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KR910007970A - 올레핀의 중합화를 위한 메탈로센 촉매의 제조방법 - Google Patents

올레핀의 중합화를 위한 메탈로센 촉매의 제조방법 Download PDF

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KR910007970A
KR910007970A KR1019900016063A KR900016063A KR910007970A KR 910007970 A KR910007970 A KR 910007970A KR 1019900016063 A KR1019900016063 A KR 1019900016063A KR 900016063 A KR900016063 A KR 900016063A KR 910007970 A KR910007970 A KR 910007970A
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ionic compound
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웬 죤
제이. 엘더 마이클
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피나 테크놀로지. 인코포레이티드
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    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/619—Component covered by group C08F4/60 containing a transition metal-carbon bond
    • C08F4/61908—Component covered by group C08F4/60 containing a transition metal-carbon bond in combination with an ionising compound other than alumoxane, e.g. (C6F5)4B-X+
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
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    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/619—Component covered by group C08F4/60 containing a transition metal-carbon bond
    • C08F4/6192—Component covered by group C08F4/60 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C08F4/61922—Component covered by group C08F4/60 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
    • C08F4/61927—Component covered by group C08F4/60 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually bridged
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    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/639—Component covered by group C08F4/62 containing a transition metal-carbon bond
    • C08F4/63908—Component covered by group C08F4/62 containing a transition metal-carbon bond in combination with an ionising compound other than alumoxane, e.g. (C6F5)4B-X+
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    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/639—Component covered by group C08F4/62 containing a transition metal-carbon bond
    • C08F4/6392—Component covered by group C08F4/62 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C08F4/63922—Component covered by group C08F4/62 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not

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Abstract

내용 없음

Description

올레핀의 중합화를 위한 메탈로센 촉매의 제조방법
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (31)

  1. a) 이혼화 이온성 화합물을 하기 일반식(I)의 메탈로센의 중성 유도체와 혼합하고; b) 이온화 이온성 화합물 및 일반식(I)의 메탈로센의 중성 유도체를, 메탈로센이 이온화 이온성 화합물에 의해 이온화되고 이온쌍이 메탈로센 양이온이 촉매로서 작용하는 곳에서 형성되도록 접촉시킴을 포함하는 촉매의 제조방법.
    Cp2MRP (I)
    상기식에서, Cp는 동일하거나 상이하며 사이클로펜타디에닐 또는 치환된 사이클로펜타디에닐 그룹이고, M은 III, IV, V 또는 VI족 금속이며, R은 동일하거나 상이하며 하이드라이드, 할로겐, 아미드 또는 하이드로카발 라이칼이고, 단 하나의 R은 하이드라이드 이며, P는 1내지 4이고; 이온화 이온성 화합물은 활성 양성자를 함유하지 않고 카보늄, 옥소늄 또는 설포늄 양이온을 함유하고; 이온화 이온성 화합물의 음이온은 메탈로센 양이온에 배위 결합되지 않거나 단지 느슨하게 배위 결합되며 메탈로센 양이온과 화학적으로 비반응성이다.
  2. 제1항에 있어서, 혼합하기 전에, 이온화 이온성 화합물을 메탈로센 양이온과 배위 결합되지 않거나 단지 느슨하게 배위 결합된 용매에 용해시키는 방법.
  3. 제2항에 있어서, 혼합하기 전에 메탈로센 중성 유도체를 동일한 용매중에 별도로 용해시키는 방법.
  4. 제3항에 있어서, 이온성 화합물에 대한 메탈로센 중성 유도체의 몰비율 범위가 메탈로겐 10몰; 이온화 화합물 1몰 내지 메탈로센 1몰: 이온화 화합물 10몰인 방법.
  5. 제4항에 있어서, 이온성 화합물에 대한 메탈로센의 중성 유도체의 몰비율 범위가 메탈로센 2몰; 이온화 화합물 1몰 내지 메탈로센 1몰; 이온화 화합물 2몰인 방법.
  6. 제5항에 있어서, 이온성 화합물에 대한 메탈로센 중성 유도체의 몰비율 범위가 메탈로센 1몰; 이온화 화합물 1몰인 방법.
  7. 제4항에 있어서, 금속이 티타늄, 지르코늄 및 하프늄으로 구성된 그룹중에서 선택된 IV족 금속인 방법.
  8. 제7항에 있어서, 금속이 하프늄인 방법.
  9. 제7항에 있어서, 금속이 지르코늄인 방법.
  10. 제9항에 있어서, R이 탄소수 1내지 20의 알킬 라디칼, 아릴 라디칼, 알케닐 라디칼, 알킬 아릴 라디칼 및 아릴 알킬 라디칼로 구성된 그룹중에서 선택된 하이드로카빌 라디칼인 방법.
  11. 제10항에 있어서, 메탈로센의 중성 유도체가 에틸렌 비스(테트라하이드로인데닐) 지르코늄 디메틸, 에틸렌 비스(인데닐)지르코늄 디메틸 및 이소프로필리덴(사이클로펜타디에닐-1-플루오레닐)지르코늄 디메틸로 구성된 그룹중에서 선택되는 방법.
  12. 제11항에 있어서, 메탈로센의 중성 유도체가 에틸렌비스(인데닐)지르코늄 디메틸인 방법.
  13. 제12항에 있어서, 이온성 화합물인 트리페닐 카베늄 테트라키스(펜타플루오르 페닐) 보로 네이트인 방법.
  14. 제13항에 있어서, 용매가 톨루엔인 방법.
  15. a) 이온화 화합물을 하기 일반식(I)의 메탈로센의 중성 유도체와 혼합하고; b) 이온화 이온성 화합물 및 메탈로센의 중성 유도체를, 메탈로센이 이온화 이온성 화합물에 의해 이온화되고 이온쌍이 메탈로센 양이온이 촉매로서 작용하는 곳에서 형성되도록 접촉시키고; (c)중합화를 수행하는 조건하에서 촉매를 올레핀과 접촉시킴을 포함하는 올레핀의 중합화 방법.
    Cp212MRp (I)
    상기식에서, Cp는 동일하거나 상이하며 사이클로펜타디에닐 또는 치환된 사이클로펜타디에닐 그룹이고, M은 III, IV, V 또는 VI족 금속이며, R은 동일하거나 상이하며 하이드라이드, 할로겐, 아미드 또는 하이드로카발 라이칼이고, 단 하나의 R은 하이드라이드 이며, P는 1내지 4이고; 이온화 이온성 화합물은 활성 양성자를 함유하지 않고 카보늄, 옥소늄 또는 설포늄 양이온을 함유하고; 이온화 이온성 화합물의 음이온은 메탈로센 양이온에 배위 결합되지 않거나 단지 느슨하게 배위 결합되며 메탈로센 양이온과 화학적으로 비반응성이다.
  16. 제15항에 있어서, 혼합하기 전에, 이온성 화합물을 메탈로센 양이온과 배위 결합되지 않거나 단지 느슨하게 배위 결합되는 용매중에 용해시키는 방법.
  17. 제16항에 있어서, 혼합하기 전에, 메탈로센의 중성 유도체를 동일한 용매중에 용해시키는 방법.
  18. 제17항에 있어서, 이온성 화합물에 대한 메탈로센의 중성 유도체의 몰 비율 범위가 메탈로센 10몰; 이온화 화합물 1몰 내지 메탈로센 1몰; 이온화 화합물 10몰인 방법.
