KR900011839A - 내인열성이 향상된 천연 고무 라텍스 필름 생성물 - Google Patents
내인열성이 향상된 천연 고무 라텍스 필름 생성물 Download PDFInfo
- Publication number
- KR900011839A KR900011839A KR1019900000209A KR900000209A KR900011839A KR 900011839 A KR900011839 A KR 900011839A KR 1019900000209 A KR1019900000209 A KR 1019900000209A KR 900000209 A KR900000209 A KR 900000209A KR 900011839 A KR900011839 A KR 900011839A
- Authority
- KR
- South Korea
- Prior art keywords
- styrene
- weight
- parts
- butadiene copolymer
- natural rubber
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
- C08J5/02—Direct processing of dispersions, e.g. latex, to articles
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61L—METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
- A61L31/00—Materials for other surgical articles, e.g. stents, stent-grafts, shunts, surgical drapes, guide wires, materials for adhesion prevention, occluding devices, surgical gloves, tissue fixation devices
- A61L31/04—Macromolecular materials
- A61L31/048—Macromolecular materials obtained by reactions only involving carbon-to-carbon unsaturated bonds
- A61L31/049—Rubbers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L7/00—Compositions of natural rubber
- C08L7/02—Latex
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2307/00—Characterised by the use of natural rubber
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L25/00—Compositions of, homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Compositions of derivatives of such polymers
- C08L25/02—Homopolymers or copolymers of hydrocarbons
- C08L25/04—Homopolymers or copolymers of styrene
- C08L25/08—Copolymers of styrene
- C08L25/10—Copolymers of styrene with conjugated dienes
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- Polymers & Plastics (AREA)
- Medicinal Chemistry (AREA)
- Vascular Medicine (AREA)
- Animal Behavior & Ethology (AREA)
- Manufacturing & Machinery (AREA)
- Engineering & Computer Science (AREA)
- Heart & Thoracic Surgery (AREA)
- Surgery (AREA)
- Dispersion Chemistry (AREA)
- Epidemiology (AREA)
- Life Sciences & Earth Sciences (AREA)
- Materials Engineering (AREA)
- General Health & Medical Sciences (AREA)
- Public Health (AREA)
- Veterinary Medicine (AREA)
- Manufacture Of Macromolecular Shaped Articles (AREA)
- Moulding By Coating Moulds (AREA)
- Orthopedics, Nursing, And Contraception (AREA)
- Materials For Medical Uses (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
Description
Claims (13)
- (a) 성형 금형을 수성 고무 라텍스 혼합물 중에 첨지시켜 금형상에 고무의 연속 필름을 형성시키고; (b)고무 필름을 금형상에서 건조 및 경화시킨 다음; (c) 건조 및 경화된 고무 필름을 금형으로 부터 분리시키는 단계를 포함하며, 여기에서, 수성 고무 라텍스 혼합물은 천연 고무 라텍스와 스티렌-부타디엔 공중합체 라텍스의 혼합물이며, 스티렌-부타디엔 공중합체 라텍스는 천연 고무 라텍스 100중량부당 약 1 내지 약 25중량부(고체기준)의 비율로 사용되고, 스티렌-부타디엔 공중합체는 50중량% 이상의 중합된 스티렌을 함유하며 나머지는 중합된 부타디엔임을 특징으로 하여, 고무 제품을 제조하는 방법.
- 제1항에 있어서, 스티렌-부타디엔 공중합체가 약 75 내지 약 85중량%의 중합된 스티렌을 함유하는 방법.
- 제1항에 있어서, 스티렌-부타디엔 공중합체 라텍스가 천연고무 라텍스 100중량부당 약 10 내지 약 20중량부(고체기준)의 비율로 사용되는 방법.
- 제2항에 있어서, 스티렌-부타디엔 공중합체 라텍스가 천연고무 라텍스 100중량부당 약 10 내지 약 20중량부(고체기준)의 비율로 사용되는 방법.
- 제1항에 있어서, 고무 제품이 예방용 콘돔인 방법.
- 제1항에 있어서, 고무 제품이 내과 또는 외과용 글러브인 방법.
