RU2005114479A - Катализатор на основе смешанных оксидов металлов - Google Patents
Катализатор на основе смешанных оксидов металлов Download PDFInfo
- Publication number
- RU2005114479A RU2005114479A RU2005114479/04A RU2005114479A RU2005114479A RU 2005114479 A RU2005114479 A RU 2005114479A RU 2005114479/04 A RU2005114479/04 A RU 2005114479/04A RU 2005114479 A RU2005114479 A RU 2005114479A RU 2005114479 A RU2005114479 A RU 2005114479A
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- Russia
- Prior art keywords
- composition according
- sub
- catalyst
- elements
- catalytic composition
- Prior art date
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- 239000003054 catalyst Substances 0.000 title claims abstract 6
- 229910003455 mixed metal oxide Inorganic materials 0.000 title 1
- 239000000203 mixture Substances 0.000 claims abstract 13
- 239000010931 gold Substances 0.000 claims abstract 11
- 239000010955 niobium Substances 0.000 claims abstract 11
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 claims abstract 9
- KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 claims abstract 4
- OTMSDBZUPAUEDD-UHFFFAOYSA-N Ethane Chemical compound CC OTMSDBZUPAUEDD-UHFFFAOYSA-N 0.000 claims abstract 3
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims abstract 3
- 239000005977 Ethylene Substances 0.000 claims abstract 3
- 229910052787 antimony Inorganic materials 0.000 claims abstract 3
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims abstract 3
- 229910052742 iron Inorganic materials 0.000 claims abstract 3
- 229910052750 molybdenum Inorganic materials 0.000 claims abstract 3
- 229910052760 oxygen Inorganic materials 0.000 claims abstract 3
- 239000001301 oxygen Substances 0.000 claims abstract 3
- 229910052697 platinum Inorganic materials 0.000 claims abstract 3
- 229910052702 rhenium Inorganic materials 0.000 claims abstract 3
- 229910052718 tin Inorganic materials 0.000 claims abstract 3
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 claims abstract 2
- 229910052770 Uranium Inorganic materials 0.000 claims abstract 2
- 229910052782 aluminium Inorganic materials 0.000 claims abstract 2
- 229910052788 barium Inorganic materials 0.000 claims abstract 2
- 229910052796 boron Inorganic materials 0.000 claims abstract 2
- 229910052793 cadmium Inorganic materials 0.000 claims abstract 2
- 229910052792 caesium Inorganic materials 0.000 claims abstract 2
- 229910052791 calcium Inorganic materials 0.000 claims abstract 2
- 229910052804 chromium Inorganic materials 0.000 claims abstract 2
- 229910052802 copper Inorganic materials 0.000 claims abstract 2
- 229910052733 gallium Inorganic materials 0.000 claims abstract 2
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 claims abstract 2
- 229910052737 gold Inorganic materials 0.000 claims abstract 2
- 229910052735 hafnium Inorganic materials 0.000 claims abstract 2
- 229910052738 indium Inorganic materials 0.000 claims abstract 2
- 229910052741 iridium Inorganic materials 0.000 claims abstract 2
- 229910052746 lanthanum Inorganic materials 0.000 claims abstract 2
- 229910052745 lead Inorganic materials 0.000 claims abstract 2
- 229910052749 magnesium Inorganic materials 0.000 claims abstract 2
- 229910052748 manganese Inorganic materials 0.000 claims abstract 2
- 239000011733 molybdenum Substances 0.000 claims abstract 2
- 229910052759 nickel Inorganic materials 0.000 claims abstract 2
- 229910052758 niobium Inorganic materials 0.000 claims abstract 2
- GUCVJGMIXFAOAE-UHFFFAOYSA-N niobium atom Chemical compound [Nb] GUCVJGMIXFAOAE-UHFFFAOYSA-N 0.000 claims abstract 2
- 230000003647 oxidation Effects 0.000 claims abstract 2
- 238000007254 oxidation reaction Methods 0.000 claims abstract 2
- 229910052763 palladium Inorganic materials 0.000 claims abstract 2
- 229910052698 phosphorus Inorganic materials 0.000 claims abstract 2
- 229910052703 rhodium Inorganic materials 0.000 claims abstract 2
- 229910052701 rubidium Inorganic materials 0.000 claims abstract 2
- 229910052707 ruthenium Inorganic materials 0.000 claims abstract 2