  19. 제18항에 있어서, 이온성 화합물에 대한 메탈로센의 중성 유도체의 몰 비율 범위가 메탈로센 2몰; 이온화 화합물 1몰 내지 메탈로센 1몰; 이온화 화합물 2몰인 방법.
  20. 제19항에 있어서, 이온성 화합물에 대한 메탈로센의 중성 유도체의 몰 비율 범위가 메탈로센 1몰; 이온화 화합물 1몰인 방법.
  21. 제18항에 있어서, 금소기 티타늄, 지르코늄 및 하프늄으로 구성된 그룹 중에서 선택된 IV족 금속인 방법.
  22. 제21항에 있어서, 금속이 하프늄인 방법.
  23. 제21항에 있어서, 금속이 지르코늄인 방법.
  24. 제23항에 있어서, R이 탄소수 1내지 20의 알킬 라디칼, 아릴 라디칼, 알케닐 라디칼, 알킬 아릴 라디칼 및 아릴 알킬 라디칼로 구성된 그룹중에서 선택된 하이드로카빌인 방법.
  25. 제24항에 있어서, 메탈로센의 중성 유도체가 에틸렌 비스(테트라하이드로인데닐) 지르코늄 디메틸, 에틸렌 비스(인데닐)지르코늄 디메틸 및 이소프로필리덴(사이클로펜타디에닐-1-플루오레닐)지르코늄 디메틸로 구성된 그룹중에서 선택되는 방법.
  26. 제25항에 있어서, 메탈로센의 중성 유도체가 에틸렌 비스(인데닐)지르코늄 디메틸인 방법.
  27. 제26항에 있어서, 이온성 화합물이 트리페닐 카베늄 테트라키스(펜타플루오로페닐)보로네이트인 방법.
  28. 제27항에 있어서, 용매가 톨루엔인 방법.
  29. 제28항에 있어서, -80℃내지 150℃범위의 반응 온도에서 개시되는 방법.
  30. 제29항에 있어서, 25℃내지 90℃범위의 반응 온도에서 개시되는 방법.
  31. 제30항에 있어서, 50℃내지 80℃범위의 반응 온도에서 개시되는 방법.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019900016063A 1989-10-30 1990-10-10 올레핀중합용메탈호센촉매의제조방법 KR0165843B1 (ko)

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Publication number Priority date Publication date Assignee Title
US5384299A (en) * 1987-01-30 1995-01-24 Exxon Chemical Patents Inc. Ionic metallocene catalyst compositions
US5391629A (en) * 1987-01-30 1995-02-21 Exxon Chemical Patents Inc. Block copolymers from ionic catalysts
US5241025A (en) * 1987-01-30 1993-08-31 Exxon Chemical Patents Inc. Catalyst system of enhanced productivity
US5198401A (en) * 1987-01-30 1993-03-30 Exxon Chemical Patents Inc. Ionic metallocene catalyst compositions
US5153157A (en) * 1987-01-30 1992-10-06 Exxon Chemical Patents Inc. Catalyst system of enhanced productivity
US5763549A (en) * 1989-10-10 1998-06-09 Fina Technology, Inc. Cationic metallocene catalysts based on organoaluminum anions
ATE137247T1 (de) * 1989-10-30 1996-05-15 Fina Technology Addition von alkylaluminium zum verbessern eines metallocenkatalysators
US6294625B1 (en) 1990-03-20 2001-09-25 Exxonmobil Chemical Patents Inc. Catalyst system of enhanced productivity and its use in polymerization process
JP2545006B2 (ja) * 1990-07-03 1996-10-16 ザ ダウ ケミカル カンパニー 付加重合触媒
CA2066247C (en) * 1990-07-24 1998-09-15 Ryuichi Sugimoto Polymerization catalyst for .alpha.-olefin and method for preparing poly-.alpha.-olefin by using it
WO1992005208A1 (en) * 1990-09-14 1992-04-02 Exxon Chemical Patents Inc. IONIC CATALYST FOR THE PRODUCTION OF POLY-α-OLEFINS OF CONTROLLED TACTICITY
US5272003A (en) * 1990-10-26 1993-12-21 Exxon Chemical Patents Inc. Meso triad syndiotactic polypropylene fibers
US5444134A (en) * 1991-07-11 1995-08-22 Idemitsu Kosan Co., Ltd. Process for producing olefin based polymers and olefin polymerization catalyst
TW309523B (ko) * 1991-11-30 1997-07-01 Hoechst Ag
JP3194438B2 (ja) * 1992-01-08 2001-07-30 出光興産株式会社 スチレン系重合体の製造方法及びその触媒
US5296433A (en) * 1992-04-14 1994-03-22 Minnesota Mining And Manufacturing Company Tris(pentafluorophenyl)borane complexes and catalysts derived therefrom
US5350723A (en) * 1992-05-15 1994-09-27 The Dow Chemical Company Process for preparation of monocyclopentadienyl metal complex compounds and method of use
US5317036A (en) * 1992-10-16 1994-05-31 Union Carbide Chemicals & Plastics Technology Corporation Gas phase polymerization reactions utilizing soluble unsupported catalysts
BE1006438A3 (fr) * 1992-12-17 1994-08-30 Solvay Systeme catalytique, utilisation de ce systeme catalytique pour la (co)polymerisation d'olefines, procede de preparation de ce systeme catalytique et procede de (co)polymerisation d'olefines.
DE69428990T2 (de) * 1993-03-31 2002-04-04 Idemitsu Kosan Co. Ltd., Tokio/Tokyo Katalysator zur herstellung von vinylpolymer und verfahren zur herstellung von vinylaromatischem polymer
CA2125247C (en) * 1993-06-07 2001-02-20 Daisuke Fukuoka Transition metal compound, olefin polymerization catalyst component comprising said compound, olefin polymerization catalyst containing said catalyst component, process for olefinpolymerization using said catalyst , propylene homopolymer, propylene copolymer and propylene elastomer
EP1209165B1 (en) * 1993-06-07 2006-04-19 Mitsui Chemicals, Inc. Propylene elastomer
JPH0733812A (ja) * 1993-07-02 1995-02-03 Idemitsu Kosan Co Ltd スチレン系重合体製造触媒及びそれを用いたスチレン系重合体の製造方法
US5514728A (en) * 1993-07-23 1996-05-07 Minnesota Mining And Manufacturing Company Catalysts and initiators for polymerization
US5498582A (en) * 1993-12-06 1996-03-12 Mobil Oil Corporation Supported metallocene catalysts for the production of polyolefins
DE4344689A1 (de) * 1993-12-27 1995-06-29 Hoechst Ag Metallocenverbindung
DE69511023T2 (de) 1994-04-11 2000-01-27 Mitsui Chemicals, Inc. Verfahren zur herstellung einer propylen-polymerzusammensetzung und propylen-polymerzusammensetzung
US6291389B1 (en) 1994-04-28 2001-09-18 Exxonmobil Chemical Patents Inc. Cationic polymerization catalysts
PL318432A1 (en) * 1994-08-03 1997-06-09 Exxon Chemical Patents Inc Ionic supported catalyst composition
US6143686A (en) * 1994-08-03 2000-11-07 Exxon Chemical Patents, Inc. Supported ionic catalyst compositions
DE4431838A1 (de) * 1994-09-07 1996-03-14 Basf Ag Geträgerte Metallocen-Katalysatorsysteme
TW369547B (en) * 1994-09-21 1999-09-11 Mitsui Chemicals Inc Olefin polymerization catalyst and process for olefin polymerization
EP0710663A1 (en) 1994-11-01 1996-05-08 Japan Polyolefins Co., Ltd. Boron-containing compound, its polymer, catalyst comprising the polymer and metallocene compound, and process for producing polyolefin
ES2116188B1 (es) 1994-12-30 1999-04-01 Repsol Quimica Sa Proceso de obtencion de poliolefinas con distribuciones de pesos moleculares anchas, bimodales o multimodales.
