US20190254335A1 - System for debossing a heat generation member, a smoking article including the debossed heat generation member, and a related method - Google Patents
System for debossing a heat generation member, a smoking article including the debossed heat generation member, and a related method Download PDFInfo
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- US20190254335A1 US20190254335A1 US15/902,665 US201815902665A US2019254335A1 US 20190254335 A1 US20190254335 A1 US 20190254335A1 US 201815902665 A US201815902665 A US 201815902665A US 2019254335 A1 US2019254335 A1 US 2019254335A1
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- Prior art keywords
- heat generation
- generation member
- spaced
- extending
- die
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Classifications
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- A—HUMAN NECESSITIES
- A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
- A24C—MACHINES FOR MAKING CIGARS OR CIGARETTES
- A24C5/00—Making cigarettes; Making tipping materials for, or attaching filters or mouthpieces to, cigars or cigarettes
- A24C5/32—Separating, ordering, counting or examining cigarettes; Regulating the feeding of tobacco according to rod or cigarette condition
- A24C5/322—Transporting cigarettes during manufacturing
- A24C5/327—Construction details of the cigarette transport drum
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- A—HUMAN NECESSITIES
- A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
- A24B—MANUFACTURE OR PREPARATION OF TOBACCO FOR SMOKING OR CHEWING; TOBACCO; SNUFF
- A24B15/00—Chemical features or treatment of tobacco; Tobacco substitutes, e.g. in liquid form
- A24B15/10—Chemical features of tobacco products or tobacco substitutes
- A24B15/16—Chemical features of tobacco products or tobacco substitutes of tobacco substitutes
- A24B15/165—Chemical features of tobacco products or tobacco substitutes of tobacco substitutes comprising as heat source a carbon fuel or an oxidized or thermally degraded carbonaceous fuel, e.g. carbohydrates, cellulosic material
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- A—HUMAN NECESSITIES
- A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
- A24C—MACHINES FOR MAKING CIGARS OR CIGARETTES
- A24C5/00—Making cigarettes; Making tipping materials for, or attaching filters or mouthpieces to, cigars or cigarettes
-
- A—HUMAN NECESSITIES
- A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
- A24C—MACHINES FOR MAKING CIGARS OR CIGARETTES
- A24C5/00—Making cigarettes; Making tipping materials for, or attaching filters or mouthpieces to, cigars or cigarettes
- A24C5/14—Machines of the continuous-rod type
- A24C5/18—Forming the rod
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- A—HUMAN NECESSITIES
- A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
- A24C—MACHINES FOR MAKING CIGARS OR CIGARETTES
- A24C5/00—Making cigarettes; Making tipping materials for, or attaching filters or mouthpieces to, cigars or cigarettes
- A24C5/47—Attaching filters or mouthpieces to cigars or cigarettes, e.g. inserting filters into cigarettes or their mouthpieces
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- A—HUMAN NECESSITIES
- A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
- A24D—CIGARS; CIGARETTES; TOBACCO SMOKE FILTERS; MOUTHPIECES FOR CIGARS OR CIGARETTES; MANUFACTURE OF TOBACCO SMOKE FILTERS OR MOUTHPIECES
- A24D1/00—Cigars; Cigarettes
- A24D1/04—Cigars; Cigarettes with mouthpieces or filter-tips
- A24D1/042—Cigars; Cigarettes with mouthpieces or filter-tips with mouthpieces
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- A—HUMAN NECESSITIES
- A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
- A24D—CIGARS; CIGARETTES; TOBACCO SMOKE FILTERS; MOUTHPIECES FOR CIGARS OR CIGARETTES; MANUFACTURE OF TOBACCO SMOKE FILTERS OR MOUTHPIECES
- A24D1/00—Cigars; Cigarettes
- A24D1/22—Cigarettes with integrated combustible heat sources, e.g. with carbonaceous heat sources
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- A—HUMAN NECESSITIES
- A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
- A24F—SMOKERS' REQUISITES; MATCH BOXES; SIMULATED SMOKING DEVICES
- A24F42/00—Simulated smoking devices other than electrically operated; Component parts thereof; Manufacture or testing thereof
- A24F42/10—Devices with chemical heating means
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- A24F47/006—
Definitions
- the present disclosure relates to products made or derived from tobacco, or that otherwise incorporate tobacco, and are intended for human consumption and, more particularly, to components and configurations of segmented-type smoking articles.
- Popular smoking articles such as cigarettes, have a substantially cylindrical rod-shaped structure and include a charge, roll or column of smokable material, such as shredded tobacco (e.g., in cut filler form), surrounded by a paper wrapper, thereby forming a so-called “smokable rod”, “tobacco rod” or “cigarette rod.”
- smokable rod such as shredded tobacco (e.g., in cut filler form)
- tobacco rod e.g., in cut filler form
- cigarette rod a so-called “smokable rod”, “tobacco rod” or “cigarette rod.”
- these popular types of cigarettes employ carbonaceous fuel elements have been commercially marketed under the brand names “Premier” and “Eclipse” by R. J. Reynolds Tobacco Company. See, for example, those types of cigarettes described in Chemical and Biological Studies on New Cigarette Prototypes that Heat Instead of Burn Tobacco, R. J.
- a system for debossing a heat generation member of an elongate smoking article comprising a dispensing mechanism configured to serially dispense a longitudinally-extending heat generation member along a machine direction, the heat generation member having an outer surface and defining a longitudinal axis; and a debos sing mechanism comprising a first die and an opposing second die each defining a longitudinally-extending channel, the channels of the opposing first and second dies each comprising spaced-apart protrusions and being arranged to receive therebetween the longitudinally-extending heat generation member from the dispensing mechanism, the protrusions in the channels being configured to extend non-parallel to the channels and cooperatively interact with the heat generation member to deboss the outer surface thereof.
- a smoking article comprising a mouth end portion disposed at a mouth end; a tobacco portion disposed between a lighting end and the mouth end portion; and an aerosol-generation system including an aerosol-generation portion disposed between the lighting end and the tobacco portion, the aerosol-generation system including a heat generation portion disposed at the lighting end, the heat generation portion comprising a longitudinally-extending heat generation member configured to be actuated by ignition of the lighting end, the heat generation member defining a plurality of spaced-apart depressions between opposed first and second ends thereof, each depression extending about a circumference of the outer surface thereof.
- a further aspect of the present disclosure provides a method for debossing a heat generation member of an elongate smoking article comprising: serially dispensing a longitudinally-extending heat generation member along a machine direction, the heat generation member having an outer surface and defining a longitudinal axis; and debossing the heat generation member by directing the heat generation member between longitudinally-extending channels of a first die and an opposing longitudinally-extending channel of a second die of a debossing mechanism, the channels of the opposing first and second dies each comprising spaced-apart protrusions, the protrusions in the channels being configured to extend non-parallel to the channels and cooperatively interacting with the heat generation member to deboss the outer surface thereof.
- FIG. 1 shows a representative system diagram of a system for debossing a heat generation member of an elongate smoking article
- FIGS. 2A-2B show detailed views of a representative debossing mechanism for the system of FIG. 1 ;
- FIGS. 3A-3B show two different representative heat generation members debossed by a debossing mechanism
- FIG. 4 shows a representative smoking article with a debossed heat generation member
- FIG. 5 shows a method flow of a method for debossing a heat generation member of an elongate smoking article.
- Example smoking article construction may include features disclosed in U.S. Pat. Nos. 8,464,726 and 9,486,013; both to Sebastian et al., which are incorporated herein by reference.
- FIG. 1 illustrates a representative system 100 for producing a representative smoking article.
- the system 100 includes a reservoir 110 , an extruding mechanism 120 , a dispensing mechanism 130 , and an assembly mechanism 140 .
- the system 100 is further configured to deboss the representative smoking article and includes a debossing mechanism 200 , described in detail in FIG. 2 .
- the reservoir 110 is configured to retain a quantity of a substance and feed the quantity of the substance to the extruding mechanism 120 .
- the reservoir 110 is configured to feed the quantity of the substance in any number of ways depending on the characteristic of the substance retained therein. For example, where the reservoir 110 retains a substance for forming heat generation members therein, the reservoir 110 may gravitationally feed the substance for forming heat generation members to the extruding mechanism 120 .
- a controller (not shown) may be in communication with the reservoir 110 to control the timing of the substance fed to the extruding mechanism 120 .
- the extruding mechanism 120 may be configured to receive the quantity of the substance from the reservoir 110 and may be configured to force (e.g., extrude) the substance through a die to thereby shape an outer circumference of an elongate member formed from the extruded quantity of the substance.
- the elongate member is then severed into a desired length to form individual monolithic elements.
- Each of the individual monolithic elements may be considered “heat generation members,” though depending on the shape extruded from the extruding mechanism 120 other functionalities may be utilized, as well.
- Shapes such as, for example, rods and cubes can be formed by first extruding the material through a die having the desired cross-section (e.g., round or square) and then optionally severing the extruded material into desired lengths.
- Techniques and equipment for extruding tobacco-related materials are set forth in U.S. Pat. No. 3,098,492 to Wursburg; U.S. Pat. No. 4,874,000 to Tamol et al.; U.S. Pat. No. 4,880,018 to Graves et al.; U.S. Pat. No. 4,989,620 to Keritsis et al.; U.S. Pat. No. 5,072,744 to Luke et al.; U.S. Pat.
