KR890010098A - 열경화 반응성 수지계 - Google Patents
열경화 반응성 수지계 Download PDFInfo
- Publication number
- KR890010098A KR890010098A KR1019880016079A KR880016079A KR890010098A KR 890010098 A KR890010098 A KR 890010098A KR 1019880016079 A KR1019880016079 A KR 1019880016079A KR 880016079 A KR880016079 A KR 880016079A KR 890010098 A KR890010098 A KR 890010098A
- Authority
- KR
- South Korea
- Prior art keywords
- reactive resin
- resin system
- formula
- mixture
- polyisocyanate
- Prior art date
Links
- 229920005989 resin Polymers 0.000 title claims 21
- 239000011347 resin Substances 0.000 title claims 21
- 229920001187 thermosetting polymer Polymers 0.000 title claims 2
- 229920001228 polyisocyanate Polymers 0.000 claims 10
- 239000005056 polyisocyanate Substances 0.000 claims 10
- 150000001875 compounds Chemical class 0.000 claims 7
- 239000000203 mixture Substances 0.000 claims 7
- 229920000647 polyepoxide Polymers 0.000 claims 7
- 239000003822 epoxy resin Substances 0.000 claims 3
- 239000000945 filler Substances 0.000 claims 3
- 239000012948 isocyanate Substances 0.000 claims 3
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims 2
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims 2
- UFWIBTONFRDIAS-UHFFFAOYSA-N Naphthalene Chemical compound C1=CC=CC2=CC=CC=C21 UFWIBTONFRDIAS-UHFFFAOYSA-N 0.000 claims 2
- 239000000654 additive Substances 0.000 claims 2
- 125000001931 aliphatic group Chemical group 0.000 claims 2
- 125000000217 alkyl group Chemical group 0.000 claims 2
- -1 aromatic epoxide Chemical class 0.000 claims 2
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 claims 2
- 229910052736 halogen Inorganic materials 0.000 claims 2
- 150000002367 halogens Chemical class 0.000 claims 2
- 150000002513 isocyanates Chemical class 0.000 claims 2
- 239000007788 liquid Substances 0.000 claims 2
- 125000000449 nitro group Chemical group [O-][N+](*)=O 0.000 claims 2
- LFSYUSUFCBOHGU-UHFFFAOYSA-N 1-isocyanato-2-[(4-isocyanatophenyl)methyl]benzene Chemical compound C1=CC(N=C=O)=CC=C1CC1=CC=CC=C1N=C=O LFSYUSUFCBOHGU-UHFFFAOYSA-N 0.000 claims 1
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims 1
- 239000005977 Ethylene Substances 0.000 claims 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims 1
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims 1
- 239000002318 adhesion promoter Substances 0.000 claims 1
- 125000002723 alicyclic group Chemical group 0.000 claims 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims 1
- 125000003710 aryl alkyl group Chemical group 0.000 claims 1
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 claims 1
- 150000001718 carbodiimides Chemical class 0.000 claims 1
- 125000004985 dialkyl amino alkyl group Chemical group 0.000 claims 1
- 229910000514 dolomite Inorganic materials 0.000 claims 1
- 239000010459 dolomite Substances 0.000 claims 1
- 239000000975 dye Substances 0.000 claims 1
- 239000005350 fused silica glass Substances 0.000 claims 1
- 125000000623 heterocyclic group Chemical group 0.000 claims 1
- 229910052739 hydrogen Inorganic materials 0.000 claims 1
- 239000001257 hydrogen Substances 0.000 claims 1
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 claims 1
- 238000000034 method Methods 0.000 claims 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims 1
