[go: up one dir, main page]

KR890700137A - 올레핀의 중합방법 - Google Patents

올레핀의 중합방법

Info

Publication number
KR890700137A
KR890700137A KR1019880700827A KR880700827A KR890700137A KR 890700137 A KR890700137 A KR 890700137A KR 1019880700827 A KR1019880700827 A KR 1019880700827A KR 880700827 A KR880700827 A KR 880700827A KR 890700137 A KR890700137 A KR 890700137A
Authority
KR
South Korea
Prior art keywords
alminooxane
aminooxane
compound
atom
transition metal
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
KR1019880700827A
Other languages
English (en)
Other versions
KR910005673B1 (ko
Inventor
도시유끼 쓰쓰이
아끼노리 도요다
노리오 가시와
Original Assignee
다께바야시 쇼오고
미쓰이 세끼유 가가꾸 고오교오 가부시끼가이샤
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from JP61275191A external-priority patent/JPH0780933B2/ja
Application filed by 다께바야시 쇼오고, 미쓰이 세끼유 가가꾸 고오교오 가부시끼가이샤 filed Critical 다께바야시 쇼오고
Publication of KR890700137A publication Critical patent/KR890700137A/ko
Application granted granted Critical
Publication of KR910005673B1 publication Critical patent/KR910005673B1/ko
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/943—Polymerization with metallocene catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)

Abstract

내용 없음

Description

올레핀의 중합방법
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (7)

  1. (A) 주기율표 제IVB족의 천이금속의 화합물, (B) 트리메틸알미늄으로 형성된 알미노옥산 및 (C) Al원자에 적어도 1개의 n-알킬기이외의 탄화수소기가 결합된 알미노옥산으로 형성된 촉매의 존재하에 올레핀을 중합 또는 공중합시키는 것을 특징으로 하는 올레핀의 중합방법.
  2. 화합물(A)의 주기율표 제 IVB족의 천이금속이 티탄, 질코늄 또는 하프늄인 것을 특징으로 하는 특허청구의 범위 제1항 기재의 방법.
  3. 트리메틸알미늄으로 형성된 알미노옥산(B)가 하기식(II)
    여기에서, n는 2이상의 수이다)로 표시되든지 또는 하기식(III)
    (여기에서, m의 정의는 상기와 같다)로 표시되는 청구의 범위 1기재의 방법.
  4. Al원자에 적어도 1개의 n-알킬기이이외의 탄화수소기가 결합된 알미노옥산(C)의 탄화수소가 분지알킬, 시크로알킬 또는 아릴인 청구의 범위 제1항 기재의 방법.
  5. 화합물(A)을 이 화합물의 천이금속이 중합반응계내에서 10-8-10-2그램원자/1의 농도가 되는 양으로 사용하는 청구의 범위 제1항 기재의 방법.
  6. 알미노옥산(B)를 이 알미노옥산(B)의 알미늄 원자가 중합 반응계내에서 3밀리그램원자/1이하가 되는 양으로 사용하는 청구의 범위 제1항 기재의 방법.
  7. 알미노옥산(C)을 이 알미노옥산(C)의 알미늄원자와 알미노옥산(B)의 알미늄 원자와의 합계에 대해서 알미노옥산(C)의 알미늄원자가 20-95%를 점하는 비율로 사용하는 청구의 범위 제1항 기재의 방법.
    참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019880700827A 1986-11-20 1987-11-19 올레핀의 중합방법 Expired KR910005673B1 (ko)

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
JP275191 1986-11-20
JP61-275191 1986-11-20
JP61275191A JPH0780933B2 (ja) 1986-11-20 1986-11-20 オレフインの重合方法
PCT/JP1987/000898 WO1988003932A1 (en) 1986-11-20 1987-11-19 Process for polymerizing olefin

Publications (2)

Publication Number Publication Date
KR890700137A true KR890700137A (ko) 1989-03-10
KR910005673B1 KR910005673B1 (ko) 1991-08-01

Family

ID=26113504

Family Applications (1)

Application Number Title Priority Date Filing Date
KR1019880700827A Expired KR910005673B1 (ko) 1986-11-20 1987-11-19 올레핀의 중합방법

Country Status (3)

Country Link
KR (1) KR910005673B1 (ko)
AT (1) ATE69243T1 (ko)
DE (1) DE3774438D1 (ko)

Also Published As

Publication number Publication date
ATE69243T1 (de) 1991-11-15
DE3774438D1 (de) 1991-12-12
KR910005673B1 (ko) 1991-08-01