- Example extrusion equipment suitable for use includes food or gum extruders, or industrial pasta extruders such as Model TP 200/300 available from Emiliomiti, LLC of Italy. In some instances, a single machine may be capable of achieving multiple steps of the processes described herein, such as, for example, kneader systems available from Buss AG.
- Representative heat generation members may comprise a generally cylindrical shape defining a longitudinal axis and having an outer surface.
- the representative heat generation members may incorporate components including, for example, a combustible carbonaceous material.
- Carbonaceous materials generally include a carbon component having a high carbon content.
- Preferred carbonaceous materials are comprised predominately of carbon, typically have carbon contents of greater than about 60 percent, generally greater than about 70 percent, often greater than about 80 percent, and frequently greater than about 90 percent, on a dry weight basis.
- the carbonaceous materials may also include other non-carbon components including, for example, tobacco components, such as powdered tobaccos or tobacco extracts; flavoring agents; salts, such as sodium chloride, potassium chloride and sodium carbonate; heat stable graphite fibers; iron oxide powder; glass filaments; powdered calcium carbonate; alumina granules; ammonia sources, such as ammonia salts; and/or binding agents, such as guar gum, ammonium alginate and sodium alginate.
- tobacco components such as powdered tobaccos or tobacco extracts
- flavoring agents salts, such as sodium chloride, potassium chloride and sodium carbonate
- heat stable graphite fibers iron oxide powder
- glass filaments glass filaments
- powdered calcium carbonate powdered calcium carbonate
- alumina granules granules
- ammonia sources such as ammonia salts
- binding agents such as guar gum, ammonium alginate and sodium alginate.
- a representative heat generation member may have
- each of the heat generation members is severed into a desired length from the material extruded from the extruding mechanism 120 through a die as a monolithic element of a carbonaceous material.
- the die of the extruding mechanism 120 may be configured to extrude the elongate member such that a plurality of longitudinally-extending grooves is formed in the outer surface of the elongate member, wherein the grooves are spaced-apart about the circumference or outer surface thereof.
- each heat generation member When the individual heat generation members are severed from the continuously extruded material (monolithic extrudate), such that each heat generation member is its own monolithic element, the grooves also extend longitudinally between opposed first and second ends of each heat generation member, such that each of the heat generation members has a “fluted” cross-section. In this manner, each of the heat generation members defines between six and ten grooves equidistantly spaced apart about the circumference. In one preferred aspect, the heat generation member defines eight grooves equidistantly spaced apart about the circumference.
- the plurality of grooves may be provided in an even number such that the plurality of grooves includes a plurality of pairs of grooves, wherein the grooves in each pair are diametrically opposed to each other across the cross-section of the heat generation member.
- the increased surface area, increased plurality of edges, and the even spacing and distribution of the grooves may facilitate more even heating/burning of the heat generation member (i.e., due to the configuration of the cross-section being substantially regular, even, and symmetrical, more consistency may be obtained in the ignition of and heat generated across the cross-sectional profile).
- Still other example embodiments of extruded heat generation members are described in U.S. Pat. No. 9,788,571 to Conner et al., which is incorporated herein by reference in its entirety.
- the heat generation members may include foamed carbon monoliths formed in a foam process.
- the heat generation members may be co-extruded with a layer of insulation, thereby reducing manufacturing time and expense.
- Still other embodiments of heat generation members may include those of the types described in U.S. Pat. No. 4,922,901 to Brooks et al. or U.S. Pat. App. Pub. No. 2009/0044818 to Takeuchi et al., each of which is incorporated herein by reference in its entirety.
- the reservoir 110 is configured to retain a plurality of objects already-formed as heat generation members, and to feed the plurality of heat generation members directly to the dispensing mechanism 130 .
- the heat generation members may have a density that is greater than about 0.5 g/cm 3 , often greater than about 0.7 g/cm 3 , and frequently greater than about 1 g/cm 3 , on a dry weight basis. See, for example, the types of heat generation elements, components, formulations and designs set forth in U.S. Pat. No. 5,551,451 to Riggs et al. and U.S. Pat. No. 7,836,897 to Borschke et al., which are incorporated herein by reference in their entirety. Particular aspects of heat generation members are described below with reference to FIGS. 3A-3C .
- the heat generation members as extruded by the extruding mechanism 120 or otherwise retained by the reservoir 110 may be fed to the dispensing mechanism 130 .
- the dispensing mechanism 130 is configured to receive each of the heat generation members and serially dispense each of the heat generation members along a machine direction.
- the dispensing mechanism 130 is configured to orient each of the heat generation members such that each of the heat generation members travels with its longitudinal axis oriented parallel to the machine direction.
- the dispensing mechanism 130 may comprise a conveyor belt, a drum or wheel rotating about an axis perpendicular to the machine direction, a chute, and the like.
- the dispensing mechanism 130 is configured to serially dispense each of the heat generation members to the debossing mechanism 200 .
- the debossing mechanism 200 is configured to receive the longitudinally-extending heat generation member from the dispensing mechanism 130 and deboss the outer surface thereof.
- deboss is defined as the causing or forming of a depression on the outer surface of the heat generation member, such that the debossing mechanism is configured to form at least one depression in the outer surface of the heat generation member between the opposed first and second ends thereof.
- the example embodiment of the debossing mechanism generally illustrated in the system 100 is provided.
- the example embodiment of the debos sing mechanism generally referred to as 200 , comprises a first die 202 and an opposing second die 204 .
- the first die 202 and the opposing second die 204 may be comprised of stainless steel or other suitable material.
- the first and second dies 202 , 204 may comprise, for example, wheels, drums or the like having the outer circumferences thereof adjacently-disposed, and configured to rotate in opposite directions about an axis perpendicular to the machine direction.
- Each of the first die and the opposing second die may define a channel 206 extending about the outer circumference thereof (i.e., about the outer surface or circumference of the wheel, drum, or the like), and are thus considered “longitudinally-extending channels.”
- the longitudinally-extending channels 206 of the opposing first and second dies 202 , 204 may be arranged to receive therebetween the longitudinally-extending heat generation member from the dispensing mechanism 130 .
- the first die 202 may rotate counterclockwise about its axis, while the second die 204 rotates clockwise about its axis in order to facilitate transport of the longitudinally-extending heat generation members along the machine direction.
- the first die 202 may rotate clockwise about its axis, while the second die 204 rotates counterclockwise about its axis in order to facilitate transport of the longitudinally-extending heat generation members opposite to the machine direction.
- FIG. 2B illustrates a detailed view of the longitudinally-extending channel 206 about the outer circumference of the first die 202 and the longitudinally-extending channel 206 about the outer circumference of the second die 204 .
- the channels 206 of the opposing first and second dies 202 , 204 each comprise spaced-apart protrusions 208 .
- the spaced-apart protrusions 208 are configured to cooperatively interact with the heat generation member to deboss the outer surface thereof and define a plurality of spaced-apart depressions between the opposed first and second ends of the heat generation member, where each depression extends about a circumference of the outer surface of the heat generation member ( FIGS. 3A-3B ).
- the protrusions 208 are configured with a constant height and extend about the longitudinally-extending channels 206 in the cross-machine direction.
- the protrusions 208 may be provided as having a varying height and may extend in different manners about the longitudinally-extending channels 206 (i.e., generally not parallel to the machine direction) depending on the desired debossing of the heat generation member.
- each of the protrusions 208 in the channels 206 of the debossing mechanism 200 is configured to deboss either a first hemicylindrical portion or an opposing second hemicylindrical portion of the outer surface of the heat generation member. More particularly, where the longitudinally-extending heat generation member is a cylindrical member received by the debos sing mechanism 200 , a first hemicylindrical portion of the heat generation member will be disposed in and will interact with the longitudinally-extending channel 206 of the first die 202 , while an opposing second hemicylindrical portion of the heat generation member will be disposed in and will interact with the longitudinally-extending channel 206 of the second die 204 .
- the protrusions 208 in the channels 206 of the opposed first and second dies cooperatively interact with the heat generation member to form the plurality of spaced-apart depressions extending about either the first hemicylindrical portion or the opposing second hemicylindrical portion of the heat generation member.
- FIGS. 3A-3B illustrate two example heat generation members 300 A- 300 B that may be produced by the system 100 and may have a plurality of spaced-apart depressions extending about either the first hemicylindrical portion or the opposing second hemicylindrical portion thereof.
- each of the heat generation members 300 A- 300 B may be extruded by the extruding mechanism 120 , dispensed by the dispensing mechanism 130 , and then debossed by the debossing mechanism 200 (e.g., debossing mechanism 200 , FIGS. 2A, 2B ).
- each of the heat generation members 300 A- 300 B include a plurality of grooves 302 A- 302 B spaced apart about the outer circumference and extending longitudinally between opposed first and second ends of the heat generation member (from the extruding mechanism 120 , e.g.) as well as a plurality of depressions 304 A- 304 B longitudinally spaced-apart between the opposed first and second ends of the heat generation member (from the debos sing mechanism 200 , e.g.).
- the heat generation members as contemplated herein need not include both the plurality of spaced-apart grooves and the plurality of spaced-apart depressions.
- the heat generation members are only debossed such that only a plurality of spaced-apart depressions is defined in the outer surface.