US6143682A (en) * 1995-06-07 2000-11-07 Exxon Chemical Patents Inc. Bimetallocyclic transition metal catalyst systems
JPH11508617A (ja) * 1995-06-28 1999-07-27 シエル・インターナシヨナル・リサーチ・マートスハツペイ・ベー・ヴエー 有機金属化合物を含む触媒組成物
TW401445B (en) * 1995-07-13 2000-08-11 Mitsui Petrochemical Ind Polyamide resin composition
ES2120868B1 (es) * 1995-08-03 2000-09-16 Repsol Quimica Sa Sistema de catalizadores hetereogeneos tipo metalogeno, para procesos de obtencion de poliolefinas.
US5700748A (en) * 1995-09-29 1997-12-23 Union Carbide Chemicals & Plastics Technology Corporation Catalyst for the production of olefin polymers comprising a bridging allyl-cyclodienyl ligand on a metal atom
HUP9603449A3 (en) 1995-12-15 2000-03-28 Union Carbide Chem Plastic Process for production of long-chain branched polyolefins, polyethylene composition and product
US5856255A (en) * 1996-01-22 1999-01-05 Albemarle Corporation Preparation of supported auxiliary catalysts at elevated temperature and pressure in a closed vessel
US5786291A (en) * 1996-02-23 1998-07-28 Exxon Chemical Patents, Inc. Engineered catalyst systems and methods for their production and use
US6066603A (en) * 1996-06-17 2000-05-23 Exxon Chemical Patents Inc. Polar monomer containing copolymers derived from olefins useful as lubricant and useful as lubricant and fuel oil additivies process for preparation of such copolymers and additives and use thereof
US5811379A (en) * 1996-06-17 1998-09-22 Exxon Chemical Patents Inc. Polymers derived from olefins useful as lubricant and fuel oil additives, processes for preparation of such polymers and additives and use thereof (PT-1267)
ES2158567T3 (es) 1996-06-17 2001-09-01 Exxonmobil Chem Patents Inc Sistemas cataliticos de metales de transicion mixtos para la polimerizacion de olefinas.
WO1998003559A1 (en) * 1996-07-23 1998-01-29 E.I. Du Pont De Nemours And Compnay Polymerization processes for olefins
US6207608B1 (en) 1996-08-09 2001-03-27 University Of Iowa Research Foundation Olefin polymerization with direct use of ansa-metallocene amide complexes as catalysts
JPH10101727A (ja) * 1996-09-24 1998-04-21 Shell Internatl Res Maatschappij Bv オレフィン又はポリマーを水素化するための触媒及び方法
WO1998016311A1 (en) * 1996-10-15 1998-04-23 Northwestern University Phenolate constrained geometry metallocene olefin polymerization catalyst, method of making, and method of using
ES2142140T3 (es) * 1996-10-30 2000-04-01 Repsol Quimica Sa Catalizadores organometalicos para la polimerizacion y copolimerizacion de alfa-olefinas.
DE69705186T2 (de) 1996-10-30 2002-03-14 Repsol Quimica S.A., Madrid Katalysatorsysteme für die (Co)Polymerisation von Alpha-Olefinen
ATE198210T1 (de) 1996-10-31 2001-01-15 Repsol Quimica Sa Katalysatorsysteme für die polymerisation und copolymerisation von alpha-olefinen
EP0856524A1 (en) 1997-02-01 1998-08-05 Repsol Quimica S.A. Heterogeneous catalyst components for olefins polymerization, preparation process and use thereof
KR100503523B1 (ko) 1997-02-07 2005-07-25 엑손모빌 케미칼 패턴츠 인코포레이티드 비닐-함유 거대단량체의 제조방법
DE69809192T2 (de) 1997-02-07 2003-07-24 Exxonmobil Chemical Patents Inc., Baytown Propylenpolymere enthaltend polyethylenmakromonomere
TW420693B (en) 1997-04-25 2001-02-01 Mitsui Chemicals Inc Olefin polymerization catalysts, transition metal compounds, and <alpha>-olefin/conjugated diene copolymers
US6228795B1 (en) 1997-06-05 2001-05-08 Exxon Chemical Patents, Inc. Polymeric supported catalysts
US6172015B1 (en) 1997-07-21 2001-01-09 Exxon Chemical Patents, Inc Polar monomer containing copolymers derived from olefins useful as lubricant and fuel oil additives, processes for preparation of such copolymers and additives and use thereof
US7232871B2 (en) 1997-08-12 2007-06-19 Exxonmobil Chemical Patents Inc. Propylene ethylene polymers and production process
US6642316B1 (en) 1998-07-01 2003-11-04 Exxonmobil Chemical Patents Inc. Elastic blends comprising crystalline polymer and crystallizable polym
US7026404B2 (en) 1997-08-12 2006-04-11 Exxonmobil Chemical Patents Inc. Articles made from blends made from propylene ethylene polymers
US6921794B2 (en) 1997-08-12 2005-07-26 Exxonmobil Chemical Patents Inc. Blends made from propylene ethylene polymers
US6635715B1 (en) 1997-08-12 2003-10-21 Sudhin Datta Thermoplastic polymer blends of isotactic polypropylene and alpha-olefin/propylene copolymers
US6100224A (en) * 1997-10-01 2000-08-08 Exxon Chemical Patents Inc Copolymers of ethylene α-olefin macromers and dicarboxylic monomers and derivatives thereof, useful as additives in lubricating oils and in fuels
DE19744102A1 (de) 1997-10-06 1999-04-15 Targor Gmbh Katalysatorsystem
US6197910B1 (en) 1997-12-10 2001-03-06 Exxon Chemical Patents, Inc. Propylene polymers incorporating macromers
US6184327B1 (en) 1997-12-10 2001-02-06 Exxon Chemical Patents, Inc. Elastomeric propylene polymers
US6117962A (en) * 1997-12-10 2000-09-12 Exxon Chemical Patents Inc. Vinyl-containing stereospecific polypropylene macromers
DE19804970A1 (de) 1998-02-07 1999-08-12 Aventis Res & Tech Gmbh & Co Katalysatorsystem
TW562810B (en) 1998-04-16 2003-11-21 Mitsui Chemicals Inc Catalyst for olefinic polymerization and method for polymerizing olefine
US7148173B2 (en) 1998-04-27 2006-12-12 Repsol Quimica, S.A. Catalytic systems for the polymerization and copolymerization of alpha-olefins
US6306960B1 (en) 1998-05-13 2001-10-23 Exxonmobil Chemical Patents Inc. Articles formed from foamable polypropylene polymer
CA2327497A1 (en) 1998-05-13 1999-11-18 Exxon Chemical Patents, Inc. Propylene homopolymers and methods of making the same
US6784269B2 (en) 1998-05-13 2004-08-31 Exxonmobil Chemical Patents Inc. Polypropylene compositions methods of making the same
