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EA201291479A1 - Способ получения синтез-газа - Google Patents

Способ получения синтез-газа

Info

Publication number
EA201291479A1
EA201291479A1 EA201291479A EA201291479A EA201291479A1 EA 201291479 A1 EA201291479 A1 EA 201291479A1 EA 201291479 A EA201291479 A EA 201291479A EA 201291479 A EA201291479 A EA 201291479A EA 201291479 A1 EA201291479 A1 EA 201291479A1
Authority
EA
Eurasian Patent Office
Prior art keywords
synthesis gas
hydrocarbon feedstock
produce
hydrogenated hydrocarbon
convertible
Prior art date
Application number
EA201291479A
Other languages
English (en)
Other versions
EA022261B1 (ru
Inventor
Ким Аасберг-Петерсен
Поль Эрик Хёйлунд Нильсен
Петер Сайер Кристенсен
Шарлотте Стуб Нильсен
Бурчин Темель
Original Assignee
Хальдор Топсёэ А/С
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Хальдор Топсёэ А/С filed Critical Хальдор Топсёэ А/С
Publication of EA201291479A1 publication Critical patent/EA201291479A1/ru
Publication of EA022261B1 publication Critical patent/EA022261B1/ru

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
    • C01B3/32—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
    • C01B3/34—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents
    • C01B3/48—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents followed by reaction of water vapour with carbon monoxide
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
    • C01B3/06—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of inorganic compounds containing electro-positively bound hydrogen, e.g. water, acids, bases, ammonia, with inorganic reducing agents
    • C01B3/12—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of inorganic compounds containing electro-positively bound hydrogen, e.g. water, acids, bases, ammonia, with inorganic reducing agents by reaction of water vapour with carbon monoxide
    • C01B3/16—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of inorganic compounds containing electro-positively bound hydrogen, e.g. water, acids, bases, ammonia, with inorganic reducing agents by reaction of water vapour with carbon monoxide using catalysts
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
    • C01B3/32—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
    • C01B3/34—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents
    • C01B3/36—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using oxygen or mixtures containing oxygen as gasifying agents
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
    • C01B3/32—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
    • C01B3/34—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents
    • C01B3/38—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using catalysts
    • C01B3/382—Multi-step processes
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
    • C01B3/32—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
    • C01B3/34—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents
    • C01B3/38—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using catalysts
    • C01B3/386—Catalytic partial combustion
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2/00—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon
    • C10G2/30—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen
    • C10G2/32—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/02—Processes for making hydrogen or synthesis gas
    • C01B2203/0205—Processes for making hydrogen or synthesis gas containing a reforming step
    • C01B2203/0227—Processes for making hydrogen or synthesis gas containing a reforming step containing a catalytic reforming step
    • C01B2203/0244—Processes for making hydrogen or synthesis gas containing a reforming step containing a catalytic reforming step the reforming step being an autothermal reforming step, e.g. secondary reforming processes
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/02—Processes for making hydrogen or synthesis gas
    • C01B2203/025—Processes for making hydrogen or synthesis gas containing a partial oxidation step
    • C01B2203/0255—Processes for making hydrogen or synthesis gas containing a partial oxidation step containing a non-catalytic partial oxidation step
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/02—Processes for making hydrogen or synthesis gas
    • C01B2203/025—Processes for making hydrogen or synthesis gas containing a partial oxidation step
    • C01B2203/0261—Processes for making hydrogen or synthesis gas containing a partial oxidation step containing a catalytic partial oxidation step [CPO]
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/02—Processes for making hydrogen or synthesis gas
    • C01B2203/0283—Processes for making hydrogen or synthesis gas containing a CO-shift step, i.e. a water gas shift step
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/06—Integration with other chemical processes
    • C01B2203/062—Hydrocarbon production, e.g. Fischer-Tropsch process
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/12—Feeding the process for making hydrogen or synthesis gas
    • C01B2203/1258—Pre-treatment of the feed
    • C01B2203/1264—Catalytic pre-treatment of the feed
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/10—Feedstock materials
    • C10G2300/1022—Fischer-Tropsch products
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/80—Additives
    • C10G2300/805—Water
    • C10G2300/807—Steam
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2400/00—Products obtained by processes covered by groups C10G9/00 - C10G69/14
    • C10G2400/02—Gasoline

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Combustion & Propulsion (AREA)
  • Inorganic Chemistry (AREA)
  • General Health & Medical Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • General Chemical & Material Sciences (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

Способ получения синтез-газа из, по существу, сухого углеводородного сырья, содержащего олефины, водород и оксид углерода, включающий следующие стадии: (а) селективную гидрогенизацию олефинов в углеводородном сырье при температуре от 60 до 190°С для получения гидрогенизованного углеводородного сырья, содержащего водород, оксид углерода и насыщенные углеводороды; (b) добавление пара в гидрогенизованное углеводородное сырье; (с) проведение реакции сдвига вода-газ при наличии пара на гидрогенизованном углеводородном сырье для получения конверсивной гидрогенизованной углеводородной смеси; (d) преобразование конверсивной гидрогенизованной углеводородной смеси для получения синтез-газа.
EA201291479A 2010-06-01 2011-05-13 Способ получения синтез-газа EA022261B1 (ru)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DKPA201000474A DK201000474A (en) 2010-06-01 2010-06-01 Process for the preparation of synthesis gas
PCT/EP2011/002378 WO2011151012A1 (en) 2010-06-01 2011-05-13 Process for the preparation of synthesis gas