- a surface area of the heat generation member is configured to be increased by at least the plurality of spaced-apart depressions, in addition to or instead of the plurality of spaced-apart grooves, exclusive of surface areas of the opposed first and second ends, over a surface area defined by an outer periphery of the heat generation member without the plurality of spaced-apart depressions or grooves (e.g., a cylinder).
- the heat generation member 300 A comprises a plurality of spaced-apart grooves 302 A spaced apart about the circumference thereof and extending longitudinally between opposed first and second ends of the heat generation member, as formed by the extruding mechanism 120 .
- the heat generation member 300 A also further comprises a plurality of longitudinally spaced-apart depressions 304 A that respectively extend about the first and second hemicylindrical portions and that are aligned with each other between the opposing hemicylindrical portions. In this manner, the longitudinally spaced-apart depressions 304 A extend continuously around the circumference of the outer surface of the heat generation member 300 A.
- the debossing mechanism 200 is configured to form the aligned, spaced-apart depressions by aligning the first die 202 and the opposing second die 204 such that the protrusions 208 in the channels 206 of the opposing dies 202 , 204 are aligned with one another. This may be accomplished by orienting or positioning the axes of each of the dies 202 , 204 so that opposing protrusions 208 are aligned in the machine direction.
- the heat generation member 300 B comprises a plurality of spaced-apart grooves 302 B about the outer surface thereof and extending longitudinally between opposed first and second ends of the heat generation member, as formed by the extruding mechanism 120 .
- the heat generation member 300 B also further comprises a plurality of longitudinally spaced-apart depressions 304 B that extend about the first hemicylindrical portion thereof and are offset in the machine direction with regard to a plurality of longitudinally spaced-apart depressions that extend about the second hemicylindrical portion thereof.
- the debossing mechanism 200 is configured to form the offset, longitudinally spaced-apart depressions by aligning the first die 202 and the opposing second die 204 such that the protrusions 208 in the channel 206 of the first die 202 are offset in the machine direction with regard to the protrusions in the channel 206 of the second die 204 . This may be accomplished by orienting or positioning the axes of each of the dies 202 , 204 so that opposing protrusions 208 are offset in the machine direction.
- the debossing mechanism 200 is configured to deboss the outer surface of the heat generation members, wherein the debossed heat generation members may then be transported to an assembly mechanism 140 .
- the assembly mechanism 140 may be an apparatus or combination of several apparatuses configured to assemble the heat generation member with other components (e.g., filters, wrapping materials, substrates, etc.) in order to form an assembled smoking article. See, for example, the various representative types of smoking article components, as well as the various smoking article designs, formats, configurations and characteristics, that are set forth in Johnson, Development of Cigarette Components to Meet Industry Needs, 52 nd T.S.R.C. (September, 1998); U.S. Pat. No.
- Example assembly mechanism(s) for assembling each of the components into a representative smoking article are disclosed in U.S. Pat. Appl. Pub. No. 2012/0120229 to Brantley et al., which is incorporated herein by reference in its entirety.
- FIG. 4 illustrates a representative smoking article 400 assembled by the assembly mechanism 140 in system 100 .
- the smoking article 400 is generally in the form of a cigarette.
- the smoking article 400 has a rod-like or cylindrical shape, and includes a lighting end 402 and a mouth end 404 .
- a longitudinally-extending, generally cylindrical, heat generation portion 406 At the lighting end 402 is positioned a longitudinally-extending, generally cylindrical, heat generation portion 406 .
- the heat generation portion 406 includes a longitudinally-extending heat generation member 408 , which may be circumscribed by insulation 410 and which may be coaxially encircled by wrapping material.
- the heat generation member 408 preferably is configured to be activated by ignition (direct ignition or indirect ignition) of the lighting end 402 .
- the smoking article 400 also includes a filter portion 412 located at the other end (mouth end 404 ), and an aerosol-generating portion 414 (which may incorporate tobacco) that is located in between the heat generation and filter portions 406 , 412 .
- the heat generation member 408 may define a plurality of spaced-apart depressions between opposed first and second ends thereof, each depression extending about a circumference of the outer surface thereof.
- each of the plurality of spaced-apart depressions extends about a first hemicylindrical portion or an opposing second hemicylindrical portion of the outer surface of the heat generation member 408 .
- each of the plurality of spaced-apart depressions may extend about a first longitudinally-extending half portion and an opposing longitudinally-extending second half portion of the heat generation member.
- the heat generation member 408 is configured such that the plurality of spaced-apart depressions extending about the first and second hemicylindrical portions are aligned with each other such that each of the longitudinally spaced-apart depressions extends continuously around the outer surface of the heat generation member.
- the heat generation member 408 is configured such that the plurality of longitudinally spaced-apart depressions extending about the first hemicylindrical portion are longitudinally offset along the heat generation member 408 with regard to the plurality of longitudinally spaced-apart depressions extending about the second hemicylindrical portion.
- the heat generation member 408 comprises a plurality of grooves spaced apart about the outer surface thereof and extending longitudinally between the opposed first and second ends thereof. In these instances, each of the plurality of depressions and/or the plurality of grooves may have a constant depth.
- a representative layer of insulation 410 can comprise glass filaments or fibers.
- the insulation 410 can act as a jacket that assists in supporting, maintaining, and/or retaining the heat generation member 408 firmly in place within the smoking article 400 .
- the insulation 410 can be provided as a multi-layer component including an inner layer or mat of non-woven glass filaments, an intermediate layer of reconstituted tobacco paper, and an outer layer of non-woven glass filaments. These may be concentrically oriented or each overwrapping and/or circumscribing the heat generation member 408 .
- the insulation may additionally be configured such that drawn air and aerosol can pass readily therethrough.
- Flame/burn retardant materials and additives useful in insulation may include silica, carbon, ceramic, metallic fibers and/or particles.
- cellulosic or other fibers such as, for example, cotton, boric acid or various organophosphate compounds may provide desirable flame-retardant properties.
- various organic or metallic nanoparticles may confer a desired property of flame-retardancy, as may diammonium phosphate and/or other salts.
- Other useful materials may include organo-phosphorus compounds, borax, hydrated alumina, graphite, potassium tripolyphosphate, dipentaerythritol, pentaerythritol, and polyols.
- An insulation fabric preferably will have sufficient oxygen diffusion capability to sustain a smoking article such as a cigarette in a lit condition during a desired usage time. Accordingly the insulation fabric preferably will be porous by virtue of its construction. In knit, woven, or combined woven and knit constructions, the required porosity may be controlled by configuring the assembly machinery to leave sufficient (desirably sized) gaps between fibers to allow for oxygen diffusion into the heat source. For non-woven fabrics, which may not be porous enough to promote evenly sustained combustion, additional porosity may be achieved by perforations into the insulation by methods known in the art including, for example, hot or cold pin perforation, flame perforation, embossing, laser cutting, drilling, blade cutting, chemical perforation, punching, and other methods.
- the insulation may include non-glass material that is woven, knit, or a combination thereof, a foamed metal material, a foamed ceramic material, a foamed ceramic-metal composite, and any combination thereof.
- an inner layer of insulation may include a variety of glass or non-glass filaments or fibers that are woven, knit, or both woven and knit (such as, for example, so-called 3-D woven/knit hybrid mats).
- an inner layer may be formed as a woven mat or tube.
- a woven or knitted mat or tube can provide improved control of air flow with regard to evenness across the insulation layer (including as any thermal-related changes may occur to the layer).
- a woven, knit, or hybrid material may provide more regular and consistent air spaces/gaps between the filaments or fibers as compared to a non-woven material which is more likely to have irregularly closed and open spaces that may provide comparatively non-uniform and/or decreased air-flow.
- Various other insulation embodiments may be molded, extruded, foamed, or otherwise formed. Particular embodiments of insulation structures may include those described in U.S. Pat. Appl. Pub. No. 2012/0042885 to Stone et al., which is incorporated by reference herein in its entirety.
- both ends of the heat generation portion 406 are open to expose at least the heat generation member 408 and insulation 410 at the lighting end 402 .
- the heat generation member 408 and the surrounding insulation 410 can be configured so that the length of both materials is co-extensive (i.e., the ends of the insulation 410 are flush with the respective ends of the heat generation member 408 , and particularly at the downstream end of the heat generation portion 406 ).
- the insulation 410 may extend slightly beyond (e.g., from about 0.5 mm to about 2 mm beyond) either or both ends of the heat generation member 408 .
- heat and/or heated air produced when the lighting end 402 is ignited during use of the smoking article 400 can readily pass through the heat generation portion 406 during draw by the smoker on the mouth end 404 .
- the heat generation portion 406 preferably is positioned with one end disposed at the lighting end 402 , and is axially aligned in an end-to-end relationship with a downstream aerosol-generating portion 414 , preferably abutting one another, but with no barrier (other than open air-space) therebetween.
- the close proximity of the heat generation portion 406 to the lighting end 402 provides for direct ignition of the heat generation member 408 of the heat generation portion 406 .
- a longitudinally-extending, cylindrical aerosol-generating portion 414 is located downstream from the heat generation portion 406 .
- the aerosol-generating portion 414 includes a substrate material 416 that, in turn, acts as a carrier for tobacco-related material (not shown).
- the aerosol-generating portion 414 can include a reconstituted tobacco material that includes processing aids, flavoring agents, and glycerin.
- the foregoing components of the aerosol-generating portion 414 can be disposed within, and circumscribed by, a wrapping material.