US6245868B1 (en) 1998-05-29 2001-06-12 Univation Technologies Catalyst delivery method, a catalyst feeder and their use in a polymerization process
CA2341167A1 (en) 1998-08-26 2000-03-09 Exxon Chemical Patents Inc. Branched polypropylene compositions
US6403773B1 (en) 1998-09-30 2002-06-11 Exxon Mobil Chemical Patents Inc. Cationic group 3 catalyst system
JP2000351813A (ja) 1999-04-09 2000-12-19 Mitsui Chemicals Inc エチレン・α−オレフィン共重合体およびその製造方法ならびにその用途
US6632885B2 (en) 1999-04-13 2003-10-14 Mitsui Chemicals, Inc. Soft syndiotactic polypropylene composition and molded product
US6174930B1 (en) 1999-04-16 2001-01-16 Exxon Chemical Patents, Inc. Foamable polypropylene polymer
DE19917985A1 (de) 1999-04-21 2000-10-26 Targor Gmbh Katalysatorsystem
US6339134B1 (en) 1999-05-06 2002-01-15 Univation Technologies, Llc Polymerization process for producing easier processing polymers
EP1209171A4 (en) * 1999-05-10 2004-04-21 Jp Agency Of Industrialscience PROCESS FOR PRODUCING LIVE OLEFIN POLYMER
US6479598B1 (en) 1999-07-20 2002-11-12 Exxonmobil Chemical Patents Inc. Petroleum resins and their production with BF3 catalyst
JP3808243B2 (ja) 1999-07-27 2006-08-09 三井化学株式会社 軟質樹脂組成物
US6403743B1 (en) 1999-09-14 2002-06-11 Exxonmobil Chemical Patents Inc. Petroleum resins and their production with supported catalyst
US6475946B1 (en) 1999-10-22 2002-11-05 Exxonmobil Chemical Patents Inc. Olefin polymerization catalysis with aryl substituted carbenium cationic complexes
US6476164B1 (en) 1999-10-22 2002-11-05 Exxonmobil Chemical Patents Inc. Carbenium cationic complexes suitable for polymerization catalysts
US6559090B1 (en) 1999-11-01 2003-05-06 W. R. Grace & Co.-Conn. Metallocene and constrained geometry catalyst systems employing agglomerated metal oxide/clay support-activator and method of their preparation
US6399535B1 (en) 1999-11-01 2002-06-04 W. R. Grace & Co.-Conn. Coordination catalyst systems employing agglomerated metal oxide/clay support-activator and method of their preparation
EP1226206B1 (en) 1999-11-04 2003-10-22 ExxonMobil Chemical Patents Inc. Propylene copolymer foams and their use
US6822057B2 (en) 1999-12-09 2004-11-23 Exxon Mobil Chemical Patents Inc. Olefin polymerization catalysts derived from Group-15 cationic compounds and processes using them
US6281306B1 (en) 1999-12-16 2001-08-28 Univation Technologies, Llc Method of polymerization
CN1333032C (zh) 1999-12-22 2007-08-22 埃克森美孚化学专利公司 聚丙烯基粘合剂组合物
KR100900931B1 (ko) 2000-01-26 2009-06-08 미쓰이 가가쿠 가부시키가이샤 올레핀 중합체 및 그의 제조 방법
CN1128168C (zh) 2000-03-31 2003-11-19 三井化学株式会社 聚烯烃组合物的制备方法
DE10025412A1 (de) 2000-05-24 2001-11-29 Basell Polypropylen Gmbh Als Cokatalysator geeignete chemische Produkte, Verfahren zu ihrer Herstellung und ihre Verwendung in Katalysatorsystemen zur Herstellung von Polyolefinen
JP2002020417A (ja) 2000-07-04 2002-01-23 Mitsui Chemicals Inc オレフィンの重合方法
SG96633A1 (en) 2000-07-04 2003-06-16 Mitsui Chemicals Inc Process for producing polar olefin copolymer and polar olefin copolymer obtained thereby
KR100467277B1 (ko) 2000-07-26 2005-01-24 미쓰이 가가쿠 가부시키가이샤 분기형 폴리올레핀 및 그 제조방법
DE60124829T2 (de) 2000-09-07 2007-06-28 Mitsui Chemicals, Inc. Polare Gruppen enthaltendes Olefin-Copolymer, Verfahren zu seiner Herstellung, dieses Copolymer enthaltende thermoplastische Harzzusammensetzung und deren Verwendung
KR100844062B1 (ko) 2001-02-21 2008-07-07 미쓰이 가가쿠 가부시키가이샤 올레핀 중합용 촉매 및 이 촉매를 사용하는 올레핀중합체의 제조방법
DE60238049D1 (de) 2001-04-12 2010-12-02 Exxonmobil Chem Patents Inc Verfahren zur Polymerisation von Propylen und Ethylen in Lösung
ATE337343T1 (de) 2001-04-30 2006-09-15 Grace W R & Co Geträgerte dualübergangsmetallkatalysatorsysteme
WO2002088196A1 (en) 2001-04-30 2002-11-07 W.R. Grace & Co.-Conn. Heterogeneous chromium catalysts and processes of polymerization of olefins using same
US6943224B2 (en) 2001-04-30 2005-09-13 W. R. Grace & Co.-Conn. Process for preparing supported transition metal catalyst systems and catalyst systems prepared thereby
KR100540049B1 (ko) 2001-04-30 2006-01-20 더블유.알. 그레이스 앤드 캄파니-콘. 지지된 전이 금속 중합 촉매의 제조 방법 및 이 방법으로형성된 조성물
WO2002102859A2 (en) 2001-04-30 2002-12-27 W. R. Grace & Co.-Conn. Coordination catalyst systems employing chromium support-agglomerate and method of their preparation
EP1421090B1 (en) 2001-06-29 2014-03-26 ExxonMobil Chemical Patents Inc. Metallocenes and catalyst compositions derived therefrom
KR100440480B1 (ko) 2001-08-31 2004-07-14 주식회사 엘지화학 폴리올레핀 제조용 촉매 및 이를 이용한 폴리올레핀의제조방법
US6916892B2 (en) 2001-12-03 2005-07-12 Fina Technology, Inc. Method for transitioning between Ziegler-Natta and metallocene catalysts in a bulk loop reactor for the production of polypropylene
CA2368724C (en) * 2002-01-21 2011-06-14 Bayer Inc. Process for preparing isobutylene-based polymers
EP1548018B1 (en) 2002-09-27 2018-10-10 Mitsui Chemicals, Inc. Crosslinked metallocene compound for olefin polymerization and method of polymerizing olefin with the same
US7943700B2 (en) 2002-10-01 2011-05-17 Exxonmobil Chemical Patents Inc. Enhanced ESCR of HDPE resins
US7223822B2 (en) 2002-10-15 2007-05-29 Exxonmobil Chemical Patents Inc. Multiple catalyst and reactor system for olefin polymerization and polymers produced therefrom
CN101724110B (zh) 2002-10-15 2013-03-27 埃克森美孚化学专利公司 用于烯烃聚合的多催化剂体系和由其生产的聚合物
US7700707B2 (en) 2002-10-15 2010-04-20 Exxonmobil Chemical Patents Inc. Polyolefin adhesive compositions and articles made therefrom
JP5221848B2 (ja) 2002-10-23 2013-06-26 三井化学株式会社 マグネシウムを含む担体成分及びオレフィン重合への応用
DE10251513A1 (de) 2002-11-04 2004-05-19 Basf Ag Übergangsmetallkatalysatoren für (Co)Polymerisation von olefinischen Monomeren
US20040102311A1 (en) 2002-11-21 2004-05-27 Abbas Razavi Bridged metallocene catalyst component, method of making, polyolefin catalyst having C1, C2, or Cs symmetry, methods of making, methods of polymerizing, olefins and products made thereof
