200920410 九、發明說明 【發明所屬之技術領域】 本發明係有關搭配磷脂質、二月桂醯麩胺酸離胺酸鹽 、電解質美容成分之液狀化粧料。更詳細係關於即便有電 解質存在，亦具有良好保存安定性，同時具有水潤的使用 感’不會產生黏腻，且具高軟化效果之液狀化粧料。 【先前技術】 自以往即在化粧水、乳液、美容液等液狀化粧料中使 用電解質做爲對肌膚的美容成分。例如，本身是電解質而 使用爲美容成分的有保濕劑（胺基酸及乳酸鈉，吡咯烷酮 羧酸鈉等）、消炎劑（甘草酸二鉀鹽等）、美白齊U(L -抗壞血 酸-2 -磷酸鎂等）、紫外線吸收劑（苯基苯並咪唑磺酸鹽等） 等。 然而當上述電解質美容成分與液狀化粧料搭配時，由 於電荷造成的影響，使液狀化粧料中之微脂體及乳化滴等 小囊泡表面的雙電荷層被壓縮，因有時該等小囊泡會產生 凝集•結合及乳凝作用，顯著降低安定性而不易確保安定 性。 目前搭配電解質之液狀化粧料檢討有含特定比例非極 性油與極性油之微細乳狀組成物（參照專利文件1 )、聚甘 油脂肪酸酯與碳數10〜22之2-羥基脂肪酸之組合物（參照 專利文件2)及高級脂肪酸與HLB爲1 0以上之非離子性界 面活性劑之組合物（參照專利文件3 )。 -4- 200920410 專利文件1 :特開2002- 1 3 8 0 1 4號公報（第1頁〜第7 頁） 專利文件2:特開平9-110635號公報（第1頁〜第7 頁） 專利文件3 :專利第343 4 1 1 5號公報（第1頁〜第8頁 【發明內容】 然而以過去的技術爲確保液狀化粧料之保存安定性， 需搭配大量的界面活性劑及水溶性高分子等，於該領域中 ，塗布於肌膚時因界面活性劑及水溶性高分子而產生滑黏 感及黏腻感等，不僅在使用面上無法獲得充分的滿足，亦 無法在柔軟感上獲得充分的滿足。 有鑑於相關現狀，本發明者進行專心檢討後，發現於 搭配電解質美容成分之液狀化粧料中，藉由倂用磷脂質與 二月桂醯麩胺酸離胺酸鹽，可顯著抑制小囊泡之凝集.結 合及乳凝作用’而顯示相乘的保存安定性提升效果。進而 發現可獲得具有水潤、不會產生黏腻的良好使用感，且具 更高軟化效果之液狀化粧料，本發明遂至完成。 亦即’本發明係有關一種液狀化粧料，其特徵爲搭配 下述成分（A)〜（D); (A) 磷脂質 (B) 二月桂醯麩胺酸離胺酸鹽 (C) 電解質美容成分 200920410 (D)水。 本發明之化粧料係即便搭配電解質，亦具有良好的保 存安定性，同時具有水潤的使用感，不會產生黏腻，且具 高軟化效果之液狀化粧料。 本發明之液狀化粧料中，成分（A)之磷脂質係作用爲 微脂體形成成分或乳化劑之成分。進而磷脂質亦對軟化效 果有所貢獻。成分（A)之磷脂質係使用於一般化粧料者， 例如可舉出大豆來源之磷脂質、蛋黃來源之磷脂質或該等 物質之加氫磷脂質，而該等磷脂質可因應需要使用一種或 二種以上，但並未限定於該等物質。本發明所使用之磷脂 質，自長期保存安定性（氣味、乳化安定性）之觀點，以磷 脂醯膽鹼（PC)純度爲30以上者爲佳，或碘價爲10以下者 爲佳。 成分（A)磷脂質之搭配量以〇·〇5〜10質量％(以下僅記 做「％」）爲佳，〇 . 2〜5 %更佳。於該範圍時可獲得充分的柔 軟感與良好的使用效果。另外’亦可成爲保存安定性良好 者。 本發明之液狀化粧料中’成分（Β)之二月桂醯魅胺酸 離胺酸鹽，係多鏈多親水基型化合物’作用爲微脂體形成 成分或乳化劑之成分。與二月桂醯楚胺酸離胺酸鹽有關之 鹽類可自鈉、鉀、三乙醇胺、氨中選出一種’但其中以鈉 自良好的使用感與保存安定性的觀點而言爲佳。 成分（Β)二月桂醯麩胺酸離胺酸鹽之搭配量以1〜 1 〇晳量％爲佳’ 〇 _ 1〜5 °/β更佳。於該範圍時可獲得充分的 -6- 200920410 柔軟感與良好的使用效果。另外，亦可成爲保存安定性良 好者。 本發明之液狀化粧料中，藉由將成分（A)之磷脂質與 成分（B)之二月桂醯麩胺酸離胺酸鹽組合使用，可成爲耐 鹽性優異之組成物。進而，該等物質之搭配質量比以1 〇 : 1〜1 : 1爲佳，7 : 1〜2 : 1更佳。於該範圍時可獲得充分 的軟化效果以及無黏腻感的良好使用感。 本發明之液狀化粧料中，成分（C)之電解質美容成分 係於皮膚科學上對肌膚有效的水溶性美容成分可使用使用 於一般化粧料者。具體而言可舉出例如胺基酸、乳酸鈉、 吡咯烷酮羧酸鈉、甘草酸二鉀鹽、尿素、L -抗壞血酸-2 -磷 酸鈉、L-抗壞血酸-2-磷酸鎂、抗壞血酸醣甘、苯基苯並咪 唑磺酸鹽、羥基甲氧基二苯甲酮磺酸鹽等，可因應需要使 用一種或二種以上，但並未限定於該等物質。 成分（C)之電解質美容成分之搭配量以〇·1〜1〇質量％ 爲佳，0.3〜3 %更佳。於該範圍時可獲得充分的對肌膚的 效果，另外，亦爲保存安定性良好者。 本發明之液狀化粧料中，成分（D)之水係使用於一般 化粧料者。成分（D)之水之搭配量並無特別限定，但爲獲 得水潤的觸感，以3 0〜9 9 %爲佳。 本發明之液狀化粧料中，可於上述必須成分（Α)至（〇) 之外，在搭配成分（Ε)做爲油性成分。該油性成分係做爲 提供軟化效果之成分。成分（Ε)之油性成分，可使用用於 一般化粧料者並無特別限定，可爲固狀、糊狀、液狀等任 200920410 一種狀態。例如液狀的油性成分可舉出酪梨油、亞麻籽油 、杏仁油、橄欖油、杏桃仁油、小麥胚芽油、芝麻油、米 胚芽油、米糠油、葵花油、大豆油、玉米油、荷荷苗油、 澳洲堅果油、紹油、棉貫油、挪子油、液狀羊毛脂、還原 羊毛脂、羊毛脂醇、醋酸羊毛脂、羊毛脂脂肪酸異丙醇、 角鯊烷、角鯊烯、流動石蠟、原始烷、聚異丁嫌、十一燦 酸、油酸、亞麻油酸、次亞麻油酸、異硬醋酸、2 _己基癸 基己二酸酯、單異硬酯酸N -烷基乙二醇酯、異十六院基 異硬脂酸酯、三異硬酯酸三羥甲基丙烷、雙_2_乙基己酸乙 一醇、錬蠟2 -乙基己酸酯、三-2 -乙基己酸三經甲基丙院 、四-2 -乙基己酸季戊四醇、鯨蠟辛酸、油醇油酸酯、辛基 十二烷醇油酸酯、新戊二醇二癸酸酯、2 -乙基己基琥珀酸 酯、硬脂酸異十六烷酯、硬脂酸丁酯、癸二酸二（2-乙基己 )酯、鯨蠟醇乳酸酯、肉宣蔻醇乳酸酯、二異硬脂醇蘋果 酸酯、甘油三異硬脂酸酯、甘油三-2-乙基己酸酯、甘油單 硬酯酸酯、雙-2-庚基十一烷酸甘油、聚甲基矽氧烷、聚甲 基苯基矽氧烷、聚乙基矽氧烷、聚乙基甲基矽氧烷、聚乙 基苯基矽氧烷、八甲基環四矽氧烷、十甲基環五矽氧烷、 蓖麻油等，糊狀的油性成分可舉出例如可可脂、雪亞脂、 硬化蓖麻油、硬化椰子油、羊毛脂、凡士林、單硬酯酸硬 化蓖麻油、單羥基硬酯酸硬化蓖麻油、膽固醇羥基硬脂酸 酯、雙季戊四醇12 -羥基硬脂酸酯、雙季戊四醇羥基硬脂 酸酯、雙季戊四醇松香酯、N-月桂醯-L-谷氨酸-雙（膽固醇 山嵛醇·辛基十二醇）、植物固醇澳洲堅果油酸酯等’ -8 - 200920410 固狀的油性成分可舉出例如棕櫚蠟、勘地里拉躐、鯨蠟、 蜂蠟、地臘、石螭、石蠟、微晶蠟、硬酯酸、山嵛酸、 1 2-羥基硬酯酸、棕櫚酸鯨蠟、雙硬酯酸聚乙二醇、三嵛 樹酸甘油酯、硬酯酸改性聚矽氧烷等，可因應需要使用一 種或二種以上該等油劑。 成分（E)之油性成分其搭配量以之搭配量以0.5〜30% 爲佳，2〜2 5 %更佳。於該範圍時可獲得充分充分的軟化效 果與良好的使用感，另外，亦爲保存安定性良好者。 於本發明之液狀化粧料中，除前述之成分外，可因應 需要搭配使用於一般的化粧品及準藥物、醫藥品等之各種 成分。該等任意成分可舉出例如醇類、保濕劑、乳化劑、 乳化安定劑、增黏劑、防腐劑、粉體、顏料、色素、紫外 線吸收劑、pH調整劑、香料、藥性成分、金屬封鎖劑等 〇 本發明之液狀化粧料，可遵循常用方法將上述必須成 分（A)至（D)以及因應需要所添加之成分（E)，及其他任意成 分’藉由混合而進行製造，有關混合的方法可使用例如均 質混合機、分散混合機等而進行製造，另外亦可使用高壓 均質機及微射流均質機等高壓乳化機而進行製造。 如此所獲得之本發明之液狀化粧料分散爲小囊泡而存 在。於本說明書中小囊泡係指於水中呈現封閉的小胞體， 亦包含微脂體及乳化滴。該小囊泡之平均粒子徑以3 0〜200920410 IX. INSTRUCTIONS OF THE INVENTION [Technical Fields of the Invention] The present invention relates to a liquid cosmetic which is formulated with a phospholipid, a bifurcium glutamate lysate, and an electrolyte cosmetic component. More specifically, it relates to a liquid cosmetic which has good preservation stability and has a moisturized feeling of use, which does not cause stickiness and has a high softening effect, even if it has a presence of a chemical substance. [Prior Art] Electrolytes have been used as a cosmetic ingredient for skin in liquid cosmetics such as lotions, lotions, and beauty lotions. For example, it