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KR970070175A - 킬레이트화제 및 그로 이루어진 세정제 - Google Patents

킬레이트화제 및 그로 이루어진 세정제 Download PDF

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KR970070175A
KR970070175A KR1019960069234A KR19960069234A KR970070175A KR 970070175 A KR970070175 A KR 970070175A KR 1019960069234 A KR1019960069234 A KR 1019960069234A KR 19960069234 A KR19960069234 A KR 19960069234A KR 970070175 A KR970070175 A KR 970070175A
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diacetic
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히로시 야마모또
야스유끼 다까야나기
기요부미 다까하시
데뜨로 나까하마
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니또가가꾸고오교 가부시끼가이샤
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    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/38—Cationic compounds
    • C11D1/62—Quaternary ammonium compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/26—Organic compounds containing nitrogen
    • C11D3/33—Amino carboxylic acids
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/20—Organic compounds containing oxygen
    • C11D3/2075—Carboxylic acids-salts thereof
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/20—Organic compounds containing oxygen
    • C11D3/2075—Carboxylic acids-salts thereof
    • C11D3/2082—Polycarboxylic acids-salts thereof
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/20—Organic compounds containing oxygen
    • C11D3/2075—Carboxylic acids-salts thereof
    • C11D3/2086—Hydroxy carboxylic acids-salts thereof
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/34—Organic compounds containing sulfur
    • C11D3/349—Organic compounds containing sulfur additionally containing nitrogen atoms, e.g. nitro, nitroso, amino, imino, nitrilo, nitrile groups containing compounds or their derivatives or thio urea
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/34—Organic compounds containing sulfur
    • C11D3/3472—Organic compounds containing sulfur additionally containing -COOH groups or derivatives thereof

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Abstract

본 발명은 하기 화학식(1)의 화합물, 및 아스팔트산, 말레산, 아크릴산, 말산, 글리신, 글리콜산, 아미노디아세트산, 니트릴로트아세트산, α-알라닌, β-알라닌, 이미노디프로피온산, 푸말산, 합성 출발 아미노산, 합성 중간체 아미노산, 및 그의 염으로 구성된 군으로분터 선택된, 화학식(1)의 화합물을 기준으로 8중량% 이하량의 1종 이상의 화합물로 이루어진 생분해성 킬레이트화제에 관한 것이다.
[식중, R1은 수소 또는 탄소수 1-10의 비치환 또는 치환 탄화수소를 나타내고 R2는 수소 또는 탄소수 1-8의 비치환 또는 치환 탄화수소기를 나타내며, 단 R1및 R2는 함께 고리를 형성할 수 있고, R1및 R2에 존재할 수 있는 치환기는 -OH, -CO2M 및 -SO3M(식중, M은 수소 또는 알카리 금속을 나타낸다)로 구성된 군으로부터 선택되는 1종 이상이고; X는를 나타낸다: 식중, R3는 수소 또는 탄소수 1-8 비치환 또는 치환 탄화수소기를 나타내고, 치환기는 -OH, -CO2M 및 -SO3M으로 구성된 군으로부터 선택된 1종 이상을 나타내고, A1및 A2는 각각 수소, CO2M 및 SO3M로 구성된 군으로부터 선택된 1종 이상을 나타내고, A5는 직쇄 또는 분지쇄이거나 고리를 형성할 수 있는 탄소수 1-8의 알킬렌기를 나타내고, 상기 알킬렌기는 사슬내에 에테르 결합 -O-, 에스테르 결합-COO-, 또는 아미드 결합 -CONH-를 함유할 수 있고, M은 수소 또는 알카리 금속을 나타내고, n은 1-8의 정수를 나타내며; Y는 수소, CO2M 및 SO3M으로 구성된 군으로부터 선택된 1종 이상을 나타낸다].

Description

킬레이트화제 및 그로 이루어진 세정제
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (17)