- 238000002156 mixing Methods 0.000 claims 1
- 125000001624 naphthyl group Chemical group 0.000 claims 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims 1
- 125000000843 phenylene group Chemical group C1(=C(C=CC=C1)*)* 0.000 claims 1
- 239000000049 pigment Substances 0.000 claims 1
- 239000000843 powder Substances 0.000 claims 1
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 claims 1
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 claims 1
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 claims 1
- 239000011342 resin composition Substances 0.000 claims 1
- 239000003381 stabilizer Substances 0.000 claims 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L67/00—Compositions of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Compositions of derivatives of such polymers
- C08L67/02—Polyesters derived from dicarboxylic acids and dihydroxy compounds
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
- H01B3/00—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties
- H01B3/18—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances
- H01B3/30—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes
- H01B3/42—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes polyesters; polyethers; polyacetals
- H01B3/421—Polyesters
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/16—Nitrogen-containing compounds
- C08K5/34—Heterocyclic compounds having nitrogen in the ring
- C08K5/3412—Heterocyclic compounds having nitrogen in the ring having one nitrogen atom in the ring
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/16—Nitrogen-containing compounds
- C08K5/34—Heterocyclic compounds having nitrogen in the ring
- C08K5/35—Heterocyclic compounds having nitrogen in the ring having also oxygen in the ring
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Physics & Mathematics (AREA)
- Spectroscopy & Molecular Physics (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Organic Insulating Materials (AREA)
- Paints Or Removers (AREA)
- Insulated Conductors (AREA)
- Polyesters Or Polycarbonates (AREA)
- Polyurethanes Or Polyureas (AREA)
Abstract
내용 없음
Description
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음
Claims (17)
- a) 적어도 하나의 에폭사이드 수지, b) 적어도 하나의 이소시아네이트 수지, c) 하기식(Ⅰ)의 반응 촉진제와 d) 적합하다면 산업 분야에서 통상적인 충전제 및/또는 첨가제를 포함하는 열경화 반응성 수지계.상기 식에서, R1은 n이 2-24인 -(CR4R5)n-, 또는 할로겐, 니트로, C1-C4알킬, C1-C4알콕시 또는 C3-C8디알킬아미노 알킬에 의하여 단일- 또는 복수 치환되거나 비치환된 페닐렌 또는 나프탈렌 또는 하기식의 라디칼이고R2와 R3는 서로 독립적으로 C1-C12알킬, 또는 할로겐, 니트로, C1-C4알킬 또는 C1-C4알콕시에 의하여 단일 또는 복수 치환되거나 비치환된 페닐 또는 나프틸 또는 C7-C13의 아릴킬이거나 또는 R1와 R3는 함께 N와 연결되어 5-윈, 6-원 또는 7윈의 헤테로 고리이며 R4와 R5는 서로 독립적으로 수소 또는 C1-C8알킬이다.
- 제1항에 있어서, 에폭사이드 수지가 폴리에폭사이드 화합물인 반응성 수지계.
- 제2항에 있어서, 폴리에폭사이드 화합물이 지방족, 지환족 또는 방향족 에폭사이드 또는 이들의 혼합물인 반응성 수지계.
- 제2항에 있어서, 폴리에폭사이드 화합물이 노블락 에폭사이드 수지 및/또는 폴리옥시알킬렌 글리콜 폴리글리시딜 에테르인 반응성 수지계.
- 제1항에 있어서, 이소시아네이트 수지는 폴리이소시아네이트 화합물인 반응성 수지계.
- 제5항에 있어서, 폴리이소시아네이트 화합물이 지방족, 지환족 또는 방향족 이소시아네이트 또는 이들의 혼합물인 반응성 수지계.
- 제5항에 있어서, 폴리이소시아네이트 화합물이 4,4'-와, 2,4'-디페닐메탄 디이소시아네이트의 이성체 혼합물, 폴리올-개질 폴리이소시아네이트 또는 고급 폴리이소시아네이트와 액체 폴리이소시아네이트의 혼합물 또는 카보디이미드-폴리이소시아네이트와 액체 폴리이시소시아네이트의 혼합물인 반응성 수지계.
- 제1항에 있어서, 식(Ⅰ)의 R'이 -(CH2)n-이고 n이 2 내지 20인 수의 반응성 수지계.
- 제8항에 있어서, 식(Ⅰ)이 n인 3 내지 6인 수인 반응성 수지계.