is an electrolyte and is used as a cosmetic ingredient with a moisturizing agent (amino acid and sodium lactate, sodium pyrrolidone carboxylate, etc.), an anti-inflammatory agent (dipotassium glycyrrhizinate, etc.), and whitening U (L-ascorbic acid-2-phosphate Magnesium, etc., ultraviolet absorber (phenyl benzimidazole sulfonate, etc.), and the like. However, when the above-mentioned electrolyte cosmetic component is combined with the liquid cosmetic, the electric double layer of the surface of the small vesicle such as the liposome and the emulsified droplet in the liquid cosmetic is compressed due to the influence of the electric charge, because sometimes Small vesicles produce agglutination, binding, and milk coagulation, which significantly reduces stability and does not easily ensure stability. At present, a liquid cosmetic composition with an electrolyte is reviewed for a combination of a fine emulsion composition containing a specific ratio of apolar oil and a polar oil (refer to Patent Document 1), a polyglycerol fatty acid ester, and a 2-hydroxy fatty acid having a carbon number of 10 to 22. The composition (see Patent Document 2) and a combination of a higher fatty acid and a nonionic surfactant having an HLB of 10 or more (see Patent Document 3). -4- 200920410 Patent Document 1: Special Publication 2002- 1 3 8 0 1 4 (Page 1 to Page 7) Patent Document 2: JP-A-9-110635 (Page 1 to Page 7) Patent Document 3: Patent No. 343 4 1 1 5 (Page 1 to Page 8 [Invention] However, in order to ensure the preservation stability of liquid cosmetics in the past, a large amount of surfactant and water solubility are required. In this field, polymers and the like, when applied to the skin, are slippery and sticky due to the surfactant and the water-soluble polymer, and are not sufficiently satisfactory on the use surface, and cannot be soft. In view of the current status quo, the inventors of the present invention have found that in liquid cosmetics with electrolyte beauty ingredients, by using phospholipids and dilaurin glutamate ionoate, Significantly inhibits the agglutination of small vesicles, combined with the coagulation effect, and shows the synergistic effect of preservation stability. It is found that a good feeling of use with hydration, no stickiness, and a higher softening effect can be obtained. Liquid cosmetic, the present invention To the completion. That is, the present invention relates to a liquid cosmetic characterized by the following components (A) to (D); (A) phospholipid (B) dilaurin glutamate lysate ( C) Electrolyte Beauty Ingredients 200920410 (D) Water. The cosmetic of the present invention has good preservation stability even with an electrolyte, and has a moisturizing feeling, does not cause stickiness, and has a high softening effect. In the liquid cosmetic of the present invention, the phospholipid of the component (A) acts as a component of the liposome-forming component or the emulsifier, and the phospholipid also contributes to the softening effect. The component (A) The phospholipids are used in general cosmetics, and examples thereof include phospholipids derived from soybeans, phospholipids derived from egg yolks, and hydrogenated phospholipids of such materials, and these phospholipids may be used alone or in combination of two or more. However, it is not limited to these substances. The phospholipid used in the present invention preferably has a phospholipid choline (PC) purity of 30 or more, or iodine, from the viewpoint of long-term storage stability (odor, emulsion stability). It is better if the price is 10 or less. The amount of the component (A) phospholipid is preferably 5 to 10% by mass (hereinafter referred to as "%"), preferably 2 to 5%. In this range, a sufficient soft feeling is obtained. Good use effect. In addition, it can also be a good preservation stability. In the liquid cosmetic of the present invention, the ingredient (Β) of the lauric acid amygdalin is a multi-chain polyhydrophilic compound. It