- 229910052710 silicon Inorganic materials 0.000 claims abstract 2
- 229910052709 silver Inorganic materials 0.000 claims abstract 2
- 229910052712 strontium Inorganic materials 0.000 claims abstract 2
- 229910052715 tantalum Inorganic materials 0.000 claims abstract 2
- 229910052714 tellurium Inorganic materials 0.000 claims abstract 2
- 229910052719 titanium Inorganic materials 0.000 claims abstract 2
- 229910052720 vanadium Inorganic materials 0.000 claims abstract 2
- LEONUFNNVUYDNQ-UHFFFAOYSA-N vanadium atom Chemical compound [V] LEONUFNNVUYDNQ-UHFFFAOYSA-N 0.000 claims abstract 2
- 229910052725 zinc Inorganic materials 0.000 claims abstract 2
- 229910052726 zirconium Inorganic materials 0.000 claims abstract 2
- 230000003197 catalytic effect Effects 0.000 claims 7
- 239000008246 gaseous mixture Substances 0.000 claims 2
- 238000000034 method Methods 0.000 claims 2
- MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 claims 1
- 229910001882 dioxygen Inorganic materials 0.000 claims 1
- 239000007789 gas Substances 0.000 claims 1
- 229910052716 thallium Inorganic materials 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
- C07C51/21—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen
- C07C51/25—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of unsaturated compounds containing no six-membered aromatic ring
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
- B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/66—Silver or gold
- B01J23/68—Silver or gold with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/002—Mixed oxides other than spinels, e.g. perovskite
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
- B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/66—Silver or gold
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
- B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/66—Silver or gold
- B01J23/68—Silver or gold with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/683—Silver or gold with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium with chromium, molybdenum or tungsten
- B01J23/686—Silver or gold with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium with chromium, molybdenum or tungsten with molybdenum
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
- C07C51/21—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen
- C07C51/215—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of saturated hydrocarbyl groups
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2523/00—Constitutive chemical elements of heterogeneous catalysts
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Catalysts (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Claims (11)
1. Каталитическая композиция для окисления этана и/или этилена до уксусной кислоты, которая включает в сочетании с кислородом элементы молибден, ванадий, ниобий и золото в отсутствии палладия в соответствии с эмпирической формулой MoaWbAucVdNbeYf (I), в которой Y обозначает один или несколько элементов, выбранных из группы, включающей Cr, Mn, Та, Ti, В, Al, Ga, In, Pt, Zn, Cd, Bi, Ce, Co, Rh, Ir, Cu, Ag, Fe, Ru, Os, K, Rb, Cs, Mg, Ca, Sr, Ba, Zr, Hf, Ni, P, Pb, Sb, Si, Sn, T1, U, Re, Те и La, a a, b, c, d, e и f обозначают такие грамм-атомные соотношения элементов, при которых 0<а≤1;0≤b<1 и а+b=1; 10-5<c≤0,02; 0,4≤d≤0,865; 0,135≤e≤0,23; и 0,55≤d+e≤1; и 0≤f≤2.
2. Каталитическая композиция по п.1, выбранная из группы, включающей MoaWbAucVdNbeYf; MoaAucVdNbeYf; MoaWbAucVdNbe и MoaAucVdNbe.
3. Каталитическая композиция по п.1 или 2, в которой а>0,01, 0,0001<с≤0,002, 0,425≤d≤0,8, 0,14≤e≤0,20, 0,6≤d+e≤0,95 и f≤0,2.
4. Каталитическая композиция по п.3, в которой 0,0005<с≤0,001, 0,45≤d≤0,7, e≥0,15, d+e≤0,9 и f≤0,02.
5. Каталитическая композиция по п.4, в которой d≥0,5, e≤0,18 и d+e≥0,7.
6. Каталитическая композиция по п.5, в которой d+е≥0,8.
7. Каталитическая композиция по п.1 или 2, в которой а=1.
8. Каталитическая композиция по п.1 или 2, в которой Y имеет значения, выбранные из группы, включающей Sn, Sb, Cu, Pt, Ag, Fe и Re.
