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MX2010014054A - Aparatos y metodos para polimerizacion radical controlada. - Google Patents

Aparatos y metodos para polimerizacion radical controlada.

Info

Publication number
MX2010014054A
MX2010014054A MX2010014054A MX2010014054A MX2010014054A MX 2010014054 A MX2010014054 A MX 2010014054A MX 2010014054 A MX2010014054 A MX 2010014054A MX 2010014054 A MX2010014054 A MX 2010014054A MX 2010014054 A MX2010014054 A MX 2010014054A
Authority
MX
Mexico
Prior art keywords
radical polymerization
controlled radical
metal
mixture
methods
Prior art date
Application number
MX2010014054A
Other languages
English (en)
Inventor
F Jacobine Anthony
G Woods John
M Glaser David
Coffey Roderick
Original Assignee
Henkel Corp Star
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Henkel Corp Star filed Critical Henkel Corp Star
Publication of MX2010014054A publication Critical patent/MX2010014054A/es

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/38—Polymerisation using regulators, e.g. chain terminating agents, e.g. telomerisation
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J19/18—Stationary reactors having moving elements inside
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/02—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds
    • B01J8/0242—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds the fluid flow within the bed being predominantly vertical
    • B01J8/025—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds the fluid flow within the bed being predominantly vertical in a cylindrical shaped bed
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10—Esters
    • C08F220/12—Esters of monohydric alcohols or phenols
    • C08F220/16—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
    • C08F220/18—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
    • C08F220/1802—C2-(meth)acrylate, e.g. ethyl (meth)acrylate
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00049—Controlling or regulating processes
    • B01J2219/00051—Controlling the temperature
    • B01J2219/00074—Controlling the temperature by indirect heating or cooling employing heat exchange fluids
    • B01J2219/00087—Controlling the temperature by indirect heating or cooling employing heat exchange fluids with heat exchange elements outside the reactor
    • B01J2219/00094—Jackets
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10—Esters
    • C08F220/12—Esters of monohydric alcohols or phenols
    • C08F220/16—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
    • C08F220/18—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
    • C08F220/1804—C4-(meth)acrylate, e.g. butyl (meth)acrylate, isobutyl (meth)acrylate or tert-butyl (meth)acrylate
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10—Esters
    • C08F220/26—Esters containing oxygen in addition to the carboxy oxygen
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2400/00—Characteristics for processes of polymerization
    • C08F2400/02—Control or adjustment of polymerization parameters
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2438/00—Living radical polymerisation
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2438/00—Living radical polymerisation
    • C08F2438/01—Atom Transfer Radical Polymerization [ATRP] or reverse ATRP

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Physics & Mathematics (AREA)
  • Fluid Mechanics (AREA)
  • Polymerisation Methods In General (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Polymerization Catalysts (AREA)
  • Graft Or Block Polymers (AREA)

Abstract

Se describe un método para conducir la polimerización radical controlada, que incluye: (a) proporcionar una mezcla de: por lo menos un monómero; por lo menos un solvente de monómero; por lo menos un metal compuesto capaz de coordinación; y por lo menos un iniciador; (b) dirigir la mezcla a una velocidad sobre una superficie sólida del catalizador contenida en una cámara externa al recipiente, el catalizador incluye un metal o compuesto de metal capaz de por lo menos dos etapas de oxidación; (c) supervisar la temperatura del recipiente de reacción; (d) ajustar el caudal cuando la temperatura está fuera del intervalo de temperatura seleccionado; y (e) permitir que la polimerización proceda al nivel de conversión deseado.
MX2010014054A 2008-06-18 2009-06-17 Aparatos y metodos para polimerizacion radical controlada. MX2010014054A (es)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US7362608P 2008-06-18 2008-06-18
PCT/US2009/047579 WO2009155303A2 (en) 2008-06-18 2009-06-17 Apparatus and methods for controlled radical polymerization

Publications (1)

Publication Number Publication Date
MX2010014054A true MX2010014054A (es) 2011-03-21

Family

ID=41434682

Family Applications (1)

Application Number Title Priority Date Filing Date
MX2010014054A MX2010014054A (es) 2008-06-18 2009-06-17 Aparatos y metodos para polimerizacion radical controlada.

