SA518400731B1 - عملية لتحويل ميثان إلى بروبانال - Google Patents
عملية لتحويل ميثان إلى بروبانالInfo
- Publication number
- SA518400731B1 SA518400731B1 SA518400731A SA518400731A SA518400731B1 SA 518400731 B1 SA518400731 B1 SA 518400731B1 SA 518400731 A SA518400731 A SA 518400731A SA 518400731 A SA518400731 A SA 518400731A SA 518400731 B1 SA518400731 B1 SA 518400731B1
- Authority
- SA
- Saudi Arabia
- Prior art keywords
- reactor
- syngas
- propanal
- water
- feeding
- Prior art date
Links
- NBBJYMSMWIIQGU-UHFFFAOYSA-N Propionic aldehyde Chemical compound CCC=O NBBJYMSMWIIQGU-UHFFFAOYSA-N 0.000 title abstract 6
- 238000006243 chemical reaction Methods 0.000 title abstract 4
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 title abstract 4
- 238000000034 method Methods 0.000 title abstract 3
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 abstract 6
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 abstract 4
- 239000005977 Ethylene Substances 0.000 abstract 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 4
- 229910002092 carbon dioxide Inorganic materials 0.000 abstract 3
- 239000001569 carbon dioxide Substances 0.000 abstract 3
- OTMSDBZUPAUEDD-UHFFFAOYSA-N Ethane Chemical compound CC OTMSDBZUPAUEDD-UHFFFAOYSA-N 0.000 abstract 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 abstract 1
- 239000003054 catalyst Substances 0.000 abstract 1
- 239000007789 gas Substances 0.000 abstract 1
- 238000010574 gas phase reaction Methods 0.000 abstract 1
- 238000005691 oxidative coupling reaction Methods 0.000 abstract 1
- 229910052760 oxygen Inorganic materials 0.000 abstract 1
- 239000001301 oxygen Substances 0.000 abstract 1
- 239000000376 reactant Substances 0.000 abstract 1
Classifications
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
- C07C45/49—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide
- C07C45/50—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide by oxo-reactions
- C07C45/505—Asymmetric hydroformylation
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J6/00—Heat treatments such as Calcining; Fusing ; Pyrolysis
- B01J6/008—Pyrolysis reactions
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
- C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
- C01B3/06—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of inorganic compounds containing electro-positively bound hydrogen, e.g. water, acids, bases, ammonia, with inorganic reducing agents
- C01B3/12—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of inorganic compounds containing electro-positively bound hydrogen, e.g. water, acids, bases, ammonia, with inorganic reducing agents by reaction of water vapour with carbon monoxide
- C01B3/16—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of inorganic compounds containing electro-positively bound hydrogen, e.g. water, acids, bases, ammonia, with inorganic reducing agents by reaction of water vapour with carbon monoxide using catalysts
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
- C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
- C01B3/32—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
- C01B3/34—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents
- C01B3/36—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using oxygen or mixtures containing oxygen as gasifying agents
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
- C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
- C01B3/32—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
- C01B3/34—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents
- C01B3/48—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents followed by reaction of water vapour with carbon monoxide
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C11/00—Aliphatic unsaturated hydrocarbons
- C07C11/02—Alkenes
- C07C11/04—Ethylene
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
- C07C2/76—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by condensation of hydrocarbons with partial elimination of hydrogen
- C07C2/82—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by condensation of hydrocarbons with partial elimination of hydrogen oxidative coupling
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
- C07C2/76—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by condensation of hydrocarbons with partial elimination of hydrogen
- C07C2/82—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by condensation of hydrocarbons with partial elimination of hydrogen oxidative coupling
- C07C2/84—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by condensation of hydrocarbons with partial elimination of hydrogen oxidative coupling catalytic