9. Каталитическая композиция по п.1, отвечающая формуле, выбранной из группы, включающей: Mo1,00V0,455Nb0,200Au0,0008Oy; Mo1,00V0,547Nb0,163Au0,0009Oy и Mo1,000V0,661Nb0,174Au0,0009Oy, где у обозначает число, которое соответствует валентностям элементов в композиции для кислорода.
10. Способ селективного получения уксусной кислоты из газообразной смеси, содержащей этан и/или этилен, который включает контактирование газообразной смеси с содержащим молекулярный кислород газом при повышенной температуре в присутствии каталитической композиции по одному из предыдущих пунктов.
11. Способ по п.10, в котором катализатор используют в форме псевдоожиженного слоя.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB0223681.8 | 2002-10-10 | ||
| GBGB0223681.8A GB0223681D0 (en) | 2002-10-10 | 2002-10-10 | Catalyst and process |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| RU2005114479A true RU2005114479A (ru) | 2006-01-20 |
| RU2350385C2 RU2350385C2 (ru) | 2009-03-27 |
Family
ID=9945751
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| RU2005114479/04A RU2350385C2 (ru) | 2002-10-10 | 2003-09-23 | Катализатор на основе смешанных оксидов металлов |
Country Status (18)
| Country | Link |
|---|---|
| US (1) | US20070185349A1 (ru) |
| EP (1) | EP1549432B1 (ru) |
| JP (1) | JP2006501993A (ru) |
| KR (1) | KR100978775B1 (ru) |
| CN (1) | CN100352543C (ru) |
| AT (1) | ATE521410T1 (ru) |
| AU (1) | AU2003267593A1 (ru) |
| BR (1) | BR0315236B1 (ru) |
| CA (1) | CA2501050C (ru) |
| GB (1) | GB0223681D0 (ru) |
| MY (1) | MY145211A (ru) |
| NO (1) | NO20052174L (ru) |
| RS (1) | RS20050277A (ru) |
| RU (1) | RU2350385C2 (ru) |
| SG (1) | SG157227A1 (ru) |
| TW (1) | TW200408446A (ru) |
| UA (1) | UA79643C2 (ru) |
| WO (1) | WO2004033090A1 (ru) |
Families Citing this family (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2005018804A1 (en) * | 2003-08-21 | 2005-03-03 | Bp Chemicals Limited | Catalyst composition and use thereof in ethane oxidation |
| RU2462307C1 (ru) * | 2011-05-30 | 2012-09-27 | Учреждение Российской академии наук Институт катализа им. Г.К. Борескова Сибирского отделения РАН | Катализатор и способ получения уксусной кислоты или смеси уксусной кислоты и этилацетата |
| DE102011109816B4 (de) * | 2011-08-09 | 2017-04-06 | Clariant Produkte (Deutschland) Gmbh | Katalysatormaterial für die Oxidation von Kohlenwasserstoffen |
| DE102011109774B4 (de) * | 2011-08-09 | 2017-04-20 | Clariant Produkte (Deutschland) Gmbh | Katalysatormaterial für die Oxidation von Kohlenwasserstoffen |
| WO2013164418A1 (en) * | 2012-05-04 | 2013-11-07 | Shell Internationale Research Maatschappij B.V. | Catalyst for alkane oxidative dehydrogenation and/or alkene oxidation |
| CN104649894B (zh) * | 2013-11-19 | 2017-06-06 | 中国石油天然气股份有限公司 | 丙烯醛选择性氧化制备丙烯酸的方法 |
| CN104649893B (zh) * | 2013-11-19 | 2016-07-13 | 中国石油天然气股份有限公司 | 一种制备不饱和酸的方法 |
Family Cites Families (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB8915410D0 (en) * | 1989-07-05 | 1989-08-23 | Bp Chem Int Ltd | Chemical process |
| GB9022127D0 (en) * | 1990-10-11 | 1990-11-21 | Bp Chem Int Ltd | Process |
| GB9807142D0 (en) * | 1998-04-02 | 1998-06-03 | Bp Chem Int Ltd | Catalyst and process utilising the catalyst |