Country Status (9)

Country Link
EP (1) EP2291412B1 (es)
JP (1) JP5642671B2 (es)
KR (1) KR101600117B1 (es)
CN (1) CN102099382B (es)
BR (1) BRPI0914145A2 (es)
CA (1) CA2730262C (es)
ES (1) ES2432385T3 (es)
MX (1) MX2010014054A (es)
WO (1) WO2009155303A2 (es)

Families Citing this family (30)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US8815971B2 (en) 2008-12-22 2014-08-26 ATRP Solutions, Inc. Control over controlled radical polymerization processes
US8822610B2 (en) 2008-12-22 2014-09-02 ATRP Solutions, Inc. Control over controlled radical polymerization processes
US9783628B2 (en) 2009-04-23 2017-10-10 ATRP Solutions, Inc. Dual-mechanism thickening agents for hydraulic fracturing fluids
US10273314B2 (en) * 2010-07-23 2019-04-30 Rohm And Haas Company Set-LRP polymerization of acrylates in the presence of acids
US8436094B2 (en) 2010-08-25 2013-05-07 Henkel Corporation Curable compositions with moisture-curable functionality clusters near the chain ends
US9587064B2 (en) 2010-12-08 2017-03-07 ATRP Solutions, Inc. Salt-tolerant star macromolecules
IN2014CN02321A (es) 2011-08-30 2015-06-19 Basf Se
KR20140070551A (ko) 2011-09-19 2014-06-10 헨켈 유에스 아이피 엘엘씨 좁지만 양봉형 분자량 분포를 갖는 (메트)아크릴레이트-기능성 폴리아크릴레이트 수지
DK2768900T3 (da) 2011-09-19 2020-05-18 Henkel IP & Holding GmbH Højfunktionaliserede harpiksblandinger
JP6294885B2 (ja) 2012-08-30 2018-03-14 エーティーアールピー ソリューションズ インコーポレイテッドＡＴＲＰ Ｓｏｌｕｔｉｏｎｓ，Ｉｎｃ． 星形高分子、星形高分子組成物および星形高分子の製造方法
US9006362B2 (en) * 2012-10-16 2015-04-14 Henkel IP & Holding GmbH Controlled radical polymerization of (meth)acrylate monomers
JP6056628B2 (ja) * 2012-11-28 2017-01-11 東ソー株式会社 フマル酸ジエステル−ケイ皮酸エステル系共重合体及びその製造方法
JP5998878B2 (ja) * 2012-11-28 2016-09-28 東ソー株式会社 フマル酸ジイソプロピル−ケイ皮酸エステル−アクリレート共重合体及びその製造方法
CN104812789B (zh) * 2012-11-28 2016-08-31 东曹株式会社 富马酸二酯-肉桂酸酯类共聚物、其制造方法及使用其的膜
JP6040752B2 (ja) * 2012-12-14 2016-12-07 東ソー株式会社 フマル酸ジイソプロピル−ケイ皮酸エステル−アクリレート共重合樹脂及びその製造方法
WO2014099748A1 (en) * 2012-12-18 2014-06-26 Henkel US IP LLC Process of controlled radical polymerization of branched polyacrylates
JP6700789B2 (ja) 2013-02-04 2020-05-27 パイロット ポリマー テクノロジーズ， インク． 耐塩性星形高分子、耐塩性星形高分子を含む耐塩性増粘剤、耐塩性組成物の製造方法、含水組成物を耐塩性化する方法、星形高分子の製造方法
US8883941B2 (en) * 2013-03-18 2014-11-11 Henkel Corporation Methods and apparatus for controlled single electron transfer living radical polymerization
CN103954732B (zh) * 2014-04-21 2015-12-02 浙江大学 一种测定乳液聚合中自由基从乳胶粒子脱吸进入连续相速率的方法
MX385886B (es) 2014-07-03 2025-03-18 Pilot Polymer Tech Inc Macromoleculas estrellas compatibles con tensoactivos.
JP2016102200A (ja) * 2014-11-17 2016-06-02 ナガセケムテックス株式会社 （メタ）アクリル酸エステル共重合体、樹脂組成物及び硬化物
EP3230327A4 (en) * 2014-12-08 2018-07-18 Henkel IP & Holding GmbH Process for making branched reactive block polymers
US9587062B2 (en) * 2014-12-15 2017-03-07 Henkel IP & Holding GmbH and Henkel AG & Co. KGaA Photocrosslinkable block copolymers for hot-melt adhesives
CN108641052B (zh) * 2018-05-16 2020-12-11 东北师范大学 一种卤代聚合物、聚合物薄膜及其制备方法和应用
FR3081554B1 (fr) * 2018-05-23 2021-05-21 Electricite De France Procede de controle non-destructif de gaine isolante elastomere de cable, dispositif et programme
WO2020131445A1 (en) * 2018-12-19 2020-06-25 Henkel Ag & Co. Kgaa Direct to substrate coating via in situ polymerization
CN112011002B (zh) * 2019-05-29 2023-09-26 立邦工业涂料(上海)有限公司 受控自由基聚合的方法以及用于受控自由基聚合的装置
TWI721476B (zh) * 2019-07-01 2021-03-11 國立中興大學 可塑性熱固型樹脂及其製備方法
US20240294689A1 (en) 2019-10-16 2024-09-05 Basf Coatings Gmbh Super advanced controlled radical polymerization
CN115010842B (zh) * 2022-05-20 2024-02-02 万华化学集团股份有限公司 一种含氟强碱性阴离子树脂催化剂、制备方法及一种（甲基）丙烯酸羟乙酯的制备方法

