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PT89423A - Processo para a preparacao de resinas epoxi avancadas modificadas - Google Patents

Processo para a preparacao de resinas epoxi avancadas modificadas Download PDF

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Publication number
PT89423A
PT89423A PT89423A PT8942389A PT89423A PT 89423 A PT89423 A PT 89423A PT 89423 A PT89423 A PT 89423A PT 8942389 A PT8942389 A PT 8942389A PT 89423 A PT89423 A PT 89423A
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PT
Portugal
Prior art keywords
γχχ
formula
quot
compound
epoxy resins
Prior art date
Application number
PT89423A
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English (en)
Other versions
PT89423B (pt
Inventor
John L Massingill Jr
Raul A Pabon Jr
Original Assignee
Dow Chemical Co
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Publication date
Application filed by Dow Chemical Co filed Critical Dow Chemical Co
Publication of PT89423A publication Critical patent/PT89423A/pt
Publication of PT89423B publication Critical patent/PT89423B/pt

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
    • C08G59/02—Polycondensates containing more than one epoxy group per molecule
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D163/00—Coating compositions based on epoxy resins; Coating compositions based on derivatives of epoxy resins
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
    • C08G59/02—Polycondensates containing more than one epoxy group per molecule
    • C08G59/04—Polycondensates containing more than one epoxy group per molecule of polyhydroxy compounds with epihalohydrins or precursors thereof
    • C08G59/06—Polycondensates containing more than one epoxy group per molecule of polyhydroxy compounds with epihalohydrins or precursors thereof of polyhydric phenols
    • C08G59/066—Polycondensates containing more than one epoxy group per molecule of polyhydroxy compounds with epihalohydrins or precursors thereof of polyhydric phenols with chain extension or advancing agents
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
    • C08G59/14—Polycondensates modified by chemical after-treatment
    • C08G59/1405—Polycondensates modified by chemical after-treatment with inorganic compounds
    • C08G59/1422—Polycondensates modified by chemical after-treatment with inorganic compounds containing phosphorus
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
    • C08G59/14—Polycondensates modified by chemical after-treatment
    • C08G59/1433—Polycondensates modified by chemical after-treatment with organic low-molecular-weight compounds
    • C08G59/1488—Polycondensates modified by chemical after-treatment with organic low-molecular-weight compounds containing phosphorus
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
    • C08G59/18—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
    • C08G59/20—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the epoxy compounds used
    • C08G59/22—Di-epoxy compounds
    • C08G59/226—Mixtures of di-epoxy compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
    • C08G59/18—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
    • C08G59/20—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the epoxy compounds used
    • C08G59/22—Di-epoxy compounds
    • C08G59/30—Di-epoxy compounds containing atoms other than carbon, hydrogen, oxygen and nitrogen

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Health & Medical Sciences (AREA)
  • General Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Inorganic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Epoxy Resins (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Description

ο DESCRIÇÃO DA PATENTE DE INVENÇÃO N-° 89 423
REQUERENTE: THE DOW CHEMICAL COMPANY, norte-americana, com sede em 20 30 Dow Center, Abbott Road, Midland, Michigan 48640 Estados Unidos da América do Norte. EPÍGRAFE: ·· PROCESSO PARA A PREPARAÇAO DE RESINAS EPOXI AVANÇADAS MODIFICADAS INVENTORES: John L.Massingill, Jr. e Raul A Pabon, Jr.
Reivindicação do direito de prioridade ao abrigo do artigo 4.° da Convenção de Paris de 20 de Março de 1883. Estados Unidos da América do Norte,em 13 de Janeiro de 1988, sob ο ηδ . 143,558. INP1. MOO. 113 RF 16732
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Claims (1)