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
- C07C45/49—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide
- C07C45/50—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide by oxo-reactions
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C47/00—Compounds having —CHO groups
- C07C47/02—Saturated compounds having —CHO groups bound to acyclic carbon atoms or to hydrogen
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
- C07C5/32—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with formation of free hydrogen
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
- C07C5/32—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with formation of free hydrogen
- C07C5/327—Formation of non-aromatic carbon-to-carbon double bonds only
- C07C5/333—Catalytic processes
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/02—Processes for making hydrogen or synthesis gas
- C01B2203/0283—Processes for making hydrogen or synthesis gas containing a CO-shift step, i.e. a water gas shift step
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/06—Integration with other chemical processes
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Health & Medical Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Combustion & Propulsion (AREA)
- Inorganic Chemistry (AREA)
- Physics & Mathematics (AREA)
- Thermal Sciences (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Abstract
يتعلّق الاختراع الحالي بتوفير طرق لتحضير بروبانال propanal في تفاعل يشتمل على الاقتران الأكسيدي للميثان oxidative coupling of methane OCM والأكسجين oxygen كتيار متفاعل reactant stream في تفاعل طور غاز gas phase reaction، على نحو مفضل في وجود الماء أو البخار steam، لتكوين الإيثيلين ethylene، والإيثان ethane، وثاني أكسيد الكربون carbon dioxide CO2، والماء وغاز التخليق syngas (أول أكسيد الكربون carbon monoxide CO وهيدروجين hydrogen H2) في مفاعل أول كتيار إيثيلين ethylene، ثم تكوين بروبانال propanal في مفاعل ثاني بالتغذية بتيار الإيثيلين ethylene إلى المفاعل الثاني مع غاز التخليق من المفاعل الأول في طور الغاز ومعالجة بهيدروفورميل hydroformylating في وجود محفز catalyst لتفاعل إزاحة الماء. في الطريقة، يتم الحفاظ على نسبة هيدروجين hydrogen H2 إلى أول أكسيد الكربون carbon monoxide CO في غاز التخليق إما عن طريق التغذية المشتركة بالبخار إلى المفاعل الأول أو المفاعل الثاني لإنتاج المزيد من هيدروجين hydrogen H2 في غاز التخليق، أو عن طريق تكوين أول أكسيد الكربون carbon monoxide CO في المفاعل الثاني
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US201662356786P | 2016-06-30 | 2016-06-30 | |
| PCT/US2017/037159 WO2018005074A1 (en) | 2016-06-30 | 2017-06-13 | Process for the conversion of methane into propanal |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| SA518400731B1 true SA518400731B1 (ar) | 2021-12-12 |
Family
ID=59216020
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| SA518400731A SA518400731B1 (ar) | 2016-06-30 | 2018-12-23 | عملية لتحويل ميثان إلى بروبانال |
Country Status (11)
| Country | Link |
|---|---|
| US (1) | US10519087B2 (ar) |
| EP (1) | EP3478631B1 (ar) |
| JP (1) | JP6920023B2 (ar) |
| KR (1) | KR102379397B1 (ar) |
| CN (1) | CN109311666B (ar) |
| BR (1) | BR112018075821B1 (ar) |
| CA (1) | CA3029396A1 (ar) |
| MX (1) | MX2018015552A (ar) |
| SA (1) | SA518400731B1 (ar) |
| SG (1) | SG11201811444YA (ar) |
| WO (1) | WO2018005074A1 (ar) |
Families Citing this family (19)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US10519087B2 (en) | 2016-06-30 | 2019-12-31 | Dow Global Technologies Llc | Process for the conversion of methane into propanal |
| WO2020242924A1 (en) * | 2019-05-24 | 2020-12-03 | Eastman Chemical Company | Recycle content propionaldehyde |
| US12031091B2 (en) | 2019-05-24 | 2024-07-09 | Eastman Chemical Company | Recycle content cracked effluent |
| EP3976732A4 (en) | 2019-05-24 | 2023-05-17 | Eastman Chemical Company | Blend small amounts of pyoil into a liquid stream processed into a gas cracker |
| US11365357B2 (en) | 2019-05-24 | 2022-06-21 | Eastman Chemical Company | Cracking C8+ fraction of pyoil |
| DE102019119543A1 (de) * | 2019-07-18 | 2021-01-21 | Linde Gmbh | Verfahren und Anlage zur Herstellung einer Zielverbindung |
| DE102019119562A1 (de) * | 2019-07-18 | 2021-01-21 | Linde Gmbh | Verfahren und Anlage zur Herstellung einer Zielverbindung |
| DE102019119540A1 (de) * | 2019-07-18 | 2021-01-21 | Linde Gmbh | Verfahren und Anlage zur Herstellung einer Zielverbindung |
| EP4003948A4 (en) | 2019-07-29 | 2023-09-06 | Eastman Chemical Company | CHANNEL WITH RECYCLED CONTENT (C4) |