US7195806B2 (en) 2003-01-17 2007-03-27 Fina Technology, Inc. High gloss polyethylene articles
US7488789B2 (en) 2003-03-28 2009-02-10 Mitsui Chemicals, Inc. Propylene copolymer, polypropylene composition, and uses thereof, transition metal compounds and catalyst for olefin polymerization
US6953764B2 (en) 2003-05-02 2005-10-11 Dow Global Technologies Inc. High activity olefin polymerization catalyst and process
US8722787B2 (en) 2003-08-25 2014-05-13 Dow Global Technologies Llc Coating composition and articles made therefrom
US7803865B2 (en) 2003-08-25 2010-09-28 Dow Global Technologies Inc. Aqueous dispersion, its production method, and its use
US8779053B2 (en) 2003-08-25 2014-07-15 Dow Global Technologies Llc Coating compositions
US7947776B2 (en) 2003-08-25 2011-05-24 Dow Global Technologies Llc Aqueous dispersion, its production method, and its use
US8158711B2 (en) 2003-08-25 2012-04-17 Dow Global Technologies Llc Aqueous dispersion, its production method, and its use
US8946329B2 (en) 2003-08-25 2015-02-03 Dow Global Technologies Llc Coating compositions
TW200517426A (en) 2003-08-25 2005-06-01 Dow Global Technologies Inc Aqueous dispersion, its production method, and its use
US8349929B2 (en) 2003-08-25 2013-01-08 Dow Global Technologies Llc Coating composition and articles made therefrom
US8357749B2 (en) 2003-08-25 2013-01-22 Dow Global Technologies Llc Coating composition and articles made therefrom
US7763676B2 (en) 2003-08-25 2010-07-27 Dow Global Technologies Inc. Aqueous polymer dispersions and products from those dispersions
US9169406B2 (en) 2003-08-25 2015-10-27 Dow Global Technologies Llc Coating compositions
EP1794197A4 (en) 2004-09-16 2009-07-01 Lg Chemical Ltd CATALYST SYSTEM FOR POLYMERIZATION OF CYCLIC OLEFIN HAVING POLAR FUNCTIONAL GROUP, POLYMERIZATION METHOD USING THE CATALYST SYSTEM, OLEFIN POLYMER PRODUCED THEREBY, AND OPTICAL ANISOTROPIC FILM COMPRISING THE OLEFIN POLYMER
JP2008516068A (ja) 2004-10-13 2008-05-15 エクソンモービル・ケミカル・パテンツ・インク エラストマー性反応ブレンド組成物
US8093341B2 (en) 2004-10-28 2012-01-10 Dow Global Technologies Llc Method of controlling a polymerization reactor
US7399874B2 (en) 2004-10-29 2008-07-15 Exxonmobil Chemical Patents Inc. Catalyst compound containing divalent tridentate ligand
US7795194B2 (en) 2004-11-26 2010-09-14 Mitsui Chemicals, Inc. Synthetic lubricating oil and lubricating oil composition
US7588706B2 (en) 2004-12-16 2009-09-15 Exxonmobil Chemical Patents Inc. Multi-layer films with improved properties
EP2281859B1 (en) 2004-12-21 2014-03-26 Dow Global Technologies LLC Polypropylene-based adhesive compounds
US7053163B1 (en) 2005-02-22 2006-05-30 Fina Technology, Inc. Controlled comonomer distribution along a reactor for copolymer production
JP5438256B2 (ja) 2006-11-17 2014-03-12 三井化学株式会社 ポリプロピレン系樹脂フィルムおよびその用途
KR20110044337A (ko) 2005-05-18 2011-04-28 미쓰이 가가쿠 가부시키가이샤 올레핀 중합용 촉매, 올레핀 중합체의 제조방법, 프로필렌계 공중합체의 제조방법, 프로필렌 중합체, 프로필렌계 중합체 조성물 및 이들의 용도
US9745461B2 (en) 2005-06-22 2017-08-29 Exxonmobil Chemical Patents Inc. Vulcanized polymer blends
US7935760B2 (en) 2005-06-22 2011-05-03 Exxonmobil Chemical Patents Inc. Process of making a heterogeneous polymer blend
US9644092B2 (en) 2005-06-22 2017-05-09 Exxonmobil Chemical Patents Inc. Heterogeneous in-situ polymer blend
US7951872B2 (en) 2005-06-22 2011-05-31 Exxonmobil Chemical Patents Inc. Heterogeneous polymer blend with continuous elastomeric phase and process of making the same
BRPI0619338B1 (pt) 2005-10-26 2018-02-27 Dow Global Technologies Inc., Artigo tendo pelo menos duas camadas, fibra e tela
US7605208B2 (en) 2005-10-31 2009-10-20 Mitsui Chemicals, Inc. Process for producing thermoplastic resin composition
EP1803747A1 (en) 2005-12-30 2007-07-04 Borealis Technology Oy Surface-modified polymerization catalysts for the preparation of low-gel polyolefin films
WO2007105483A1 (ja) 2006-03-10 2007-09-20 Mitsui Chemicals, Inc. インフレーション成形による成形体の製造方法
EP2006071B1 (en) 2006-03-27 2012-02-22 Mitsui Chemicals, Inc. Process for producing shaped article by t-die molding
JP2007261201A (ja) 2006-03-29 2007-10-11 Mitsui Chemicals Inc ブロー成形による成形体の製造方法
EP2002955A4 (en) 2006-03-30 2009-09-16 Mitsui Chemicals Inc METHOD FOR PRODUCING A MOLDED OBJECT BY INJECTION MOLDING
JP5603595B2 (ja) 2006-05-17 2014-10-08 ダウ グローバル テクノロジーズ エルエルシー エチレン／α−オレフィン／ジエン溶液重合方法及びポリマー
WO2007145478A1 (en) 2006-06-16 2007-12-21 Lg Chem, Ltd. Method for polymerizing cyclic olefin having polar functional group, olefin polymer produced thereby, optical antisotropic film comprising the same, and catalyst composition for polymerizing the cyclic olefin
KR101096836B1 (ko) 2006-07-31 2011-12-22 가부시키가이샤 프라임 폴리머 에틸렌계 수지 또는 에틸렌계 수지 조성물로 이루어지는 필름 또는 적층체
WO2008047878A1 (fr) 2006-10-20 2008-04-24 Mitsui Chemicals, Inc. Copolymère, modificateur de viscosité d'huile lubrifiante et composition d'huile lubrifiante
US7985804B2 (en) 2006-11-06 2011-07-26 Exxonmobil Chemical Patents Inc. Rubber toughened compositions, articles, films, and methods of making the same
CN101558089B (zh) 2006-12-19 2012-09-19 三井化学株式会社 烯烃聚合用固体状催化剂、烯烃聚合方法以及由该聚合方法得到的烯烃聚合物粒子
US8143352B2 (en) 2006-12-20 2012-03-27 Exxonmobil Research And Engineering Company Process for fluid phase in-line blending of polymers
EP2105464B1 (en) 2007-01-16 2012-03-28 Prime Polymer Co., Ltd. Ethylene resin composition for blow molded body, and blow molded body obtained from the same
EP2121776B1 (en) 2007-03-07 2012-12-12 Dow Global Technologies LLC Tethered supported transition metal complex
WO2008152933A1 (ja) 2007-06-14 2008-12-18 Mitsui Chemicals, Inc. 熱可塑性エラストマー組成物
JP5226973B2 (ja) 2007-06-15 2013-07-03 三井化学株式会社 エチレン系共重合体、該共重合体を含む組成物ならびにその用途
