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KR920703518A - 보다 활성인 종의 함량이 많은 사이퍼메트린 또는 사이플루트린 이성체 혼합물의 제조방법 - Google Patents

보다 활성인 종의 함량이 많은 사이퍼메트린 또는 사이플루트린 이성체 혼합물의 제조방법

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Publication number
KR920703518A
KR920703518A KR1019920701159A KR920701159A KR920703518A KR 920703518 A KR920703518 A KR 920703518A KR 1019920701159 A KR1019920701159 A KR 1019920701159A KR 920701159 A KR920701159 A KR 920701159A KR 920703518 A KR920703518 A KR 920703518A
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KR
South Korea
Prior art keywords
configuration
phenoxyphenylacetonitrile
hydroxy
acid chloride
cyfluthrin
Prior art date
Application number
KR1019920701159A
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English (en)
Other versions
KR940011906B1 (ko
Inventor
스테펜 글렌 마이클
Original Assignee
챨스 씨. 펠로우스
에프엠씨 코포레이션
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Application filed by 챨스 씨. 펠로우스, 에프엠씨 코포레이션 filed Critical 챨스 씨. 펠로우스
Publication of KR920703518A publication Critical patent/KR920703518A/ko
Application granted granted Critical
Publication of KR940011906B1 publication Critical patent/KR940011906B1/ko

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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C255/00—Carboxylic acid nitriles
    • C07C255/01—Carboxylic acid nitriles having cyano groups bound to acyclic carbon atoms
    • C07C255/32—Carboxylic acid nitriles having cyano groups bound to acyclic carbon atoms having cyano groups bound to acyclic carbon atoms of a carbon skeleton containing at least one six-membered aromatic ring
    • C07C255/38—Carboxylic acid nitriles having cyano groups bound to acyclic carbon atoms having cyano groups bound to acyclic carbon atoms of a carbon skeleton containing at least one six-membered aromatic ring the carbon skeleton being further substituted by esterified hydroxy groups
    • C07C255/39—Carboxylic acid nitriles having cyano groups bound to acyclic carbon atoms having cyano groups bound to acyclic carbon atoms of a carbon skeleton containing at least one six-membered aromatic ring the carbon skeleton being further substituted by esterified hydroxy groups with hydroxy groups esterified by derivatives of 2,2-dimethylcyclopropane carboxylic acids, e.g. of chrysanthemumic acids
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C253/00—Preparation of carboxylic acid nitriles
    • C07C253/30—Preparation of carboxylic acid nitriles by reactions not involving the formation of cyano groups

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)
  • Instrument Panels (AREA)
  • Digital Computer Display Output (AREA)
  • Controls And Circuits For Display Device (AREA)

Abstract

내용 없음

Description

보다 활성인 종의 함량이 많은 사이퍼메트린 또는 사이플루트린 이성체 혼합물의 제조방법
[도면의 간단한 설명]
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (8)

  1. 불활성 대기중 75 내지 1150℃의 온도에서 산 수용체의 부재하에서, 적절한 α-하이드록시-3-페녹시페닐아세토니트릴을 탄화수소 용매중의 3-(2,2-디클로로에테닐)-2,2-디메틸사이클로프로판카보닐 클로라이드의 용액과 반응시키고, 반응 혼합물을 수성 염기로 세척한 후, 생성물을 회수함을 특징으로 하는, 보다 살충활성이 큰 이성체의 함량이 많은 사이퍼메트린 또는 사이플루트린의 이성체 혼합물의 제조방법.
  2. 제1항에 있어서, α-하이드록시-3-페녹시페닐아세토니트릴이 R, S배위를 가지며, 산 클로라이드가 R, S-시스/트랜스 배위를 가짐을 특징으로 하는 방법.
  3. 제1항에 있어서, α-하이드록시-3-페녹시페닐아세토니트릴이 R, S배위를 가지며, 산 클로라이드가 R, S-시스 배위를 가짐을 특징으로 하는 방법.
  4. 제1항에 있어서, α-하이드록시-3-페녹시페닐아세토니트릴이 R, S배위를 가지며, 산 클로라이드가 R, S-트랜스 배위를 가짐을 특징으로 하는 방법.
  5. 제1항에 있어서, α-하이드록시-3-페녹시페닐아세토니트릴이 S배위를 가지며, 산 클로라이드가 R, S-시스/트랜스 배위를 가짐을 특징으로 하는 방법.
  6. 제1항에 있어서, α-하이드록시-3-페녹시페닐아세토니트릴이 S배위를 가지며, 산 클로라이드가 R, S-시스 배위를 가짐을 특징으로 하는 방법.
  7. 제1항에 있어서, α-하이드록시-3-페녹시페닐아세토니트릴이 S배위를 가지며, 산 클로라이드가 R, S-트랜스 배위를 가짐을 특징으로 하는 방법.
  8. ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019920701159A 1989-11-17 1990-10-01 보다 활성인 종의 함량이 많은 사이퍼메트린 또는 사이플루트린 이성체 혼합물의 제조방법 KR940011906B1 (ko)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US438,657 1989-11-17
US07/438,657 US5028731A (en) 1989-11-17 1989-11-17 Preparation of mixtures of cypermethrin or cyfluthrin isomers enriched in more active species
PCT/US1990/005578 WO1991007379A1 (en) 1989-11-17 1990-10-01 Preparation of mixtures of cypermethrin or cyfluthrin isomers enriched in more active species