- 경화된 천연 고무 및 스티렌-부타디엔 공중합체를 포함하며, 여기서 스티렌-부타디엔 공중합체는 50중량% 이상의 중합된 스티렌을 함유하고 나머지는 중합된 부타디엔 이며, 천연 고무 100중량부당 약 1 내지 약 25중량부 범위내의 양으로 존재함을 특징으로 하는 천연 고무 필름 제품.
- 제7항에 있어서, 스티렌-부타디엔 공중합체가 약 75 내지 약 85중량%의 중합된 스티렌을 함유하는 방법.
- 제7항에 있어서, 스티렌-부타디엔 공중합체가 천연고무 100중량부당 약 10 내지 약 20중량부의 양으로 존재하는 제품.
- 제8항에 있어서 스티렌-부타디엔 공중합체가 천연고무 100중량부당 약 10 내지 약 20중량부의 양으로 존재하는 제품.
- 제7항에 있어서, 예방용 콘돔 형태인 제품.
- 제7항에 있어서, 내과 또는 외과용 글러브인 형태인 제품.
- 제7항에 있어서, 골무 형태인 제품.※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US295,679 | 1989-01-11 | ||
US07/295,679 US4963623A (en) | 1989-01-11 | 1989-01-11 | Natural rubber latex film products with improved tear resistance |
Publications (2)
Publication Number | Publication Date |
---|---|
KR900011839A true KR900011839A (ko) | 1990-08-02 |
KR0179983B1 KR0179983B1 (ko) | 1999-05-15 |
Family
ID=23138768
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
KR1019900000209A Expired - Lifetime KR0179983B1 (ko) | 1989-01-11 | 1990-01-10 | 내인열성이 향상된 천연 고무 라텍스 필름 생성물 |
Country Status (20)
Country | Link |
---|---|
US (1) | US4963623A (ko) |
EP (1) | EP0378380B1 (ko) |
JP (1) | JP2998844B2 (ko) |
KR (1) | KR0179983B1 (ko) |
AR (1) | AR246178A1 (ko) |
AU (1) | AU627818B2 (ko) |
BR (1) | BR9000086A (ko) |
CA (1) | CA2007404A1 (ko) |
CS (1) | CS275357B2 (ko) |
DD (1) | DD297787A5 (ko) |
DE (1) | DE69001551T2 (ko) |
DK (1) | DK6390A (ko) |
ES (1) | ES2041125T3 (ko) |
MX (1) | MX172995B (ko) |
NO (1) | NO900117L (ko) |
NZ (1) | NZ232074A (ko) |
PT (1) | PT92822A (ko) |
RU (1) | RU2061002C1 (ko) |
TR (1) | TR26236A (ko) |
ZA (1) | ZA90179B (ko) |
Families Citing this family (26)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB8820945D0 (en) * | 1988-09-07 | 1988-10-05 | Smith & Nephew | Medical articles |
CZ282211B6 (cs) * | 1989-05-24 | 1997-06-11 | Ústav Makromolekulární Chemie Avčr | Vodou a vodnými roztoky botnavé pryže a způsob jejich výroby |
US5014362A (en) * | 1990-05-11 | 1991-05-14 | Tillotson Corporation | Elastomeric covering material and hand glove made therewith |
US5195537A (en) * | 1991-05-10 | 1993-03-23 | Tillotson Corporation | Elastomeric condom |
JPH05329172A (ja) * | 1991-07-03 | 1993-12-14 | Smith & Nephew Inc | エラストマー物品 |
US5284157A (en) * | 1991-07-26 | 1994-02-08 | Ortho Pharmaceutical Corporation | Elastomeric film products with improved chemical resistance |
AU4788993A (en) * | 1992-07-29 | 1994-03-03 | Washington University | Use of pouch for implantation of living cells |
US5500469A (en) * | 1994-09-22 | 1996-03-19 | The Dow Chemical Company | Preparation of a novel article from a thermally gellable artificial latex |
DE19545096A1 (de) | 1995-12-04 | 1997-06-05 | Basf Ag | Verfahren zur Herstellung einer wäßrigen Polymerisatdispersion |
CA2290998A1 (en) | 1997-05-28 | 1998-12-03 | Venkataram Krishnan | Elastomeric material for rubber articles |
US5910533A (en) * | 1997-08-04 | 1999-06-08 | Reichhold Chemicals, Inc. | Elastomeric material for rubber articles |
US6369154B1 (en) | 1999-07-26 | 2002-04-09 | Reichhold, Inc. | Compositions suitable for making elastomeric articles of manufacture |
US6624274B1 (en) | 2000-11-09 | 2003-09-23 | Dow Reichhold Specialty Latex Llc | Polymers having novel cure system |
JP2002348409A (ja) * | 2001-05-28 | 2002-12-04 | Fuji Latex Kk | ゴムラテックス組成物 |
