RU2015142848A - Гибридные водные дисперсии, композиционные латексные эмульсии сополимера (поли)этилена и (мет)акриловой кислоты, гибридные органосилановые композиционные латексные эмульсии сополимера (поли)этилена и (мет)акриловой кислоты и полученные из них композиции для покрытия - Google Patents
Гибридные водные дисперсии, композиционные латексные эмульсии сополимера (поли)этилена и (мет)акриловой кислоты, гибридные органосилановые композиционные латексные эмульсии сополимера (поли)этилена и (мет)акриловой кислоты и полученные из них композиции для покрытия Download PDFInfo
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- ethylene
- acrylic acid
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- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 title claims 18
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 title claims 17
- 239000005977 Ethylene Substances 0.000 title claims 17
- 239000004816 latex Substances 0.000 title claims 17
- 239000002131 composite material Substances 0.000 title claims 16
- 239000000839 emulsion Substances 0.000 title claims 14
- 239000000203 mixture Substances 0.000 title claims 6
- 150000001282 organosilanes Chemical class 0.000 title claims 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 title claims 2
- 229910001868 water Inorganic materials 0.000 title claims 2
- 239000006185 dispersion Substances 0.000 title 1
- 229920001577 copolymer Polymers 0.000 claims 16
- 229920000126 latex Polymers 0.000 claims 15
- -1 organosilane compound Chemical class 0.000 claims 10
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 claims 9
- 239000000178 monomer Substances 0.000 claims 7
- 239000011541 reaction mixture Substances 0.000 claims 5
- LYCAIKOWRPUZTN-UHFFFAOYSA-N ethylene glycol Natural products OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims 4
- 229920002554 vinyl polymer Polymers 0.000 claims 4
- CDNRJNMBEAKKLM-UHFFFAOYSA-N bis(ethenyl)tin Chemical compound C=C[Sn]C=C CDNRJNMBEAKKLM-UHFFFAOYSA-N 0.000 claims 3
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 claims 3
- PUPZLCDOIYMWBV-UHFFFAOYSA-N (+/-)-1,3-Butanediol Chemical compound CC(O)CCO PUPZLCDOIYMWBV-UHFFFAOYSA-N 0.000 claims 2
- MYRTYDVEIRVNKP-UHFFFAOYSA-N 1,2-Divinylbenzene Chemical compound C=CC1=CC=CC=C1C=C MYRTYDVEIRVNKP-UHFFFAOYSA-N 0.000 claims 2
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims 2
- 239000003795 chemical substances by application Substances 0.000 claims 2
- 239000011248 coating agent Substances 0.000 claims 2
- 239000008199 coating composition Substances 0.000 claims 2
- 238000000576 coating method Methods 0.000 claims 2
- 239000003431 cross linking reagent Substances 0.000 claims 2
- 239000012802 nanoclay Substances 0.000 claims 2
- 230000003472 neutralizing effect Effects 0.000 claims 2
- 229920001568 phenolic resin Polymers 0.000 claims 2
- 239000000758 substrate Substances 0.000 claims 2
- 229940058015 1,3-butylene glycol Drugs 0.000 claims 1
- KXGFMDJXCMQABM-UHFFFAOYSA-N 2-methoxy-6-methylphenol Chemical compound [CH]OC1=CC=CC([CH])=C1O KXGFMDJXCMQABM-UHFFFAOYSA-N 0.000 claims 1
- 125000003903 2-propenyl group Chemical group [H]C([*])([H])C([H])=C([H])[H] 0.000 claims 1
- XDLMVUHYZWKMMD-UHFFFAOYSA-N 3-trimethoxysilylpropyl 2-methylprop-2-enoate Chemical compound CO[Si](OC)(OC)CCCOC(=O)C(C)=C XDLMVUHYZWKMMD-UHFFFAOYSA-N 0.000 claims 1
- HRPVXLWXLXDGHG-UHFFFAOYSA-N Acrylamide Chemical compound NC(=O)C=C HRPVXLWXLXDGHG-UHFFFAOYSA-N 0.000 claims 1
- 239000004641 Diallyl-phthalate Substances 0.000 claims 1
- SLGBZMMZGDRARJ-UHFFFAOYSA-N Triphenylene Natural products C1=CC=C2C3=CC=CC=C3C3=CC=CC=C3C2=C1 SLGBZMMZGDRARJ-UHFFFAOYSA-N 0.000 claims 1
- 229920001807 Urea-formaldehyde Polymers 0.000 claims 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims 1
- 150000008044 alkali metal hydroxides Chemical class 0.000 claims 1
- QUDWYFHPNIMBFC-UHFFFAOYSA-N bis(prop-2-enyl) benzene-1,2-dicarboxylate Chemical compound C=CCOC(=O)C1=CC=CC=C1C(=O)OCC=C QUDWYFHPNIMBFC-UHFFFAOYSA-N 0.000 claims 1
- 235000019437 butane-1,3-diol Nutrition 0.000 claims 1
- 150000002118 epoxides Chemical class 0.000 claims 1
- 125000005670 ethenylalkyl group Chemical group 0.000 claims 1
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims 1
- MSYLJRIXVZCQHW-UHFFFAOYSA-N formaldehyde;6-phenyl-1,3,5-triazine-2,4-diamine Chemical compound O=C.NC1=NC(N)=NC(C=2C=CC=CC=2)=N1 MSYLJRIXVZCQHW-UHFFFAOYSA-N 0.000 claims 1
- SLGWESQGEUXWJQ-UHFFFAOYSA-N formaldehyde;phenol Chemical compound O=C.OC1=CC=CC=C1 SLGWESQGEUXWJQ-UHFFFAOYSA-N 0.000 claims 1
- VOZRXNHHFUQHIL-UHFFFAOYSA-N glycidyl methacrylate Chemical compound CC(=C)C(=O)OCC1CO1 VOZRXNHHFUQHIL-UHFFFAOYSA-N 0.000 claims 1
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 claims 1
- 238000000034 method Methods 0.000 claims 1
- 125000000962 organic group Chemical group 0.000 claims 1
- 239000005011 phenolic resin Substances 0.000 claims 1
- 229920001515 polyalkylene glycol Polymers 0.000 claims 1
- ODGAOXROABLFNM-UHFFFAOYSA-N polynoxylin Chemical compound O=C.NC(N)=O ODGAOXROABLFNM-UHFFFAOYSA-N 0.000 claims 1
