱讀背面之注意事項再填寫本頁) «濟部中央標準局8工消Φ合泎杜印製 圍與制所 包 周其控時 與 件使 ,出 機 元 ,率輸 壓 燃後速機 擠 助機之懕 在 壓壓定擠 為 擠擠確償 . 於出所補 法 接退此助 方 外物如有 一 層 壓用法 另 料擠使此 。之 材在並 C 異異 使為 ,成差差 制佳接完之出 控較阽所上輸 , 此置 度度機 率。裝速速壓 速度量之送擠 産速測置輪償 生器率裝之補 際機速捲遇 實之 一包遭 本紙張尺度適用由屬國…家屏ri^TUNS )甲4)ί?;^Γ2Τΐ1 X—297公釐丨 經濟部中央標準局員工消贽合作社印製 235906 A6 B6 五、發明説明(7.) 捲裝置間之進給管综包括一延羥環路。該延遲環路應為 足夠大小及幾何形狀,以補償擠壓物供給之正常差異, 並應避免擠壓物管線上之急劇輋折,俥避免使擠壓物斷 裂或斷開。較佳為,包捲裝置及延運環路均用以使擠壓 物至包捲裝置之供給速率穩定。 本發明在製造作菜中為最佳之一方面,為在擠壓機 與包捲裝置間之行進過程中,利用翼面支撐擠壓物。翼 面為擠壓物與包捲裝置間行進之擠壓物藉之至少部份由 空氣激流予以支撐之支承裝置。對於避免産生不均勻, 有機械性缺陷之燃料成份,此種支承可能很重要。翼面 也作用使擠壓物略微冷卻及乾燥,而同時將其输送至包 捲裝置。 本發明成功操作之一項很重要要素,為藉以將助燃 元件粘接至外接材料之方法。較佳為,外接材料在包捲 於助燃元件前,以一種引起粘附之材料予以處理。例如, 在玻璃餓維外接材料之情形,使果膠粘劑再活化,可藉 以獲得外接玻擒繼維層與含碩燃料元件間之粘附.市上 所供售之玻璃纖維,以其重量計,通常包括有少置之此 種粘劑。玻璃戡維較佳為在其與擠壓物之足夠逆流處, 以少量水予以潤濕,致使果膠有機會被所加之水份潤濕 及活化。此過程所加之水份量很少,較佳為僅足以使果 矇活化,以使助燃元件固持在助燃成份中。一般為,所 .........................」............·.......................................裝......................訂........... 線 (請先間讀背面之注意事項再填寫本頁) 本紙張尺度適用中國家標耳規格(2Τ0Ύ297公釐) 經濟部中央櫺準局β工消货合泎社印製 235906 A6 _B6 _ 五、發明説明(8.) ΐ 加水之量约為最後燃元件重量之1 一 2%。可藉一小 , 孔徑管.較佳為一開口 18 — 20橄米之管施加水。也較佳 I · ! 為採用一展佈锟,致使加至彈性材料之水展佈於將會接 ; 觭助燃元坪外表面之玻璃鐵維墊區域之一部份。 較佳為以美國專利4,893 ,637號中所述之方式提供 及供給玻璃绻維墊或其他外接材料,此專利說明一種漏 斗或喇叭形成形裝置,有弧形表面引導網片之邊綠環撓 助燃元件。在使用超過一層網Η狀層之情形,可使用多 個成形裝置,以形成燃料元件周圍諸層之毎一層。不過 ,可使用根據該專利之單一成形裝置,同時形成相同之 網片狀材料。例如.要製成以上所掲示,具有夾層式结 構之助燃成份,亦即使用二層玻璃繼維,而有一層插入 之煙草紙,可將煙草紙層輿一層或另一層玻璃鐵維層同 璃 煙在裝較 玻。香持一前 導件於固同目 引元捲會在 。 置燃包將均作 裝助份份為工 形接成成佳等 成外該該較此 ,均將使此成 形層為致 。完 情二 , ,度會 此使段封長將 在致階密之器 。-造纸望機 置線製將希用 裝邊後 ,至商 形之最中斷干 成紙之紙切若 一 草份之其有 同煙成當將 , 至及燃適並成 给層助他.完 進維 其起上 時纖 或一置 一 所 之上 诰以 製如 。 所為制 y 佳控 an最以 ΓΠ度予 Ge速度 , 之 速 rg器型 bu機線 Π 2 a I 之 H F 丨 D 物 ofK 壓 ,。擠 ni機出 aujfi排 Η製機 2,嘴壓 F-濾擠 KD煙由 為香 -佳種述 ......................4.................................................^......................•可.............:4 一請先閲讀背面之注意事項再填寫本頁)