acts as a component of the liposome-forming component or emulsifier. The salt associated with the diammonium sulphate can be selected from sodium, potassium, triethanolamine and ammonia, but the sodium is used well. The feeling is better than the viewpoint of preservation stability. The amount of the component (Β) laurel glutamic acid lysate is preferably 1 to 1 〇% ' 1 _ 1~5 °/β is better . In this range, sufficient -6-200920410 softness and good use effect can be obtained. In addition, it can also be a good preserver. In the liquid cosmetic of the present invention, by using the phospholipid of the component (A) in combination with the divalent lauric acid glutamate deaminate of the component (B), it is possible to obtain a composition excellent in salt tolerance. Further, the mass ratio of the materials is preferably 1 〇 : 1 to 1: 1 and 7 : 1 to 2 : 1 is better. Within this range, a sufficient softening effect and a good feeling of use without stickiness can be obtained. In the liquid cosmetic of the present invention, the electrolyte cosmetic component of the component (C) is a water-soluble cosmetic component which is effective for dermatological skin and can be used for general cosmetics. Specific examples thereof include amino acid, sodium lactate, sodium pyrrolidone carboxylate, dipotassium glycyrrhizinate, urea, sodium L-ascorbyl-2-phosphate, magnesium L-ascorbic acid-2-phosphate, ascorbyl glycoside, and phenyl group. The benzimidazole sulfonate, the hydroxymethoxybenzophenone sulfonate, and the like may be used alone or in combination of two or more, but are not limited thereto. The amount of the electrolyte cosmetic component of the component (C) is preferably 〇·1 to 1 〇 mass%, more preferably 0.3 to 3%. In this range, sufficient skin effect can be obtained, and it is also good in preservation stability. In the liquid cosmetic of the present invention, the water of the component (D) is used in general cosmetics. The amount of the water of the component (D) is not particularly limited, but in order to obtain a moist feeling, it is preferably from 30 to 99%. In the liquid cosmetic of the present invention, the collateral component (Ε) may be used as an oil component in addition to the above-mentioned essential components (Α) to (〇). This oily component is used as a component to provide a softening effect. The oily component of the component (Ε) is not particularly limited as long as it can be used for general cosmetics, and may be in the form of a solid, a paste, or a liquid. Examples of the liquid oily component include avocado oil, linseed oil, almond oil, olive oil, apricot kernel oil, wheat germ oil, sesame oil, rice germ oil, rice bran oil, sunflower oil, soybean oil, corn oil, and lotus. Lotus seed oil, macadamia nut oil, sauer oil, cotton oil, scorpion oil, liquid lanolin, reduced lanolin, lanolin alcohol, lanolin acetate, lanolin fatty acid isopropanol, squalane, squalene , mobile paraffin, raw alkane, polyisobutyl, eleven acid, oleic acid, linoleic acid, linoleic acid, iso-hard acetic acid, 2 _hexyldecyl adipate, monoisostearic acid N - Alkyl glycol ester, isohexyl isostearate, triisomethylolpropane triisopropionate, ethyl 2-oxoethylhexanoate, anthracene 2-ethylhexanoate, Tris-2-ethylhexanoic acid trimethyl ketone, tetrakis-2-ethylhexanoic acid pentaerythritol, cetyl octanoic acid, oleyl oleate, octyldodecanol oleate, neopentyl glycol Phthalate, 2-ethylhexyl succinate, isohexadecyl stearate, butyl stearate, di(2-ethylhexyl) sebacate, cetyl lactate, Phytosterol lactate, diisostearyl malate, glyceryl triisostearate, glycerol tris-2-ethylhexanoate, glyceryl monostearate, bis-2-heptyl eleven Alkanoic acid glycerin, polymethyl siloxane, polymethyl phenyl siloxane, polyethyl siloxane, polyethyl methyl oxane, polyethyl phenyl oxane, octamethyl ring Examples of the oily component of the paste, such as cocoa butter, sorbitol, hardened castor oil, hardened coconut oil, lanolin, petrolatum, and monostearic acid, may be mentioned