- 제1항에 있어서, 식(Ⅰ)의 R2와 R3가 서로 독립적으로 C1-C5알킬인 반응성 수지계.
- 제10항에 있어서, 식(Ⅰ)의 R2와 R3가 서로 독립적으로 메틸 또는 에틸인 반응성 수지계.
- 제10항에 있어서, R1이 에틸렌 또는 프로필렌이고 R2와 R3가 동일하여 에틸, 프로필, 또는 부틸인 반응성 수지계.
- 제1항에 있어서, 식(Ⅰ)의 반응촉진제가 반응수지계에 비첨가성형 수지 조성물을 기준하여 0.01-5.0중량%의 양으로 첨가된 반응성 수지계.
- 제1항에 있어서, 충전제가 무기 및/또는 섬유형인 반응성 수지계.
- 제14항에 있어서, 분말실리카, 용융실리카, 알루미나 또는 돌로마이트가 충전제로서 사용되는 반응성 수지계.
- 제1항에 있어서, 산업분야에서 통상적으로 사용되는 염료, 안료, 안정제 및/또는 부착촉진제가 첨가제로서 사용되는 반응성 수지계.
- 제1항의 반응촉진제를 상기 혼합물에 배합함으로서 폴리에폭사이드와 폴리이소시아네이트의 반응성 수지 혼합물을 경화시키는 방법.※참고사항 : 최초출원 내용에 의하여 공개하는 것임.
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CH4707/87-6 | 1987-12-02 | ||
| JP?62-311547 | 1987-12-09 | ||
| JP62311547A JP2624974B2 (ja) | 1987-12-09 | 1987-12-09 | 電 線 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| KR890010098A true KR890010098A (ko) | 1989-08-05 |
| KR920001567B1 KR920001567B1 (ko) | 1992-02-18 |
Family
ID=18018549
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| KR1019880016073A KR920001567B1 (ko) | 1987-12-09 | 1988-12-02 | 난연성 수지 조성물과 전선 |
| KR1019880016073A KR890010103A (ko) | 1987-12-09 | 1988-12-02 | 난연성 수지 조성물과 전선 |
Family Applications After (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| KR1019880016073A KR890010103A (ko) | 1987-12-09 | 1988-12-02 | 난연성 수지 조성물과 전선 |
Country Status (4)
| Country | Link |
|---|---|
| US (1) | US4954541A (ko) |
| EP (1) | EP0320159A1 (ko) |
| JP (1) | JP2624974B2 (ko) |
| KR (2) | KR920001567B1 (ko) |
Families Citing this family (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH0694500B2 (ja) * | 1987-10-02 | 1994-11-24 | ポリプラスチックス株式会社 | 難燃性改良成形用熱可塑性ポリエステル樹脂の製造法 |
| US5139885A (en) * | 1987-12-09 | 1992-08-18 | Polyplastics Co., Ltd. | Flame-retardant resin composition and electric wire |
| US5295040A (en) * | 1989-05-05 | 1994-03-15 | Minnesota Mining And Manufacturing Company | High purity aromatic polyesters |
| US4967306A (en) * | 1989-05-05 | 1990-10-30 | Minnesota Mining And Manufacturing Company | High purity aromatic polyesters |
| US5318938A (en) * | 1989-05-05 | 1994-06-07 | Minnesota Mining And Manufacturing Company | Thermographic elements |
| JP2928266B2 (ja) * | 1989-05-08 | 1999-08-03 | ポリプラスチックス株式会社 | ポリエステル樹脂組成物及び成形品 |
| BE1006297A3 (nl) * | 1992-10-26 | 1994-07-12 | Axxis Nv | Kunststofplaat, een werkwijze voor de vervaardiging daarvan en vormdelen die de plaat bevatten. |
| US5480926A (en) * | 1995-04-28 | 1996-01-02 | Eastman Chemical Company | Blends of ultraviolet absorbers and polyesters |
| JP3411774B2 (ja) * | 1997-02-14 | 2003-06-03 | リケンテクノス株式会社 | 導電性樹脂組成物 |
| US7642303B2 (en) * | 2004-10-15 | 2010-01-05 | Shakely Thomas L | Thermoplastic articles for packaging UV sensitive materials, processes for the articles production and use and novel UV absorbers |