EP2174928B1 (en) 2007-07-04 2015-03-11 Mitsui Chemicals, Inc. Transition metal complex compound, olefin oligomerization catalyst containing the compound, and method for producing olefin oligomer performed in the presence of the catalyst
TW200932762A (en) 2007-10-22 2009-08-01 Univation Tech Llc Polyethylene compositions having improved properties
US7906588B2 (en) 2007-10-26 2011-03-15 Exxonmobil Chemical Patents Inc. Soft heterogeneous isotactic polypropylene compositions
TW200936619A (en) 2007-11-15 2009-09-01 Univation Tech Llc Polymerization catalysts, methods of making, methods of using, and polyolefin products made therefrom
ES2435568T3 (es) 2007-11-19 2013-12-20 Dow Global Technologies Llc Copolímeros de propileno-alfa-olefina con ramificación de cadena larga
ES2434959T3 (es) 2007-11-19 2013-12-18 Mitsui Chemicals, Inc. Catalizador de la polimerización de olefinas con metaloceno en puentes y polímero de etileno obtenido usando el catalizador
EP2275493B1 (en) 2008-03-27 2013-02-27 Mitsui Chemicals, Inc. Resin composition and use thereof
US9469756B2 (en) 2008-03-31 2016-10-18 Mitsui Chemicals, Inc. Resin composition and melt bag
US9938400B2 (en) 2008-04-23 2018-04-10 Exxonmobil Chemical Patents Inc. Propylene copolymers in soft thermoplastic blends
US8242198B2 (en) 2008-06-09 2012-08-14 Exxonmobil Chemical Patents Inc. Polyolefin adhesive compositions
WO2010021304A1 (ja) 2008-08-19 2010-02-25 三井化学株式会社 混合触媒によるオレフィン重合体の製造方法
US10161063B2 (en) 2008-09-30 2018-12-25 Exxonmobil Chemical Patents Inc. Polyolefin-based elastic meltblown fabrics
US9498932B2 (en) 2008-09-30 2016-11-22 Exxonmobil Chemical Patents Inc. Multi-layered meltblown composite and methods for making same
US8664129B2 (en) 2008-11-14 2014-03-04 Exxonmobil Chemical Patents Inc. Extensible nonwoven facing layer for elastic multilayer fabrics
US9168718B2 (en) 2009-04-21 2015-10-27 Exxonmobil Chemical Patents Inc. Method for producing temperature resistant nonwovens
EP2172490A1 (en) 2008-10-03 2010-04-07 Ineos Europe Limited Controlled polymerisation process
WO2010074815A1 (en) 2008-12-15 2010-07-01 Exxonmobil Chemical Patents Inc. Thermoplastic olefin compositions
JP5650138B2 (ja) 2009-02-27 2015-01-07 エクソンモービル・ケミカル・パテンツ・インク 多層不織ｉｎ ｓｉｔｕラミネートおよびその製造方法
KR101327598B1 (ko) 2009-04-21 2013-11-12 가부시키가이샤 프라임 폴리머 올레핀 중합체의 제조 방법
US8378042B2 (en) 2009-04-28 2013-02-19 Exxonmobil Chemical Patents Inc. Finishing process for amorphous polymers
US20120028865A1 (en) 2010-07-28 2012-02-02 Sudhin Datta Viscosity Modifiers Comprising Blends of Ethylene-Based Copolymers
US9127151B2 (en) 2009-04-28 2015-09-08 Exxonmobil Chemical Patents Inc. Polymer compositions having improved properties as viscosity index improvers and use thereof in lubricating oils
CN102803280A (zh) 2009-06-11 2012-11-28 格雷斯公司 制造铝氧烷的方法和包括由此制备的铝氧烷的催化剂
US9017593B2 (en) 2009-06-16 2015-04-28 Exxonmobil Chemical Patents Inc. Composite materials comprising propylene-based polymer blend coatings
JP5675609B2 (ja) 2009-07-01 2015-02-25 三井化学株式会社 有機金属化合物およびその製造方法
US20110020619A1 (en) 2009-07-23 2011-01-27 Van Den Bossche Linda M Polypropylene-Based Elastomer Coating Compositions
US9005739B2 (en) 2009-07-23 2015-04-14 Exxonmobil Chemical Patents Inc. Laminated articles and their production
KR20140143847A (ko) 2009-10-02 2014-12-17 엑손모빌 케미칼 패턴츠 인코포레이티드 다층 용융취입 복합체 및 이의 제조 방법
US8859696B2 (en) 2009-10-19 2014-10-14 Sasol Technology (Pty) Limited Oligomerisation of olefinic compounds with reduced polymer formation
WO2011053406A1 (en) 2009-10-29 2011-05-05 Exxonmobil Chemical Patents Inc. Pressure-sensitive hot melt adhesive compositions
US8668975B2 (en) 2009-11-24 2014-03-11 Exxonmobil Chemical Patents Inc. Fabric with discrete elastic and plastic regions and method for making same
EP2510019A2 (en) 2009-12-07 2012-10-17 Univation Technologies, LLC Methods for reducing static charge of a catalyst and methods for using the catalyst to produce polyolefins
WO2011078054A1 (ja) 2009-12-21 2011-06-30 三井化学株式会社 シンジオタクティックα‐オレフィン重合体の製造方法
EP2357035A1 (en) 2010-01-13 2011-08-17 Ineos Europe Limited Polymer powder storage and/or transport and/or degassing vessels
JP5750453B2 (ja) 2010-01-22 2015-07-22 エクソンモービル・ケミカル・パテンツ・インク 潤滑油組成物及びそれらの製造方法
CN102725319B (zh) 2010-01-27 2014-10-15 埃克森美孚化学专利公司 共聚物、其组合物及制造它们的方法
CN102791917B (zh) 2010-03-12 2014-11-05 埃克森美孚化学专利公司 制备耐热无纺织物的方法
EP2383301A1 (en) 2010-04-30 2011-11-02 Ineos Europe Limited Polymerization process
EP2383298A1 (en) 2010-04-30 2011-11-02 Ineos Europe Limited Polymerization process
US20120135903A1 (en) 2010-05-11 2012-05-31 Mitsui Chemicals, Inc. Lubricating oil composition
CA2802108C (en) 2010-07-28 2015-05-26 Exxonmobil Chemical Patents Inc. Viscosity modifiers comprising blends of ethylene-based copolymers
CA2802324C (en) 2010-07-28 2015-04-21 Exxonmobil Chemical Patents Inc. Ethylene based copolymer compositions as viscosity modifiers and methods for making them
CN103025818B (zh) 2010-07-28 2015-06-17 埃克森美孚化学专利公司 含乙烯-基共聚物的共混物的粘度改性剂
CN103154123B (zh) 2010-10-15 2016-01-27 埃克森美孚化学专利公司 聚丙烯-基粘合剂组合物
WO2012072417A1 (en) 2010-11-29 2012-06-07 Ineos Commercial Services Uk Limited Polymerisation control process
WO2012097146A1 (en) 2011-01-14 2012-07-19 W. R. Grace & Co.-Conn. Process of making modified metallocene catalyst, catalyst produced and use thereof
WO2012134725A2 (en) 2011-03-25 2012-10-04 Exxonmobil Chemical Patent Inc. Amphiphilic block polymers prepared by alkene metathesis
WO2012134721A2 (en) 2011-03-25 2012-10-04 Exxonmobil Chemical Patents Inc. Vinyl terminated higher olefin polymers and methods to produce thereof
CN103476809A (zh) 2011-05-18 2013-12-25 三井化学株式会社 丙烯系共聚物、丙烯系共聚物组合物、其成型体及其发泡体、及它们的制造方法
US8658556B2 (en) 2011-06-08 2014-02-25 Exxonmobil Chemical Patents Inc. Catalyst systems comprising multiple non-coordinating anion activators and methods for polymerization therewith
