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KR930012741A - 4-히드록시메틸테트라히드로피란의 제조방법 - Google Patents

4-히드록시메틸테트라히드로피란의 제조방법 Download PDF

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Publication number
KR930012741A
KR930012741A KR1019920023254A KR920023254A KR930012741A KR 930012741 A KR930012741 A KR 930012741A KR 1019920023254 A KR1019920023254 A KR 1019920023254A KR 920023254 A KR920023254 A KR 920023254A KR 930012741 A KR930012741 A KR 930012741A
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KR
South Korea
Prior art keywords
hydrogen
alkyl
general formula
preparing
hydrogenation catalyst
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KR1019920023254A
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English (en)
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KR100236667B1 (ko
Inventor
헨켈만 요헴
륄 토마즈
짐머만 호르스트
괴츠 노르베르트
슈피글러 볼프강
퀴켄회너 토마즈
Original Assignee
랑핑어·방에르트
바스프 악티엔게젤샤프트
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Publication of KR930012741A publication Critical patent/KR930012741A/ko
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Publication of KR100236667B1 publication Critical patent/KR100236667B1/ko

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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D309/00—Heterocyclic compounds containing six-membered rings having one oxygen atom as the only ring hetero atom, not condensed with other rings
    • C07D309/02—Heterocyclic compounds containing six-membered rings having one oxygen atom as the only ring hetero atom, not condensed with other rings having no double bonds between ring members or between ring members and non-ring members
    • C07D309/04—Heterocyclic compounds containing six-membered rings having one oxygen atom as the only ring hetero atom, not condensed with other rings having no double bonds between ring members or between ring members and non-ring members with only hydrogen atoms, hydrocarbon or substituted hydrocarbon radicals, directly attached to ring carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D309/00—Heterocyclic compounds containing six-membered rings having one oxygen atom as the only ring hetero atom, not condensed with other rings
    • C07D309/02—Heterocyclic compounds containing six-membered rings having one oxygen atom as the only ring hetero atom, not condensed with other rings having no double bonds between ring members or between ring members and non-ring members
    • C07D309/04—Heterocyclic compounds containing six-membered rings having one oxygen atom as the only ring hetero atom, not condensed with other rings having no double bonds between ring members or between ring members and non-ring members with only hydrogen atoms, hydrocarbon or substituted hydrocarbon radicals, directly attached to ring carbon atoms
    • C07D309/06—Radicals substituted by oxygen atoms

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Pyrane Compounds (AREA)
  • Catalysts (AREA)
  • Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
  • Nitrogen Condensed Heterocyclic Rings (AREA)
  • Saccharide Compounds (AREA)

Abstract

본 발명은, 50 내지 400℃ 및 1 내지 400bar에서, 수소 및 수소화 촉매의 존재하에, 하기 일반식(Ⅱ)의 테트라히드로피란카르복실산 에스테르를 반응시키는 것으로 이루어지는 하기 일반식(Ⅰ)의 4-히드록시메틸테트라히드로피란의 제조방법에 관한 것이다:
상기 식에서, R1, R2, R3및 R4는 수소, C1-C12-알킬, C3-C8-시클로알킬, 아릴 또는 C7-C20-아랄킬이고, R5는 수소 또는 C1-C12-알킬이다.

Description

4-히드록시메틸테트라히드로피란의 제조방법
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (3)