- the wrapping material can be configured to facilitate the transfer of heat from the lighting end 402 of the smoking article 400 (e.g., from the heat generation portion 406 ) to components of the aerosol-generating portion 414 .
- the aerosol-generating portion 414 and the heat generation portion 406 can be configured in a heat exchange relationship with one another.
- the heat exchange relationship is such that sufficient heat from the heat generation member 408 is supplied to the aerosol-formation region to volatilize aerosol-forming material for aerosol formation.
- the heat exchange relationship is achieved by positioning those portions in close proximity to one another.
- a heat exchange relationship also can be achieved by extending a heat conductive material from the vicinity of the heat generation member 408 into or around the region occupied by the aerosol-generating portion 414 .
- Particular embodiments of substrates may include those described below or those described in U.S. Pat. App. Pub. No. 2012/0042885 to Stone et al., which is incorporated by reference herein in its entirety.
- both ends of the aerosol-generating portion 414 are open to expose the substrate material thereof. Together, the heat generating portion 406 and the aerosol-generating portion 414 form an aerosol-generation system. Those portions can abut one another, or be positioned in a slightly spaced apart relationship, which may include a buffer region 418 . The outer cross-sectional shapes and dimensions of those portions, when viewed transversely to the longitudinal axis of the smoking article 400 , can be essentially identical to one another.
- the components of the aerosol-generation system preferably are attached to one another, and secured in place using an overwrap material 420 .
- the overwrap material 420 can include a paper wrapping material or a laminated paper-type material that circumscribes each of at least a portion of the outer longitudinally-extending surface of the heat generation portion 406 and the aerosol-generating portion 414 .
- the inner surface of the overwrap material 420 may be secured to the outer surfaces of the components it circumscribes by a suitable adhesive.
- the smoking article 400 preferably includes a suitable mouthpiece such as, for example, a filter portion 412 .
- the filter portion 412 preferably is positioned at the mouth end 404 of the cigarette rod adjacent to one end of the aerosol-generating portion 414 , such that the filter portion 412 and the aerosol-generating portion 414 are axially aligned in an end-to-end relationship, abutting one another but without any barrier therebetween.
- the general cross-sectional shapes and dimensions of those portions 412 , 414 are essentially identical to one another when viewed transversely to the longitudinal axis of the smoking article.
- the filter portion 412 may include filter material 422 that is overwrapped along the longitudinally-extending surface thereof with circumscribing plug wrap material.
- the filter material 422 includes plasticized cellulose acetate tow, while in some examples the filter material may further include activated charcoal in an amount from about 20 mg to about 80 mg disposed as a discrete charge or dispersed throughout the acetate tow in a “Dalmatian type” filter. Both ends of the filter portion 412 preferably are open to permit the passage of aerosol therethrough.
- the aerosol-generating system preferably is attached to the filter portion 412 using tipping material 424 .
- the filter portion 412 may also include a crushable flavor capsule of the type described in U.S. Pat. No. 7,479,098 to Thomas et al. and U.S. Pat. No. 7,793,665 to Dube et al.; and U.S. Pat.
- the filter portion 412 may additionally or alternatively contain strands of tobacco containing material, such as described in U.S. Pat. No. 5,025,814, which is incorporated herein by reference in its entirety.
- the smoking article 400 may include an air dilution provision, such as a series of perforations 426 , each of which may extend through the filter element tipping material 424 and plug wrap material in the manner shown, and/or which may extend to or into the substrate.
- an air dilution provision such as a series of perforations 426 , each of which may extend through the filter element tipping material 424 and plug wrap material in the manner shown, and/or which may extend to or into the substrate.
- the smoker lights the lighting end 402 of the smoking article 400 using a match or cigarette lighter, in a manner similar to the way that conventional smoking articles are lit, such that the heat generation member 408 at the lighting end 402 is ignited.
- the mouth end 404 of the smoking article 400 is placed in the lips of the smoker.
- Thermal decomposition products e.g., components of tobacco smoke
- the smoking article yields visible mainstream aerosol that resembles the mainstream tobacco smoke of traditional cigarettes that burn tobacco cut filler.
- Direct ignition actuates the heat generation member 408 of the heat generation portion 406 such that it preferably will be ignited or otherwise activated (e.g., begin to burn or smolder).
- the heat generation member 408 within the aerosol-generation system once ignited, will provide heat to volatilize aerosol-forming material within the aerosol-generating portion 414 as a result of the heat exchange relationship between those two segments.
- Certain heat generation members will not experience volumetric decrease during activation, while others may degrade in a manner that reduces their volume.
- the components of the aerosol-generating portion 414 do not experience thermal decomposition (e.g., charring or burning) to any significant degree. Volatilized components are entrained in the air that is drawn through the aerosol-generating region. The aerosol so formed will be drawn through the filter portion 412 , and into the mouth of the smoker.
- FIG. 5 illustrates a method for debossing a heat generation member of an elongate smoking article, generally referred to as 500 .
- a longitudinally-extending heat generation member is serially dispensed along a machine direction, the heat generation member having an outer surface and defining a longitudinal axis.
- the heat generation member is debossed by being received between longitudinally-extending channels of opposing first and second dies of a debossing mechanism, wherein the channels of the opposing first and second dies each comprise spaced-apart protrusions along the channels, and wherein the protrusions in the channels are configured to extend non-parallel to the channels and to cooperatively interact with the heat generation member to deboss the outer surface thereof.
- serially dispensing a longitudinally-extending heat generation member comprises extruding the heat generation member as a monolithic element of a carbonaceous material.
- extruding the single carbonaceous material comprises forming a plurality of spaced-apart grooves in and about a circumference of the monolithic element, the grooves extending longitudinally between opposed first and second ends of the heat generation member.
- debossing the heat generation member by receiving the heat generation member such that the protrusions in the channels of the debossing mechanism cooperatively interact with the heat generation member to deboss the outer surface thereof comprises defining a plurality of longitudinally spaced-apart, circumferentially-extending depressions between the opposed first and second ends of the heat generation member, each depression extending about a circumference of the outer surface of the heat generation member.
- the method 500 further comprises aligning the first die and the opposing second die such that the protrusions in the channels of the dies are aligned with one another, the dies cooperatively interacting with the heat generation member to form the plurality of spaced-apart depressions, wherein the plurality of spaced-apart depressions extending about first and second hemicylindrical portions of the heat generation member are aligned with each other such that the spaced-apart depressions extend continuously around the outer surface of the heat generation member.
- the method further comprises aligning the first die and the opposing second die such that the protrusions in the channel of the first die are offset in the machine direction with regard to the protrusions in the channel of the second die, the dies cooperatively interacting with the heat generation member to form the plurality of spaced-apart depressions, wherein the plurality of longitudinally spaced-apart depressions extending about a first hemicylindrical portion of the heat generation member are offset in the machine direction with regard to the plurality of longitudinally spaced-apart depressions extending about a second opposing hemicylindrical portion of the heat generation member.
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Abstract
Description
- The present disclosure relates to products made or derived from tobacco, or that otherwise incorporate tobacco, and are intended for human consumption and, more particularly, to components and configurations of segmented-type smoking articles.
- Popular smoking articles, such as cigarettes, have a substantially cylindrical rod-shaped structure and include a charge, roll or column of smokable material, such as shredded tobacco (e.g., in cut filler form), surrounded by a paper wrapper, thereby forming a so-called “smokable rod”, “tobacco rod” or “cigarette rod.” In some aspects, these popular types of cigarettes employ carbonaceous fuel elements have been commercially marketed under the brand names “Premier” and “Eclipse” by R. J. Reynolds Tobacco Company. See, for example, those types of cigarettes described in Chemical and Biological Studies on New Cigarette Prototypes that Heat Instead of Burn Tobacco, R. J. Reynolds Tobacco Company Monograph (1988) and Inhalation Toxicology, 12:5, p. 1-58 (2000). Additionally, a similar type of cigarette recently has been marketed in Japan by Japan Tobacco Inc. under the brand name “Steam Hot One.” Furthermore, various types of smoking products incorporating carbonaceous fuel elements for heat generation and aerosol formation recently have been set forth in the patent literature. See, for example, the types of smoking products proposed in U.S. Pat. No. 7,836,897 to Borschke et al.; U.S. Pat. No. 8,469,035 to Banerjee et al., U.S. Pat. No. 8,616,217 to Tsuruizumi et al; U.S. Pat. No. 8,915,255 to Poget et al; and U.S. Pat. No. 8,464,726 to Sebastian et al.; US Pat. Pub. Nos. 2012/0042885 to Stone et al.; and 2013/0133675 to Shinozaki et al.; PCT WO No. 2012/0164077 to Gladden et al.; 2013/098380 to Raether et al.; 2013/098405 to Zuber et al.; 2013/098410 to Zuber et al.; 2013/104914 to Woodcock; 2013/120849 to Roudier et al.; 2013/120854 to Mironov; EP 1808087 to Baba et al. and EP 2550879 to Tsuruizumi et al.; which are incorporated by reference herein in their entirety. A historical perspective of technology related to various types of smoking products incorporating carbonaceous fuel elements for heat generation and aerosol formation may be found, for example, in the Background of US Pat. Pub. No. 2007/0215167 to Llewellyn Crooks et al., which is also incorporated herein by reference.
