KR970010875A - 난연성을 갖는 열가소성 수지 조성물 - Google Patents
난연성을 갖는 열가소성 수지 조성물 Download PDFInfo
- Publication number
- KR970010875A KR970010875A KR1019950024618A KR19950024618A KR970010875A KR 970010875 A KR970010875 A KR 970010875A KR 1019950024618 A KR1019950024618 A KR 1019950024618A KR 19950024618 A KR19950024618 A KR 19950024618A KR 970010875 A KR970010875 A KR 970010875A
- Authority
- KR
- South Korea
- Prior art keywords
- weight
- resin
- styrene
- resin composition
- parts
- Prior art date
Links
- 239000011342 resin composition Substances 0.000 title claims abstract description 12
- 229920005992 thermoplastic resin Polymers 0.000 title claims abstract 4
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims abstract 12
- 229920005989 resin Polymers 0.000 claims abstract 7
- 239000011347 resin Substances 0.000 claims abstract 7
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 claims abstract 4
- CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical compound CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 claims abstract 4
- -1 aryl phosphate Chemical compound 0.000 claims abstract 3
- 239000005062 Polybutadiene Substances 0.000 claims abstract 2
- 238000007334 copolymerization reaction Methods 0.000 claims abstract 2
- 229920000578 graft copolymer Polymers 0.000 claims abstract 2
- 229910052736 halogen Inorganic materials 0.000 claims abstract 2
- 150000002367 halogens Chemical class 0.000 claims abstract 2
- 239000000203 mixture Substances 0.000 claims abstract 2
- 229920002857 polybutadiene Polymers 0.000 claims abstract 2
- 229920005668 polycarbonate resin Polymers 0.000 claims abstract 2
- 239000004431 polycarbonate resin Substances 0.000 claims abstract 2
- 229920001169 thermoplastic Polymers 0.000 claims abstract 2
- 239000004416 thermosoftening plastic Substances 0.000 claims abstract 2
- 229920001577 copolymer Polymers 0.000 claims 3
- BFKJFAAPBSQJPD-UHFFFAOYSA-N tetrafluoroethene Chemical group FC(F)=C(F)F BFKJFAAPBSQJPD-UHFFFAOYSA-N 0.000 claims 3
- 125000006736 (C6-C20) aryl group Chemical group 0.000 claims 1
- 125000006737 (C6-C20) arylalkyl group Chemical group 0.000 claims 1
- BQCIDUSAKPWEOX-UHFFFAOYSA-N 1,1-Difluoroethene Chemical compound FC(F)=C BQCIDUSAKPWEOX-UHFFFAOYSA-N 0.000 claims 1
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 claims 1
- 239000002033 PVDF binder Substances 0.000 claims 1
- 239000000654 additive Substances 0.000 claims 1
- 230000000996 additive effect Effects 0.000 claims 1
- 239000003963 antioxidant agent Substances 0.000 claims 1
- 230000003078 antioxidant effect Effects 0.000 claims 1
- 229910052731 fluorine Inorganic materials 0.000 claims 1
- 239000011737 fluorine Substances 0.000 claims 1
- 239000012760 heat stabilizer Substances 0.000 claims 1
- HCDGVLDPFQMKDK-UHFFFAOYSA-N hexafluoropropylene Chemical group FC(F)=C(F)C(F)(F)F HCDGVLDPFQMKDK-UHFFFAOYSA-N 0.000 claims 1
- 239000004611 light stabiliser Substances 0.000 claims 1
- 238000000034 method Methods 0.000 claims 1
- 239000000049 pigment Substances 0.000 claims 1
- 229920001343 polytetrafluoroethylene Polymers 0.000 claims 1
- 239000004810 polytetrafluoroethylene Substances 0.000 claims 1
- 229920002981 polyvinylidene fluoride Polymers 0.000 claims 1
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 abstract 1
- 229910019142 PO4 Inorganic materials 0.000 abstract 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 abstract 1
- 239000003063 flame retardant Substances 0.000 abstract 1
- 239000010452 phosphate Substances 0.000 abstract 1
- 229910052698 phosphorus Inorganic materials 0.000 abstract 1
- 239000011574 phosphorus Substances 0.000 abstract 1