- JXUKBNICSRJFAP-UHFFFAOYSA-N triethoxy-[3-(oxiran-2-ylmethoxy)propyl]silane Chemical compound CCO[Si](OCC)(OCC)CCCOCC1CO1 JXUKBNICSRJFAP-UHFFFAOYSA-N 0.000 claims 1
- BPSIOYPQMFLKFR-UHFFFAOYSA-N trimethoxy-[3-(oxiran-2-ylmethoxy)propyl]silane Chemical compound CO[Si](OC)(OC)CCCOCC1CO1 BPSIOYPQMFLKFR-UHFFFAOYSA-N 0.000 claims 1
- 229920001567 vinyl ester resin Polymers 0.000 claims 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 claims 1
- 229910052725 zinc Inorganic materials 0.000 claims 1
- 239000011701 zinc Substances 0.000 claims 1
- 150000003754 zirconium Chemical class 0.000 claims 1
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F265/00—Macromolecular compounds obtained by polymerising monomers on to polymers of unsaturated monocarboxylic acids or derivatives thereof as defined in group C08F20/00
- C08F265/02—Macromolecular compounds obtained by polymerising monomers on to polymers of unsaturated monocarboxylic acids or derivatives thereof as defined in group C08F20/00 on to polymers of acids, salts or anhydrides
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- C08J3/00—Processes of treating or compounding macromolecular substances
- C08J3/02—Making solutions, dispersions, lattices or gels by other methods than by solution, emulsion or suspension polymerisation techniques
- C08J3/03—Making solutions, dispersions, lattices or gels by other methods than by solution, emulsion or suspension polymerisation techniques in aqueous media
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- C09D123/00—Coating compositions based on homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Coating compositions based on derivatives of such polymers
- C09D123/02—Coating compositions based on homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Coating compositions based on derivatives of such polymers not modified by chemical after-treatment
- C09D123/04—Homopolymers or copolymers of ethene
- C09D123/08—Copolymers of ethene
- C09D123/0846—Copolymers of ethene with unsaturated hydrocarbons containing other atoms than carbon or hydrogen atoms
- C09D123/0869—Acids or derivatives thereof
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- B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
- B65D—CONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
- B65D25/00—Details of other kinds or types of rigid or semi-rigid containers
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- C08F255/00—Macromolecular compounds obtained by polymerising monomers on to polymers of hydrocarbons as defined in group C08F10/00
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- C08F255/00—Macromolecular compounds obtained by polymerising monomers on to polymers of hydrocarbons as defined in group C08F10/00
- C08F255/02—Macromolecular compounds obtained by polymerising monomers on to polymers of hydrocarbons as defined in group C08F10/00 on to polymers of olefins having two or three carbon atoms
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- C08F265/04—Macromolecular compounds obtained by polymerising monomers on to polymers of unsaturated monocarboxylic acids or derivatives thereof as defined in group C08F20/00 on to polymers of esters
- C08F265/06—Polymerisation of acrylate or methacrylate esters on to polymers thereof
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- C08J3/00—Processes of treating or compounding macromolecular substances
- C08J3/24—Crosslinking, e.g. vulcanising, of macromolecules
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- C09D123/00—Coating compositions based on homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Coating compositions based on derivatives of such polymers
- C09D123/02—Coating compositions based on homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Coating compositions based on derivatives of such polymers not modified by chemical after-treatment
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- C09D151/00—Coating compositions based on graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Coating compositions based on derivatives of such polymers
- C09D151/003—Coating compositions based on graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Coating compositions based on derivatives of such polymers grafted on to macromolecular compounds obtained by reactions only involving unsaturated carbon-to-carbon bonds
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- C09D151/00—Coating compositions based on graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Coating compositions based on derivatives of such polymers
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Claims (17)
1. Композиционная латексная эмульсия сополимера (поли)этилена и (мет)акриловой кислоты, полученная по способу, включающему:
a) смешивание сополимера (поли)этилена и (мет)акриловой кислоты и нейтрализующего агента в воде для формирования смеси; и
b) смешивание смеси с этилен-ненасыщенным мономерным компонентом для формирования композиционной латексной эмульсии сополимера (поли)этилена и (мет)акриловой кислоты.