as a phthalic oil, a decyl pentoxide, a castor oil, etc. Hardened castor oil, monohydroxystearic acid hardened castor oil, cholesterol hydroxystearate, dipentaerythritol 12-hydroxystearate, dipentaerythritol hydroxystearate, dipentaerythritol rosin ester, N-laurel-L- Glutamate-bis (cholesterol behenyl octyldodecanol), phytosterol macadamia oleate, etc. -8 - 200920410 Examples of solid oily components include palm wax, scorpion scorpion, and whale Wax, beeswax, ground wax, sarcophagus, paraffin, microcrystalline wax, stearic acid, behenic acid, 1 2-hydroxystearic acid, palmitic acid cetyl And bis-bisuccinic acid polyethylene glycol, triterpenic acid glyceride, stearic acid modified polyoxyalkylene, etc., one or more of these oil agents may be used as needed. The oil component of the component (E) is preferably used in an amount of 0.5 to 30%, more preferably 2 to 25%. Within this range, a sufficiently sufficient softening effect and a good feeling of use can be obtained, and also a good storage stability is obtained. In addition to the above-mentioned components, the liquid cosmetic of the present invention can be used in combination with various components such as general cosmetics, quasi-drugs, and pharmaceuticals. Examples of such optional components include alcohols, humectants, emulsifiers, emulsion stabilizers, tackifiers, preservatives, powders, pigments, pigments, ultraviolet absorbers, pH adjusters, perfumes, medicinal ingredients, and metal blockades. The liquid cosmetic of the present invention can be manufactured by mixing the above-mentioned essential components (A) to (D) and the component (E) added as needed, and other optional components by a usual method. The mixing method can be produced by using, for example, a homomixer or a dispersing mixer, or can be produced by using a high-pressure emulsifier such as a high-pressure homogenizer or a micro-jet homogenizer. The liquid cosmetic of the present invention thus obtained is dispersed as small vesicles. In the present specification, a small vesicle means a closed small cell body in water, and also contains a liposome and an emulsified droplet. The average particle diameter of the small vesicle is 3 0~
3 0 Onm爲佳。於該範圍時，較少產生乳凝作用，可爲保存 安定性更良好者。且小囊泡之平均粒子徑係以C 0 U L T E R 200920410 N-4型（BECKMAN C O ULTER公司製）所測定之値。？ 之液狀化粧料爲獲得保存性良好且具有水潤、無黏旗 用感以及軟化效果，以水中油型乳化化粧料爲最佳。 本發明之液狀化粧料於25 °C之導電度（係使用身 波工業公司製 導電度計 CM-60G進行測定）以C 4S/m爲佳，進而以0.1〜3S/m更佳。於該範圍時，π 發揮電解質美容成分效果之保濕效果及美白效果，上 持系的安定性。 本發明中液狀化粧料之液狀，係指藉由布鲁克H 型旋轉黏度計，測定30°C之黏度値爲1〜20〇〇mpa. 。黏度爲該範圍時，可獲得水潤的使用感。 本發明之液狀化粧料並未限定於一般的皮膚化粧 亦包含準藥物、醫藥品等全部的液狀液狀化粧料，功 別限定其形態，可因應目的而加以選擇。例如可舉杜 、化粧水、美容液、面膜、清潔用料、彩妝化粧料、 等形態。 【實施方式】 實施例 其次’舉實施例及比較例將本發明更詳細地力卩 ’但本發明並未因此而有任何限制。 實施例1〜1 0以及比較例1〜5液狀化粧料 根據以下所示之製造方法，製造下記表1以及 :發明 :的使 亞電 .0 5〜 '充分 可保 爾德 S者 料， 未特 乳液 氣膠 說明 2所 -10- 200920410 示組成之液狀化粧料。再針對（1)使戶 腻感程度）、（2)軟化效果、（3)保存$ (5)乳化滴之平均粒子徑之評價項目以 ，結果合倂表不於表1以及表2。 丨感（水潤程度、無黏 :定性、（4)導電度、 下述之方法進行評價 -11 - 200920410 5 蜀 o m 1 Ο <Ν ο ο 餘量 严 ◎ ◎ ◎ ◎ 0.652 100-200 〇\ ^Ti 1 ίΤ) ο ο 1 ο ο 餘量 rn y~* m ◎ ◎ 〇 ◎ 0.1962 1 1 50-250 | 00 1 W-) ο 1 ο ο 餘量 m m ◎ ◎ ◎ 〇 1.45 1 50-250 | 卜 <n 1 w-ΐ ο 1 ο ο 餘量 ο > _ _H ΠΊ ◎ 〇 ◎ 〇 3.76 50-250 in 1 ΚΤ) 2 (Ν ο ο 餘量 ◎ ◎ ◎ ◎ 0.612 1 100-200 i u l/n 〇 1 0.025 , 1 ο ο 餘量 « r < ◎ 〇 〇 〇 0,62 Γ | 300-500 寸 CN 1 (Ν Ο ιη ίΝ ο ο 餘量 o >'t ◎ 〇 ◎ ◎ 0.582 100-300 m 1 (Ν Ο 1 I ο ο 餘量 < ◎ 〇 ◎ ◎ 0.558 50-150 (N 〇 1 Ο κη CS 1 ο ο 餘量 »« — 〇 〇 ◎ 〇 0.682 50-250 r » t—1 1 CN Ο (Ν 1 ο ο , 餘量 CN 〇 ◎ 〇 〇 1 1 0.568 Γ | 100-300 成分 im化大豆卵磷脂※1 l硬酯酸鈉 二月桂醯麩胺酸離胺酸鈉 三2-乙基己酸甘油 油酸植物甾醇 氍 11 Η ΓΟ 1 甘油 純水 乳酸鈉 成分(A):成分(B) 評價項目 使用感(水潤程度） 使用感(無黏腻感程度） 軟化效果 保存安定性 導電度(S/m)(25°C) 平均粒子徑(nm) d r· (N m 寸 卜 〇〇 ο (N 寸 κη 。9·9 _}塵 ' %soo-ps:窠od t (EtM^^^^swOI-socoaqli -12- 200920410 表2 比較例 No. 成分 1 2 3 4 5 1 氫化大豆卵磷脂以 — — 一 1.5 3 2 硬酯酸鈉 2 — — — — 3 二月桂醯麩胺酸離胺酸鈉 — 0.5 1 — — 4 三2-乙基己酸甘油 10 10 10 10 10 5 油酸植物留醇 2 2 2 2 2 6 1，3-丁二醇 10 10 10 10 10 7 甘油 10 10 10 10 10 8 純水 餘量 餘量 餘量 餘量 餘量 9 乳酸鈉 1 1 1 2 3 評價項目 1 "感(水潤程度） 〇 〇 〇 〇 〇 使用感(無黏腻感程度） Δ 〇 〇 〇 〇 2 軟化效果 Δ Δ Δ Δ Δ 3 保存安定性 X X X Δ Δ 4 導電度(S/m)(25t：) 0.578 0.577 0.552 0.512 0.535 5 平均粒子徑(nm) 400-500 100-250 100-300 250-350 250-350 (製造方法） ί Α.