US20030012946A1 (en) * | 2001-06-28 | 2003-01-16 | Davis Stephen C. | Coated polymeric foam |
US20070025807A1 (en) * | 2003-07-28 | 2007-02-01 | Liberatore Raymond A | Spreader Apparatus, For Use With Dispensers |
WO2005056612A1 (ja) * | 2003-12-08 | 2005-06-23 | Nitta Corporation | ゴム状製品又はゴム状物質含有製品 |
RU2362789C2 (ru) * | 2004-04-16 | 2009-07-27 | АНСЕЛЛ ХЕЛТКЭА ПРОДАКТС ЭлЭлСи | Беспорошковые перчатки и способ изготовления беспорошковых перчаток в поточном режиме |
MY147739A (en) * | 2005-07-20 | 2013-01-15 | Diptech Pte Ltd | Elastomeric films and gloves |
GB0625551D0 (en) * | 2006-12-21 | 2007-01-31 | Lrc Products | Thin condoms |
US20090030156A1 (en) * | 2007-05-16 | 2009-01-29 | Ploenpit Boochathum | Process for producing special-grade natural rubber |
CA2732248C (en) * | 2008-08-27 | 2018-11-06 | Kimberly-Clark Worldwide, Inc. | Thin, smooth nitrile rubber gloves |
US20120325222A1 (en) * | 2011-06-21 | 2012-12-27 | Carr Alesa J | Skin-tone colored condoms |
RU2548436C2 (ru) * | 2013-07-23 | 2015-04-20 | Открытое акционерное общество "Калининский завод резиновых изделий" | Перчатки латексные защитные модифицированные |
CN111745876A (zh) * | 2020-07-07 | 2020-10-09 | 山东利尔新材股份有限公司 | 一种防水防渗透胶乳手套的制备方法 |
CN113480743B (zh) * | 2021-05-31 | 2023-08-22 | 中国工程物理研究院材料研究所 | 一种可制备高性能柔性制品的复合胶乳及其配合工艺 |
Family Cites Families (15)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2266263A (en) * | 1939-01-19 | 1941-12-16 | Davol Rubber Co | Manufacture of rubber articles |
US2327638A (en) * | 1940-09-07 | 1943-08-24 | Harrison & Morton Lab Inc | Manufacture of rubber products and apparatus therefor |
US2661339A (en) * | 1946-03-02 | 1953-12-01 | Jasco Inc | Blends of resinous styrene-conjugated diene copolymers and rubbery materials |
US2896949A (en) * | 1950-08-22 | 1959-07-28 | Dunker Henry Christian Louis | Tennis balls |
BE519478A (ko) * | 1952-04-25 | |||
US2747229A (en) * | 1952-09-03 | 1956-05-29 | Us Rubber Co | Method and composition for making lined dipped goods from latex |
US2809175A (en) * | 1953-06-24 | 1957-10-08 | Goodyear Tire & Rubber | High sulphur rubber composition containing a resinous styrene/diene copolymer |
NL202720A (ko) * | 1954-12-24 | |||
GB984619A (en) * | 1963-02-05 | 1965-02-24 | Veedip Ltd | Improvements in the manufacture by a dipping process of articles of a plasticised polymer or co-polymer of vinyl chloride |
US3286011A (en) * | 1964-03-18 | 1966-11-15 | Us Rubber Co | Method of making gloves |
US4356824A (en) * | 1980-07-30 | 1982-11-02 | Vazquez Richard M | Multiple lumen gastrostomy tube |
GB2088389B (en) * | 1980-11-26 | 1984-01-11 | Lrc Products | Manufacture of rubber articles by dipping |
US4590123A (en) * | 1982-04-13 | 1986-05-20 | Bridgestone Tire Co., Ltd. | Low-resilience rubber compositions and foams |
US4675347A (en) * | 1983-10-29 | 1987-06-23 | Unitika Ltd. | Antimicrobial latex composition |
US4867968A (en) * | 1987-12-29 | 1989-09-19 | Florida-Kansas Health Care, Inc. | Elastomeric composition containing therapeutic agents and articles manufactured therefrom |
-
1989
- 1989-01-11 US US07/295,679 patent/US4963623A/en not_active Expired - Lifetime
-
1990
- 1990-01-09 AU AU47813/90A patent/AU627818B2/en not_active Expired
- 1990-01-09 CA CA002007404A patent/CA2007404A1/en not_active Abandoned
