RU2005133161A - Способ получения обогащенного водородом потока - Google Patents
Способ получения обогащенного водородом потока Download PDFInfo
- Publication number
- RU2005133161A RU2005133161A RU2005133161/15A RU2005133161A RU2005133161A RU 2005133161 A RU2005133161 A RU 2005133161A RU 2005133161/15 A RU2005133161/15 A RU 2005133161/15A RU 2005133161 A RU2005133161 A RU 2005133161A RU 2005133161 A RU2005133161 A RU 2005133161A
- Authority
- RU
- Russia
- Prior art keywords
- conversion
- stage
- methanol
- carbon monoxide
- water
- Prior art date
Links
- 238000004519 manufacturing process Methods 0.000 title 1
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 claims 12
- 238000000034 method Methods 0.000 claims 7
- 238000006243 chemical reaction Methods 0.000 claims 5
- 239000007789 gas Substances 0.000 claims 4
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 claims 3
- 229910002091 carbon monoxide Inorganic materials 0.000 claims 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims 3
- 229930195733 hydrocarbon Natural products 0.000 claims 2
- 150000002430 hydrocarbons Chemical class 0.000 claims 2
- 238000002407 reforming Methods 0.000 claims 2
- 239000004215 Carbon black (E152) Substances 0.000 claims 1
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 claims 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims 1
- 229910052782 aluminium Inorganic materials 0.000 claims 1
- 239000003054 catalyst Substances 0.000 claims 1
- 229910052804 chromium Inorganic materials 0.000 claims 1
- 239000011651 chromium Substances 0.000 claims 1
- 229910052802 copper Inorganic materials 0.000 claims 1
- 239000010949 copper Substances 0.000 claims 1
- 229910052739 hydrogen Inorganic materials 0.000 claims 1
- 239000001257 hydrogen Substances 0.000 claims 1
- 239000007788 liquid Substances 0.000 claims 1
- 229910052725 zinc Inorganic materials 0.000 claims 1
- 239000011701 zinc Substances 0.000 claims 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
- C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
- C01B3/32—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
- C01B3/34—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents
- C01B3/48—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents followed by reaction of water vapour with carbon monoxide
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
- C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
- C01B3/06—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of inorganic compounds containing electro-positively bound hydrogen, e.g. water, acids, bases, ammonia, with inorganic reducing agents
- C01B3/12—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of inorganic compounds containing electro-positively bound hydrogen, e.g. water, acids, bases, ammonia, with inorganic reducing agents by reaction of water vapour with carbon monoxide
- C01B3/16—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of inorganic compounds containing electro-positively bound hydrogen, e.g. water, acids, bases, ammonia, with inorganic reducing agents by reaction of water vapour with carbon monoxide using catalysts
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
- C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
- C01B3/22—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by decomposition of gaseous or liquid organic compounds
- C01B3/24—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by decomposition of gaseous or liquid organic compounds of hydrocarbons
- C01B3/26—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by decomposition of gaseous or liquid organic compounds of hydrocarbons using catalysts
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
- C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
- C01B3/32—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
- C01B3/323—Catalytic reaction of gaseous or liquid organic compounds other than hydrocarbons with gasifying agents
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
- C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
- C01B3/32—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
- C01B3/34—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents
- C01B3/38—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using catalysts
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/02—Processes for making hydrogen or synthesis gas
- C01B2203/0205—Processes for making hydrogen or synthesis gas containing a reforming step
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/02—Processes for making hydrogen or synthesis gas
- C01B2203/0283—Processes for making hydrogen or synthesis gas containing a CO-shift step, i.e. a water gas shift step
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/02—Processes for making hydrogen or synthesis gas
- C01B2203/0283—Processes for making hydrogen or synthesis gas containing a CO-shift step, i.e. a water gas shift step
- C01B2203/0288—Processes for making hydrogen or synthesis gas containing a CO-shift step, i.e. a water gas shift step containing two CO-shift steps
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/10—Catalysts for performing the hydrogen forming reactions
- C01B2203/1041—Composition of the catalyst
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/10—Catalysts for performing the hydrogen forming reactions
- C01B2203/1041—Composition of the catalyst
- C01B2203/1076—Copper or zinc-based catalysts
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/14—Details of the flowsheet
- C01B2203/142—At least two reforming, decomposition or partial oxidation steps in series
- C01B2203/143—Three or more reforming, decomposition or partial oxidation steps in series
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/14—Details of the flowsheet
- C01B2203/148—Details of the flowsheet involving a recycle stream to the feed of the process for making hydrogen or synthesis gas
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Combustion & Propulsion (AREA)
- Inorganic Chemistry (AREA)
- Hydrogen, Water And Hydrids (AREA)
- Catalysts (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Claims (7)
1. Способ получения обогащенного водородом потока газа, включающий добавление метанола к газу, содержащему оксид углерода, и контактирование газа, содержащего оксид углерода, метанола и воды в, по меньшей мере, одну стадию конверсии без внешней подачи тепла в присутствии катализатора, включающего медь, цинк и алюминий и/или хром, при температуре на входе, по меньшей мере, 280°С и давлении, по меньшей мере, 2,0 МПа.