混合溶解1〜7。（70Τ：) B _ 力口熱 8。（ 7 0 〇C ) C .添加B至A並進行乳化。（7 0 °C ) D. 將C冷卻至4(TC。 E. 使用微射流均質機將D進行分散。 F ·添加9至E中。 [評價方法]評價項目（1)，（2) 以化粧經歷1 0年以上之2 0名女性爲調查對象，分別 針對（1)使用感（水潤程度、無黏腻感程度），（2 )軟化效果 等評價項目使用基準A之5階段進行評價，再自其平均點 -13- 200920410 數進行判定。 (基準A) 5點：非常良好 4點：良好 3點：普通 2點：不良好 1點：非常不良好 (判定） ◎:平均數4 · 5點以上 〇：平均數3 . 5點以上未達4.5點 △:平均數2.5點以上未達3 . 5點 X:平均數未達2.5點 [評價方法]評價項目（3) 保存安定性之評價方法係藉由目視觀察表1所示之液 狀化粧料於4 0°C下保存一定時間後之狀態，遵循下述基準 B進行評價。 (基準B) 6個月未發現分離、乳化現象：◎ 6個月未發現分離但發現些許乳化現象：〇 1個月發現分離、乳化現象：△ -14 - 200920410 1星期發現分離、乳化現象：χ [評價方法]評價項目（4) 將表1所示之液狀化粧料之乳化滴之平均粒子徑，以 COULTER N-4 型（BECKMAN COULTER 公司製）進行測定 〇 由表1及表2之結果可知，本發明之液狀化粧料，無 論做爲電解質美容成分之乳酸鈉（保濕劑）是否存在，其保 存安定性良好，且爲具有水潤、無黏腻的使用感以及高軟 化效果之液狀化粧料。相對於此，以硬酯酸鈉取代氫化大 豆卵磷脂及二月桂醯麩胺酸離胺酸鈉，做爲乳化劑而進行 搭配之比較例1，保存安定性極差。另外，於未搭配氫化 大豆卵磷脂之比較例2，同樣地保存安定性不佳，而針對 未搭配二月桂醯麩胺酸離胺酸鈉之比較例4，亦同樣地爲 保存安定性不佳者。另外如比較例3及5，即便將氫化大 豆卵磷脂或二月桂醯麩胺酸離胺酸鈉之搭配量以加倍的方 式處理，因分別單獨使用幾乎無法改善保存安定性，顯示 藉由倂用該等成分保存安定性會有相乘的提升效果。於本 實施例及比較例之黏度均於30°C爲1〜2000mPa . s。 實施例1 1美白化粧水 (成分） (%) (1)氫化大豆卵磷脂* 1 0.5 (2)二月桂醯麩胺酸離胺酸鈉 0.1 -15- 200920410 (3) 2-鯨蠟辛酸 2〇 (4) 二季戊四醇12-羥基脂肪酸/硬酯酸/松脂酸酯 〇.05 (5) 硬脂酸 0.05 (6) 雙丙甘醇 2.〇 (7 )甘油 3.0 (8 )純水 1〇.〇 (9) L-抗壞血酸-2-磷酸鎂 3.〇 (10) 檸檬酸鈉 1.0 (1 1)對羥基苯甲酸甲酯 適量 (1 2)香料 適量 (13) 乙醇 10.0 (14) 純水 餘量 (製造方法） A. 混合溶解1〜7。（ 7 0 °C ) B. 加熱 8。（7〇t ) C. 添加B至A並進行乳化。（7〇°C ) D. 將C冷卻至40°C。 E. 使用高壓均質機將D進行分散。 F. 添加9〜14至E中。 實施例11中，無論做爲電解質美容成分之L-抗壞血 酸-2 -磷酸鎂（美白劑）是否存在，其保存安定性良好，同時 爲具有水潤、無黏腻的使用感以及高軟化效果之美白化粧 -16 - 200920410 水。本實施例之黏度均爲3 (TC，1 0 m P a . s。本實施例之 乳化滴之平均粒子徑爲100〜250nm。 實施例1 2軟化效果美容液 (成分） （％) (1 )氫化大豆卵磷脂85 1 1.0 (2) 二月桂醯麩胺酸離胺酸鈉 0.2 (3) 甲基硬脂醯基牛磺酸鈉 〇.05 (4) 2-鯨蠟辛酸 2.0 (5) 羥基硬脂酸膽固醇 0.5 (6 )丙甘醇 3.0 (7 )甘油 3.0 (8 )純水 2 0.0 (9 )乳酸鈉 2.0 (10) 吡咯烷酮羧酸鈉 2.0 (11) 對羥基苯甲酸甲酯 適量 (1 2 )香料 適量 (13)乙醇 5.0 (1 4 )純水 餘量 (製造方法） A ·混合溶解1〜7。（ 7 (TC ) B. 加熱 8。（70°C ) C. 添加B至A並進行乳化。（70°C ) -17- 200920410 D. 將C冷卻至40°C。 E. 使用高壓乳化機將D進行分散。 F. 添加9〜14至E中。 實施例1 2中，無論做爲電解質美容成分之乳酸鈉及 吡咯烷酮羧酸鈉（保濕劑）是否存在，其保存安定性良好， 同時爲具有水潤、無黏腻的使用感以及高軟化效果之軟化 效果美容液。本實施例之黏度爲20mPa· s。本實施例之 乳化滴之平均粒子徑爲5 0〜2 5 Onm。 實施例1 3乳液 (成分） （％) (1) 氫化大豆卵磷脂* 1 !.〇 (2) 氫化大豆溶血磷脂 〇5 (3 )二月桂醯鍵胺酸離胺酸鈉 0.3 (4) 角鯊烷 (5) 微晶蠟 1() (6) 1,3 — 丁二醇 10.〇 ⑺们由 10.〇 (8) 純水 3()() (9) 甘草酸二鉀鹽 ^0 (1〇)ρΗ調整劑 適量 (Π)對羥基苯甲酸甲酯 適量 〇2)香料 適量 -18- 200920410 (13)純水 餘量 (製造方法） A_混合溶解1〜7。（70°C ) Β·加熱 8。（70°C ) C. 添加B至A並進行乳化。（70°C ) D. 將C冷卻至40°C。 E. 添加9〜13至D中。 實施例1 3中，無論做爲電解質之甘草酸二鉀鹽（消炎 劑）是否存在，其爲保存安定性良好，同時爲具有水潤、 無黏腻的使用感以及高軟化效果之乳液。本實施例之黏度 爲 25mPa · s。本實施例之乳化滴之平均粒子徑爲 40〜 2 8 0 nm。 實施例1 4防曬乳霜 (成分） （％) (1) 氫化大豆卵磷脂 0.5 (2) 二月桂醯麩胺酸離胺酸鈉 0.2 (3) 2-鯨鱲辛酸 2.0 (4) 二甲基環戊矽氧烷 3.0 (5) 對甲氧基苯丙烯酸-2-乙基己基酯 5.0 (6 )雙丙甘醇 丨〇 . 〇 (7 )甘油 3.0 -19- 200920410 (8) 羧基乙烯聚合物 (9) 純水 (10) 苯基苯並咪唑磺酸 (11) 三乙醇胺 (12) 對羥基苯甲酸甲酯 適量 (1 3 )香料 適量 (14)乙醇 5.0 (1 5 )純水 餘量 (製造方法） A _混合溶解1〜7。（ 7 0 °C ) B ·混合 8，9。（ 7 0 °C ) C. 添加B至A並進行乳化。（70t：) D. 將C冷卻至40°C。 E. 以微射流均質機將D進行分散。 F. 添加10〜15至E中。 實施例14中’無論做爲電解質美容液之苯基苯並咪 唑磺酸（紫外線吸收劑）是否存在，其爲保存安定性良好， 同時爲具有水潤、無黏腻的使用感以及高軟化效果之防曬 乳霜。本實施例之黏度爲1 OOmPa . s。本實施例之乳化滴 之平均粒子徑爲80〜200nm。 實施例1 5清潔乳霜 -20- 200920410 (成分） （％) (1 )氫化大豆卵磷脂& 1 2.0 (2)二月桂醯麩胺酸離胺酸鈉 〇.53 0 Onm is better. In this range, the milk coagulation is less likely to occur, and the stability is better. Further, the average particle diameter of the small vesicles was measured by C 0 U L T E R 200920410 N-4 type (manufactured by BECKMAN C O ULTER Co., Ltd.). ? The liquid cosmetic is preferably water-based emulsified cosmetic in order to obtain good storage stability, moisturizing, non-sticking feeling and softening effect. The liquid cosmetic of the present invention preferably has a conductivity of 25 ° C (measured by using a conductivity meter CM-60G manufactured by Shobo Industries Co., Ltd.) of C 4 S/m, more preferably 0.1 to 3 S/m. In this range, π exerts the moisturizing effect and whitening effect of the electrolyte beauty component effect, and maintains the stability of the system. The liquid form of the liquid cosmetic in the present invention means that the viscosity at 30 ° C is 1 to 20 〇〇 mpa by a Brooke H-type rotational viscometer. When the viscosity is in this range, a moist