2. Композиционная латексная эмульсия сополимера (поли)этилена и (мет)акриловой кислоты по п. 1, в которой реакционная смесь дополнительно содержит органосилановое соединение.
3. Композиционная латексная эмульсия сополимера (поли)этилена и (мет)акриловой кислоты по п. 2, в которой органосилановое соединение содержит реакционноспособную органическую группу и гидролизуемую неорганическую метоксисилильную группу.
4. Композиционная латексная эмульсия сополимера (поли)этилена и (мет)акриловой кислоты по п. 2, в которой органосилановое соединение содержит 3-метакрилоксипропилтриметоксисилан, 3-глицидилоксипропилтриэтоксисилан, 3-глицидилоксипропилтриметоксисилан или их сочетание.
5. Композиционная латексная эмульсия сополимера (поли)этилена и (мет)акриловой кислоты по п. 1, в которой реакционная смесь содержит наноглину.
6. Композиционная латексная эмульсия сополимера (поли)этилена и (мет)акриловой кислоты по п. 1, в которой реакционная смесь дополнительно содержит сшивающий агент.
7. Композиционная латексная эмульсия сополимера (поли)этилена и (мет)акриловой кислоты по п. 6, в которой сшивающий агент содержит фенольную смолу, мочевиноформальдегид, фенолформальдегид, бензогуанаминформальдегид, гидроксиды щелочных металлов, комплексы цинка/циркония, эпоксид или их сочетание.
8. Композиционная латексная эмульсия сополимера (поли)этилена и (мет)акриловой кислоты по п. 1, в которой реакционная смесь дополнительно содержит нейтрализующий агент.
9. Композиционная латексная эмульсия сополимера (поли)этилена и (мет)акриловой кислоты по п. 1, в которой реакционная смесь дополнительно содержит наноглину.
10. Композиционная латексная эмульсия сополимера (поли)этилена и (мет)акриловой кислоты по п. 1, в которой этилен-ненасыщенный мономерный компонент содержит ди(мет)акрилат трипропиленгликоля, ди(мет)акрилат диэтиленгликоля, ди(мет)акрилат этиленгликоля, 1,6-гександиолди(мет)акрилат, глицеринди(мет)акрилат, глицидилметакрилат, 1,4-бутандиолди(мет)акрилат, гидроксипропил(мет)акрилат, (мет)акриловую кислоту, виниловый мономер, акриловый мономер, аллиловый мономер, акриламидный мономер, виниловый сложный эфир, винилгалогенид, виниловый ароматический углеводород, виниловый алифатический углеводородный мономер, винилалкиловый простой эфир, акриловый мономер, (мет)акрилат 1,3-бутиленгликоля, ди(мет)акрилат полиалкиленгликоля, диаллилфталат, триметилолпропантри(мет)акрилат, дивинилбензол, дивинилтолуол, тривинилбензол, дивинилнафталин или их сочетание.
11. Гибридный органосилановый композиционный латекс сополимера (поли)этилена и (мет)акриловой кислоты, полученный введением в реакцию смеси композиционного латекса сополимера (поли)этилена и (мет)акриловой кислоты по п. 1 с органосилановым соединением.
12. Композиция для покрытия, содержащая композиционную латексную эмульсию сополимера (поли)этилена и (мет)акриловой кислоты по п. 1.
13. Композиция для покрытия, содержащая гибридную органосилановую композиционную латексную эмульсию сополимера (поли)этилена и (мет)акриловой кислоты по п. 11.