  1. 화학식(1)의 화합물, 및 아스팔트산, 말레산, 아크릴산, 말산, 글리신, 글리콜산, 아미노디아세트산, 니트릴로트아세트산, α-알라닌, β-알라닌, 이미노디프로피온산, 푸말산, 합성 출발 아미노산, 합성 중간체 아미노산, 및 그의 염으로 구성된 군으로분터 선택된, 화학식(1)의 화합물을 기준으로 8중량% 이하량의 1종 이상의 화합물로 이루어진 킬레이트화제:
    [식중, R1은 수소 또는 탄소수 1-10의 비치환 또는 치환 탄화수소를 나타내고 R2는 수소 또는 탄소수 1-8의 비치환 또는 치환 탄화수소기를 나타내며, 단 R1및 R2는 함께 고리를 형성할 수 있고, R1및 R2에 존재할 수 있는 치환기는 -OH, -CO2M 및 -SO3M(식중, M은 수소 또는 알카리 금속을 나타낸다)로 구성된 군으로부터 선택되는 1종 이상이고; X는를 나타낸다: 식중, R3는 수소 또는 탄소수 1-8 비치환 또는 치환 탄화수소기를 나타내고, 치환기는 -OH, -CO2M 및 -SO3M으로 구성된 군으로부터 선택된 1종 이상이고 R4는 수소, CO2M 및 SO3M으로 구성된 군으로부터 선택된 1종 이상을 나타내고, A1및 A2는 각각 수소, CO2M 및 SO<A5M로 구성된 군으로부터 선택된 1종 이상을 나타내고, A3는 직쇄 또는 분지쇄이거나 고리를 형성할 수 있는 탄소수 1-8의 알킬렌기를 나타내고, 상기 알킬렌기는 사슬내에 에테르 결합 -O-, 에스테르 결합-COO-, 또는 아미드 결합 -CONH-를 함유할 수 있고, M은 수소 또는 알카리 금속을 나타내고, n은 1-8의 정수를 나타내며; Y는 수소, CO2M 및 SO3M으로 구성된 군으로부터 선택된 1종 이상을 나타낸다].
  2. 하기 화학식(1)의 화합물, 및 아스팔트산, 말레산, 아크릴산, 말산, 글리신, 글리콜산, 아미노디아세트산, 니트릴로트아세트사, α-알라닌, β-알라닌, 이미노디프로피온산, 푸말산, 합성 출발 아미노산, 합성 중간체 아미노산, 및 그의 염으로 구성된 군으로분터 선택된, 화학식(1)의 화합물을 기준으로 총25중량% 이하량의 1종 이상의 화합물로 이루어진 수용액 또는 슬러리 형태의 킬레이트화제:
    〔식중, R1은 수소 또는 탄소수 1-10의 비치환 또는 치환 탄화수소기를 나타내고 R2는 수소 또는 탄소수 1-8의 비치환 또는 치환 탄화수소기를 나타내며, 단 R1및 R2는 함께 고리를 형성할 수 있고, R1및 R2에 존재할 수 있는 치환기는 -OH, -CO2M 및 -SO3M(식중, M은 수소 또는 알카리 금속을 나타낸다)로 구성된 군으로부터 선택되는 1종 이상이고; X는를 나타낸다: 식중, R3는 수소 또는 탄소수 1-8의 비치환 또는 치환 탄화수소기를 나타내고, 치환기는 -OH, -CO2M 및 -SO3M으로 구성된 군으로부터 선택되는 1종 이상이고, R4는 수소, -CO2M 및 -SO3M으로 구성된 군으로부터 선택된 1종 이상을 나타내고, A1및 A2는 각각 수소, CO2M 및 SO3M로 구성된 군으로부터 선택된 1종 이상을 나타내고, A5는 직쇄 또는 분지쇄이거나 고리를 형성할 수 있는 탄소수 1-8의 알킬렌기를 나타내고, 상기 알킬렌기는 사슬내에 에테르 결합 -O-, 에스테르 결합-COO-, 또는 아미드 결합 -CONH-를 함유할 수 있고, M은 수소 또는 알카리 금속을 나타내고, n은 1-8의 정수를 나타내며; Y는 수소, CO2M 및 SO3M으로 구성된 군으로부터 선택된 1종 이상을 나타낸다〕.
  3. 제1 또는 제2항에 있어서, 화학식(1)내의 X가(식중, R3및 R4는 상기 정의된 바와 같음)인 킬레이트화제.
  4. 제1항 또는 제2항에 있어서, 화학식 1 내지 X가(식중, A3, A2및 A3는 상기 정의된 바와 같음)인 킬레이트화제.
  5. 제3항에 있어서, 화학식(1)의 화합물이 아스팔트산-N-모노아세트산, 아스팔트산-N, N-디아세트산, 아스팔트산-N-모노프로피온산, 이미노디숙신산, N-(2-술포메틸)아스팔트산, N-(2-술포에틸)아스팔트산, 글루탐산-N, N-디아세트산, N-(2-술포메틸)글루탐산, N-2-술포에틸)글루탐산 N-메틸이미노디아세트산, α-알라닌-N, N-디아세트산, β-알레닌-N, N-디아세트산, 세린-N, N-디아세트산, 이소세린-N, N-디아세트산, 페닐알라닌-N, N-디아세트산, 안트라닐산-N, N-디아세트산, 술파닐산-N,N-디아세트산, 타우린-N,N-디아세트산, 및 술포메틸-N,N-디아세트산 및 그의 알카리 금속염 또는 암모늄염으로 이루어진 군으로부터 선택되는 킬레이트화제.