| DE19823052A1 (de) * | 1998-05-22 | 1999-11-25 | Consortium Elektrochem Ind | Schalenkatalysator zur Herstellung von Essigsäure durch Gasphasenoxidation von gesättigten und/oder ungesättigten C4-Kohlenwasserstoffen |
| GB9819221D0 (en) * | 1998-09-04 | 1998-10-28 | Bp Chem Int Ltd | Process for the production of acetic acid |
| GB9907704D0 (en) * | 1999-04-01 | 1999-05-26 | Bp Chem Int Ltd | Catalyst and process utilising the catalyst |
| JP2001033149A (ja) * | 1999-07-19 | 2001-02-09 | Fujitsu General Ltd | 冷蔵庫 |
| DE10024437A1 (de) * | 2000-05-19 | 2001-11-29 | Aventis Res & Tech Gmbh & Co | Verfahren zur selektiven Herstellung von Essigsäure durch katalytische Oxidation von Ethan |
| US6407280B1 (en) * | 2000-09-28 | 2002-06-18 | Rohm And Haas Company | Promoted multi-metal oxide catalyst |
-
2002
- 2002-10-10 GB GBGB0223681.8A patent/GB0223681D0/en not_active Ceased
-
2003
- 2003-09-23 SG SG200702541-4A patent/SG157227A1/en unknown
- 2003-09-23 EP EP03748285A patent/EP1549432B1/en not_active Expired - Lifetime
- 2003-09-23 AT AT03748285T patent/ATE521410T1/de not_active IP Right Cessation
- 2003-09-23 RS YUP-2005/0277A patent/RS20050277A/sr unknown
- 2003-09-23 CA CA2501050A patent/CA2501050C/en not_active Expired - Fee Related
- 2003-09-23 UA UAA200504372A patent/UA79643C2/uk unknown
- 2003-09-23 AU AU2003267593A patent/AU2003267593A1/en not_active Abandoned
- 2003-09-23 CN CNB038239736A patent/CN100352543C/zh not_active Expired - Fee Related
- 2003-09-23 RU RU2005114479/04A patent/RU2350385C2/ru not_active IP Right Cessation
- 2003-09-23 JP JP2004542603A patent/JP2006501993A/ja not_active Ceased
- 2003-09-23 WO PCT/GB2003/004060 patent/WO2004033090A1/en active Application Filing
- 2003-09-23 US US10/530,715 patent/US20070185349A1/en not_active Abandoned
- 2003-09-23 KR KR1020057005976A patent/KR100978775B1/ko not_active Expired - Fee Related
- 2003-09-23 BR BRPI0315236-7A patent/BR0315236B1/pt not_active IP Right Cessation
- 2003-09-26 TW TW092126694A patent/TW200408446A/zh unknown
- 2003-10-07 MY MYPI20033826A patent/MY145211A/en unknown
-
2005
- 2005-05-03 NO NO20052174A patent/NO20052174L/no not_active Application Discontinuation
Also Published As
| Publication number | Publication date |
|---|---|
| EP1549432A1 (en) | 2005-07-06 |
| EP1549432B1 (en) | 2011-08-24 |
| BR0315236B1 (pt) | 2013-02-05 |
| AU2003267593A1 (en) | 2004-05-04 |
| SG157227A1 (en) | 2009-12-29 |
| TW200408446A (en) | 2004-06-01 |
| GB0223681D0 (en) | 2002-11-20 |
| RS20050277A (en) | 2007-06-04 |
| CA2501050A1 (en) | 2004-04-22 |
| JP2006501993A (ja) | 2006-01-19 |
| CA2501050C (en) | 2011-06-14 |
| RU2350385C2 (ru) | 2009-03-27 |
| BR0315236A (pt) | 2005-08-23 |
| MY145211A (en) | 2012-01-13 |
| US20070185349A1 (en) | 2007-08-09 |
| CN100352543C (zh) | 2007-12-05 |
| KR100978775B1 (ko) | 2010-08-30 |
| ATE521410T1 (de) | 2011-09-15 |
| NO20052174L (no) | 2005-05-03 |
| UA79643C2 (en) | 2007-07-10 |
| KR20050049527A (ko) | 2005-05-25 |
| WO2004033090A1 (en) | 2004-04-22 |
| CN1688389A (zh) | 2005-10-26 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| MM4A | The patent is invalid due to non-payment of fees |
Effective date: 20150924 |