14. Подложка, покрытая композицией для покрытия по п. 1.
15. Подложка, покрытая композицией для покрытия по п. 11.
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| PCT/EP2014/054762 WO2014140057A1 (en) | 2013-03-15 | 2014-03-12 | Hybrid water dispersions, (poly)ethylene (meth)acrylic acid copolymer composite latex emulsions, hybrid (poly)ethylene (meth)acrylic acid organosilane composite latex emulsions, and coating compositions formed therefrom |
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| US11981822B2 (en) | 2014-12-24 | 2024-05-14 | Swimc Llc | Crosslinked coating compositions for packaging articles such as food and beverage containers |
| HUE050566T2 (hu) | 2014-12-24 | 2020-12-28 | Swimc Llc | Bevonatkészítmények áruk csomagolására, például élelmiszer- és italtároló edények |
| WO2016105502A1 (en) | 2014-12-24 | 2016-06-30 | Valspar Sourcing, Inc. | Styrene-free coating compositions for packaging articles such as food and beverage containers |
| US9852543B2 (en) | 2015-03-27 | 2017-12-26 | Snap Inc. | Automated three dimensional model generation |
| CN113416457A (zh) | 2015-05-29 | 2021-09-21 | Ppg工业俄亥俄公司 | 涂布有乳液聚合的胶乳聚合物的包装 |
| AR108133A1 (es) | 2016-04-15 | 2018-07-18 | Valspar Sourcing Inc | Composiciones de revestimiento que contienen copolímeros libres de estireno |
| BR112019000804A2 (pt) | 2016-07-15 | 2019-04-24 | Swimc Llc | artigo, método, e, composição de revestimento |
| BR112019007974B1 (pt) | 2016-10-19 | 2023-02-07 | Swimc Llc | Composição de revestimento, método de revestimento de uma lata para alimentos ou bebidas, e, lata para alimentos ou bebidas |
| AU2018248576B2 (en) | 2017-04-07 | 2023-11-23 | Akzo Nobel Coatings International B.V. | Coating compositions containing a hydroxyphenyl functional polymer and a latex polymer |
| WO2018185094A1 (en) | 2017-04-07 | 2018-10-11 | Akzo Nobel Coatings International B.V. | Coating compositions containing a hydroxyphenyl functional polymer and a latex polymer |
| KR102611581B1 (ko) * | 2017-05-19 | 2023-12-08 | 허니웰 인터내셔날 인코포레이티드 | 저 표면 에너지 기재에 대한 접착성을 개선하기 위한 공중합체 제형을 포함하는 조성물 |
| MX2020002307A (es) | 2017-09-01 | 2020-09-10 | Swimc Llc | Látexes poliméricos de múltiples etapas, composiciones de recubrimiento que contienen tales látexes y artículos recubiertos con estos. |
| CN117126576A (zh) | 2017-09-01 | 2023-11-28 | 宣伟投资管理有限公司 | 多级聚合物胶乳、含有该胶乳的涂料及其涂布的制品 |
| CN111448265B (zh) | 2017-12-11 | 2022-04-15 | 宣伟公司 | 用于制造水可分散聚合物和水分散的聚合物的方法 |
| WO2019241209A1 (en) * | 2018-06-11 | 2019-12-19 | Swimc Llc | Packaging coating containing water-dispersible acrylic block copolymer |
| CN110862493A (zh) * | 2018-08-27 | 2020-03-06 | 上海溢珂新材料科技有限公司 | 水性标线乳液及水性标线涂料的制备方法 |
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| MX2023013348A (es) | 2021-05-19 | 2023-11-27 | Swimc Llc | Metodos para recubrir sustratos metalicos y elaborar envasado metalico, sustratos metalicos recubiertos, envasado metalico y sistemas de composicion de recubrimiento en polvo. |
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| US20160024325A1 (en) | 2016-01-28 |
| KR20150127169A (ko) | 2015-11-16 |
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| EP2970548A1 (en) | 2016-01-20 |
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| CN105189586B (zh) | 2018-01-19 |
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| EP2970548B1 (en) | 2017-12-27 |
| ES2662851T3 (es) | 2018-04-10 |
| BR112015021948A2 (pt) | 2017-07-18 |
| WO2014140057A1 (en) | 2014-09-18 |
| CA2904173A1 (en) | 2014-09-18 |
| RU2642423C2 (ru) | 2018-01-25 |
| AU2014230876A1 (en) | 2015-09-10 |
| US9404006B2 (en) | 2016-08-02 |
| PL2970548T3 (pl) | 2018-06-29 |
| AU2014230876B2 (en) | 2017-03-02 |
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