- 1990-01-09 DD DD90337013A patent/DD297787A5/de unknown
- 1990-01-10 ES ES199090300268T patent/ES2041125T3/es not_active Expired - Lifetime
- 1990-01-10 ZA ZA90179A patent/ZA90179B/xx unknown
- 1990-01-10 CS CS90131A patent/CS275357B2/cs not_active IP Right Cessation
- 1990-01-10 DK DK006390A patent/DK6390A/da not_active Application Discontinuation
- 1990-01-10 DE DE90300268T patent/DE69001551T2/de not_active Revoked
- 1990-01-10 NO NO90900117A patent/NO900117L/no unknown
- 1990-01-10 AR AR90315920A patent/AR246178A1/es active
- 1990-01-10 KR KR1019900000209A patent/KR0179983B1/ko not_active Expired - Lifetime
- 1990-01-10 EP EP90300268A patent/EP0378380B1/en not_active Revoked
- 1990-01-10 RU SU904742945A patent/RU2061002C1/ru active
- 1990-01-10 NZ NZ232074A patent/NZ232074A/en unknown
- 1990-01-10 PT PT92822A patent/PT92822A/pt not_active Application Discontinuation
- 1990-01-10 BR BR909000086A patent/BR9000086A/pt not_active IP Right Cessation
- 1990-01-11 JP JP2002659A patent/JP2998844B2/ja not_active Expired - Lifetime
- 1990-01-11 MX MX019100A patent/MX172995B/es unknown
- 1990-01-11 TR TR90/0089A patent/TR26236A/xx unknown
Also Published As
Publication number | Publication date |
---|---|
EP0378380A1 (en) | 1990-07-18 |
AU627818B2 (en) | 1992-09-03 |
EP0378380B1 (en) | 1993-05-12 |
MX172995B (es) | 1994-01-27 |
CA2007404A1 (en) | 1990-07-11 |
CS9000131A3 (en) | 1992-02-19 |
DD297787A5 (de) | 1992-01-23 |
DK6390A (da) | 1990-07-12 |
NZ232074A (en) | 1991-05-28 |
BR9000086A (pt) | 1990-10-16 |
US4963623A (en) | 1990-10-16 |
AU4781390A (en) | 1990-07-19 |
AR246178A1 (es) | 1994-07-29 |
DK6390D0 (da) | 1990-01-10 |
PT92822A (pt) | 1990-07-31 |
ZA90179B (en) | 1991-09-25 |
CS275357B2 (en) | 1992-02-19 |
RU2061002C1 (ru) | 1996-05-27 |
DE69001551D1 (de) | 1993-06-17 |
NO900117D0 (no) | 1990-01-10 |
KR0179983B1 (ko) | 1999-05-15 |
NO900117L (no) | 1990-07-12 |
TR26236A (tr) | 1995-02-15 |
JPH02289316A (ja) | 1990-11-29 |
ES2041125T3 (es) | 1993-11-01 |
DE69001551T2 (de) | 1994-01-05 |
JP2998844B2 (ja) | 2000-01-17 |
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Legal Events
Date | Code | Title | Description |
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PA0109 | Patent application |
Patent event code: PA01091R01D Comment text: Patent Application Patent event date: 19900110 |
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A201 | Request for examination | ||
PA0201 | Request for examination |
Patent event code: PA02012R01D Patent event date: 19950110 Comment text: Request for Examination of Application Patent event code: PA02011R01I Patent event date: 19900110 Comment text: Patent Application |
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Comment text: Notification of reason for refusal Patent event date: 19980221 Patent event code: PE09021S01D |
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E701 | Decision to grant or registration of patent right | ||
PE0701 | Decision of registration |
Patent event code: PE07011S01D Comment text: Decision to Grant Registration Patent event date: 19980904 |
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GRNT | Written decision to grant | ||
PR0701 | Registration of establishment |
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