  6. 제3항에 있어서, 화학식(1)의 혼합물이 (S)-아스팔트산-모노아세트산, (S)-아스팔트산-N,N-디아세트산, (S)-아스팔트산-모노프로피온산, (S,S)-아미노디숙신산, (S,R)-이미노디숙신산, (S)-2-술포메틸글루탐산, (S)-2-슬포에틸아스팔트산, -(S)-글루탐산-N,N-디아세트산, (S)-2-술포메틸글루탐산, (S)-2-술포에틸글루탐산, (S)-α-알라닌-N,N-디아세트산, (2)-세린-N,N-디아세트산, 및 (S)-페닐알라닌-N,N-디아세트산 및 그의 알카리 금속염 또는 암모늄염으로 이루어진 군으로부터 선택되는 킬레이트화제.
  7. 제4항에 있어서, 화학식(1)의 화합물이 에틸렌디아민디숙신산, 1,3-프로판디아민디숙신산, 에틸렌디아민디글루타르산, 1,3-프로판디아민디글루타르산, 2-히드록시-1,3-프로판디아민디숙신산, 2-히드록시-1,3-프로판디아민디글루타르산 및 그의 알카리 금속염으로 이루어진 군으로부터 선택되는 킬레이트화제.
  8. 제4항에 있어서, 화학식(1)의 화합물이 (S,S)-에틸렌디아민디숙신산, (S,S)-1,3-프로판디아민디숙신산, (S,S)-에틸렌디아민디글루타르산, (S,S)-1,3-프로판디아민디글루타르산, (S,S)-2-히드록시-1,3-프로판디아민디숙신산,(S,S)-2-히드록시-1,3-프로판디아민디글루타르산 및 그의 알카리 금속염으로 이루어진 군으로부터 선택되는 킬레이트화제.
  9. 킬레이트화제로서 (S)-아스팔트산-N,N-디아세트산, 타우린-N,N-디아세트산 또는 그의 혼합물을 함유하는 세정제 조성물.
  10. 제9항에 있어서, 비이온성 계면활성제 및 음이온성 계면활성제를 더 함유하는 세정제 조성물.
  11. 제9항에 있어서, 비이온성 계면활성제 및 음이온성 계면활성제 및 규산염을 더 함유하는 세정제 조성물.
  12. 제9항에 있어서, 비이온성 계면활성제 및 음이온성 계면활성제, 규산염 및 표백제를 더 함유하는 세정제 조성물.
  13. 제10항에 있어서, 하기 조성으로 이루어진 세정제 조성물: (a) 청구항 9의 킬레이트화제 0.5-80중량%, (b) 비이온성 계면활성제 0.2-60중량%, 및 (c) 음이온성 계면활성제 0.2-60중량%.
  14. 제11항에 있어서, 하기 조성으로 이루어진 세정제 조성물: (a) 청구항 9의 킬레이트화제 0.5-80중량%, (b) 비이온성 계면활성제 0.2-60중량%, 및 (c) 음이온성 계면활성제 0.2-60중량%, 및 (d) 규산염 0.5-80중량%.
  15. 제12항에 있어서, 하기 조성으로 이루어진 세정제 조성물: (a) 청구항 1 또는 2의 킬레이트화제 0.5-80중량%, (b) 바이온성 계면활성제 0.2-60중량%, (c) 음이온성 계면활성제 0.2-60중량%, 및 (d) 규산염 0.5-80중량%, 및 (e) 표백제 0.5-60중량%.
  16. 제9항에 있어서, 지방산 염을 더 함유하는 세정제 조성물.
  17. 하기 세개의 군중 2개 이상의 군의 각각으로부터 선택된 1종 이상의 성분을 동시에 함유하는 세정제 조성물: A군: (S)-아스팔트산-N,N-디아세트산, B군:타우린-N,N-디아세트산, 및 C군:메틸이미노디아세트산, (S)-아스팔트산-N,N-모노아세트산 및 (S)-아스팔트산-N-모노프로피온산.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
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US6221834B1 (en) 2001-04-24
US6451757B2 (en) 2002-09-17
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CN1515545A (zh) 2004-07-28
EP0783034A2 (en) 1997-07-09
US6426229B1 (en) 2002-07-30
KR100543822B1 (ko) 2006-04-21
US20020039980A1 (en) 2002-04-04
EP0783034A3 (en) 1998-07-08
US20010034318A1 (en) 2001-10-25

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