feeling of use can be obtained. The liquid cosmetic of the present invention is not limited to general skin makeup, and includes all liquid liquid cosmetics such as quasi drugs and pharmaceuticals, and the form thereof is limited, and can be selected depending on the purpose. For example, there may be mentioned forms such as a lotion, a lotion, a beauty lotion, a mask, a cleansing material, a makeup, and the like. [Embodiment] EXAMPLES Next, the present invention is applied in more detail to the examples and comparative examples, but the present invention is not limited thereto. Examples 1 to 10 and Comparative Examples 1 to 5 Liquid Cosmetics According to the production method described below, the following Table 1 and Invention: Made of Asia Electric. 0 5~ 'Full Ward S, No special emulsion gas gel description 2 -10 200920410 shows the composition of liquid cosmetics. For the evaluation items of (1) the degree of sensation of the household), (2) the softening effect, and (3) the preservation of the average particle diameter of the (5) emulsified droplets, the results are not shown in Table 1 and Table 2. Sense of sensation (degree of hydration, no stickiness: qualitative, (4) conductivity, evaluation by the following method -11 - 200920410 5 蜀om 1 Ο <Ν ο ο balance ◎ ◎ ◎ ◎ 0.652 100-200 〇 \^Ti 1 ίΤ) ο ο 1 ο ο balance rn y~* m ◎ ◎ 〇 ◎ 0.1962 1 1 50-250 | 00 1 W-) ο 1 ο ο balance mm ◎ ◎ ◎ 〇 1.45 1 50-250卜<n 1 w-ΐ ο 1 ο ο balance ο > _ _H ΠΊ ◎ 〇 ◎ 〇 3.76 50-250 in 1 ΚΤ) 2 (Ν ο ο balance ◎ ◎ ◎ ◎ 0.612 1 100-200 iul /n 〇1 0.025 , 1 ο ο balance « r < ◎ 〇〇〇0,62 Γ | 300-500 inch CN 1 (Ν Ο ιη ίΝ ο ο balance o >'t ◎ 〇◎ ◎ 0.582 100 -300 m 1 (Ν Ο 1 I ο ο balance < ◎ 〇 ◎ ◎ 0.558 50-150 (N 〇1 Ο κη CS 1 ο ο balance »« — 〇〇◎ 〇0.682 50-250 r » t— 1 1 CN Ο (Ν 1 ο ο , balance CN 〇 ◎ 〇〇 1 1 0.568 Γ | 100-300 Ingredients im soy lecithin ※1 l sodium stearate dilaurate glutamic acid sodium sulphate 3 -ethylhexanoic acid glycerol oleic acid phytosterol 氍11 Η ΓΟ 1 Glycerol pure water sodium lactate component (A): Ingredient (B) Evaluation item use sensation (degree of hydration) Sense of use (no stickiness) Softening effect Preservation stability (S/m) (25 ° C Average particle diameter (nm) dr· (N m inch 〇〇ο (N inch κη.9·9 _} dust' %soo-ps:窠od t (EtM^^^^swOI-socoaqli -12- 200920410 Table 2 Comparative Example No. Ingredient 1 2 3 4 5 1 Hydrogenated Soy Lecithin - 1 - 1.5 3 2 Sodium Stearate 2 - - 3 Aliuric Acid Sodium Succinate - 0.5 1 - 4 Triethyl 2-ethylhexanoate 10 10 10 10 10 5 oleic acid plant alcohol 2 2 2 2 2 6 1,3-butanediol 10 10 10 10 10 7 glycerol 10 10 10 10 10 8 pure water balance Amount of balance margin 9 Sodium lactate 1 1 1 2 3 Evaluation item 1 "Sense (degree of hydration) 〇〇〇〇〇 Sense of use (no stickiness) Δ 〇〇〇〇2 Softening effect Δ Δ Δ Δ Δ 3 Preservation stability XXX Δ Δ 4 Conductivity (S/m) (25t:) 0.578 0.577 0.552 0.512 0.535 5 Average particle diameter (nm) 400-500 100-250 100-300 250-350 250-350 (manufacture square Method) ί Α. Mix and dissolve 1~7. (70Τ:) B _ Strong heat 8. ( 7 0 〇C ) C . Add B to A and emulsifie. (7 0 °C) D. Cool C to 4 (TC. E. Disperse D using a microfluidizer. F · Add 9 to E. [Evaluation method] Evaluation items (1), (2) 20 women who have been wearing makeup for more than 10 years are evaluated according to (1) feeling of use (degree of hydration, degree of non-stickiness), and (2) evaluation of softening effect, using the fifth stage of benchmark A. Then, judge from the average point -13 - 200920410. (Baseline A) 5 points: Very good 4 points: Good 3 points: Normal 2 points: Not good 1 point: Very bad (decision) ◎: Average 4 · 5 points or more 〇: The average number is 3. 5 points or more is less than 4.5 points △: The average number is 2.5 points or more and less than 3. 