  1. \
    V
    Ο -Ο ΡΟΊ'· o. 1 - i ; f ι c ?.ο ?· carac r,er iza.do por sa proc soar - raac ·; 5 o \ ··’: · ΟΡΡΟ :'ã;SÍ0 f i'J Ρ;ρ·:_,*:. 1 V'.’ ;_;v d'J'? pOS; C S“ S U i. PP ã: 0- S a S C CS·-1 U-; 1 uma. co^poíícso o a rsiiri? apoxi compr eanaanoo (a; paio manos,· uma rasinã epoxi ta· οό·:· uma Χ:·:!.;ί Pa pai a pua um, pas náo rnais ao pua dois prupass apa· · . i vizinooa iiiO ί èc 1 s a pua contas1 paio manos; uu çri-^o o - a lS:j Isno ou oa- i quiruno íuosiiouaio por mo 1 âc u I a ; a > ,:d; psi o manos um c *1‘SV-p*o»'ís to tanoo oois ρη'ορ·ο..· ·" o ore· .· .i ^ ._· aro-· o : por moiaculs; a 0··!· PUS: OS c oppOnan o a;· : i: ' £ *. j.5 z? ·:.4 c · ’ d; ; ::·.·_· a··: · a.:. ":: i *: v;u f ·;· r na c ao o a si a rala â a. o o a 3 r upos h i o ·’ aso i i ·.:· -1 Γ . d · ' Í r : 0-0 ΡΟΓ 'li vp·· ca- o o a d ; . ; ;i 1 .a : i; c om 1 a-o ·. o '.· um costposto contando fósforo seiacc lonaco --nora f 1 - a c i cio f oo f 6r i co ; a- acioo supar fosfórico, - . : s· ·. so '' :: . .. * a1 ata v C1, o U ; .o o cua 1 quar combina·; So óa camparo an o ao fo— li, '·. b_u) ou ·. 5* o·s ; am pua os c omponan ·: as (A) a < S > estão pre santas raia --uant xo lai pua a raι açSc· oa mo 1 es oa componan ta - ο·. ; p-a ra 3ropOS ap contidos no componente (A) é óa 0, i:1 a 5:1.
    2ê . - Processo da acordo com a rai v i no i cc-, r i. z: - o Ρ'_·Γ os c a· i ; i;-: ο ί ί a n o- a ·. h í i c vO - ρ· .u:- ρ. sp ·, · s _· · o - pcí-Oj ursa rasina epo.xi a qual tem uma ;··ό=·ό i os: ao; n r. — i a Ό ... pua a r <_ a. Oa CO 1 s pr uia-a-s -, 1 o· l 0 1 )’ 1 s; pua d . r iapo f a oa resina ap··.· i de ·. A-l-a· : ···· o tos ad-o: a r á-; .-o as t«o presentes --o qu-no mame o a ·::''· a·.· s:m aqo i va i trPvC s ca·;. \
    ο/ \ H2C ç CH2 R Ο/ \ ch2 -C —CH2 I R
    DO J. 1
    \ -CH-CH- R2 R1 XX *—· X τ,: L ,ρ X ·:.* Γ" 'Γ.Γ Χ\ SciO 1 ΠΟΟΡ'Χ1 Π ;ΐί*~ \~· ν XX ;Χ XX X ; ‘ r I ·’: -' ;Χ ·ρ ·Χ X 1 X 0'X X : : X χ 10 χχ·: χ 'χ ι , χ- ·:·χ χ x:xxxcaro: ioxi txx-I - 1,1 ao a caxo:: xx ':)Xrv “ x-x —x ~ a·'·'· x a fc~ á χχ -Γν.'^ρο χ ι x x ·. I ·: ί χχχχ· χχ-- ~ -- ,. X · X X ' X ; a ί. 9. ϋΐΛ Γί; X ·:! : 7·.'··!: 1 XX·;. X X X 'X X; - - -ν: , X X X V ο .· χ ·: χχρ·χχχπ χχ < Α·~·1~χ> sa r χχχ ra·.-.-? : χ a τ.:χ··_·.· ι χ·χ -'.ixtx—x ' -τΧ λ X .--. ζ: :. ί Γ Xi"1 X a ! "ί I-ΟΟ pc? ί * Ο '1' ΓΧΧ I -Χ X 'X X: X XX X X X V., | , V X | ϊ ’· χ·χ χ ·*χ χ χ;··χ· ι · - χ όχχ ·
    Formula VIII
    0 / \ C — C«2 I R Formula IX O / \ ch2 - c —ch2 I R O / \ HoC - C-CH20 -(-CH-CH-0)m I I I R R2 RI orrriu i
    Formula V
    Formula VI
    η τ_. r .¾ ·) Γ·? η ·}. χ _·*
    RUA VlCTCil CC-nCOM. 10-A. ΚΙ 200 USSOA
PT89423A 1988-01-13 1989-01-11 Processo para a preparacao de resinas epoxi avancadas modificadas PT89423B (pt)

