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KR960010806A - 방사선 경화성 실리콘 함유 폴리아크릴레이트 경질도막 조성물의 제조 방법 - Google Patents

방사선 경화성 실리콘 함유 폴리아크릴레이트 경질도막 조성물의 제조 방법 Download PDF

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Publication number
KR960010806A
KR960010806A KR1019950029380A KR19950029380A KR960010806A KR 960010806 A KR960010806 A KR 960010806A KR 1019950029380 A KR1019950029380 A KR 1019950029380A KR 19950029380 A KR19950029380 A KR 19950029380A KR 960010806 A KR960010806 A KR 960010806A
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South Korea
Prior art keywords
colloidal silica
weight
mixture
alcohol
gelling inhibitor
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KR1019950029380A
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English (en)
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KR100384910B1 (ko
Inventor
닐 루이스 래리
앰발랄 파텔 가우탐
로날드 질레트 그레고리
프레드릭 메드포드 죠지
Original Assignee
제이 엘. 채스킨
제네랄 일렉트릭 캄파니
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Publication of KR100384910B1 publication Critical patent/KR100384910B1/ko

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    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
    • C09D133/04—Homopolymers or copolymers of esters
    • C09D133/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, the oxygen atom being present only as part of the carboxyl radical
    • C09D133/08—Homopolymers or copolymers of acrylic acid esters
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D4/00—Coating compositions, e.g. paints, varnishes or lacquers, based on organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond ; Coating compositions, based on monomers of macromolecular compounds of groups C09D183/00 - C09D183/16
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/31504—Composite [nonstructural laminate]
    • Y10T428/31507—Of polycarbonate

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Paints Or Removers (AREA)
  • Treatments Of Macromolecular Shaped Articles (AREA)
  • Application Of Or Painting With Fluid Materials (AREA)
  • Coating Of Shaped Articles Made Of Macromolecular Substances (AREA)
  • Polymerisation Methods In General (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

본 발명은 C(3-5)분지된 지방족 알콜(예;이소프리필 알콜)중 콜로이드성 실리카 분산액을 사용함을 기초로 하여 방사선 경화성 실리콘 함유 폴리아크릴레이트 경질도막 조성물을 제거하기 위한 방법을 제공한다. 콜로이드성 실리카 분산액을 알콕시실릴아크릴레이트로 처리한 후 다작용성 반응성 아크릴 단량체로 처리하고 상기 혼합물을 스트리핑하는 동안, 겔화되지 않으면서 과량의 용매를 사용함이 줄어든다.

Description

방사선 경화성 실리콘 함유 폴리아크릴레이트 경질도막 조성물의 제조 방법
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (9)

  1. (A) (i) 약 5중량% 내지 약 20중량%의 알콕시실릴아크릴레이트와 (ii) 사응하게 약 80중량% 내지 약 95중량%의 콜로이드성 실리카 알콜계 분산액의 혼합물(이때, 상기 콜로이드성 실리카 알콜계 분산액은 C(3-5)분지된 지방족 알콜과 C(1-5)직쇄 알콜의 혼합물 중 콜로이드성 실리카로 필수적으로 이루어지며, 약 5중량% 내지 약70중량% 양의 콜로이드성 실리카를 포함하고, 알콕시실릴아크릴레이트를 가수분해하기에 충분한 양의 물을 포함한다)의 약 20℃ 내지 약 100℃ 온도에서의 반응 생성물 100중량부; (B) 하나 이상의 다작용성 반응성 아크릴 단량체 약 10 내지 약 400중량부; 및 (C) 효과량이 겔화 억제제를 포함하는 실리콘 함유 폴리아크릴레이트 혼합물로 부터 휘발 물질을 25℃ 내지 100℃의 온도 및 1 토르 내지 760 토르 압력에서 상당히 제거함을 포함하는, 경화성 실리콘 함유 폴리아프릴레이트 경질도막 조성물의 제조방법.
  2. 제1항에 있어서, 상기 콜로이드성 실리카 알콜계 분산액이 콜로이드성 실리카 및 이소프로판올로 필수적으로 이루어진 방법.
  3. 제1항에 있어서, 상기 콜로이드성 실리카 알콜계 분산액이 콜로이드성 실리카, 및 메탄올과 이소프로판올의 혼합물로 필수적으로 이루어진 방법.
  4. 제1항에 있어서, 혐기성 겔화 억제제를 가진 방법.
  5. 제1항에 있어서, 상기 혐기성 겔화 억제제가 갈빈옥실인 방법.
  6. 제1항에 있어서, 상기 혐기성 겔화 억제제가 4-하이드록시 TEMPO인 방법.
  7. 제1항에 있어서, 상기 혐기성 겔화 억제제가 비스(2,2,6,6-테트라메틸-4-피페리디닐옥시)세바케이트인 방법.
  8. 제1항에 있어서, 상기 알콕시실릴아크릴레이트가 메틸아크릴옥시프로필트리메톡시실란인 방법.
  9. 제1항에 있어서, 상기 다작용성 반응성 아크릴 단량체가 헥산디올디아크릴레이트인 방법.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019950029380A 1994-09-12 1995-09-07 방사선경화성규소함유폴리아크릴레이트경질도막조성물의제조방법 KR100384910B1 (ko)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US30429894A 1994-09-12 1994-09-12
US08/304,298 1994-09-12

Publications (2)

Publication Number Publication Date
KR960010806A true KR960010806A (ko) 1996-04-20
KR100384910B1 KR100384910B1 (ko) 2003-08-19

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KR1019950029380A KR100384910B1 (ko) 1994-09-12 1995-09-07 방사선경화성규소함유폴리아크릴레이트경질도막조성물의제조방법

Country Status (7)

Country Link
US (1) US5712325A (ko)
JP (1) JP3844084B2 (ko)
KR (1) KR100384910B1 (ko)
DE (1) DE19533057B4 (ko)
FR (1) FR2724389B1 (ko)
GB (1) GB2292946B (ko)
TW (1) TW339355B (ko)

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KR100679676B1 (ko) * 2003-12-30 2007-02-07 김명조 잣기름 및/또는 잣박을 포함하는 잣김
KR100848656B1 (ko) * 1999-03-26 2008-07-28 데이비드 에이. 라포인트 내마모성 코팅 및 이로써 피막된 제품

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KR100679676B1 (ko) * 2003-12-30 2007-02-07 김명조 잣기름 및/또는 잣박을 포함하는 잣김

Also Published As

Publication number Publication date
KR100384910B1 (ko) 2003-08-19
FR2724389A1 (fr) 1996-03-15
DE19533057B4 (de) 2009-09-03
US5712325A (en) 1998-01-27
FR2724389B1 (fr) 1998-10-23
JP3844084B2 (ja) 2006-11-08
JPH08209026A (ja) 1996-08-13
DE19533057A1 (de) 1996-03-14
GB2292946B (en) 1998-04-15
GB2292946A (en) 1996-03-13
TW339355B (en) 1998-09-01
GB9517614D0 (en) 1995-11-01

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