衣飫張尺度適用中·國1家樣塔+T(JNs )甲4+現格(210 X 297公蛩I 235906 A6 B6 丨恕濟紙·".央氣準局^工消"合作";£,,!知! 五、發明説明(9.) 由本發明所獲得之最大益處無疑為速度及生産力。 在先前方法,必須使擠壓物通過一連串之乾燥裝置,諸 如翼面,俾乾燥諸段燃料元件,致使其可予以處理及儲 存。然後必須將諸段收集,裝至托盤中,諸托盤復予裝 入進料機,以供如例如1 9 88年11月8日發布之美國專利 4 ,7.8 2, 644號中所述,將燃料元件以適當方向進給至插 入機。 新方法可改至成倍數生産助燃元件,然後可利用熟 知之香煙製造技術,將其接合至吸煙物品之其他部份。 可全速操作,KDF-2可處理毎分鐘約4GC直線呎之擠壓物 。以4或更大之倍數切斷,該方法因此可毎分鐘生産數 以千計之助燃成份。 翼面之主要目的,為在擠壓機與包捲/切斷裝置之 間提供最小之接铕傳輸,而非作為使擠壓物乾燥之裝置 。利用本發明所可能之直接注射法,在將助燃元件包括 於助燃成份中時,其水含量基本上仍然很高,諸如约為 28%至3G%。大部份之乾燥於助燃.元件在助燃成份中時 發生.最後水份含量,以重置計,約為2%至1〇%,較 佳约為4%至6%。因此,大部份乾燥設備予以免除. 以及托盤,處理,進给機械.插入機械,及實際上整値 插入過程均予免除。 不僅大為減少加工以及必要之設備及處理,並且也 -1 1 - 本纸H度適用啦1T翅▼標-準(CNS )甲_4規=== ...........................:·........................................裝......................訂:............線 (請先閱讀背面之注意事項再填寫本頁) 經濟部中央標準局員工消货合泎社印^" 235906 A6 B6 五、發明説明(10.) 大為改進所獲得之産品。助燃元件粘接至周圍材料,此 —事實有效防止助燃元件之脱落。減少加工裝置,助燃 元件便受到遠為較少之撞擊,碎裂,斷裂及處理錯誤, 導致大為改進總皚製品品質,及大為減少廢料率。 而且,與插入法之结果比較,助燃元件在助燃成份 ί 中之位置更為一致。因此使最级之吸煙裂品更為一致, 吸煙者可毫無困難點燃在插入過程中皤入香煙中之助燃 元件。 I 較佳為,本發明之助燃元件為配合一實際單獨之煙 蓀産生裝置使用,此煙霧産生裝置包含一帶有煙蓀形成 材料之基體。煙孩産生裝置較佳為縱向位於靠近助燃元 件,較佳為在助燃元件後面間隔1至10毫米,俥減少芯 吸。較佳之基體為一種组基鹾。 較佳為,包括有本發明之助燃元件之吸煙物品諸如 香煙,在香煙之口端利用一口端件,將香煙所産生之煙 锈輸送至吸煙者。較佳之口端件包括一段位於煙霧産生 裝置順流處之滾壓煙草紙,有一低效率濾嘴,例如一在 香煙之口端位於煙草紙插塞順流處之聚乙烯濾嘴。 在吸煙時,來自燃燒助燃元件之熱,在使用本發明 之成份之香煙迅速傳輸至煙蓀産生裝置,並且此熱致使 其中所含之煙菝形成材料揮發,這復通過吸煙物品之口 端件對吸煙者産生一種”煙狀”煙蓀。 -12- ..........................................….........t......................'訂:...............4 (請先閱讀背面之注意事項再塡寫本頁) 本紙張尺度適用♦凼函~家標準丨CNS)甲4規格1210X297公釐ϊ 235906 Λ 6 Β6 五、發明説明(1L ) 種煙 I 之 供成 提構 能所 份物 成化 佳氣 較之 些碩 有 , 之氣 明空 發由 本上 ,本 外基 處 , 好單 述簡 上造 除構 學 化 發 择 之 望 希 他 其 或 料 香 之 望 。 希料 何材 任他 括其 包之 劑置 成徹 形及 蓀以 煙 , , 料 孬材 草 圍 煙周 之置 量裝 干生 若産 有孩 括煙 包 } 中或 成 { 组及 料 , 燃圍 在周 例件 施一兀 實燃 佳助 較在 他 } 其或 /IV 及 煙至 ,味 料香 填之 斷 良 切改 如出 例釋 , 品 草物 煙煙 之吸 式等 形此 il 種 〇 某等 含物 包出 層提 料草 材煙 熱 , 绝舐 〇 之草煙 e 煙 AO香 氐 fcfc "佳 或較 少之 很明 為發 佳本 較在 Η Ρ , WTSP 生亦 産 , 所動 煙活 香量 佳測 較可 之之 明得 發測 本所 驗 試 ,出量 所劑 品之 産著 等顯 此無 至或 露少 暴很 物為 生佳 微較 驗 , 試間 準之 標體 在變 與突 ΡΗ復 WT回 之干 生若 産之 所砠 及ΑΒ, 關見人 相請等 量。以 劑料ag 之材Μ 箸變); 顯突75 ,起(19 者引{ 持有64 支在-3 之存47 驗中3 試品1: es製 3 S , A 之 . 據驗es 根試β 。所 t 傺示Mu 關指 , 應應人 反反等 (請先閱讀背面之注意事項再塡寫本頁) as 、V5 绶濟部中央標準局員工消“合泎社印製 予可物 偽不之 ” 及 含 蓀見所 煙可内 ” * 置 ,物裝 的似生 目類産 之及孩 案 ,煙 本粒在 供徹 , 僅 ,晃 且體感 並氣所 , , 者 稱氣煙 所蒸吸 中括是 文包別 本為特 定 -界見 熱也 之詞 件 一 元 ” 燃霧 助煙 燒” 燃 , 由義 , 定 方所 地此 他如 其依 之 0 品分 物成 煙之 吸生 在産 或所 , 用 上作 質之 適 尺 uy, 氏 *.·