Family Cites Families (15)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| BE755318A (fr) * | 1970-06-16 | 1971-02-26 | Celanese Corp | Composition peu ou pas combustible de poly (terephtalate d'alkylene) a mouler |
| JPS4855236A (ko) * | 1971-11-11 | 1973-08-03 | ||
| DE2519583A1 (de) * | 1975-05-02 | 1976-11-18 | Basf Ag | Thermoplastische polybutylenterephthalat-formmassen |
| DE2533097A1 (de) * | 1975-07-24 | 1977-02-24 | Basf Ag | Polybutylenterephthalat-formmassen mit verbesserter bestaendigkeit gegen waerme und sauerstoff |
| JPS56120757A (en) * | 1980-02-29 | 1981-09-22 | Teijin Ltd | Preparation of polyester molded article |
| JPS572353A (en) * | 1980-06-06 | 1982-01-07 | Toray Ind Inc | Polyester resin composition |
| JPS57137348A (en) * | 1981-02-20 | 1982-08-24 | Teijin Ltd | Flame-retardant polyester resin molded article |
| NL8201867A (nl) * | 1981-05-07 | 1982-12-01 | Dynamit Nobel Ag | Vlamwerende polytetramethyleentereftalaat-vormmassa's met verbeterde eigenschappen. |
| JPS57209979A (en) * | 1981-06-19 | 1982-12-23 | Teijin Ltd | Ultraviolet light absorber and method for using same |
| EP0074337B1 (de) * | 1981-09-09 | 1986-03-05 | Ciba-Geigy Ag | Stabilisierte thermoplastische Polyesterformmasse |
| JPS5912952A (ja) * | 1982-07-15 | 1984-01-23 | Teijin Ltd | 新規な紫外線吸収剤を用いる紫外線からの保護 |
| JPS5958050A (ja) * | 1982-09-28 | 1984-04-03 | Teijin Ltd | ポリエステル混合体 |
| US4546126A (en) * | 1983-07-13 | 1985-10-08 | Ciba Geigy Corporation | Flame-retarding, reinforced moulding material based on thermoplastic polyesters and the use thereof |
| JPH0830141B2 (ja) * | 1986-03-31 | 1996-03-27 | 鐘淵化学工業株式会社 | 難燃樹脂組成物 |
| JPH0717822B2 (ja) * | 1986-10-25 | 1995-03-01 | 東洋紡績株式会社 | 熱可塑性ポリエステルブロック共重合体組成物 |
-
1987
- 1987-12-09 JP JP62311547A patent/JP2624974B2/ja not_active Expired - Lifetime
-
1988
- 1988-11-15 US US07/271,323 patent/US4954541A/en not_active Expired - Fee Related
- 1988-11-29 EP EP88311272A patent/EP0320159A1/en not_active Ceased
- 1988-12-02 KR KR1019880016073A patent/KR920001567B1/ko not_active Application Discontinuation
- 1988-12-02 KR KR1019880016073A patent/KR890010103A/ko not_active IP Right Cessation
Also Published As
| Publication number | Publication date |
|---|---|
| KR920001567B1 (ko) | 1992-02-18 |
| JP2624974B2 (ja) | 1997-06-25 |
| JPH01152153A (ja) | 1989-06-14 |
| KR890010103A (ko) | 1989-08-05 |
| US4954541A (en) | 1990-09-04 |
| EP0320159A1 (en) | 1989-06-14 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PA0109 | Patent application |
Patent event code: PA01091R01D Comment text: Patent Application Patent event date: 19881202 |
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| PG1501 | Laying open of application | ||
| PC1203 | Withdrawal of no request for examination | ||
| WITN | Application deemed withdrawn, e.g. because no request for examination was filed or no examination fee was paid |