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US5248741A (en) * 1987-07-16 1993-09-28 The Dow Chemical Company Cationic, advanced epoxy resin compositions incorporating glycidyl ethers of oxyalkylated aromatic or cycloaliphatic diols
US5021470A (en) * 1987-07-24 1991-06-04 Basf Corporation Flexible aryl alkyl epoxy resins, their amine resin derivatives and their use in electrodeposition coatings
CA1336029C (en) * 1987-11-06 1995-06-20 Michiharu Kitabatake Coating resin composition containing an epoxy-polyamine resin
US5360838A (en) * 1987-12-03 1994-11-01 The Dow Chemical Company Cationic, capped advanced epoxy resin compositions from glycidyl ethers of oxyalkylated aromatic or cycloaliphatic diols
AU612794B2 (en) * 1988-01-13 1991-07-18 Dow Chemical Company, The Modified advanced epoxy resins
EP0358096A3 (en) * 1988-09-07 1990-09-26 The Dow Chemical Company Organic solvent solutions of phosphate esters of epoxy resins
US5086094A (en) * 1988-09-07 1992-02-04 The Dow Chemical Company Organic solvent solutions of phosphate esters of epoxy resins
US4952646A (en) * 1989-07-20 1990-08-28 Akzo America Inc. Epoxy resin compositions containing a polyphosphoric/polyphosphonic anhydride curing agent
FR2650794B1 (fr) * 1989-08-08 1991-11-29 Bennes Marrel Dispositif de bennage a bras modulaires
MY106546A (en) * 1990-05-15 1995-06-30 Dow Chemical Co Advanced and unadvanced compositions, nucleophilic derivatives thereof curable and coating compositions thereof
US5244998A (en) * 1990-05-15 1993-09-14 The Dow Chemical Company Advanced and unadvanced compositions, nucleophilic derivatives thereof and curable coating compositions thereof
US5095050A (en) * 1990-11-21 1992-03-10 The Dow Chemical Company Advanced epoxy compositions, curable compositions and cured products
GB9027406D0 (en) * 1990-12-18 1991-02-06 Ciba Geigy Ag Production of compounds
JPH04268319A (ja) * 1991-02-22 1992-09-24 Dow Chem Nippon Kk 水分散可能なエポキシ樹脂及びその製造方法
BR9305824A (pt) * 1992-01-28 1997-02-18 Dow Chemical Co Composição composição curável ou composição de revestimento
JPH07179728A (ja) * 1993-12-21 1995-07-18 Yuka Shell Epoxy Kk 半導体封止用難燃化エポキシ樹脂組成物
JP3308397B2 (ja) * 1994-07-07 2002-07-29 住友ベークライト株式会社 半導体封止用エポキシ樹脂組成物
GB9421405D0 (en) * 1994-10-21 1994-12-07 Dow Chemical Co Low voc laminating formulations
US5993787A (en) * 1996-09-13 1999-11-30 Johnson & Johnson Consumer Products, Inc. Composition base for topical therapeutic and cosmetic preparations
US5811498A (en) * 1997-04-16 1998-09-22 The Dexter Corporation α-glycol endcapped resins, their method of manufacture, and compositions containing the same
KR100740895B1 (ko) * 2005-12-30 2007-07-19 제일모직주식회사 재작업이 가능한 고신뢰성 반도체 사이드필용 액상 에폭시수지 조성물 및 이를 이용한 반도체 소자
US10550220B2 (en) * 2015-03-19 2020-02-04 Zephyros, Inc. Esterified acids for use in polymeric materials
EP3348621A1 (en) * 2017-01-16 2018-07-18 ALLNEX AUSTRIA GmbH Aqueous coating composition for corrosion protection
JP6854661B2 (ja) * 2017-02-10 2021-04-07 株式会社Adeka 樹脂組成物及び硬化物