- It would be highly desirable to provide smoking articles that demonstrate the ability to provide to a smoker many of the benefits and advantages of conventional cigarette smoking, without delivering considerable quantities of incomplete combustion and pyrolysis products. In conjunction with such desirable characteristics, it would also be desirable for a direct ignition smoking article to be readily ignited, and to remain ignited, while being used by the smoker.
- The above and other needs are met by aspects of the present disclosure which, in one aspect, provides a system for debossing a heat generation member of an elongate smoking article comprising a dispensing mechanism configured to serially dispense a longitudinally-extending heat generation member along a machine direction, the heat generation member having an outer surface and defining a longitudinal axis; and a debos sing mechanism comprising a first die and an opposing second die each defining a longitudinally-extending channel, the channels of the opposing first and second dies each comprising spaced-apart protrusions and being arranged to receive therebetween the longitudinally-extending heat generation member from the dispensing mechanism, the protrusions in the channels being configured to extend non-parallel to the channels and cooperatively interact with the heat generation member to deboss the outer surface thereof.
- Another aspect of the present disclosure provides a smoking article comprising a mouth end portion disposed at a mouth end; a tobacco portion disposed between a lighting end and the mouth end portion; and an aerosol-generation system including an aerosol-generation portion disposed between the lighting end and the tobacco portion, the aerosol-generation system including a heat generation portion disposed at the lighting end, the heat generation portion comprising a longitudinally-extending heat generation member configured to be actuated by ignition of the lighting end, the heat generation member defining a plurality of spaced-apart depressions between opposed first and second ends thereof, each depression extending about a circumference of the outer surface thereof.
- A further aspect of the present disclosure provides a method for debossing a heat generation member of an elongate smoking article comprising: serially dispensing a longitudinally-extending heat generation member along a machine direction, the heat generation member having an outer surface and defining a longitudinal axis; and debossing the heat generation member by directing the heat generation member between longitudinally-extending channels of a first die and an opposing longitudinally-extending channel of a second die of a debossing mechanism, the channels of the opposing first and second dies each comprising spaced-apart protrusions, the protrusions in the channels being configured to extend non-parallel to the channels and cooperatively interacting with the heat generation member to deboss the outer surface thereof.
- Further features and advantages of the present disclosure are set forth in more detail in the following description.
- Having thus described the disclosure in general terms, reference will now be made to the accompanying drawings, which are not necessarily drawn to scale, and wherein:
FIG. 1 shows a representative system diagram of a system for debossing a heat generation member of an elongate smoking article; -
FIGS. 2A-2B show detailed views of a representative debossing mechanism for the system ofFIG. 1 ; -
FIGS. 3A-3B show two different representative heat generation members debossed by a debossing mechanism; -
FIG. 4 shows a representative smoking article with a debossed heat generation member; and -
FIG. 5 shows a method flow of a method for debossing a heat generation member of an elongate smoking article. - The present disclosure now will be described more fully hereinafter with reference to the accompanying drawings, in which some, but not all aspects of the disclosure are shown. Indeed, the disclosure may be embodied in many different forms and should not be construed as limited to the aspects set forth herein; rather, these aspects are provided so that this disclosure will satisfy applicable legal requirements. Like numbers refer to like elements throughout.
- Aspects and embodiments of the present disclosure relate, for example, to various smoking articles, and the arrangement of various components thereof. Example smoking article construction may include features disclosed in U.S. Pat. Nos. 8,464,726 and 9,486,013; both to Sebastian et al., which are incorporated herein by reference.
-
FIG. 1 illustrates arepresentative system 100 for producing a representative smoking article. In some aspects, thesystem 100 includes areservoir 110, anextruding mechanism 120, adispensing mechanism 130, and anassembly mechanism 140. In some example aspects, thesystem 100 is further configured to deboss the representative smoking article and includes adebossing mechanism 200, described in detail inFIG. 2 . - In some example embodiments, the
reservoir 110 is configured to retain a quantity of a substance and feed the quantity of the substance to theextruding mechanism 120. Thereservoir 110 is configured to feed the quantity of the substance in any number of ways depending on the characteristic of the substance retained therein. For example, where thereservoir 110 retains a substance for forming heat generation members therein, thereservoir 110 may gravitationally feed the substance for forming heat generation members to theextruding mechanism 120. A controller (not shown) may be in communication with thereservoir 110 to control the timing of the substance fed to theextruding mechanism 120. - The
extruding mechanism 120 may be configured to receive the quantity of the substance from thereservoir 110 and may be configured to force (e.g., extrude) the substance through a die to thereby shape an outer circumference of an elongate member formed from the extruded quantity of the substance. The elongate member is then severed into a desired length to form individual monolithic elements. Each of the individual monolithic elements may be considered “heat generation members,” though depending on the shape extruded from theextruding mechanism 120 other functionalities may be utilized, as well. Shapes such as, for example, rods and cubes can be formed by first extruding the material through a die having the desired cross-section (e.g., round or square) and then optionally severing the extruded material into desired lengths. Techniques and equipment for extruding tobacco-related materials are set forth in U.S. Pat. No. 3,098,492 to Wursburg; U.S. Pat. No. 4,874,000 to Tamol et al.; U.S. Pat. No. 4,880,018 to Graves et al.; U.S. Pat. No. 4,989,620 to Keritsis et al.; U.S. Pat. No. 5,072,744 to Luke et al.; U.S. Pat. No. 5,829,453 to White et al.; and U.S. Pat. No. 6,182,670 to White et al.; each of which is incorporated herein by reference in its entirety. Example extrusion equipment suitable for use includes food or gum extruders, or industrial pasta extruders such as Model TP 200/300 available from Emiliomiti, LLC of Italy. In some instances, a single machine may be capable of achieving multiple steps of the processes described herein, such as, for example, kneader systems available from Buss AG. - Representative heat generation members may comprise a generally cylindrical shape defining a longitudinal axis and having an outer surface. In some example aspects, the representative heat generation members may incorporate components including, for example, a combustible carbonaceous material. Carbonaceous materials generally include a carbon component having a high carbon content. Preferred carbonaceous materials are comprised predominately of carbon, typically have carbon contents of greater than about 60 percent, generally greater than about 70 percent, often greater than about 80 percent, and frequently greater than about 90 percent, on a dry weight basis. The carbonaceous materials may also include other non-carbon components including, for example, tobacco components, such as powdered tobaccos or tobacco extracts; flavoring agents; salts, such as sodium chloride, potassium chloride and sodium carbonate; heat stable graphite fibers; iron oxide powder; glass filaments; powdered calcium carbonate; alumina granules; ammonia sources, such as ammonia salts; and/or binding agents, such as guar gum, ammonium alginate and sodium alginate. A representative heat generation member may have a length of about 12 mm and an overall outside diameter of about 4.2 mm.