2. Способ по п.1, где метанол и вода присутствуют в паровой форме.
3. Способ по п.1, где метанол и вода присутствуют в жидкой форме.
4. Способ по п.1, где, по меньшей мере, одна стадия конверсии представляет собой стадию конверсии при умеренной температуре или высокой температуре.
5. Способ по п.4, где стадия конверсии при низкой температуре следует за стадией конверсии при умеренной температуре или высокой температуре.
6. Способ по любому из пп.1-5, где газ, содержащий оксид углерода, получают из реформинга углеводородного сырья.
7. Способ по п.6, где углеводородное сырье представляет собой подвергнутое предварительному реформингу сырье перед стадией реформинга.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DKPA200300499 | 2003-04-01 | ||
| DKPA200300499 | 2003-04-01 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| RU2005133161A true RU2005133161A (ru) | 2006-04-27 |
Family
ID=33104008
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| RU2005133161/15A RU2005133161A (ru) | 2003-04-01 | 2004-03-25 | Способ получения обогащенного водородом потока |
Country Status (11)
| Country | Link |
|---|---|
| US (1) | US7527781B2 (ru) |
| EP (1) | EP1613553A1 (ru) |
| JP (1) | JP2006521989A (ru) |
| KR (1) | KR20060002903A (ru) |
| CN (2) | CN1331731C (ru) |
| AU (1) | AU2004226236A1 (ru) |
| CA (1) | CA2520988A1 (ru) |
| MX (1) | MXPA05010538A (ru) |
| RU (1) | RU2005133161A (ru) |
| WO (1) | WO2004087567A1 (ru) |
| ZA (2) | ZA200507925B (ru) |
Families Citing this family (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP4653108B2 (ja) * | 2003-11-17 | 2011-03-16 | ハルドール・トプサー・アクチエゼルスカベット | 尿素の製造方法 |
| CA2496839A1 (en) | 2004-07-19 | 2006-01-19 | Woodland Chemical Systems Inc. | Process for producing ethanol from synthesis gas rich in carbon monoxide |
| CN101227975A (zh) * | 2005-06-15 | 2008-07-23 | 俄亥俄州立大学 | 用于从水气转化反应生产氢气的催化剂 |
| US8088832B2 (en) * | 2006-04-05 | 2012-01-03 | Woodland Biofuels Inc. | System and method for converting biomass to ethanol via syngas |
| CN101177240B (zh) * | 2007-11-09 | 2010-04-07 | 清华大学 | 一种集成式二甲醚水蒸气重整制氢装置及方法 |
| CA2710994A1 (en) * | 2007-12-26 | 2009-07-09 | Nellcor Puritan Bennett Llc | Historical trend icons for physiological parameters |
| GB0914500D0 (en) * | 2009-08-19 | 2009-09-30 | Johnson Matthey Plc | Process |
| DE102013104893A1 (de) * | 2013-05-13 | 2014-11-13 | L'Air Liquide, Société Anonyme pour l'Etude et l'Exploitation des Procédés Georges Claude | Verfahren zur Inbetriebnahme einer Vorreformierungsstufe |
| EP3647264B1 (de) * | 2018-10-31 | 2023-10-11 | L'air Liquide, Société Anonyme Pour L'Étude Et L'exploitation Des Procédés Georges Claude | Verfahren und anlage zum herstellen eines gereinigten und konvertierten synthesegases |
| CN112960645B (zh) * | 2019-12-14 | 2022-08-05 | 中国科学院大连化学物理研究所 | 一种自热重整制氢反应用水汽变换反应器及提高水汽变换反应co转化率的方法 |
| CN110980642B (zh) * | 2019-12-30 | 2021-12-24 | 北京蓝玖新能源科技有限公司 | 一种制氢设备及其工艺和应用 |
Family Cites Families (19)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4091086A (en) * | 1976-12-20 | 1978-05-23 | Engelhard Minerals & Chemicals Corporation | Process for production of hydrogen |
| DK147705C (da) * | 1982-09-07 | 1985-05-13 | Haldor Topsoe As | Fremgangsmaade til fremstilling af carbonhydrider ud fra syntesegas |
| JPS59203702A (ja) | 1983-05-04 | 1984-11-17 | Mitsubishi Heavy Ind Ltd | 水素の製造法 |
| JP3020984B2 (ja) | 1990-03-02 | 2000-03-15 | 株式会社東芝 | 燃料電池発電装置 |