Family Cites Families (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5763548A (en) * 1995-03-31 1998-06-09 Carnegie-Mellon University (Co)polymers and a novel polymerization process based on atom (or group) transfer radical polymerization
US7125938B2 (en) * 1997-03-11 2006-10-24 Carnegie Mellon University Atom or group transfer radical polymerization
JP2000053723A (ja) * 1998-08-11 2000-02-22 Kanegafuchi Chem Ind Co Ltd 水酸基末端重合体組成物及び用途
DE60041644D1 (de) * 1999-06-08 2009-04-09 Kaneka Corp Verfahren zur kontinuierlichen katonischen lebenden polymerisation
US6639029B1 (en) * 2000-11-13 2003-10-28 Rohmax Additives Gmbh Process for continuous synthesis of polymer compositions as well as use of same
US7345127B2 (en) * 2001-03-23 2008-03-18 University Of Pennsylvania Living radical polymerization of halogen-containing and acrylic monomers and the formation of block copolymers therefrom
JP4323406B2 (ja) * 2004-10-04 2009-09-02 住友化学株式会社 連続重合装置およびそれを用いた連続重合方法
JP2006199728A (ja) * 2005-01-18 2006-08-03 Kaneka Corp ラジカル重合体の製造方法

Also Published As

Publication number Publication date
CN102099382B (zh) 2014-01-29
BRPI0914145A2 (pt) 2015-10-20
CN102099382A (zh) 2011-06-15
EP2291412B1 (en) 2013-07-24
ES2432385T3 (es) 2013-12-03
KR101600117B1 (ko) 2016-03-04
KR20110042287A (ko) 2011-04-26
WO2009155303A2 (en) 2009-12-23
JP2011524942A (ja) 2011-09-08
JP5642671B2 (ja) 2014-12-17
EP2291412A2 (en) 2011-03-09
EP2291412A4 (en) 2011-09-21
CA2730262C (en) 2015-06-09
CA2730262A1 (en) 2009-12-23
WO2009155303A3 (en) 2010-04-22

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