- As such, in one example, each of the heat generation members is severed into a desired length from the material extruded from the
extruding mechanism 120 through a die as a monolithic element of a carbonaceous material. Further, the die of theextruding mechanism 120 may be configured to extrude the elongate member such that a plurality of longitudinally-extending grooves is formed in the outer surface of the elongate member, wherein the grooves are spaced-apart about the circumference or outer surface thereof. When the individual heat generation members are severed from the continuously extruded material (monolithic extrudate), such that each heat generation member is its own monolithic element, the grooves also extend longitudinally between opposed first and second ends of each heat generation member, such that each of the heat generation members has a “fluted” cross-section. In this manner, each of the heat generation members defines between six and ten grooves equidistantly spaced apart about the circumference. In one preferred aspect, the heat generation member defines eight grooves equidistantly spaced apart about the circumference. In such aspects, the plurality of grooves may be provided in an even number such that the plurality of grooves includes a plurality of pairs of grooves, wherein the grooves in each pair are diametrically opposed to each other across the cross-section of the heat generation member. In this manner, the increased surface area, increased plurality of edges, and the even spacing and distribution of the grooves may facilitate more even heating/burning of the heat generation member (i.e., due to the configuration of the cross-section being substantially regular, even, and symmetrical, more consistency may be obtained in the ignition of and heat generated across the cross-sectional profile). Still other example embodiments of extruded heat generation members are described in U.S. Pat. No. 9,788,571 to Conner et al., which is incorporated herein by reference in its entirety. - In some other aspects, the heat generation members may include foamed carbon monoliths formed in a foam process. In still further embodiments, the heat generation members may be co-extruded with a layer of insulation, thereby reducing manufacturing time and expense. Still other embodiments of heat generation members may include those of the types described in U.S. Pat. No. 4,922,901 to Brooks et al. or U.S. Pat. App. Pub. No. 2009/0044818 to Takeuchi et al., each of which is incorporated herein by reference in its entirety. Where the heat generation members are not extruded and/or the
extruding mechanism 120 is not used to form the heat generation members in thesystem 100, thereservoir 110 is configured to retain a plurality of objects already-formed as heat generation members, and to feed the plurality of heat generation members directly to thedispensing mechanism 130. The heat generation members may have a density that is greater than about 0.5 g/cm3, often greater than about 0.7 g/cm3, and frequently greater than about 1 g/cm3, on a dry weight basis. See, for example, the types of heat generation elements, components, formulations and designs set forth in U.S. Pat. No. 5,551,451 to Riggs et al. and U.S. Pat. No. 7,836,897 to Borschke et al., which are incorporated herein by reference in their entirety. Particular aspects of heat generation members are described below with reference toFIGS. 3A-3C . - The heat generation members as extruded by the
extruding mechanism 120 or otherwise retained by thereservoir 110, may be fed to thedispensing mechanism 130. In some embodiments, thedispensing mechanism 130 is configured to receive each of the heat generation members and serially dispense each of the heat generation members along a machine direction. In some preferred embodiments, thedispensing mechanism 130 is configured to orient each of the heat generation members such that each of the heat generation members travels with its longitudinal axis oriented parallel to the machine direction. In this manner, thedispensing mechanism 130 may comprise a conveyor belt, a drum or wheel rotating about an axis perpendicular to the machine direction, a chute, and the like. - The
dispensing mechanism 130 is configured to serially dispense each of the heat generation members to thedebossing mechanism 200. In some embodiments, and as illustrated in greater detail inFIGS. 2A, 2B , thedebossing mechanism 200 is configured to receive the longitudinally-extending heat generation member from thedispensing mechanism 130 and deboss the outer surface thereof. As used herein, “deboss” is defined as the causing or forming of a depression on the outer surface of the heat generation member, such that the debossing mechanism is configured to form at least one depression in the outer surface of the heat generation member between the opposed first and second ends thereof. - More particularly and referring to
FIGS. 2A, 2B , one example embodiment of the debossing mechanism generally illustrated in thesystem 100 is provided. As illustrated inFIG. 2A , the example embodiment of the debos sing mechanism, generally referred to as 200, comprises afirst die 202 and an opposingsecond die 204. Thefirst die 202 and the opposing second die 204 may be comprised of stainless steel or other suitable material. The first and second dies 202, 204 may comprise, for example, wheels, drums or the like having the outer circumferences thereof adjacently-disposed, and configured to rotate in opposite directions about an axis perpendicular to the machine direction. Each of the first die and the opposing second die may define achannel 206 extending about the outer circumference thereof (i.e., about the outer surface or circumference of the wheel, drum, or the like), and are thus considered “longitudinally-extending channels.” The longitudinally-extendingchannels 206 of the opposing first and second dies 202, 204 may be arranged to receive therebetween the longitudinally-extending heat generation member from thedispensing mechanism 130. Thefirst die 202 may rotate counterclockwise about its axis, while thesecond die 204 rotates clockwise about its axis in order to facilitate transport of the longitudinally-extending heat generation members along the machine direction. Alternatively, thefirst die 202 may rotate clockwise about its axis, while thesecond die 204 rotates counterclockwise about its axis in order to facilitate transport of the longitudinally-extending heat generation members opposite to the machine direction. -
FIG. 2B illustrates a detailed view of the longitudinally-extendingchannel 206 about the outer circumference of thefirst die 202 and the longitudinally-extendingchannel 206 about the outer circumference of thesecond die 204. As illustrated inFIG. 2B , and in some aspects, thechannels 206 of the opposing first and second dies 202, 204 each comprise spaced-apartprotrusions 208. The spaced-apartprotrusions 208 are configured to cooperatively interact with the heat generation member to deboss the outer surface thereof and define a plurality of spaced-apart depressions between the opposed first and second ends of the heat generation member, where each depression extends about a circumference of the outer surface of the heat generation member (FIGS. 3A-3B ). In some aspects, theprotrusions 208 are configured with a constant height and extend about the longitudinally-extendingchannels 206 in the cross-machine direction. However, in other aspects (not shown), theprotrusions 208 may be provided as having a varying height and may extend in different manners about the longitudinally-extending channels 206 (i.e., generally not parallel to the machine direction) depending on the desired debossing of the heat generation member. - In some aspects, each of the
protrusions 208 in thechannels 206 of thedebossing mechanism 200 is configured to deboss either a first hemicylindrical portion or an opposing second hemicylindrical portion of the outer surface of the heat generation member. More particularly, where the longitudinally-extending heat generation member is a cylindrical member received by thedebos sing mechanism 200, a first hemicylindrical portion of the heat generation member will be disposed in and will interact with the longitudinally-extendingchannel 206 of thefirst die 202, while an opposing second hemicylindrical portion of the heat generation member will be disposed in and will interact with the longitudinally-extendingchannel 206 of thesecond die 204. As such, theprotrusions 208 in thechannels 206 of the opposed first and second dies cooperatively interact with the heat generation member to form the plurality of spaced-apart depressions extending about either the first hemicylindrical portion or the opposing second hemicylindrical portion of the heat generation member. -
FIGS. 3A-3B illustrate two exampleheat generation members 300A-300B that may be produced by thesystem 100 and may have a plurality of spaced-apart depressions extending about either the first hemicylindrical portion or the opposing second hemicylindrical portion thereof. Specifically, each of theheat generation members 300A-300B may be extruded by theextruding mechanism 120, dispensed by thedispensing mechanism 130, and then debossed by the debossing mechanism 200 (e.g.,debossing mechanism 200,FIGS. 2A, 2B ). As such, each of theheat generation members 300A-300B include a plurality ofgrooves 302A-302B spaced apart about the outer circumference and extending longitudinally between opposed first and second ends of the heat generation member (from theextruding mechanism 120, e.g.) as well as a plurality ofdepressions 304A-304B longitudinally spaced-apart between the opposed first and second ends of the heat generation member (from the debos singmechanism 200, e.g.). However, the heat generation members as contemplated herein need not include both the plurality of spaced-apart grooves and the plurality of spaced-apart depressions. For example, in some aspects, the heat generation members are only debossed such that only a plurality of spaced-apart depressions is defined in the outer surface. Accordingly, a surface area of the heat generation member is configured to be increased by at least the plurality of spaced-apart depressions, in addition to or instead of the plurality of spaced-apart grooves, exclusive of surface areas of the opposed first and second ends, over a surface area defined by an outer periphery of the heat generation member without the plurality of spaced-apart depressions or grooves (e.g., a cylinder). - In
FIG. 3A , theheat generation member 300A comprises a plurality of spaced-apart grooves 302A spaced apart about the circumference thereof and extending longitudinally between opposed first and second ends of the heat generation member, as formed by theextruding mechanism 120. Theheat generation member 300A also further comprises a plurality of longitudinally spaced-apartdepressions 304A that respectively extend about the first and second hemicylindrical portions and that are aligned with each other between the opposing hemicylindrical portions. In this manner, the longitudinally spaced-apartdepressions 304A extend continuously around the circumference of the outer surface of theheat generation member 300A. In some aspects, thedebossing mechanism 200 is configured to form the aligned, spaced-apart depressions by aligning thefirst die 202 and the opposing second die 204 such that theprotrusions 208 in thechannels 206 of the opposing dies 202, 204 are aligned with one another. This may be accomplished by orienting or positioning the axes of each of the dies 202, 204 so that opposingprotrusions 208 are aligned in the machine direction. - In