- 238000003917 TEM image Methods 0.000 description 5
- 230000000052 comparative effect Effects 0.000 description 4
- 230000005540 biological transmission Effects 0.000 description 1
Classifications
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L69/00—Compositions of polycarbonates; Compositions of derivatives of polycarbonates
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/49—Phosphorus-containing compounds
- C08K5/51—Phosphorus bound to oxygen
- C08K5/52—Phosphorus bound to oxygen only
- C08K5/521—Esters of phosphoric acids, e.g. of H3PO4
- C08K5/523—Esters of phosphoric acids, e.g. of H3PO4 with hydroxyaryl compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L27/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
- C08L27/02—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L27/12—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment containing fluorine atoms
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/02—Flame or fire retardant/resistant
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2666/00—Composition of polymers characterized by a further compound in the blend, being organic macromolecular compounds, natural resins, waxes or and bituminous materials, non-macromolecular organic substances, inorganic substances or characterized by their function in the composition
- C08L2666/02—Organic macromolecular compounds, natural resins, waxes or and bituminous materials
- C08L2666/04—Macromolecular compounds according to groups C08L7/00 - C08L49/00, or C08L55/00 - C08L57/00; Derivatives thereof
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
Description
Claims (3)
- (A) (a1) 할로겐을 함유하지 않은 열가소성 폴리카보네이트 수지 80∼96중량%; 및 (a2) 부티디엔 고무 50∼70중량%에 메틸메타아크릴레이트, 부틸아크릴레이트 및 스티렌을 30∼50중량% 그라프트 공중합시킨 수지로서, 그 그라프트된 조성중에서 메틸메타크릴레이트는 30∼50중량%, 부틸아크릴레이트는 0∼15중량%, 및 스티렌은 40∼60중량%를 이루며, 그 그라프트율이 40%이상인 스티렌-함유 그라프트 공중합체 수지 20∼4중량%로 이루어지는 100중량부의 기초수지; (B) 상기 기초수지 100중량부에 대하여 하기 일반식을 갖고 n의 값이 0.3 내지 0.8의 범위인 아릴포스페이트 올리고머; 및상기 식에서 R1, R2, R3, R4, 및 R5는 서로 독립적으로 할로겐으로 함유하지 않은 C6-C20아릴기 또는 알킬치환된 것임.(C) 상기 기초수지 100중량부에 대하여 0.1∼2.0중량부의 플루오르계 수지로 구성되는 것을 특징으로 하는 난연성을 갖는 열가소성 수지 조성물.
- 제1항에 있어서, 상기 플루오르계 수지(C)는 폴리테트라플루오로에틸렌, 폴리비닐리덴플루오라이드, 테트라플루오로에틸렌과 비닐리덴플루오라이드의 공중합체, 테트라플루오로에틸렌과 플루오로알킬비닐에테르의 공중합체 및 테트라플루오로에틸렌과 헥사플루오로프로필렌의 공중합체로 이루어지는 군으로부터 선택된 하나 이상인 것을 특징으로 하는 난연성을 갖는 열가소성 수지 조성물.
- 제1항에 있어서, 상기 수지 조성물이 무기물 첨가제, 열안정제, 산화방지제, 광안정제, 안료 및/또는 염료를 더 포함하는 것을 특징으로 하는 난연성을 갖는 열가소성 수지 조성물.※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
KR1019950024618A KR0144382B1 (ko) | 1995-08-10 | 1995-08-10 | 난연성을 갖는 열가소성 수지 조성물 |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
KR1019950024618A KR0144382B1 (ko) | 1995-08-10 | 1995-08-10 | 난연성을 갖는 열가소성 수지 조성물 |
Publications (2)
Publication Number | Publication Date |
---|---|
KR970010875A true KR970010875A (ko) | 1997-03-27 |
KR0144382B1 KR0144382B1 (ko) | 1998-07-15 |
Family
ID=19423206
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
KR1019950024618A KR0144382B1 (ko) | 1995-08-10 | 1995-08-10 | 난연성을 갖는 열가소성 수지 조성물 |
Country Status (1)
Country | Link |
---|---|
KR (1) | KR0144382B1 (ko) |
Families Citing this family (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US11879042B2 (en) | 2021-08-02 | 2024-01-23 | B/E Aerospace, Inc. | Fire resistant thermoplastic-based resin for fiber-reinforced composites |
-
1995
- 1995-08-10 KR KR1019950024618A patent/KR0144382B1/ko not_active IP Right Cessation
Also Published As
Publication number | Publication date |
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KR0144382B1 (ko) | 1998-07-15 |
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