  1. 50 내지 400℃ 및 1 내지 400bar에서, 수소 및 수소화 촉매의 존재하에, 하기 일반식(Ⅱ)의 테트라히드로피란카르복실산 에스테르를 반응시키는 것으로 이루어지는 하기 일반식(Ⅰ)의 4-히드록시메틸테트라히드로피란의 제조방법:
    상기 식에서, R1, R2, R3및 R4는 수소, C1-C12-알킬, C3-C8-시클로알킬, 아릴 또는 C7-C20-아랄킬이고, R5는 수소 또는 C1-C12-알킬이다.
  2. 제1항에 있어서, 사용되는 수소화 촉매가 구리, 및/또는 원소주기율표의 아족 Ⅶ 및/또는 Ⅷ으로부터의 하나 이상의 금속원소를 함유함을 특징으로 하는 방법.
  3. 제1항에 있어서, 액체상으로 수행됨을 특징으로 하는 방법.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019920023254A 1991-12-13 1992-12-04 4-히드록시메틸테트라히드로피란의 제조방법 KR100236667B1 (ko)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DEP4141222.2 1991-12-13
DE4141222A DE4141222A1 (de) 1991-12-13 1991-12-13 Verfahren zur herstellung von 4-hydroxymethyl- tetrahydropyranan

Publications (2)

Publication Number Publication Date
KR930012741A true KR930012741A (ko) 1993-07-21
KR100236667B1 KR100236667B1 (ko) 2000-03-02

Family

ID=6447020

Family Applications (1)

Application Number Title Priority Date Filing Date
KR1019920023254A KR100236667B1 (ko) 1991-12-13 1992-12-04 4-히드록시메틸테트라히드로피란의 제조방법

Country Status (9)

Country Link
US (1) US5252755A (ko)
EP (1) EP0546396B1 (ko)
JP (1) JP3244816B2 (ko)
KR (1) KR100236667B1 (ko)
AT (1) ATE134628T1 (ko)
CA (1) CA2083650A1 (ko)
DE (2) DE4141222A1 (ko)
HU (2) HU9203947D0 (ko)
IL (1) IL103822A (ko)

Families Citing this family (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5412120A (en) * 1991-12-13 1995-05-02 Basf Aktiengesellschaft Preparation of carboxylic esters
DE4233430A1 (de) * 1992-10-05 1994-04-07 Basf Ag Verfahren zur Herstellung von 4-Hydroxymethyltetrahydropyran
DE4419514A1 (de) * 1994-06-03 1995-12-07 Basf Ag Verfahren zur Herstellung von Aldehyden
CN1052481C (zh) * 1996-06-28 2000-05-17 中国人民解放军第二军医大学 一种新型血小板激活因子拮抗剂及其制备方法
JP5645065B2 (ja) * 2010-09-13 2014-12-24 国立大学法人 千葉大学 δ−バレロラクトンの製造方法
JP6388916B2 (ja) * 2013-04-29 2018-09-12 ビーエーエスエフ ソシエタス・ヨーロピアＢａｓｆ Ｓｅ 反応器カスケード中で２−置換４−ヒドロキシ−４−メチルテトラヒドロピランを製造する方法

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2479283A (en) * 1946-12-02 1949-08-16 Shell Dev Cyclic organic compounds
US3124599A (en) * 1957-02-20 1964-03-10 Union Carbide Corp process for preparing 1,6-diacetoxy-2,5-dimethyl-2.hexene; 1,2,6-triacetoxy-2,5-dimethyl-hexane; and 2,5-dimethyl-tetra-hydropyran-2-methanol acetate
US3187012A (en) * 1961-05-15 1965-06-01 Quaker Oats Co Process for preparing 2-hydroxymethyl-tetrahydropyran

Also Published As

Publication number Publication date
HU9203947D0 (en) 1993-03-29
KR100236667B1 (ko) 2000-03-02
EP0546396A1 (de) 1993-06-16
IL103822A (en) 1996-05-14
HUT63402A (en) 1993-08-30
DE4141222A1 (de) 1993-06-17
EP0546396B1 (de) 1996-02-28
ATE134628T1 (de) 1996-03-15
DE59205480D1 (de) 1996-04-04
US5252755A (en) 1993-10-12
CA2083650A1 (en) 1993-06-14
JPH05247023A (ja) 1993-09-24
JP3244816B2 (ja) 2002-01-07
IL103822A0 (en) 1993-04-04
HU209551B (en) 1994-07-28

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