5 points X: The average number is less than 2.5 points [Evaluation method] Evaluation item (3) Preservation stability The evaluation method was carried out by visually observing the state in which the liquid cosmetic shown in Table 1 was stored at 40 ° C for a certain period of time, and was evaluated according to the following criteria B. (Base B) No separation or emulsification was observed for 6 months. Phenomenon: ◎ No separation was found for 6 months but some emulsification was found: 分离 1 month found separation and emulsification phenomenon: △ -14 - 200920 410. Separation and emulsification were observed for one week: χ [Evaluation method] Evaluation item (4) The average particle diameter of the emulsified liquid of the liquid cosmetic shown in Table 1 was measured by COULTER N-4 (manufactured by BECKMAN COULTER Co., Ltd.). From the results of Tables 1 and 2, it is understood that the liquid cosmetic of the present invention has good preservation stability and is moist and non-sticky regardless of the presence of sodium lactate (humectant) as an electrolyte cosmetic component. A liquid cosmetic having a high softening effect, and a hydrogenated soy lecithin and sodium lauric acid glutamate sodium sulphate are used as an emulsifier in comparison with Comparative Example 1 The storage stability was extremely poor. In addition, in Comparative Example 2, which was not mixed with hydrogenated soybean lecithin, the stability was poor in the same manner, and the same was true for Comparative Example 4 without sodium lauric acid glutamate. In order to preserve poor stability, as in Comparative Examples 3 and 5, even if the amount of hydrogenated soybean lecithin or sodium lauric acid glutamate is doubled, it can hardly be changed by using it alone. The stability is preserved, and the effect of improving the stability by using these components is multiplied. The viscosity in the present example and the comparative example is 1 to 2000 mPa at 30 ° C. Example 1 1 Whitening Makeup Water (ingredients) (%) (1) Hydrogenated soy lecithin * 1 0.5 (2) Sodium glutamate glutamate sodium amide 0.1 -15- 200920410 (3) 2-Cetyl octanoic acid 2 〇 (4) Dipentaerythritol 12-hydroxy fatty acid/stearonic acid/rosinate 〇.05 (5) Stearic acid 0.05 (6) Dipropylene glycol 2. 〇(7) glycerol 3.0 (8) Pure water 1 〇.〇(9) L - Ascorbyl-2-phosphate magnesium 3. 〇 (10) Sodium citrate 1.0 (1 1) Methylparaben (1 2) Proper amount (13) Ethanol 10.0 (14) Pure water balance (manufacturing method) A. Mix and dissolve 1~7. ( 7 0 °C) B. Heating 8. (7〇t) C. Add B to A and emulsifie. (7 ° ° C) D. Cool C to 40 ° C. E. Disperse D using a high pressure homogenizer. F. Add 9~14 to E. In Example 11, whether or not L-ascorbic acid-2-magnesium phosphate (whitening agent) is present as an electrolyte cosmetic component, its storage stability is good, and at the same time, it has a moisturizing, non-sticky feeling of use and a high softening effect. Whitening Makeup-16 - 200920410 Water. The viscosity of this example is 3 (TC, 10 m P a. s. The average particle diameter of the emulsified droplets of this embodiment is 100 to 250 nm. Example 1 2 Softening effect beauty liquid (ingredient) (%) (1 ) Hydrogenated Soy Lecithin 85 1 1.0 (2) Sodium Bismuth Sodium Succinate 0.2 (3) Sodium Methyl Stearate Sodium Taurate 〇.05 (4) 2-Cetyl Octanoic Acid 2.0 (5) Hydroxystearic acid cholesterol 0.5 (6 ) propylene glycol 3.0 (7 ) glycerol 3.0 (8 ) pure water 2 0.0 (9) sodium lactate 2.0 (10) sodium pyrrolidone carboxylate 2.0 (11) methyl p-hydroxybenzoate (1 2) Proper amount of spices (13) Ethanol 5.0 (1 4 ) Pure water balance (manufacturing method) A · Mix and dissolve 1 to 7. (7 (TC) B. Heat 8. (70 ° C) C. Add B to A And emulsified. (70 ° C) -17- 200920410 D. Cool C to 40 ° C. E. Disperse D using a high-pressure emulsifier F. Add 9 to 14 to E. In Example 1 2, Whether it is sodium lactate or sodium pyrrolidone carboxylate (humectant) as an electrolyte beauty ingredient, it has good preservation stability, and is a moisturizing effect beauty liquid with moisturizing, non-sticky feeling and high softening effect. The viscosity of this embodiment is 20 mPa·s. The average particle diameter of the emulsified droplets of this embodiment is 50 to 25 Onm. Example 1 3 Emulsion (ingredient) (%) (1) Hydrogenated soybean lecithin * 1 !. 