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S 235906 A6 B6 五、發明説明(12·) 否 是 其 論 不 而 劑 發 hint 擇 他 其 VI/ 或 /IV 及 劑 〇 香蓀 增煙 性之 發見 揮可 括生 包産 造之 製分 以百 用約 或少 件至 元用 燃使 助 , 在中 指量 ” 含 碩料 含材 - 捿 ·. MeD , 固 稱之 所糊 中之 文件 本元 如燃。 助碩 此50 明 說 要 簡 之 圖 附 之 香 備 之 製 份 所 成 意 燃 旨 助 之 示 明 。所 發 圖中 本 視 2 據 端及 根 。之 1 示例例圖 ,施施如 圖實實諸 面之之用 剖份中利 向成 1 種 縱燃圖一 為助為為 1. 品 2 3 圖物圖圖 煙 吸 製 以 用 為 備 設 此 圖 略 之 例 施 實 之 備 設 —tit 種 〇 1 例為 施4 實圖 之 垂 0 製 以 用 為 備 設 此 ο » 者圖 份略 成之 之例 品施 物實 煙一 吸另 之之 明備 發設 本為 據 5 根圖 供 •造 统 条 0 噴 佳 較 之 〇 用 者使 份 備 成設 之示 品所 物中 煙 4 吸圖 之合 明配 發可 本為 據 6 〇 根圖圖 供 略 造 之 (請先閲讀背面之注意事項再塡寫本頁) 裝 '?τ .線 經濟部中央標準局員工消贷合作社印製 較 明 說 细 詳 之 例 助份 之成 品燃 物助 煙 一 吸每 供 , 成 1 製圖 程照 過參 缅請 I- HJ 一 特 在 , 可圖 -附 明照 發參 本請 施據 。 根份 成 燃 適 度 尺 CN 準 標 釐 公 235906 A 6 B6 經濟部中央標準局員工消1?合泎社印製 五、發明説明(13.) 10包含一擠壓之组成12被一固體材料15所外接並粘接至 此材料,並且較佳為以一外紙狀包捲材料18予以包捲。 該成份一般為直徑約7 — 8毫米,長度依助燃元件在吸煙 物品上之希望熱産生特性而有所改變。長度也較佳予以 選擇為致使在助燃元件熄滅後,助燃元件之一部份保持 仍粘接至固持層。可以很容易製成具有其他直徑及構形 : 之助燃元件。 關於本發明之使用擠壓组成12,包含一種含硪材料 供助燃元件之實施例,燃料一般為在一種繼維質繼維素 材料,在大約攝氏400°至900° ,較佳约為攝氏550° 至750° ,在非氣化大氣中,藉熱解作用製備而成。將 熱解之材料切斷為短纖維長度,與粘劑,水,及其他適 當材料混合,諸如供最佳可點燃性及發煙特性之硪酸鈉 或其他鈉來源混合,供特裂吸煙製品之門冬醛胺,一種 形式供産生香味之煙草或所希望之其他材料,然後擠壓 成希望之形狀。授予Riggs等人,參考併入本文之美國 專利5, 178, 167號中說明助燃物中納含置之控制及門冬醛 1 胺之使用。 助燃物構形及組成將依助燃元件使用於吸煙物品時所 具有之特性而定。例如,助燃元件可由—種以重量計, 含有90%Kraft硬木磺化木漿,研磨至平均頼粒大小12 徹米,及l〇%Kelco HV溪朊酸胺粘劑之摻合物製成。石只 -1 5 - 本饫張尺度適用中_囪國家榡準niNS)甲1¾¾ 沔7公釐I "*—~~~^ ……::’::.............-.......... ........................裝------------------------------------訂…:.............線 (請先閱讀背面之注意事項再塡寫本頁) 235906 Λ6 B6 五、發明説明(14·) . 粉及粘劑之此種摻合物,較佳為與適當強度之磺酸納水 溶液混合在一起,以形成擠壓混合物,助燃元件自其加 工成為其最後形式,依使用電感鋇合等離子體原子發射 光譜法(ICP - AES)所測量,含有大約2000至20,000ppb ^(Na)。可將以重量計大約30%Na2C〇3溶液加至摻合 物,代替部份或所有水,以形成各種擠壓混合物。