Similar Documents

Publication Publication Date Title
EP0324856A4 (en) POLYMERIZATION PROCESS FOR OLEFINS.
KR910000806A (ko) 올레핀의 중합방법 및 중합용 촉매
KR910006335A (ko) 올레핀 중합 촉매
KR970042568A (ko) 사이클로올레핀 공중합체의 제조방법
KR880011205A (ko) 올레핀 중합방법 및 중합촉매
KR940014456A (ko) 올레핀 중합체의 제조방법
ATE36863T1 (de) Katalysator und verfahren zur polymerisation von olefinen.
KR890005155A (ko) 광범위한 분자량 분포를 갖는 폴리올레핀 제조용 촉매시스탬
EP0472741A4 (en) Olefin polymerization catalyst
RU95112455A (ru) Инденильные соединения, компонент катализатора для полимеризации олефинов, способ полимеризации олефинов, полиолефин
KR880013990A (ko) 올레핀 중합용 고체촉매
KR890700138A (ko) 올레핀 중합용 고체촉매 및 그 제조법
BR8603716A (pt) Processo para polimerizacao de alfa-olefinas
DK0725086T3 (da) Understøttet metallocenkatalysator til (co)polymerisation af olefiner
KR937000516A (ko) 신규한 천이금속화합물 및 이것을 이용한 올레핀의 중합방법
DE69612331D1 (de) Metallocenkatalysator für die Homo- oder Copolymerisation von Alpha-Olefinen
KR910000807A (ko) 액체촉매성분, 그 성분을 함유하는 촉매계, 및 그 촉매계를 사용하는 에틸렌-α-올레핀 공중합체의 제조방법
KR890700140A (ko) 불포화된 에틸렌 중합체
KR940009217A (ko) 에틸렌 중합용 티타늄 촉매성분, 에틸렌 중합촉매 및 그를 사용한 에틸렌중합방법
KR910004671A (ko) 알파-올레핀류의 중합반응 및 공중합반응촉매와 그 방법
KR960000935A (ko) 사이클로올레핀 공중합체를 제조하는 방법
DK0955304T3 (da) Metallocenkomplekser med bro til (co)polymerisation af olefiner
KR960041200A (ko) 유기 금속 화합물
KR890013063A (ko) 올레핀 중합용 촉매 및 올레핀의 중합방법
BR9307696A (pt) Catalisador e processo para uma polimeração ziegler

Legal Events

Date Code Title Description
A201 Request for examination
PA0105 International application

St.27 status event code: A-0-1-A10-A15-nap-PA0105

PA0201 Request for examination

St.27 status event code: A-1-2-D10-D11-exm-PA0201

R17-X000 Change to representative recorded

St.27 status event code: A-3-3-R10-R17-oth-X000

PG1501 Laying open of application

St.27 status event code: A-1-1-Q10-Q12-nap-PG1501

G160 Decision to publish patent application
PG1605 Publication of application before grant of patent

St.27 status event code: A-2-2-Q10-Q13-nap-PG1605

E701 Decision to grant or registration of patent right
PE0701 Decision of registration

St.27 status event code: A-1-2-D10-D22-exm-PE0701

GRNT Written decision to grant
PR0701 Registration of establishment

St.27 status event code: A-2-4-F10-F11-exm-PR0701

PR1002 Payment of registration fee

St.27 status event code: A-2-2-U10-U12-oth-PR1002

Fee payment year number: 1

PR1001 Payment of annual fee

St.27 status event code: A-4-4-U10-U11-oth-PR1001

Fee payment year number: 4

PR1001 Payment of annual fee

St.27 status event code: A-4-4-U10-U11-oth-PR1001

Fee payment year number: 5

PR1001 Payment of annual fee

St.27 status event code: A-4-4-U10-U11-oth-PR1001

Fee payment year number: 6

PR1001 Payment of annual fee

St.27 status event code: A-4-4-U10-U11-oth-PR1001

Fee payment year number: 7

PR1001 Payment of annual fee

St.27 status event code: A-4-4-U10-U11-oth-PR1001

Fee payment year number: 8

PN2301 Change of applicant

St.27 status event code: A-5-5-R10-R13-asn-PN2301

St.27 status event code: A-5-5-R10-R11-asn-PN2301

PR1001 Payment of annual fee

St.27 status event code: A-4-4-U10-U11-oth-PR1001

Fee payment year number: 9

PR1001 Payment of annual fee

St.27 status event code: A-4-4-U10-U11-oth-PR1001

Fee payment year number: 10

FPAY Annual fee payment

Payment date: 20010725

Year of fee payment: 11

PR1001 Payment of annual fee

St.27 status event code: A-4-4-U10-U11-oth-PR1001

Fee payment year number: 11

LAPS Lapse due to unpaid annual fee
PC1903 Unpaid annual fee

St.27 status event code: A-4-4-U10-U13-oth-PC1903

Not in force date: 20020802

Payment event data comment text: Termination Category : DEFAULT_OF_REGISTRATION_FEE

PC1903 Unpaid annual fee

St.27 status event code: N-4-6-H10-H13-oth-PC1903

Ip right cessation event data comment text: Termination Category : DEFAULT_OF_REGISTRATION_FEE

Not in force date: 20020802

R18-X000 Changes to party contact information recorded

St.27 status event code: A-5-5-R10-R18-oth-X000

P22-X000 Classification modified

St.27 status event code: A-4-4-P10-P22-nap-X000

P22-X000 Classification modified

St.27 status event code: A-4-4-P10-P22-nap-X000

R18-X000 Changes to party contact information recorded

St.27 status event code: A-5-5-R10-R18-oth-X000