| US11945998B2 (en) | 2019-10-31 | 2024-04-02 | Eastman Chemical Company | Processes and systems for making recycle content hydrocarbons |
| US11319262B2 (en) | 2019-10-31 | 2022-05-03 | Eastman Chemical Company | Processes and systems for making recycle content hydrocarbons |
| KR20220091549A (ko) | 2019-10-31 | 2022-06-30 | 이스트만 케미칼 컴파니 | 재활용된 폐기물을 위한 열분해 방법 및 시스템 |
| WO2021092309A1 (en) * | 2019-11-07 | 2021-05-14 | Eastman Chemical Company | Recycle content propanol |
| US12104121B2 (en) | 2019-11-07 | 2024-10-01 | Eastman Chemical Company | Recycle content mixed esters and solvents |
| KR20220093368A (ko) | 2019-11-07 | 2022-07-05 | 이스트만 케미칼 컴파니 | 재활용물 알파 올레핀 및 지방 알코올 |
| EP3922621B1 (de) | 2020-06-10 | 2023-08-30 | Linde GmbH | Prozess zur herstellung von propylen |
| EP4015495A1 (de) | 2020-12-18 | 2022-06-22 | Linde GmbH | Verfahren und anlage zur herstellung einer zielverbindung |
| KR102536935B1 (ko) * | 2020-12-31 | 2023-05-26 | 주식회사 카카오 | 사용자 프로필 관리 방법 및 장치 |
| US12195674B2 (en) | 2021-09-21 | 2025-01-14 | Eastman Chemical Company | Using spent caustic solution from pygas treatment to neutralize halogens from liquified waste plastic |
Family Cites Families (16)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| AU4536396A (en) | 1995-01-18 | 1996-08-07 | Exxon Chemical Patents Inc. | Oxygenates and processes for their manufacture |
| ATE240924T1 (de) * | 1996-04-01 | 2003-06-15 | Union Carbide Chem Plastic | Verfahren zur herstellung von methylmercatopropanal |
| CN1298859A (zh) * | 1999-12-09 | 2001-06-13 | 中国科学院成都有机化学研究所 | 一种天然气旋焰乙炔炉余热喷油产混合气的使用方法 |
| CN100551884C (zh) * | 2005-12-02 | 2009-10-21 | 四川大学 | 一种由甲烷氧化偶联和气相氧化耦合制取丙醛原料的方法 |
| WO2010133461A1 (de) * | 2009-05-20 | 2010-11-25 | Basf Se | Anlage und verfahren zur herstellung von höherwertigen kohlenwasserstoffen aus methan |
| EP2499111B1 (en) | 2009-11-11 | 2018-07-04 | Dow Global Technologies LLC | Reductive hydroformylation of an alkylene to an alkanol |
| DE102010030209A1 (de) | 2010-06-17 | 2011-12-22 | Evonik Oxeno Gmbh | Energieeffiziente Synthese von aliphatischen Adelhyden aus Alkanen und Kohlendioxid |
| CN102442894B (zh) * | 2010-09-30 | 2014-08-06 | 中国石油化工股份有限公司 | 一种利用炼厂干气中乙烯制备丙醛的方法 |
| CA2828727A1 (en) | 2011-03-02 | 2012-09-07 | Mark Allen Nunley | Methods for integrated natural gas purification and products produced therefrom |
| WO2013098272A1 (en) | 2011-12-27 | 2013-07-04 | Shell Internationale Research Maatschappij B.V. | Process for the production of alcohols |
| US9598328B2 (en) | 2012-12-07 | 2017-03-21 | Siluria Technologies, Inc. | Integrated processes and systems for conversion of methane to multiple higher hydrocarbon products |
| CA2902192C (en) | 2013-03-15 | 2021-12-07 | Siluria Technologies, Inc. | Catalysts for petrochemical catalysis |
| KR102293168B1 (ko) | 2013-09-30 | 2021-08-24 | 다우 글로벌 테크놀로지스 엘엘씨 | 알킬 알카노에이트의 기상 제조 |
| CN105517978B (zh) | 2013-10-16 | 2017-11-14 | 沙特基础工业公司 | 将甲烷转化成乙烯的方法 |
| KR101914520B1 (ko) | 2013-11-29 | 2018-11-05 | 디아이씨 가부시끼가이샤 | 중합성 화합물, 조성물, 중합체, 광학 이방체, 액정 표시 소자 및 유기 ｅｌ 소자 |
| US10519087B2 (en) | 2016-06-30 | 2019-12-31 | Dow Global Technologies Llc | Process for the conversion of methane into propanal |
-
2017
- 2017-06-13 US US16/304,469 patent/US10519087B2/en active Active
- 2017-06-13 WO PCT/US2017/037159 patent/WO2018005074A1/en unknown
- 2017-06-13 SG SG11201811444YA patent/SG11201811444YA/en unknown
- 2017-06-13 EP EP17733247.5A patent/EP3478631B1/en active Active
- 2017-06-13 JP JP2018565774A patent/JP6920023B2/ja active Active
- 2017-06-13 MX MX2018015552A patent/MX2018015552A/es unknown
- 2017-06-13 CN CN201780039024.XA patent/CN109311666B/zh active Active
- 2017-06-13 CA CA3029396A patent/CA3029396A1/en active Pending
- 2017-06-13 KR KR1020197001767A patent/KR102379397B1/ko active Active
- 2017-06-13 BR BR112018075821-3A patent/BR112018075821B1/pt active IP Right Grant
-
2018
- 2018-12-23 SA SA518400731A patent/SA518400731B1/ar unknown
Also Published As
| Publication number | Publication date |
|---|---|
| CN109311666A (zh) | 2019-02-05 |
| JP2019519547A (ja) | 2019-07-11 |
| CA3029396A1 (en) | 2018-01-04 |
| JP6920023B2 (ja) | 2021-08-18 |
| CN109311666B (zh) | 2022-07-19 |
| EP3478631A1 (en) | 2019-05-08 |
| MX2018015552A (es) | 2019-06-06 |
| EP3478631B1 (en) | 2020-04-22 |
| US20190292122A1 (en) | 2019-09-26 |
| US10519087B2 (en) | 2019-12-31 |
| BR112018075821B1 (pt) | 2022-11-16 |
| BR112018075821A2 (pt) | 2019-03-26 |
| WO2018005074A1 (en) | 2018-01-04 |
| KR102379397B1 (ko) | 2022-03-28 |
| SG11201811444YA (en) | 2019-01-30 |
| KR20190024967A (ko) | 2019-03-08 |
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