含碩 材料之其他適當來源有椰子殼磺,諸如Calgon Carbon C o r p o r a t i ο η , P i 11 s b u r g,P A 以 P C B 供應之 P X C 碩,以及 以批號 B-11030-CAC-5,批號 B-11250-CAC-115 及批號 089-A12-CAC-45供應之實驗用碩。 硬木木漿碩可例如藉使不含滑石级之Grand Prairie Kraft硬木紙在氮墊下碩化,以足以使紙之氣化最少之 逐步方式,使溫度增加至至少攝氏750°之最後碩化溫 度製備而成。所獲得之碩在氮下面冷卻至低於約攝氏 35° ,然後研磨為平均顆粒大小约為直徑12橄米之细粉 (使用Microtrac所測定)。 將助燃物混合物擠壓通過對助燃元件提供剖面形狀之 模具。例如,如圖1- 3中所示,擠壓之助燃物棒有六艏 裝......................訂................線 一請先閱讀背面之注意事項再填寫本頁) 經濟部Φ央標準局^工消汾合作社印製 槽 凹 或 隙 缝 邊 周 之ρίο 隔t 間02 等。 相约 约 度 深 為 各 度 寬 及 吋 供 以 形 圖 之 示 圖 如 為 佳 較 面 表 内 之 槽 四 之 明 發 本 在 持 固 件 元 燃 助 將 層 持 固 藉 0 » 性述 整所 完上 構以 结如 進 增 本紙張尺度適用中1國一家標準(CNST申—Ϊ規格Γ210 X 297公楚丨 235906 經濟部中央標準局員工消"合泎社印製 Λ 6 Β6 五、發明説明(15.) 助燃成份内。固持裝置較佳為外接助燃元件之整館縱向 | 周邊。該層也可延伸超過助燃元件之任一端或兩端,使 助燃元件有效凹入,使其舆香煙之其他成份分開。固持 裝置之較佳彈性特性可允許其部份伸入助燃元件周邊上 之任何凹槽。較佳之固持裝置也有助保持熱,並限制在 使用時否則可能流至助燃元件之徑向大氣量。較佳之固 持裝置因此作用如一绝熱構件。 固持材料可包含玻璃缕維(例如Owens-Corning ”C” 玻璃),一種煙草《料/玻璃缕維混合物,聚集或切碎 煙草紙,聚集或切碎磺紙,煙草切斷填料,或類似者。 如圖3中所示,一種包括有本發明之較佳助燃成份 之代表性香煙或吸煙装置,包含縱向靠近煙菝産生装置 20之助燃成份10。圖示之煙蓀産生装置包含一帶有—種 煙蓀形成材料,諸如甘油,及一包捲组22,例如阻檔紙 之基饈21。煙孩産生裝置20可宜為被硬紙或其他適當材 料之外包捲紙或管23所外接。煙蓀産生裝置位於管23而 與其兩端間開。依基體之長度而定,在基體與口端件30 之前端間可存在一空隙或空間26。如果希望,該空間可 含有煙草,諸如切斷填料或煙草纸。較佳為,煙孩産生 裝置及助燃成份藉另一可與助燃成份之鲇燃端間開之外 包捲纸25结合在一起。基體2 1及助燃元件12較佳為分開 一空間2 4 ,這有肋避免煙孩形成材料之轉移及避免基體 -1 7 - 本纸張尺度適用中1_囪家標準公坌I ' =«== 裝…................訂…:線 ί請先閱讀背面之注意事項再填寫本頁) 235906 經濟部中央標準局員工消"合泎社印製 A6 B6 五、發明説明(16.) 之過度加熱。 香煙另包含一 口端件30,此口端件為以一煙草紙或 其他適當材料卷31所構成,結合至一例如以聚丙烯或其 他適當材料裂成之低效率濾嘴35。 為容易處理,分別以紙32及36外包煙草紙卷31及嫫 料35,並且此二成份複與外包捲紙33结合。 如圖3中所示,口端件30較佳為藉另一外包捲紙37 结合至香煙之前端。 —種較佳之煙霧産生裝置包括一種煙蓀形成材料( 例如甘油),某種形式之煙草(例如煙草粉,煙草提出 物或煙草灰),以及其他煙菝形成材料及(或)煙草增 香劑,諸如可可,甘草精及糖。煙孩形成材料通常由一 基體,諸如聚集纸,聚集煙草组,或另一形式之基匾所 帶有。煙草材料可包圍助燃元件,基體,及(或)用於 本發明之吸煙物品之其他地方。 基體較佳為單塊或基體。基醱為紙型材料時,此種 基體最佳為位於與助燃元件成間開關傜。間開關係希望 使助燃!元件與基體間之接觴減為最少,藉以防止煙霧形 成材料轉移至助燃,以及限制紙基體之任何燒焦.或燃燒 。間隔24可由助燃元件在绝熱及固持裝置之凹入性質, 或在製诰時在助燃元件與基底間造成寅際之空間(亦即 間隙)所提供。 -1 8 - 本纸張尺度適用中國國家標準FCNS j甲4規格297公" ......^ ............................................................................