US8383740B1 (en) 2011-08-12 2013-02-26 Ineos Usa Llc Horizontal agitator
BR112014009411A2 (pt) 2011-10-17 2017-04-18 Ineos Europe Ag controle de processo de desgaseificação de polímero
US9000200B2 (en) 2011-12-19 2015-04-07 Saudi Basic Industries Corporation Process for the preparation of metallocene complexes
CN107721797A (zh) 2011-12-19 2018-02-23 沙特基础工业公司 用于制备茂金属络合物的方法
CN103987779B (zh) 2011-12-27 2016-04-06 三井化学株式会社 4－甲基－1－戊烯(共)聚合物组合物、包含该组合物的膜和中空成型体
CA2862245C (en) 2011-12-28 2016-10-25 Prime Polymer Co., Ltd. Ethylene polymer composition and shaped article of the same
JP6088548B2 (ja) 2012-02-03 2017-03-01 エクソンモービル ケミカル パテンツ インコーポレイテッド 油改質剤として有用なポリマー組成物を製造する方法
US10316176B2 (en) 2012-02-03 2019-06-11 Exxonmobil Chemical Patents Inc. Polymer compositions and methods of making them
US9139794B2 (en) 2012-02-03 2015-09-22 Exxonmobil Chemical Patents Inc. Process for the production of polymeric compositions useful as oil modifiers
JP5800984B2 (ja) 2012-03-21 2015-10-28 三井化学株式会社 オレフィン重合体の製造方法
US9865752B2 (en) 2012-03-28 2018-01-09 Mitsui Chemicals, Inc. Encapsulating material for solar cell and solar cell module
CN106866850B (zh) 2012-09-25 2020-07-03 三井化学株式会社 丙烯聚合物和成型体
CN104662050B (zh) 2012-09-25 2017-03-22 三井化学株式会社 烯烃聚合物的制造方法及烯烃聚合物
EP2917677A1 (en) 2012-11-12 2015-09-16 Univation Technologies, LLC Recycle gas cooler systems for gas-phase polymerization processes
KR101394943B1 (ko) 2012-11-19 2014-05-14 대림산업 주식회사 에틸렌과 알파-올레핀의 공중합체 및 그 제조방법
EP2922925B1 (en) 2012-12-28 2019-12-04 Dow Global Technologies LLC Coating compositions
KR102239585B1 (ko) 2012-12-28 2021-04-12 다우 글로벌 테크놀로지스 엘엘씨 코팅 조성물 및 그로부터 제조된 물품
EP2945972B1 (en) 2013-01-18 2023-10-11 Dow Global Technologies LLC Polymerization processes for high molecular weight polyolefins
US10548367B2 (en) 2013-01-29 2020-02-04 Exxonmobil Chemical Patents Inc. Footwear sole comprising a propylene-based elastomer, footwear comprising said sole, and methods of making them
WO2014129511A1 (ja) 2013-02-20 2014-08-28 株式会社プライムポリマー 二軸延伸フィルムおよびエチレン系重合体組成物
US9616421B2 (en) 2013-02-27 2017-04-11 Mitsui Chemicals, Inc. Catalyst for olefin multimerization and method for producing olefin multimer in presence of catalyst for olefin multimerization
SG11201507471PA (en) 2013-03-12 2015-10-29 Mitsui Chemicals Inc Production method of olefin polymer and olefin polymerization catalyst
CN105518096B (zh) 2013-10-18 2018-04-13 三井化学株式会社 含有乙烯·α‑烯烃共聚物的粘合剂
JP6774184B2 (ja) 2014-02-13 2020-10-21 三井化学株式会社 エチレン・α−オレフィン・非共役ポリエン共重合体およびその用途、並びにその製造方法
JP6492018B2 (ja) 2014-02-13 2019-03-27 三井化学株式会社 エチレン／α−オレフィン共重合体の製造方法
US10131726B2 (en) 2014-02-14 2018-11-20 Mitsui Chemicals, Inc. Ethylene/α-olefin/non-conjugated polyene copolymer, and production process and use thereof
CN105980454B (zh) 2014-02-28 2019-07-19 三井化学株式会社 交联物及其制造方法及用途、以及乙烯系共聚物
WO2015147186A1 (ja) 2014-03-28 2015-10-01 三井化学株式会社 オレフィン系樹脂およびその製造方法
US10040884B2 (en) 2014-03-28 2018-08-07 Mitsui Chemicals, Inc. Ethylene/α-olefin copolymers and lubricating oils
JP6017089B2 (ja) 2014-03-28 2016-10-26 三井化学株式会社 オレフィン系樹脂、その製造方法およびプロピレン系樹脂組成物
KR101970078B1 (ko) 2014-09-10 2019-04-17 미쓰이 가가쿠 가부시키가이샤 윤활유 조성물
US9944728B2 (en) 2014-09-11 2018-04-17 Mitsui Chemicals, Inc. Production method of olefin (co)polymer containing constituent unit derived from 1-butene
CN106715483B (zh) * 2014-10-03 2018-04-20 旭化成株式会社 乙烯聚合物和将其拉伸而得到的拉伸成形物以及乙烯聚合物的制造方法
WO2016076969A1 (en) 2014-11-12 2016-05-19 Exxonmobil Chemical Patents Inc. Purification of plasticizer and use thereof in a polymer production process and plant
WO2016093266A1 (ja) 2014-12-09 2016-06-16 三井化学株式会社 プロピレン系樹脂組成物
EP3272790B1 (en) 2015-03-20 2023-07-05 Mitsui Chemicals, Inc. Thermoplastic elastomer composition, use thereof, method for producing same, ethylene/ -olefin/unconjugated polyene copolymer and use thereof
EP3272805B1 (en) 2015-03-20 2021-08-11 Mitsui Chemicals, Inc. Thermoplastic elastomer composition and method for producing same
KR101913992B1 (ko) 2015-03-31 2018-10-31 미쓰이 가가쿠 가부시키가이샤 수지 조성물 및 그의 용도
DE112016004386T5 (de) 2015-09-28 2018-06-07 Denka Company Limited Kreuz-Copolymere sowie Herstellungsverfahren dafür
US20180320102A1 (en) 2015-11-09 2018-11-08 Mitsui Chemicals, Inc. Viscosity modifier for lubricating oils, additive composition for lubricating oils, and lubricating oil compositions
JP6694510B2 (ja) 2015-12-16 2020-05-13 エクソンモービル・ケミカル・パテンツ・インク 低結晶性ポリマー組成物
CN108698383A (zh) 2016-03-04 2018-10-23 三井化学株式会社 层叠体及其用途
WO2017172102A1 (en) 2016-03-31 2017-10-05 Exxonmobil Chemical Patents Inc. Low crystalline polymer compositions prepared in a dual reactor
US10647626B2 (en) 2016-07-12 2020-05-12 Chevron Phillips Chemical Company Lp Decene oligomers
US11155768B2 (en) 2017-01-16 2021-10-26 Mitsui Chemicals, Inc. Lubricant oil compositions for automotive gears
WO2018151103A1 (ja) 2017-02-20 2018-08-23 三井化学株式会社 積層体
WO2018151104A1 (ja) 2017-02-20 2018-08-23 三井化学株式会社 積層体
US11691136B2 (en) 2017-07-06 2023-07-04 Mitsui Chemicals, Inc. Olefin oligomerization catalyst and method for producing olefin oligomer in the presence of the same catalyst
WO2019027524A1 (en) 2017-08-02 2019-02-07 Exxonmobil Chemical Patents Inc. MULTILAYER FILMS AND METHODS OF MANUFACTURE
JP6941225B2 (ja) 2018-03-20 2021-09-29 三井化学株式会社 エチレン・α−オレフィン・非共役ポリエン共重合体、その製造方法および用途
EP3807358B1 (en) 2018-06-13 2023-11-15 ExxonMobil Chemical Patents Inc. Polyolefin blend compositions
US11993699B2 (en) 2018-09-14 2024-05-28 Fina Technology, Inc. Polyethylene and controlled rheology polypropylene polymer blends and methods of use
JP7182644B2 (ja) 2018-12-04 2022-12-02 三井化学株式会社 ４－メチル－１－ペンテン共重合体を含有する樹脂組成物、およびキャパシタ用フィルム
MX2021006769A (es) 2019-02-20 2021-07-15 Fina Technology Composiciones de polimero con baja distorsion.