Family Cites Families (19)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3937679A (en) * 1968-10-31 1976-02-10 Ppg Industries, Inc. Electrodepositable compositions
US3842037A (en) * 1972-06-08 1974-10-15 Shell Oil Co Process for preparing higher molecular weight polyepoxide products by condensing lower molecular weight polyepoxide with polyhydric phenols
US4256844A (en) * 1976-12-23 1981-03-17 The Dow Chemical Company Fire retardant, thermosetting, resinous reaction products of phosphoric acid and methyol- or alkoxymethyl-substituted epoxides
US4164487A (en) * 1976-12-23 1979-08-14 The Dow Chemical Company Water-thinnable mixtures of base-neutralized products of reaction of H3 PO4 with polyether epoxides and with other type epoxides
US4289812A (en) * 1977-11-21 1981-09-15 The Dow Chemical Company Method of water-solubilizing high performance polyether epoxide resins, the solubilized resins and thermoset, hydrophobic coatings derived therefrom
US4316922A (en) * 1980-10-23 1982-02-23 The Dow Chemical Company Aqueous epoxy phosphate dispersions comprising n-butanol, n-hexanol and ethylene glycol monobutyl ether
US4360613A (en) * 1981-05-18 1982-11-23 Celanese Corporation Ether-ester water reducible coating compositions
US4397970A (en) * 1981-06-24 1983-08-09 The Dow Chemical Company Process for epoxy phosphate coating resins
US4608313A (en) * 1982-06-10 1986-08-26 The Dow Chemical Company Advanced epoxy resins crosslinked with polyisocyanates
AU571499B2 (en) * 1983-04-01 1988-04-21 Dow Chemical Company, The Preparing epoxy resins
US4452929A (en) * 1983-09-09 1984-06-05 Celanese Corporation Water reducible epoxy based coating compositions
US4507461A (en) * 1983-10-14 1985-03-26 Wilmington Chemical Corporation Low viscosity epoxy resins
US4481347A (en) * 1983-10-24 1984-11-06 The Dow Chemical Company Epoxy resins containing phosphorus
GB2158074B (en) * 1984-05-01 1987-09-16 Asahi Denka Kogyo Kk Coating composition
CA1262794A (en) * 1984-09-10 1989-11-07 Terence J. Hart Blends of phosphated epoxy and acrylic resins and the use thereof in coating compositions
US4613661A (en) * 1985-05-28 1986-09-23 The Dow Chemical Company Epoxy phosphate compositions
DE3601560A1 (de) * 1986-01-21 1987-07-23 Herberts Gmbh Waessriges, hitzehaertbares ueberzugsmittel, dessen verwendung und damit beschichtete gegenstaende
US4692382A (en) * 1986-07-21 1987-09-08 Ppg Industries, Inc. Elastomeric coating compositions
GB8712121D0 (en) * 1987-05-22 1987-06-24 Dow Chemical Rheinwerk Gmbh Film-forming resin compositions

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KR900700517A (ko) 1990-08-13
WO1989006661A1 (en) 1989-07-27
JP2670160B2 (ja) 1997-10-29
JPH02502927A (ja) 1990-09-13
PT89423B (pt) 1993-09-30
ZA89291B (en) 1990-09-26
MY104947A (en) 1994-07-30
US4820784A (en) 1989-04-11
EP0324389A3 (en) 1990-09-26
NO893641L (no) 1989-09-12
BR8807419A (pt) 1990-05-15
CA1299804C (en) 1992-04-28
NO893641D0 (no) 1989-09-12
NO173392B (no) 1993-08-30
AU2945489A (en) 1989-08-11
NO173392C (no) 1993-12-08
EP0324389A2 (en) 1989-07-19

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