裝…:......................訂…:.......4 ~請先閱讀背面之注意事項再塡寫本頁) 235906 Λ6 B6 經濟部中央標準局員工消贽合诈社印製 五、發明説明(17.) 口端件30備供將煙霧輪送至吸煙者口腔,一般為, 口端件具有大致管狀形狀,並含有煙草材料(例如聚集 煙草之圓柱形裝料)及一填料元件。 一種適當之燃料组成包含約60至99重量百分比磺; 约1至20重量百分比適當粘劑;約1至5重置百分比氨 釋出化合物;以及依使用ICP-AES所測定,約2000至 20,OOOppa納(Ha)。在助燃组成之燃燒狀況下,能釋出 ; 氨之化合物包括諸如尿素,無機及有機鹽類(例如磺晈 銨.藻朊酸銨,或者磷酸一,二,或三銨);氨基糖( 例如脯氨酸果糖或門冬醛胺果糖);氨基酸,尤其是α 氛基酸(例如谷匿胺,甘氛酸,門冬醛胺,脯氨酸,丙 氨酸,胱氨酸,門冬氨酸,苯基丙氨酸或谷氨酸);二 肽或三肽;季銨化合物,及類似化合物。此等燃枓组成 '詳细說明於授予Riggs等人,參考併入之美國專利5, 178, 167 丨號。 請參照圖4 ,可使用一衝壓活塞擠壓機5Q,諸如 Hydramat American Inc.之 HET-120A,摘® 潮濕混合物 。擠壓之混合物12退出一模具,如一有希望剖面形狀之 連缠擠壓物,並積箸至一翼面輪送機52。擠壓物12由此 處以後接觸一可為速率表之棍53,以側量擠壓物流動之 直線速度,此速度可用以控制包捲裝置60,諸如改良型 KDF-2之速度。擠壓物通常在速率锟53與空轉棍54之間形 -1 9 - 本紙張尺度適用中國國家標準_(CNS_)甲4规格(2Ίϋχ__297公货I — 一 _ ~ ..............................…:...............................-.........裝——::——訂-------------------線 (請先閲讀背面之注意事項再填寫本頁) 235906 Λ6 B6 五、發明説明(18·) 成一延遲或滞後環路,以適應設備之諸組件,特別是擠 壓機5 0與K D F - 2間之速度化。固持材料5 8備供以一層材t 料外接擠壓物。較佳為,固持層設有一種在包捲於助燃 元件周圍前,將會有肋於以此等助燃元件之外表面形成 粘接之材料。在固持層為一種含有例如以重量計约3% 至5%果謬之玻璃維層之情形,可比包捲助燃元件而玻 璃繼維中之果膠將會活化粘接至助燃元件足夠提前,以 水噴塗玻璃纖維墊之至少部份表面,而藉以産生粘接。 較佳之翼面輸送機52為一溝道,包含在壓力通風糸 统上之一種孔型,供給低壓空氣,在擠壓物排出擠壓機 時支撐此擠壓物,並且在其移動時,在材料網片進入 KDF-2機器時與其合併或結合。可例如使用空轉輪使翼 面輸送機中止,以形成一擠壓物圈環,KDF-2及擠壓機 之速度變化因而將不會使擠壓物斷開。 包捲裝置較佳為一種市售之填料製造機,由Hauni of Hamburg以標記KDF-2發售者。包捲装置將外接助燃 元件之固持層包捲於外包捲紙中,並將該複合構件切斷 為預定之長度。 圖5中略示製造本發明助燃成份之設備之另一較佳 實施例。如圖示,使用一種複式擠壓機,如雙螺之後式 擠壓機80,將混合物擠壓成希望之形狀。此型之適當儕 壓機為一種 Baker-Perkins MP-50-35 DE XLT 濟壓機; -2 0 - 本纸張尺度適用中西國家中4规格丨210>:297公釐) ::~— = ' ...............................一............·· ....................................$.:..................、玎.........................-^ (請先閱讀背面之注意事項再塡寫本頁) 235906 A 6 B6 經濟部Φ央標準局員工消¢-合泎杜印製 五、發明説明(19,) 較佳為配備有一包括一連串前進螺旋段,葉Η段及進給 ! 螺旋段之螺旋。 I . 在自擠壓機排出時,擠壓物12接觸速率表輪81,其 直線周邊速度由適當裝置予以準確測量。例如,速率表 輪之旋轉速度可由一光電威測器(未示)予以測量,此 烕測器設置為記錄一附著至速率表輪81之齒輪之齒。來 自速度感測器之信號被控制裝置82傳輸至控制包捲及切 斷裝置1〇〇速度之控制器。 在離開速率表輪81後,擠壓物12降入一延運或滯後 環路83,此環路幫助補償擠壓機與包捲及切斷裝置間生 産速率之差異。 