RU2006124733A - Процесс получения смеси алкоксилированных спиртов - Google Patents
Процесс получения смеси алкоксилированных спиртов Download PDFInfo
- Publication number
- RU2006124733A RU2006124733A RU2006124733/04A RU2006124733A RU2006124733A RU 2006124733 A RU2006124733 A RU 2006124733A RU 2006124733/04 A RU2006124733/04 A RU 2006124733/04A RU 2006124733 A RU2006124733 A RU 2006124733A RU 2006124733 A RU2006124733 A RU 2006124733A
- Authority
- RU
- Russia
- Prior art keywords
- fischer
- hydrocarbon fraction
- alcohols
- catalyst
- tropsch
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G29/00—Refining of hydrocarbon oils, in the absence of hydrogen, with other chemicals
- C10G29/20—Organic compounds not containing metal atoms
- C10G29/22—Organic compounds not containing metal atoms containing oxygen as the only hetero atom
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C41/00—Preparation of ethers; Preparation of compounds having groups, groups or groups
- C07C41/01—Preparation of ethers
- C07C41/02—Preparation of ethers from oxiranes
- C07C41/03—Preparation of ethers from oxiranes by reaction of oxirane rings with hydroxy groups
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C43/00—Ethers; Compounds having groups, groups or groups
- C07C43/02—Ethers
- C07C43/03—Ethers having all ether-oxygen atoms bound to acyclic carbon atoms
- C07C43/04—Saturated ethers
- C07C43/10—Saturated ethers of polyhydroxy compounds
- C07C43/11—Polyethers containing —O—(C—C—O—)n units with ≤ 2 n≤ 10
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2/00—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon
- C10G2/30—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen
- C10G2/32—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2/00—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon
- C10G2/30—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen
- C10G2/32—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts
- C10G2/33—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts characterised by the catalyst used
- C10G2/331—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts characterised by the catalyst used containing group VIII-metals
- C10G2/332—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts characterised by the catalyst used containing group VIII-metals of the iron-group
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- General Chemical & Material Sciences (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Catalysts (AREA)
Claims (10)
1. Способ получения смеси алкоксилированных спиртов, содержащей один или несколько алкоксилированных спиртов, включающий стадии:
(а) взаимодействие монооксида углерода с водородом в условиях реакции Фишера-Тропша в присутствии катализатора Фишера-Тропша;
(b) отделение от продукта стадии (а), по меньшей мере, одной фракции углеводородов, содержащей парафины, имеющие от 9 до 17 атомов углерода и олефины, имеющие от 9 до 17 атомов углерода, углеводородной фракции, дополнительно содержащей, по меньшей мере, одну часть спиртов;
(c) контактирование одной или нескольких фракций, полученных на стадии (b), с алкиленоксидом и
(d) извлечение смеси алкоксилированных спиртов из продукта реакции стадии (с).
2. Способ по п.1, в котором катализатор Фишера-Тропша содержит кобальт или железо.
3. Способ по п.2, в котором катализатор Фишера-Тропша является кобальтовым катализатором на инертном носителе, в котором инертный носитель выбирается из двуокиси титана, двуокиси циркония и двуокиси кремния или их смеси.
4. Способ по п.3, в котором катализатор Фишера-Тропша является кобальтовым катализатором на носителе из двуокиси титана.
5. Способ по п.2, в котором катализатор Фишера-Тропша является катализатором на основе железа.
6. Способ по любому из пп.1-5, в котором стадия (а) включает взаимодействие монооксида углерода с водородом при температуре в интервале от 125 до 350°С и давлении в интервале от 5 до 150 абс. бар.
7. Способ по любому из пп.1-5, в котором алкоксилированные спирты имеют формулу (IV)
в которой R1 представляет собой линейную или разветвленную алкильную группу, имеющую от 1 до 30 атомов углерода, EO, PO и BO представляют собой части этиленокси, пропиленокси и бутиленокси и p, q и r являются целыми числами от 0 до 70.