〇(2) hydrogenated soy lysophospholipid 〇5 (3) sodium laurate sodium sulphate 0.3 (4) squalane (5) microcrystalline wax 1 () (6) 1,3 - butanediol 10 〇(7) by 10.〇(8) pure water 3()() (9) dipotassium glycyrrhizinate ^0 (1〇)ρΗ adjuster appropriate amount (Π) p-hydroxybenzoic acid methyl ester 〇 2) spices Appropriate amount -18- 200920410 (13) Pure water balance (manufacturing method) A_ Mixing and dissolving 1 to 7. (70 ° C) Β · Heating 8. (70 ° C) C. Add B to A and emulsify. 70 ° C) D. C is cooled to 40 ° C. E. Add 9 to 13 to D. In Example 1 3, whether or not the dipotassium glycyrrhizinate (anti-inflammatory agent) is present as an electrolyte, it is preserved It has good stability and is a moisturizing, non-sticky feeling of use and a high softening effect. The viscosity of this embodiment is 25 mPa · s. The average particle diameter of the emulsified droplet of this embodiment is 40 to 2 80 nm. Example 1 4 sunscreen cream (ingredients) (% (1) Hydrogenated Soy Lecithin 0.5 (2) Sodium Bismuth Sodium Citrate 0.2 (3) 2-Whale octanoic acid 2.0 (4) Dimethylcyclopentaoxane 3.0 (5) Dimethoxy 2-ethylhexyl phenyl acrylate 5.0 (6 ) dipropylene glycol oxime. 〇 (7 ) glycerol 3.0 -19- 200920410 (8) carboxyvinyl polymer (9) pure water (10) phenyl benzo Imidazole sulfonic acid (11) Triethanolamine (12) Methylparaben (1 3 ) Proper amount (14) Ethanol 5.0 (1 5 ) Pure water balance (manufacturing method) A _ mixed and dissolved 1 to 7. ( 7 0 °C) B · Mix 8,9. (70 ° C) C. Add B to A and emulsifie. (70t:) D. Cool C to 40 °C. E. Disperse D with a microfluidizer. F. Add 10~15 to E. In Example 14, 'whether or not the phenyl benzimidazole sulfonic acid (ultraviolet absorber) is present as an electrolyte cosmetic liquid, it has good preservation stability, and has a moisturizing, non-sticky feeling of use and a high softening effect. Sunscreen lotion. The viscosity of this embodiment is 100 MPa. The emulsified droplets of this example have an average particle diameter of 80 to 200 nm. Example 1 5 Cleansing Cream -20- 200920410 (Ingredients) (%) (1) Hydrogenated Soy Lecithin & 1 2.0 (2) Sodium Bismuth Sodium Citrate Sodium Hydrate 〇.5
(3 )流動石蠟 HO (4) 二甲基環戊矽氧烷 5.0 (5) 1，3 — 丁二醇 1〇.〇 (6) 甘油 5.0 (7 )純水 3 0.0 (8) N-乙醯-L-谷胺酸 〇.5 (9) L-絲胺酸 〇.5 (10) 對羥基苯甲酸甲酯 適量 (1 1 )香料 滴量 (12) 乙醇 1〇.〇 (13) 黄原膠 〇5 (1 4 )純水 餘量 (製造方法） A ·混合溶解1〜6。（ 7 Ot ) B 混合 7，1 3。（ 7 0 °C ) C.添加B至A並進行乳化。（70°C ) D .將C冷卻至4 0 °C。 E.添加8〜12，14至D中。 實施例1 5中無論做爲電解質美容液之N -乙醯-L -谷胺 -21 - 200920410 酸，L -絲胺酸（保濕劑）是否存在，其爲保存安定性良好， 同時爲具有水潤、無黏腻的使用感以及高軟化效果之清潔 乳霜。本實施例之黏度爲1 5 00mPa s。本實施例之乳化 滴之平均粒子徑爲50〜250nm。 本發明之液狀化粧料’無論有無搭配電解質美容成分 ，因可抑制小囊泡之凝集·結合以及乳化作用，而爲保存 安定性良好，同時爲具有良好水潤、無黏腻的使用感進而 爲具高軟化效果者。因此其爲極適用於美白等各種用途之 化粧料。 -22-(3) Mobile paraffin HO (4) Dimethylcyclopentaoxane 5.0 (5) 1,3 - Butanediol 1〇.〇(6) Glycerin 5.0 (7) Pure water 3 0.0 (8) N-B醯-L-glutamate.5 (9) L-Leserinate.5 (10) Methylparaben (1 1 ) Fragrance (12) Ethanol 1〇.〇(13) Yellow Raw rubber 〇 5 (1 4 ) Pure water balance (manufacturing method) A · Mix and dissolve 1 to 6. ( 7 Ot ) B Mix 7,1 3. (70 ° C) C. Add B to A and emulsifie. (70 ° C) D. Cool C to 40 °C. E. Add 8~12, 14 to D. Example 1 Whether N-acetam-L-glutamine-21 - 200920410 acid as an electrolyte beauty liquid, L-serine (humectant) is present, which has good preservation stability and has water A clean, non-sticky, cleansing cream with a high softening effect. The viscosity of this embodiment is 1 500 mPa s. The emulsified droplets of this example have an average particle diameter of 50 to 250 nm. The liquid cosmetic of the present invention is capable of inhibiting agglutination, binding and emulsification of small vesicles regardless of the presence or absence of an electrolyte cosmetic component, and is excellent in preservation stability and has a good moisturizing and non-sticky feeling of use. For those with high softening effect. Therefore, it is a cosmetic material which is extremely suitable for various uses such as whitening. -twenty two-