擠壓物然後進入翼面輸送機84,輸送至站85,在此 .站,網片材料90之固持層外接於助燃元件周圍。例如, 助燃元件可被Owens-Corning C -玻璃纖維之一種彈性SS 所外接。有關此材料特性之詳情,請見名稱為” cheBlical and Biological Studies of New Cigarette Prototypes That Heat Instead of Burn Tobacco 專 論,PP.4-52, R. T. Reynolds Tobacco Co· ( 1 9 8 8)。 在包捲及切斷機100,玻璃雜維層復被一包捲紙, 較佳為參考併入木文之美國專利4, 938, 238中所述之紙 外接。 可將擠壓物及材料纲片進给至例如一配備有美國專 -2 1 - ίϋ尺度適用中围酊家標準丨CNTS )甲4規格TZ1 (Γ5Γ297公皆T -------- —..............................................::......................裝………,.:…訂...........................線 一請先閲讀背面之注意事項再填寫本頁) 經濟部中夬標準局員工消·tf合泎杜印製 235906 A 6 B6 五、發明説明(2α ) 利 4,893,637號中所述形成装置之HauniKDF-2擯料製造 機,而製成該等成份。在包捲裝置,以美國專利 4, 9 3 8 , 2 3 8號中所述之紙,或其他香煙包捲紙包捲該複 合構件。在包捲紙18 (圖2)包捲及密封於彈性層15周 圍後,複合物之直徑便固定。一刀具横向於包捲裝置設 置;用以將包捲之複合物切斷為預定之長度,以供在製 造吸煙物品時之3外處理。一般為,長度為希望供毎一 吸煙物品使用之大小之倍數。例如,如果10毫米成份長 度用於供每一吸煙物品,包捲複合構件之長度可例如為 40毫米,為4値助燃成份之倍數,然後可將其切斷並結 合至値別之基體,以構成香煙之前端,此前端複可予結 合至傕別口端件,以製成香煙。 如圖5中所示,用以將固持材或塾粘接至助燃元件 表面之裝置包括一粘著引起材料源91, 一導管92及小直 徑管93,導管將材料傳送至進给芦捲於擠壓物周圍之墊 附近,小直徑管在绢片材料90包捲於擠壓物周圍前,粘 接引起材料噴塗於其表面上。用以施加粘著引起材料之 裝置,其位置依使用之拈接引起材料之置,以及足夠引 起粘箸,以便利用助燃元件與外接材料間之現有接W完 成粘著所必要之任何延運期間而定。 例如,在含有果膠之玻璃鐵維塾之情形,粘接引起 材料為一種將會使果膠活化以形成粘接者。較佳之黏接 -2 2 - 本纸張尺度適用中_國3Γ家標TTCNS)甲4_規格(210X297公釐' ~ ' ~ ................................................. ...............................裝...........................訂……——……線 (請先閲讀背面之注意事項再塡寫本頁) 235906 A 6 B6 經濟部+央標準局負工消贷合泎社印5i 五、發明説明(22 ) 材料為水。用以施加粘接引起材料之裝置,其位置依塾 之果膠含量,糸统之速度等而定,以便足夠在果膠或其 他粘接材料在其外接於面燃元件周圍時或其後不久將會 被活化之時間以前,以活化材料潤濕玻璃纖維墊。用以 使網片材料活化之水,其量很少,以助燃成份之重置計 ,約為1 %至3 %。 可使用一供給管及針狀構件將粘接引起材料施加至 擠壓物,何在預定高度由供給源藉重力進給,或藉計量 ,或熟練技工很容易供给之其他適當裝置控制流動速率 〇 圖6中示用以施加粘接引起材料之適當裝置之更詳 细示意圖。水或其他粘接引起材料112傜由源110所獲得 ,並通過小直徑管111噴至展佈或分配棍113。分配棍113 接觸固持層表面之一部扮,此部份表面將會接觸最後助 燃成份中之助燃元件之表面。如圖示,該棍如上述美國 專利4,8 9 3,6 3 7號中所述,間開為於固持層90沿包捲裝 置之弧形表面114供給時,接觸此固持層。實際上,施 加粘接引起材料之位置,偽如上述由擠壓物之速度及其 他因素所決定,以便施加足夠粘接引起材料至外接材料 足夠時間,致使可發生適當之粘接。在玻璃戡維塾之情 形,使水與固持層接觸足夠時間,以允許果膠或其他粘 接形成材料活化。分配棍1 1 3之表面較佳為予以壓花,以 有肋粘接引起材料之分佈。 -23- ........................................………:- ’: ::^----------------------•玎.............….^- ~請先閱讀背面之注意事項再填寫本頁) 本纸張尺度適用中國國家標舉—丨甲4蜣^Γ21(ίχ297公釐、 235906 A6 B6 五、發明説明(21.) 要在擠壓物與彈性層之間形成粘接,含水可活化粘 接材料之彈性層較佳為剛好在外接助燃元件前予以潤濕 。較佳為,使用水作為潤濕劑,使粘接材料在材料層之 表面溶液化或以其他方式活化,以供於水蒸發時與擠出 物之表面粘著或粘接。依外接®之組成,粘接劑之组成 ,及携壓物之组成而定,可採用其他滴當溶劑。在溶劑 或潤濕劑中,或在擠壓物之表面,也可採用另一種粘接 劑,以便促進粘著或粘接。例如,可將果膠或RaCHC溶 解於水中,以在彈性層與擠壓物之間促進或提供粘著。 在本發明之較佳助燃成分,助燃元件為一種含硪材 料,包含至少約50重量百分比元素碩。助燃元件通常至 少長約10毫米,較佳為至少長約12毫米。助燃元件之最 大長度較佳約為20毫米,較佳長度約為16毫米或以下 。助燃元件之很大長度較佳為予以露出以供燃燒,並且 燃料元件之很大部份在吸煙物品中設罝為致使在抽吸吸 煙物品時不燃燒。這允許助燃元件很大部份間之粘接在 吸煙過程中保持不受所産生之熱干擾。因此,就16毫米 長助燃物而言,可使最先6毫米露出以供燃燒,而有一氣 阻擋或吸熱元件置於致使助燃元件將會约在6毫米自行 熄滅。抽吸此種吸煙物品可預期破萌助燃元件間之粘接 ,略微超過熄減點,例如距助燃元件之最初鲇燃端最 -2 4 - 本纸張尺度適用中家標準丨CNS1甲4規格(210X297公釐1 _ ' ===== 裝......................訂........…:…線 (請先閱讀背面之注意事項再塡寫本頁) 235906 A6 B6 經濟部中央標準局8工消"合作社印製 五、發明説明(2立)多8毫米◊然而助燃元件間之粘接,例如距元件點燃端 8毫米與16毫米之間者將會保持,因此實際保證防止助 i 燃元件之脱落。 根據本發明之助燃元件可予擠壓很多不同形狀。 在實施本發明時,供可壓缩彈性外包捲層15用之材 料,可為可外接於擠壓物12周圍,以提供一助燃成份1〇 之任何材料,此助燃成份有一外圓柱形表面較佳為供製 造及在使用時提供若干彈性。彈性材料在吸煙物品之使 用狀況下較佳為熱穩定。 可用材料之實例包括玻璃或陶瓷纖維,煙草,彈性 组成,聚集紙網片及類材料。 煙草或含煙草组用以形成彈性層時,諸如用以供根 據本發明之煙菝産生組成時,煙草可釋出煙菝,例如芳 畚氣味。 較佳為,用以根據本發明,製成助燃组成.中之固持 層之材料也為绝熱材料。 本文中所稱”绝熱材料”一詞適用於主要作用如绝 熱體之所有材料。較佳為,此等材料在使用時實際不燃 燒,但其在使用時可熔化,諸如低溫级玻璃繊維。適當绝 熱體之導熱率以克一卡/(秒)(平方厘米)(度攝氏 /厘米)計,小於約〇 . 〇 5 ,較佳為小於約0 . 0 2 ,最佳為小 =¾ 0 . 0 0 5 〇 請見 ’’Hach’s Chemical Dictionary”, 3 4 -2 5 - 本紙張尺度適用中ΪΪΓΤ標"準(CNTS)甲4'规格(汀〇_又7^7公釐' — — :―:: 裝......................訂—-…:.:線 I請先閱讀背面之注意事項再填寫本頁) 235906 Λ 6 Β6 經濟部中央標準局員工消费合作社印製 五、發明説明(24.) 頁,第 4 販,1969 年及 ’’Lange’s Handbook of Chemistry”, 10, 272-274頁,第 11版,1973年。較佳 之绝熱材料形成一層15,通常至少厚約0.5毫米,較佳 為至少厚約1.0毫米。包圍助燃元件之绝熱及(或)固 持材料,其成份可有所變化。此材料較佳為一種傾向不 燃燒,或燃燒而不分解之材料。適當材料之實例包括玻 璃鐵維及授予White等人之美國專利5, 105, 838號;歃洲 專利公布336,690號;及名稱為” Chemical and Biological Studies of New Cigarette Prototypes That _Heat Instead of Burn Tobacco”之專論 48-52頁, R. J. Reynolds Tobacco Co.所述類型之其他材料。 較佳為以一層或多層香煙紙18外包捲助燃成份10。 較佳之紙在助燃元件燃燒時應無火焰。另外.纸較佳為 應具有可控制之發煙特性,並應産生灰白色似香煙灰燼 Ο 本發明包括其較佳實施例業經予以詳細説明。不過 ,請予察知,精於此項技e者考處本發明之掲示,可對 下列申請專利範圍所閨釋之本發明作成種種修改及(或 )改進。 -26-