Publications (2)

Publication Number Publication Date
KR920703518A true KR920703518A (ko) 1992-12-18
KR940011906B1 KR940011906B1 (ko) 1994-12-27

Family

ID=23741488

Family Applications (1)

Application Number Title Priority Date Filing Date
KR1019920701159A KR940011906B1 (ko) 1989-11-17 1990-10-01 보다 활성인 종의 함량이 많은 사이퍼메트린 또는 사이플루트린 이성체 혼합물의 제조방법

Country Status (17)

Country Link
US (1) US5028731A (ko)
EP (1) EP0500572B1 (ko)
JP (1) JPH0662536B2 (ko)
KR (1) KR940011906B1 (ko)
BR (1) BR9007850A (ko)
CA (1) CA2068532C (ko)
DE (1) DE69025478T2 (ko)
DK (1) DK0500572T3 (ko)
ES (1) ES2085916T3 (ko)
HU (1) HU208304B (ko)
IL (1) IL96298A (ko)
MX (1) MX171955B (ko)
RU (1) RU2060990C1 (ko)
TR (1) TR25423A (ko)
TW (1) TW200447B (ko)
WO (1) WO1991007379A1 (ko)
ZA (1) ZA908570B (ko)

Families Citing this family (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CA1275108A (en) * 1985-01-16 1990-10-09 Laszlo Pap Insecticidal composition comprising more than one active ingredients
US5164411A (en) * 1991-01-25 1992-11-17 Fmc Corporation Pyrethroid compositions
US9107416B2 (en) * 2005-12-22 2015-08-18 Fmc Corporation Insecticidal and miticidal mixtures of bifenthrin and cyano-pyrethroids
CA2836135A1 (en) * 2011-05-26 2012-11-29 Allergy Technologies, Llc Compositions and methods for treating materials with insecticides and potentiating agents
WO2019145221A1 (en) 2018-01-29 2019-08-01 BASF Agro B.V. New agrochemical formulations

Family Cites Families (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2769835A (en) * 1953-12-09 1956-11-06 Monsanto Chemicals Process of producing alkyl acrylates by dehydrohalogenation using an anhydrous calcium sulfate catalyst
US3078306A (en) * 1958-04-24 1963-02-19 Basf Ag Process for the production of alphachloroximes and their hydrochlorides
US3082236A (en) * 1959-04-29 1963-03-19 Wallace & Tiernan Inc Peroxy esters of p-menthane hydroperoxides
US4024163A (en) * 1972-05-25 1977-05-17 National Research Development Corporation Insecticides
DE2850502A1 (de) * 1977-11-24 1979-05-31 Ciba Geigy Ag 2,4,4,4-tetrachlorbuttersaeure-1,2,4, 4,4-pentachlor-but-1-enylester
DE2928986A1 (de) * 1979-07-18 1981-02-05 Bayer Ag (+)-cis und (+) trans-2,2-dimethyl- 3-(2,2-dichlor-vinyl)-cyclopropan-1- carbonsaeure-(+-) - alpha -cyano-3-phenoxy4-fluor-benzylester, verfahren zu ihrer herstellung sowie ihre verwendung als insektizide und akarizide
FR2471369A1 (fr) * 1979-12-17 1981-06-19 Roussel Uclaf Nouvelles imines, derivant d'esters d'acides formyl cyclopropane carboxyliques, leur procede de preparation et leur application a la preparation d'esters insecticides
DE3200484A1 (de) * 1982-01-09 1983-07-21 Bayer Ag, 5090 Leverkusen Aminoalkylester, verfahren zu ihrer herstellung und ihre verwendung in schaedlingsbekaempfungsmittel
JPS60202843A (ja) * 1984-03-27 1985-10-14 Sumitomo Chem Co Ltd エステル誘導体の合成方法
JP2982339B2 (ja) * 1991-02-25 1999-11-22 ソニー株式会社 光ディスクカートリッジと光ディスク装置

Also Published As

Publication number Publication date
IL96298A0 (en) 1991-08-16
KR940011906B1 (ko) 1994-12-27
CA2068532C (en) 1995-05-16
EP0500572A4 (en) 1992-10-07
JPH05501110A (ja) 1993-03-04
EP0500572B1 (en) 1996-02-21
HUT62554A (en) 1993-05-28
WO1991007379A1 (en) 1991-05-30
US5028731A (en) 1991-07-02
HU9201627D0 (en) 1993-04-28
CA2068532A1 (en) 1991-05-18
RU2060990C1 (ru) 1996-05-27
MX171955B (es) 1993-11-24
IL96298A (en) 1995-10-31
HU208304B (en) 1993-09-28
DE69025478D1 (de) 1996-03-28
ES2085916T3 (es) 1996-06-16
BR9007850A (pt) 1992-10-06
TR25423A (tr) 1993-03-01
ZA908570B (en) 1991-08-28
EP0500572A1 (en) 1992-09-02
DK0500572T3 (da) 1996-06-24
JPH0662536B2 (ja) 1994-08-17
DE69025478T2 (de) 1996-10-24
TW200447B (ko) 1993-02-21

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