8. Способ по п.7, в котором p равно 1 или 2, q равно 0 и r равно 0.
9. Способ по любому из пп.1-5, в котором углеводородная фракция, которой снабжается стадия (с), представляет собой С13/С14 углеводородную фракцию.
10. Способ по любому из пп.1-5, в котором углеводородная фракция, которой снабжается стадия (с) представляет собой С11/С12 углеводородную фракцию.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US52869303P | 2003-12-11 | 2003-12-11 | |
| US60/528,693 | 2003-12-11 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| RU2006124733A true RU2006124733A (ru) | 2008-01-20 |
| RU2358965C2 RU2358965C2 (ru) | 2009-06-20 |
Family
ID=34699891
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| RU2006124733/04A RU2358965C2 (ru) | 2003-12-11 | 2004-12-10 | Процесс получения смеси алкоксилированных спиртов |
Country Status (20)
| Country | Link |
|---|---|
| US (1) | US7105706B2 (ru) |
| EP (1) | EP1708983B1 (ru) |
| JP (1) | JP4611998B2 (ru) |
| KR (1) | KR20060111649A (ru) |
| CN (1) | CN1890202A (ru) |
| AR (1) | AR046754A1 (ru) |
| AT (1) | ATE469114T1 (ru) |
| AU (1) | AU2004298437B2 (ru) |
| BR (1) | BRPI0417487A (ru) |
| CA (1) | CA2548649A1 (ru) |
| DE (1) | DE602004027419D1 (ru) |
| GC (1) | GC0000861A (ru) |
| MX (1) | MXPA06006531A (ru) |
| MY (1) | MY137501A (ru) |
| NZ (1) | NZ547761A (ru) |
| RU (1) | RU2358965C2 (ru) |
| SG (1) | SG122709A1 (ru) |
| TW (1) | TW200523237A (ru) |
| WO (1) | WO2005058784A1 (ru) |
| ZA (1) | ZA200604524B (ru) |
Families Citing this family (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2009015137A1 (en) * | 2007-07-24 | 2009-01-29 | Shell Oil Company | Process for making a secondary alcohol cleaning product |
| WO2009058654A1 (en) * | 2007-10-29 | 2009-05-07 | Shell Oil Company | Process for producing secondary alcohol alkoxy sulfates |
| GB2502030C (en) * | 2011-02-07 | 2018-08-15 | Velocys Tech Limited | Catalysts |
| EP3636691B1 (en) | 2015-10-07 | 2021-03-03 | Elementis Specialties, Inc. | Wetting and anti-foaming agent |
| AR125687A1 (es) * | 2021-04-15 | 2023-08-09 | Unilever Global Ip Ltd | Una composición de lavavajillas a mano |
Family Cites Families (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0345861B1 (en) | 1988-06-09 | 1993-01-20 | Shell Internationale Researchmaatschappij B.V. | Alkoxylation process catalyzed by compounds of the rare earth elements |
| US5057627A (en) | 1988-06-09 | 1991-10-15 | Shell Oil Company | Alkoxylation process catalyzed by phosphate salts of the rare earth elements |
| US5907067A (en) * | 1996-05-06 | 1999-05-25 | Henkel Corporation | Method of alkoxylating alcohols |
| DE19840846A1 (de) * | 1998-09-07 | 2000-03-09 | Basf Ag | Verfahren zur Herstellung von Fettalkoholalkoxylaten |
| US6514898B2 (en) | 2000-12-15 | 2003-02-04 | Shell Oil Company | Process of preparing a fluid rare earth alkoxylation catalyst |
| US6706931B2 (en) * | 2000-12-21 | 2004-03-16 | Shell Oil Company | Branched primary alcohol compositions and derivatives thereof |