本紙張尺度適用中國國家標準_(CNS )甲4規格(2TO又2:£Γ7公釐I .....................................................……:::::——I......................、可…:.............^ (請先閱讀背面之注意事項再填寫本頁)
Claims (1)
- 經濟部中央標準局*C工消费合作社印製 235906 as es i 、丨:正C8 * ' ^ Γί --·{ι y" _D8 六、申請專利範圍 專利申請案第82101879號 ROC Patent Appln. No.82101879 修正之申請專利範困中文本-附件(一) Amended Claims in Chinese - Enel. (I) (民國83年8月卻日送呈) (Submitted on August 1994) 1 ·—種連續形成供吸煙物品之助燃成份之方法,該方 法包含: 連續濟壓一種助燃组成,以形成具有預選形狀之 擠壓物; 以一固持材料層外接連缅擠壓组成,以形成一複合 構件,並將固持層粘接至助燃组成。 2. 根據申請專利範圍第1項之方法,其中助燃,组成 為含碩。 3. 根據申請專利範圍第1項之方法,另包括將複合構 件切斷為預定長度之步驟。 4. 根據申請專利範圍第1項之方法,另包括包捲複合 構件以界定複合構件之外徑。 5. 根據申請專利範圍第1或第2項之方法.其中該方 法另包括在外接步驟前潤濕擠壓物。 6. 根據申請專利範圍第2項之方法,其中固持層包含 内含果廖之玻璃m維。 -27.- (請先閲讀背面之注意事項再填寫本頁) .裝. ,tr 線 本紙張尺度適用中《國家標準(CNS〉A4规格(210X297公釐) 235906 經濟部中央標準局負工消費合作社印裝 A8 B8 C8 D8六、申請專利範圍 7. —種連缠形成供吸煙物品之助燃成份之方法,該方 法包含: 連缜擠壓一包含含碩材料之組成,以形成具有預選 形狀之擠壓物;以一可壓编彈性材料層外接連缳擠 壓组成,以形成一複合構件;以及將所獲得之複合 構件切斷為預定之長度。 8. 根據申諳專利範圍第7項之方法,另包括包捲複合 構件,以在切斷步驟前確定外徑。 9 .根據申請專利範圍第7或第8項之方法,其中在外 接步驟前,該方法另包括濕擠壓物。 10·用以製造供吸煙物品用之助燃成份之設備,包含一 擠壓機,用以測量擠壓物直線速度之裝置,用以包 捲擠壓物乏包捲裝置,用以將擠壓物自擠壓機输送 至包捲裝置之輸送裝置,以及用以補償來自擠壓機 之擠壓物速度與包捲装置速度之裝置。 11.根據申請專利範圍第10項之設備,其中補值裝置包 含用以測量擠壓物直综速度之裝置,以及用以逛應 擠壓物之實測速度改變包捲速度之裝置。 (請先閲讀背面之注意事項再填寫本頁) .裝. 訂 線_ -2& - 本紙張尺度逋用中困國家標準(CNS ) A4規格(210X297公釐)
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1993
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- 1993-03-16 JP JP08024593A patent/JP3472591B2/ja not_active Expired - Fee Related
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- 1993-03-24 KR KR1019930004759A patent/KR100269437B1/ko not_active Expired - Lifetime
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US8074706B2 (en) | 2006-04-21 | 2011-12-13 | Taiwan Microloops Corp. | Heat spreader with composite micro-structure |
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