BR112021018486A2 (pt) 2019-03-19 2021-11-23 Mitsui Chemicals Inc Composição de resina de propileno, artigo conformado e polímero de propileno
EP3950898A4 (en) 2019-03-26 2022-08-10 Mitsui Chemicals, Inc. COMPOSITION OF LUBRICANT OIL FOR AUTOMOTIVE TRANSMISSIONS AND METHOD OF PRODUCTION THEREOF
EP3950900A4 (en) 2019-03-26 2022-08-10 Mitsui Chemicals, Inc. COMPOSITION OF LUBRICATING OIL FOR INTERNAL COMBUSTION ENGINE, AND METHOD OF MAKING THE SAME
CN113574142A (zh) 2019-03-26 2021-10-29 三井化学株式会社 液压油用润滑油组合物及其制造方法
WO2020194551A1 (ja) 2019-03-26 2020-10-01 三井化学株式会社 圧縮機油用潤滑油組成物およびその製造方法
EP3950892A4 (en) 2019-03-26 2022-08-10 Mitsui Chemicals, Inc. FAT COMPOSITION AND PROCESS FOR PRODUCTION THEREOF
KR20210139402A (ko) 2019-03-26 2021-11-22 미쓰이 가가쿠 가부시키가이샤 내연 기관용 윤활유 조성물 및 그의 제조 방법
KR102730694B1 (ko) 2019-03-26 2024-11-18 미쓰이 가가쿠 가부시키가이샤 윤활유 조성물 및 그의 제조 방법
US20220169938A1 (en) 2019-03-26 2022-06-02 Mitsui Chemicals, Inc. Lubrication oil composition and method for producing same
WO2020194547A1 (ja) 2019-03-26 2020-10-01 三井化学株式会社 自動車変速機油用潤滑油組成物およびその製造方法
EP3950893B1 (en) 2019-03-26 2024-07-17 Mitsui Chemicals, Inc. Lubricating oil composition for industrial gears and method for producing same
JP7297054B2 (ja) 2019-03-29 2023-06-23 三井化学株式会社 樹脂組成物
EP4011961A4 (en) 2019-08-08 2023-07-12 Prime Polymer Co., Ltd. PROPYLENE RESIN COMPOSITION AND MOLDING ARTICLES
JP7322164B2 (ja) 2019-10-07 2023-08-07 三井化学株式会社 エチレン・α－オレフィン共重合体組成物およびその用途
CN114364733B (zh) 2019-10-29 2023-11-10 三井化学株式会社 乙烯系共聚物组合物及其用途
KR20220123062A (ko) 2020-01-30 2022-09-05 미쓰이 가가쿠 가부시키가이샤 폴리아마이드 조성물
EP4227331A4 (en) 2020-10-06 2025-01-22 Mitsui Chemicals Inc RESIN COMPOSITION
CN116829642A (zh) 2021-01-18 2023-09-29 三井化学株式会社 水分散体组合物、该水分散体组合物的制造方法及乙烯·α-烯烃共聚物酸改性物
EP4303238A4 (en) 2021-03-05 2025-03-26 Mitsui Chemicals Inc THERMOPLASTIC ELASTOMER COMPOSITION
CN117120490A (zh) 2021-03-31 2023-11-24 三井化学株式会社 乙烯－α-烯烃共聚物、热塑性树脂组合物和膜
WO2022210845A1 (ja) 2021-03-31 2022-10-06 三井化学株式会社 エチレン系樹脂組成物および成形体
EP4316833A4 (en) 2021-03-31 2025-03-26 Mitsui Chemicals Inc ETHYLENE-α-OLEFIN COPOLYMER, THERMOPLASTIC RESIN COMPOSITION, FILM AND LAMINATE
KR20240001127A (ko) 2021-04-26 2024-01-03 피나 테크놀러지, 인코포레이티드 얇은 단일-부위 촉매화된 중합체 시트
WO2022244879A1 (ja) 2021-05-20 2022-11-24 三井化学株式会社 樹脂組成物及びその用途ならびに製造方法
US20240352253A1 (en) 2021-11-16 2024-10-24 Mitsui Chemicals, Inc. Resin composition and use thereof
CN118871529A (zh) 2022-03-17 2024-10-29 三井化学株式会社 热塑性树脂组合物
JPWO2023182473A1 (ko) 2022-03-24 2023-09-28
CN119421910A (zh) 2022-06-27 2025-02-11 三井化学株式会社 清漆状的环状烯烃系共聚物组合物的制造方法、环状烯烃系共聚物组合物、交联体、膜或片、层叠体、电路基板、电子设备及预浸料
CN119421911A (zh) 2022-06-27 2025-02-11 三井化学株式会社 环状烯烃系共聚物的制造方法、环状烯烃系共聚物、交联体、膜或片、层叠体、电路基板、电子设备及预浸料

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
PL276385A1 (en) * 1987-01-30 1989-07-24 Exxon Chemical Patents Inc Method for polymerization of olefines,diolefins and acetylene unsaturated compounds
IL85097A (en) * 1987-01-30 1992-02-16 Exxon Chemical Patents Inc Catalysts based on derivatives of a bis(cyclopentadienyl)group ivb metal compound,their preparation and their use in polymerization processes

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