FIG. 3B , theheat generation member 300B comprises a plurality of spaced-apartgrooves 302B about the outer surface thereof and extending longitudinally between opposed first and second ends of the heat generation member, as formed by theextruding mechanism 120. Theheat generation member 300B also further comprises a plurality of longitudinally spaced-apartdepressions 304B that extend about the first hemicylindrical portion thereof and are offset in the machine direction with regard to a plurality of longitudinally spaced-apart depressions that extend about the second hemicylindrical portion thereof. In some aspects, thedebossing mechanism 200 is configured to form the offset, longitudinally spaced-apart depressions by aligning thefirst die 202 and the opposing second die 204 such that theprotrusions 208 in thechannel 206 of thefirst die 202 are offset in the machine direction with regard to the protrusions in thechannel 206 of thesecond die 204. This may be accomplished by orienting or positioning the axes of each of the dies 202, 204 so that opposingprotrusions 208 are offset in the machine direction. - Returning back to
FIG. 1 , thedebossing mechanism 200 is configured to deboss the outer surface of the heat generation members, wherein the debossed heat generation members may then be transported to anassembly mechanism 140. Theassembly mechanism 140 may be an apparatus or combination of several apparatuses configured to assemble the heat generation member with other components (e.g., filters, wrapping materials, substrates, etc.) in order to form an assembled smoking article. See, for example, the various representative types of smoking article components, as well as the various smoking article designs, formats, configurations and characteristics, that are set forth in Johnson, Development of Cigarette Components to Meet Industry Needs, 52nd T.S.R.C. (September, 1998); U.S. Pat. No. 5,101,839 to Jakob et al.; U.S. Pat. No. 5,159,944 to Arzonico et al.; U.S. Pat. No. 5,220,930 to Gentry; U.S. Pat. No. 6,779,530 to Kraker; U.S. Pat. No. 7,237,559 to Ashcraft et al., and U.S. Pat. No. 7,565,818 to Thomas et al.; and U.S. Pat. Appl. Pub. Nos. 2007/0246055 to Oglesby and 2005/0066986 to Nestor et al.; each of which is incorporated herein by reference in its entirety. Example assembly mechanism(s) for assembling each of the components into a representative smoking article, such as that disclosed herein, are disclosed in U.S. Pat. Appl. Pub. No. 2012/0120229 to Brantley et al., which is incorporated herein by reference in its entirety. -
FIG. 4 illustrates arepresentative smoking article 400 assembled by theassembly mechanism 140 insystem 100. In some aspects, thesmoking article 400 is generally in the form of a cigarette. Thesmoking article 400 has a rod-like or cylindrical shape, and includes alighting end 402 and amouth end 404. At thelighting end 402 is positioned a longitudinally-extending, generally cylindrical,heat generation portion 406. Theheat generation portion 406 includes a longitudinally-extendingheat generation member 408, which may be circumscribed byinsulation 410 and which may be coaxially encircled by wrapping material. Theheat generation member 408 preferably is configured to be activated by ignition (direct ignition or indirect ignition) of thelighting end 402. Thesmoking article 400 also includes afilter portion 412 located at the other end (mouth end 404), and an aerosol-generating portion 414 (which may incorporate tobacco) that is located in between the heat generation and filter 406, 412.portions - The
heat generation member 408 may define a plurality of spaced-apart depressions between opposed first and second ends thereof, each depression extending about a circumference of the outer surface thereof. In some aspects, each of the plurality of spaced-apart depressions extends about a first hemicylindrical portion or an opposing second hemicylindrical portion of the outer surface of theheat generation member 408. Where other shapes of theheat generation member 408 are contemplated, each of the plurality of spaced-apart depressions may extend about a first longitudinally-extending half portion and an opposing longitudinally-extending second half portion of the heat generation member. - More particularly, in some aspects (e.g., 300A,
FIG. 3A ), theheat generation member 408 is configured such that the plurality of spaced-apart depressions extending about the first and second hemicylindrical portions are aligned with each other such that each of the longitudinally spaced-apart depressions extends continuously around the outer surface of the heat generation member. In other aspects (e.g., 300B,FIG. 3B ), theheat generation member 408 is configured such that the plurality of longitudinally spaced-apart depressions extending about the first hemicylindrical portion are longitudinally offset along theheat generation member 408 with regard to the plurality of longitudinally spaced-apart depressions extending about the second hemicylindrical portion. In some additional aspects, theheat generation member 408 comprises a plurality of grooves spaced apart about the outer surface thereof and extending longitudinally between the opposed first and second ends thereof. In these instances, each of the plurality of depressions and/or the plurality of grooves may have a constant depth. - A representative layer of
insulation 410 can comprise glass filaments or fibers. Theinsulation 410 can act as a jacket that assists in supporting, maintaining, and/or retaining theheat generation member 408 firmly in place within thesmoking article 400. Theinsulation 410 can be provided as a multi-layer component including an inner layer or mat of non-woven glass filaments, an intermediate layer of reconstituted tobacco paper, and an outer layer of non-woven glass filaments. These may be concentrically oriented or each overwrapping and/or circumscribing theheat generation member 408. The insulation may additionally be configured such that drawn air and aerosol can pass readily therethrough. Examples of insulation materials, components of insulation assemblies, configurations of representative insulation assemblies within heat generation segments, wrapping materials for insulation assemblies, and manners and methods for producing those components and assemblies, are set forth in U.S. Pat. No. 4,807,809 to Pryor et al.; U.S. Pat. No. 4,893,637 to Hancock et al.; U.S. Pat. No. 4,938,238 to Barnes et al.; U.S. Pat. No. 5,027,836 to Shannon et al.; U.S. Pat. No. 5,065,776 to Lawson et al.; U.S. Pat. No. 5,105,838 to White et al.; U.S. Pat. No. 5,119,837 to Banerjee et al.; U.S. Pat. No. 5,247,947 to Clearman et al.; U.S. Pat. No. 5,303,720 to Banerjee et al.; U.S. Pat. No. 5,345,955 to Clearman et al.; U.S. Pat. No. 5,396,911 to Casey, III et al.; U.S. Pat. No. 5,546,965 to White; U.S. Pat. No. 5,727,571 to Meiring et al.; U.S. Pat. No. 5,902,431 to Wilkinson et al.; U.S. Pat. No. 5,944,025 to Cook et al.; U.S. Pat. No. 8,424,538 to Thomas et al.; and U.S. Pat. No. 8,464,726 to Sebastian et al.; which are incorporated herein by reference. Certain insulation assemblies have been incorporated within the types of cigarettes commercially marketed under the trade names “PREMIER” and “ECLIPSE” by R. J. Reynolds Tobacco Company, and as “STEAM HOT ONE” cigarette marketed by Japan Tobacco Inc. - Flame/burn retardant materials and additives useful in insulation may include silica, carbon, ceramic, metallic fibers and/or particles. When treating cellulosic or other fibers such as, for example, cotton, boric acid or various organophosphate compounds may provide desirable flame-retardant properties. In addition, various organic or metallic nanoparticles may confer a desired property of flame-retardancy, as may diammonium phosphate and/or other salts. Other useful materials may include organo-phosphorus compounds, borax, hydrated alumina, graphite, potassium tripolyphosphate, dipentaerythritol, pentaerythritol, and polyols. Others such as nitrogenous phosphonic acid salts, mono-ammonium phosphate, ammonium polyphosphate, ammonium bromide, ammonium chloride, ammonium borate, ethanolammonium borate, ammonium sulphamate, halogenated organic compounds, thio-urea, and antimony oxides may be used but are not preferred agents. In each embodiment of flame-retardant, burn-retardant, and/or scorch-retardant materials used in insulation, substrate material and other components (whether alone or in any combination with each other and/or other materials), the desirable properties most preferably are provided without undesirable off-gassing or melting-type behavior.
- An insulation fabric preferably will have sufficient oxygen diffusion capability to sustain a smoking article such as a cigarette in a lit condition during a desired usage time. Accordingly the insulation fabric preferably will be porous by virtue of its construction. In knit, woven, or combined woven and knit constructions, the required porosity may be controlled by configuring the assembly machinery to leave sufficient (desirably sized) gaps between fibers to allow for oxygen diffusion into the heat source. For non-woven fabrics, which may not be porous enough to promote evenly sustained combustion, additional porosity may be achieved by perforations into the insulation by methods known in the art including, for example, hot or cold pin perforation, flame perforation, embossing, laser cutting, drilling, blade cutting, chemical perforation, punching, and other methods. The insulation may include non-glass material that is woven, knit, or a combination thereof, a foamed metal material, a foamed ceramic material, a foamed ceramic-metal composite, and any combination thereof.
- In some embodiments, an inner layer of insulation may include a variety of glass or non-glass filaments or fibers that are woven, knit, or both woven and knit (such as, for example, so-called 3-D woven/knit hybrid mats). When woven, an inner layer may be formed as a woven mat or tube. A woven or knitted mat or tube can provide improved control of air flow with regard to evenness across the insulation layer (including as any thermal-related changes may occur to the layer). Those of skill in the art will appreciate that a woven, knit, or hybrid material may provide more regular and consistent air spaces/gaps between the filaments or fibers as compared to a non-woven material which is more likely to have irregularly closed and open spaces that may provide comparatively non-uniform and/or decreased air-flow. Various other insulation embodiments may be molded, extruded, foamed, or otherwise formed. Particular embodiments of insulation structures may include those described in U.S. Pat. Appl. Pub. No. 2012/0042885 to Stone et al., which is incorporated by reference herein in its entirety.