| US6740683B2 (en) | 2001-05-23 | 2004-05-25 | Sasol Technology (Proprietary) Limited | Chemicals from synthesis gas |
| MY128880A (en) * | 2001-06-12 | 2007-02-28 | Shell Int Research | Process for the preparation of a highly liear alcohol composition |
| RU2220945C2 (ru) * | 2001-11-06 | 2004-01-10 | ОАО "Сибур-Нефтехим" | Способ получения смеси моноалкиловых эфиров полиэтиленгликолей |
| WO2003091190A1 (de) * | 2002-04-26 | 2003-11-06 | Basf Aktiengesellschaft | Alkoxylatgemische und diese enthaltende waschmittel |
-
2004
- 2004-12-07 AR ARP040104556A patent/AR046754A1/es unknown
- 2004-12-08 GC GCP200404071 patent/GC0000861A/xx active
- 2004-12-09 US US11/008,047 patent/US7105706B2/en not_active Expired - Fee Related
- 2004-12-09 MY MYPI20045090A patent/MY137501A/en unknown
- 2004-12-09 TW TW093138190A patent/TW200523237A/zh unknown
- 2004-12-10 EP EP04804761A patent/EP1708983B1/en not_active Expired - Lifetime
- 2004-12-10 WO PCT/EP2004/053391 patent/WO2005058784A1/en active Application Filing
- 2004-12-10 RU RU2006124733/04A patent/RU2358965C2/ru not_active IP Right Cessation
- 2004-12-10 CN CNA2004800366953A patent/CN1890202A/zh active Pending
- 2004-12-10 CA CA002548649A patent/CA2548649A1/en not_active Abandoned
- 2004-12-10 KR KR1020067013200A patent/KR20060111649A/ko not_active Withdrawn
- 2004-12-10 NZ NZ547761A patent/NZ547761A/en unknown
- 2004-12-10 AU AU2004298437A patent/AU2004298437B2/en not_active Ceased
- 2004-12-10 SG SG2006037501A patent/SG122709A1/en unknown
- 2004-12-10 BR BRPI0417487-9A patent/BRPI0417487A/pt not_active IP Right Cessation
- 2004-12-10 AT AT04804761T patent/ATE469114T1/de not_active IP Right Cessation
- 2004-12-10 DE DE602004027419T patent/DE602004027419D1/de not_active Expired - Lifetime
- 2004-12-10 JP JP2006543554A patent/JP4611998B2/ja not_active Expired - Fee Related
-
2006
- 2006-06-02 ZA ZA200604524A patent/ZA200604524B/en unknown
- 2006-06-08 MX MXPA06006531 patent/MXPA06006531A/es active IP Right Grant
Also Published As
| Publication number | Publication date |
|---|---|
| MXPA06006531A (es) | 2006-07-31 |
| DE602004027419D1 (de) | 2010-07-08 |
| TW200523237A (en) | 2005-07-16 |
| CA2548649A1 (en) | 2005-06-30 |
| EP1708983B1 (en) | 2010-05-26 |
| US20050192363A1 (en) | 2005-09-01 |
| WO2005058784A1 (en) | 2005-06-30 |
| MX259928B (ru) | 2008-08-25 |
| JP4611998B2 (ja) | 2011-01-12 |
| GC0000861A (en) | 2009-03-31 |
| RU2358965C2 (ru) | 2009-06-20 |
| CN1890202A (zh) | 2007-01-03 |
| BRPI0417487A (pt) | 2007-05-22 |
| EP1708983A1 (en) | 2006-10-11 |
| AU2004298437A1 (en) | 2005-06-30 |
| ATE469114T1 (de) | 2010-06-15 |
| SG122709A1 (en) | 2006-07-26 |
| MY137501A (en) | 2009-02-27 |
| KR20060111649A (ko) | 2006-10-27 |
| US7105706B2 (en) | 2006-09-12 |
| AR046754A1 (es) | 2005-12-21 |
| NZ547761A (en) | 2009-01-31 |
| AU2004298437B2 (en) | 2008-01-17 |
| ZA200604524B (en) | 2007-09-26 |
| JP2007513924A (ja) | 2007-05-31 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| MM4A | The patent is invalid due to non-payment of fees |
Effective date: 20141211 |