| JP2755804B2 (ja) * | 1990-08-27 | 1998-05-25 | 株式会社東芝 | 水素製造方法 |
| US5830425A (en) * | 1993-02-09 | 1998-11-03 | Sud-Chemie Ag | Chromium-free catalyst based on iron oxide for conversion of carbon monoxide |
| US5498370A (en) * | 1994-12-15 | 1996-03-12 | Amoco Corporation | Process for hydroshifting dimethyl ether |
| US5990040A (en) * | 1995-01-11 | 1999-11-23 | United Catalysts Inc. | Promoted and stabilized copper oxide and zinc oxide catalyst and preparation |
| DK173416B1 (da) * | 1995-07-21 | 2000-10-02 | Topsoe Haldor As | Fremgangsmåde til fremstilling af hydrogenrig gas |
| GB9820608D0 (en) * | 1998-09-23 | 1998-11-11 | Ici Plc | Hydrogen |
| JP2000143209A (ja) * | 1998-11-05 | 2000-05-23 | Idemitsu Kosan Co Ltd | 一酸化炭素の転化方法および触媒 |
| DE10010069A1 (de) * | 2000-03-02 | 2001-09-20 | Xcellsis Gmbh | Verfahren zum Betreiben einer Gaserzeugungsvorrichtung bzw. eines Brennstoffzellensystems, Gaserzeugungsvorrichtung und Brennstoffzellensystem |
| DE10010070A1 (de) | 2000-03-02 | 2001-09-20 | Xcellsis Gmbh | Gaserzeugungsvorrichtung |
| JP3496051B2 (ja) * | 2000-06-07 | 2004-02-09 | 独立行政法人産業技術総合研究所 | メタノールの酸化的水蒸気改質反応による水素ガス製造触媒及びその製造法 |
| DE10059674A1 (de) | 2000-12-01 | 2002-06-20 | Xcellsis Gmbh | Brennstoffzellensystem |
| DE10111198A1 (de) * | 2001-03-08 | 2002-09-19 | Basf Ag | Methanolreformierungskatalysator mit verringertem Volumenschwund |
| DE10111197A1 (de) * | 2001-03-08 | 2002-09-19 | Basf Ag | Verfahren zur Herstellung von Katalysatoren mit geringem Volumenschwund |
| JP2003010685A (ja) * | 2001-06-27 | 2003-01-14 | Nkk Corp | 水素製造触媒およびその製造方法ならびに水素を製造する方法 |
| JP4175452B2 (ja) * | 2001-08-07 | 2008-11-05 | 三菱重工業株式会社 | ジメチルエーテル改質触媒およびジメチルエーテル改質方法 |
-
2004
- 2004-03-25 EP EP04723209A patent/EP1613553A1/en not_active Withdrawn
- 2004-03-25 ZA ZA200507925A patent/ZA200507925B/en unknown
- 2004-03-25 US US10/548,802 patent/US7527781B2/en active Active
- 2004-03-25 CN CNB2004800088271A patent/CN1331731C/zh not_active Expired - Fee Related
- 2004-03-25 KR KR1020057018604A patent/KR20060002903A/ko not_active Withdrawn
- 2004-03-25 WO PCT/EP2004/003159 patent/WO2004087567A1/en not_active Application Discontinuation
- 2004-03-25 ZA ZA200507926A patent/ZA200507926B/en unknown
- 2004-03-25 AU AU2004226236A patent/AU2004226236A1/en not_active Abandoned
- 2004-03-25 CN CNA2004800090248A patent/CN1856441A/zh active Pending
- 2004-03-25 JP JP2006504860A patent/JP2006521989A/ja active Pending
- 2004-03-25 RU RU2005133161/15A patent/RU2005133161A/ru not_active Application Discontinuation
- 2004-03-25 CA CA002520988A patent/CA2520988A1/en not_active Abandoned
- 2004-03-25 MX MXPA05010538A patent/MXPA05010538A/es active IP Right Grant
Also Published As
| Publication number | Publication date |
|---|---|
| US7527781B2 (en) | 2009-05-05 |
| US20060165589A1 (en) | 2006-07-27 |
| ZA200507926B (en) | 2006-12-27 |
| CN1856441A (zh) | 2006-11-01 |
| MXPA05010538A (es) | 2005-11-23 |
| WO2004087567A1 (en) | 2004-10-14 |
| EP1613553A1 (en) | 2006-01-11 |
| CN1768004A (zh) | 2006-05-03 |
| ZA200507925B (en) | 2006-12-27 |
| CA2520988A1 (en) | 2004-10-14 |
| AU2004226236A1 (en) | 2004-10-14 |
| KR20060002903A (ko) | 2006-01-09 |
| JP2006521989A (ja) | 2006-09-28 |
| CN1331731C (zh) | 2007-08-15 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| FA92 | Acknowledgement of application withdrawn (lack of supplementary materials submitted) |
Effective date: 20080625 |