Publications (2)

Publication Number Publication Date
EA201291479A1 true EA201291479A1 (ru) 2013-04-30
EA022261B1 EA022261B1 (ru) 2015-11-30

Family

ID=44303360

Family Applications (1)

Application Number Title Priority Date Filing Date
EA201291479A EA022261B1 (ru) 2010-06-01 2011-05-13 Способ получения синтез-газа

Country Status (11)

Country Link
US (1) US8765019B2 (ru)
CN (1) CN103189307B (ru)
AR (1) AR081347A1 (ru)
AU (1) AU2011260624B2 (ru)
BR (1) BR112012030714B1 (ru)
CA (1) CA2800832C (ru)
DK (1) DK201000474A (ru)
EA (1) EA022261B1 (ru)
MX (1) MX2012013556A (ru)
WO (1) WO2011151012A1 (ru)
ZA (1) ZA201208672B (ru)

Families Citing this family (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2014056535A1 (en) * 2012-10-11 2014-04-17 Haldor Topsøe A/S Process for the production of synthesis gas
GB201303723D0 (en) * 2013-03-01 2013-04-17 Johnson Matthey Plc Process for treating gas mixtures
EP3166885B1 (en) 2014-07-09 2020-05-06 Haldor Topsøe A/S Process for producing hydrogen
CN107001034A (zh) * 2014-12-01 2017-08-01 托普索公司 用于消除氨装置中的挥发性有机化合物和有害空气污染物的方法
US9545619B2 (en) 2014-12-04 2017-01-17 Clariant Corporation Catalyst materials for hydrogenating olefins and shifting carbon monoxide
CN114746170A (zh) 2019-12-04 2022-07-12 托普索公司 电加热的一氧化碳反应器
EP3889105B1 (de) * 2020-04-02 2022-12-14 L'air Liquide, Société Anonyme Pour L'Étude Et L'exploitation Des Procédés Georges Claude Verfahren und anlage zum herstellen eines wasserstoff und kohlenoxide enthaltenden synthesegasprodukts
CN114075461A (zh) * 2020-08-12 2022-02-22 山西潞安煤基清洁能源有限责任公司 一种低氢高碳富甲烷气的处理利用工艺及系统
AU2022213780A1 (en) 2021-01-27 2023-07-06 Topsoe A/S Synthesis gas production from co2 and steam for synthesis of fuels
CN113501491B (zh) * 2021-07-20 2022-11-22 广东博大新能源科技有限公司 一种二氧化碳低温常压转化获得合成气的方法

Family Cites Families (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DK148882C (da) * 1979-01-18 1986-05-26 Haldor Topsoe As Fremgangsmaade og anlaeg til fremstilling af syntesegas
NO311081B1 (no) * 1999-12-09 2001-10-08 Norske Stats Oljeselskap Optimalisert FT-syntese ved reformering og resirkulering av tail-gass fra FT-syntesen
US20030083390A1 (en) 2001-10-23 2003-05-01 Shah Lalit S. Fischer-tropsch tail-gas utilization
AU2002255950A1 (en) 2002-03-27 2003-10-13 Rentech, Inc. Fischer-tropsch synthesis using industrial process off gas feedstreams
EP1413547A1 (en) * 2002-09-26 2004-04-28 Haldor Topsoe A/S Process for the production of synthesis gas
ITMI20031739A1 (it) * 2003-09-11 2005-03-12 Enitecnologie Spa Procedimento di ossidazione parziale catalitica per
WO2006056594A1 (en) 2004-11-26 2006-06-01 Shell Internationale Research Maatschappij B.V. Method for treatment of a gas
AU2006257650B2 (en) * 2005-06-14 2011-06-16 Haldor Topsoe A/S Process for the preparation and conversion of synthesis gas
EP1860063A1 (en) 2006-05-22 2007-11-28 Shell Internationale Researchmaatschappij B.V. Process for preparing a paraffin product
US20080237090A1 (en) * 2007-03-30 2008-10-02 Nicholas Musich Process and system for redcuing the olefin content of a hydrocarbon feed gas and production of a hydrogen-enriched gas therefrom
US7850944B2 (en) * 2008-03-17 2010-12-14 Air Products And Chemicals, Inc. Steam-hydrocarbon reforming method with limited steam export
US8664459B2 (en) * 2008-03-31 2014-03-04 Air Products And Chemicals, Inc. Process for hydrogenating olefins

Also Published As

Publication number Publication date
CA2800832A1 (en) 2011-12-08
EA022261B1 (ru) 2015-11-30
US20130082211A1 (en) 2013-04-04
ZA201208672B (en) 2014-01-29
CN103189307A (zh) 2013-07-03
DK201000474A (en) 2011-12-02
BR112012030714A2 (pt) 2016-11-08
AU2011260624B2 (en) 2013-08-01
CN103189307B (zh) 2016-01-20
AU2011260624A1 (en) 2012-12-20
MX2012013556A (es) 2013-01-24
BR112012030714B1 (pt) 2019-12-10
AR081347A1 (es) 2012-08-08
WO2011151012A1 (en) 2011-12-08
US8765019B2 (en) 2014-07-01
CA2800832C (en) 2018-06-19

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