- Preferably, both ends of the
heat generation portion 406 are open to expose at least theheat generation member 408 andinsulation 410 at thelighting end 402. Theheat generation member 408 and the surroundinginsulation 410 can be configured so that the length of both materials is co-extensive (i.e., the ends of theinsulation 410 are flush with the respective ends of theheat generation member 408, and particularly at the downstream end of the heat generation portion 406). Optionally, though not necessarily preferably, theinsulation 410 may extend slightly beyond (e.g., from about 0.5 mm to about 2 mm beyond) either or both ends of theheat generation member 408. Moreover, heat and/or heated air produced when thelighting end 402 is ignited during use of thesmoking article 400 can readily pass through theheat generation portion 406 during draw by the smoker on themouth end 404. - The
heat generation portion 406 preferably is positioned with one end disposed at thelighting end 402, and is axially aligned in an end-to-end relationship with a downstream aerosol-generatingportion 414, preferably abutting one another, but with no barrier (other than open air-space) therebetween. The close proximity of theheat generation portion 406 to thelighting end 402 provides for direct ignition of theheat generation member 408 of theheat generation portion 406. - A longitudinally-extending, cylindrical aerosol-generating
portion 414 is located downstream from theheat generation portion 406. The aerosol-generatingportion 414 includes asubstrate material 416 that, in turn, acts as a carrier for tobacco-related material (not shown). For example, the aerosol-generatingportion 414 can include a reconstituted tobacco material that includes processing aids, flavoring agents, and glycerin. The foregoing components of the aerosol-generatingportion 414 can be disposed within, and circumscribed by, a wrapping material. The wrapping material can be configured to facilitate the transfer of heat from thelighting end 402 of the smoking article 400 (e.g., from the heat generation portion 406) to components of the aerosol-generatingportion 414. That is, the aerosol-generatingportion 414 and theheat generation portion 406 can be configured in a heat exchange relationship with one another. The heat exchange relationship is such that sufficient heat from theheat generation member 408 is supplied to the aerosol-formation region to volatilize aerosol-forming material for aerosol formation. In some embodiments, the heat exchange relationship is achieved by positioning those portions in close proximity to one another. A heat exchange relationship also can be achieved by extending a heat conductive material from the vicinity of theheat generation member 408 into or around the region occupied by the aerosol-generatingportion 414. Particular embodiments of substrates may include those described below or those described in U.S. Pat. App. Pub. No. 2012/0042885 to Stone et al., which is incorporated by reference herein in its entirety. - In some preferred smoking articles, both ends of the aerosol-generating
portion 414 are open to expose the substrate material thereof. Together, theheat generating portion 406 and the aerosol-generatingportion 414 form an aerosol-generation system. Those portions can abut one another, or be positioned in a slightly spaced apart relationship, which may include abuffer region 418. The outer cross-sectional shapes and dimensions of those portions, when viewed transversely to the longitudinal axis of thesmoking article 400, can be essentially identical to one another. The components of the aerosol-generation system preferably are attached to one another, and secured in place using anoverwrap material 420. For example, theoverwrap material 420 can include a paper wrapping material or a laminated paper-type material that circumscribes each of at least a portion of the outer longitudinally-extending surface of theheat generation portion 406 and the aerosol-generatingportion 414. The inner surface of theoverwrap material 420 may be secured to the outer surfaces of the components it circumscribes by a suitable adhesive. - The
smoking article 400 preferably includes a suitable mouthpiece such as, for example, afilter portion 412. Thefilter portion 412 preferably is positioned at themouth end 404 of the cigarette rod adjacent to one end of the aerosol-generatingportion 414, such that thefilter portion 412 and the aerosol-generatingportion 414 are axially aligned in an end-to-end relationship, abutting one another but without any barrier therebetween. Preferably, the general cross-sectional shapes and dimensions of those 412, 414 are essentially identical to one another when viewed transversely to the longitudinal axis of the smoking article. Theportions filter portion 412 may includefilter material 422 that is overwrapped along the longitudinally-extending surface thereof with circumscribing plug wrap material. In one example, thefilter material 422 includes plasticized cellulose acetate tow, while in some examples the filter material may further include activated charcoal in an amount from about 20 mg to about 80 mg disposed as a discrete charge or dispersed throughout the acetate tow in a “Dalmatian type” filter. Both ends of thefilter portion 412 preferably are open to permit the passage of aerosol therethrough. The aerosol-generating system preferably is attached to thefilter portion 412 usingtipping material 424. Thefilter portion 412 may also include a crushable flavor capsule of the type described in U.S. Pat. No. 7,479,098 to Thomas et al. and U.S. Pat. No. 7,793,665 to Dube et al.; and U.S. Pat. No. 8,186,359 to Ademe et al., which are incorporated herein by reference in their entirety. Thefilter portion 412 may additionally or alternatively contain strands of tobacco containing material, such as described in U.S. Pat. No. 5,025,814, which is incorporated herein by reference in its entirety. - The
smoking article 400 may include an air dilution provision, such as a series ofperforations 426, each of which may extend through the filterelement tipping material 424 and plug wrap material in the manner shown, and/or which may extend to or into the substrate. - During use, the smoker lights the
lighting end 402 of thesmoking article 400 using a match or cigarette lighter, in a manner similar to the way that conventional smoking articles are lit, such that theheat generation member 408 at thelighting end 402 is ignited. Themouth end 404 of thesmoking article 400 is placed in the lips of the smoker. Thermal decomposition products (e.g., components of tobacco smoke) generated by the aerosol generation system are drawn through thesmoking article 400, through thefilter portion 412, and into the mouth of the smoker. That is, when smoked, the smoking article yields visible mainstream aerosol that resembles the mainstream tobacco smoke of traditional cigarettes that burn tobacco cut filler. - Direct ignition actuates the
heat generation member 408 of theheat generation portion 406 such that it preferably will be ignited or otherwise activated (e.g., begin to burn or smolder). Theheat generation member 408 within the aerosol-generation system, once ignited, will provide heat to volatilize aerosol-forming material within the aerosol-generatingportion 414 as a result of the heat exchange relationship between those two segments. Certain heat generation members will not experience volumetric decrease during activation, while others may degrade in a manner that reduces their volume. Preferably, the components of the aerosol-generatingportion 414 do not experience thermal decomposition (e.g., charring or burning) to any significant degree. Volatilized components are entrained in the air that is drawn through the aerosol-generating region. The aerosol so formed will be drawn through thefilter portion 412, and into the mouth of the smoker. -
FIG. 5 illustrates a method for debossing a heat generation member of an elongate smoking article, generally referred to as 500. In a first step, 502, a longitudinally-extending heat generation member is serially dispensed along a machine direction, the heat generation member having an outer surface and defining a longitudinal axis. In a second step, 504, the heat generation member is debossed by being received between longitudinally-extending channels of opposing first and second dies of a debossing mechanism, wherein the channels of the opposing first and second dies each comprise spaced-apart protrusions along the channels, and wherein the protrusions in the channels are configured to extend non-parallel to the channels and to cooperatively interact with the heat generation member to deboss the outer surface thereof. - In some aspects, serially dispensing a longitudinally-extending heat generation member comprises extruding the heat generation member as a monolithic element of a carbonaceous material.
- In some aspects, extruding the single carbonaceous material comprises forming a plurality of spaced-apart grooves in and about a circumference of the monolithic element, the grooves extending longitudinally between opposed first and second ends of the heat generation member.
- In some aspects, debossing the heat generation member by receiving the heat generation member such that the protrusions in the channels of the debossing mechanism cooperatively interact with the heat generation member to deboss the outer surface thereof comprises defining a plurality of longitudinally spaced-apart, circumferentially-extending depressions between the opposed first and second ends of the heat generation member, each depression extending about a circumference of the outer surface of the heat generation member.
- In some aspects, the
method 500 further comprises aligning the first die and the opposing second die such that the protrusions in the channels of the dies are aligned with one another, the dies cooperatively interacting with the heat generation member to form the plurality of spaced-apart depressions, wherein the plurality of spaced-apart depressions extending about first and second hemicylindrical portions of the heat generation member are aligned with each other such that the spaced-apart depressions extend continuously around the outer surface of the heat generation member. - In some aspects, the method further comprises aligning the first die and the opposing second die such that the protrusions in the channel of the first die are offset in the machine direction with regard to the protrusions in the channel of the second die, the dies cooperatively interacting with the heat generation member to form the plurality of spaced-apart depressions, wherein the plurality of longitudinally spaced-apart depressions extending about a first hemicylindrical portion of the heat generation member are offset in the machine direction with regard to the plurality of longitudinally spaced-apart depressions extending about a second opposing hemicylindrical portion of the heat generation member.
- Many modifications and other aspects of the disclosures set forth herein will come to mind to one skilled in the art to which these disclosures pertain having the benefit of the teachings presented in the foregoing descriptions and the associated drawings. For example, those of skill in the art will appreciate that embodiments not expressly illustrated or described herein may be practiced within the scope of the present disclosure, including that features described herein for different embodiments may be combined with each other and/or with currently-known or future-developed technologies while remaining within the scope of the claims presented here. Therefore, it is to be understood that the disclosures are not to be limited to the specific aspects disclosed and that equivalents, modifications, and other aspects are intended to be included within the scope of the appended claims. Although specific terms are employed herein, they are used in a generic and descriptive sense only and not for purposes of limitation.
Claims (20)
Priority Applications (6)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US15/902,665 US20190254335A1 (en) | 2018-02-22 | 2018-02-22 | System for debossing a heat generation member, a smoking article including the debossed heat generation member, and a related method |
| KR1020207026841A KR20200121356A (en) | 2018-02-22 | 2019-02-18 | System for debossing heating elements, smoking articles comprising debossed heating elements, and related methods |
| EP19711709.6A EP3755165A1 (en) | 2018-02-22 | 2019-02-18 | A system for debossing a heat generation member, a smoking article including the debossed heat generation member, and a related method |
| RU2020128271A RU2807569C2 (en) | 2018-02-22 | 2019-02-18 | System for blind embossing of heat-generating element and corresponding method |
| JP2020544499A JP2021514628A (en) | 2018-02-22 | 2019-02-18 | System for debossing heat generating members, smoking products including debossed heat generating members and related methods |
| PCT/IB2019/051303 WO2019162815A1 (en) | 2018-02-22 | 2019-02-18 | A system for debossing a heat generation member, a smoking article including the debossed heat generation member, and a related method |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US15/902,665 US20190254335A1 (en) | 2018-02-22 | 2018-02-22 | System for debossing a heat generation member, a smoking article including the debossed heat generation member, and a related method |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| US20190254335A1 true US20190254335A1 (en) | 2019-08-22 |
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| US15/902,665 Abandoned US20190254335A1 (en) | 2018-02-22 | 2018-02-22 | System for debossing a heat generation member, a smoking article including the debossed heat generation member, and a related method |
Country Status (5)
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|---|---|
| US (1) | US20190254335A1 (en) |
| EP (1) | EP3755165A1 (en) |
| JP (1) | JP2021514628A (en) |
| KR (1) | KR20200121356A (en) |
| WO (1) | WO2019162815A1 (en) |
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| US1330434A (en) * | 1919-07-11 | 1920-02-10 | Otto Wilhelm Einar Gosling | Briqueting-press |
| US5247947A (en) * | 1990-02-27 | 1993-09-28 | R. J. Reynolds Tobacco Company | Cigarette |
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| WO2021224878A1 (en) | 2020-05-08 | 2021-11-11 | R.J. Reynolds Tobacco Company | Aerosol delivery device |
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Also Published As
| Publication number | Publication date |
|---|---|
| WO2019162815A1 (en) | 2019-08-29 |
| EP3755165A1 (en) | 2020-12-30 |
| RU2020128271A (en) | 2022-03-22 |
| JP2021514628A (en) | 2021-06-17 |
| KR20200121356A (en) | 2020-10-23 |
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