KR890003815A - 올레핀/co 공중합체 및 이의 제조방법 - Google Patents
올레핀/co 공중합체 및 이의 제조방법 Download PDFInfo
- Publication number
- KR890003815A KR890003815A KR1019880010903A KR880010903A KR890003815A KR 890003815 A KR890003815 A KR 890003815A KR 1019880010903 A KR1019880010903 A KR 1019880010903A KR 880010903 A KR880010903 A KR 880010903A KR 890003815 A KR890003815 A KR 890003815A
- Authority
- KR
- South Korea
- Prior art keywords
- copolymer
- process according
- less
- compound
- catalyst composition
- Prior art date
Links
- 229920001577 copolymer Polymers 0.000 title claims 7
- 150000001336 alkenes Chemical class 0.000 title 1
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 title 1
- 238000002360 preparation method Methods 0.000 title 1
- 239000000203 mixture Substances 0.000 claims 6
- 239000003054 catalyst Substances 0.000 claims 3
- 150000001875 compounds Chemical class 0.000 claims 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims 2
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 claims 2
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims 2
- 239000005977 Ethylene Substances 0.000 claims 2
- KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 claims 2
- QQONPFPTGQHPMA-UHFFFAOYSA-N Propene Chemical compound CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 claims 2
- 229910002091 carbon monoxide Inorganic materials 0.000 claims 2
- 239000000178 monomer Substances 0.000 claims 2
- 150000002941 palladium compounds Chemical class 0.000 claims 2
- 125000004204 2-methoxyphenyl group Chemical group [H]C1=C([H])C(*)=C(OC([H])([H])[H])C([H])=C1[H] 0.000 claims 1
- 239000004215 Carbon black (E152) Substances 0.000 claims 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 claims 1
- 239000002253 acid Substances 0.000 claims 1
- 150000001450 anions Chemical class 0.000 claims 1
- 229910052787 antimony Inorganic materials 0.000 claims 1
- WATWJIUSRGPENY-UHFFFAOYSA-N antimony atom Chemical compound [Sb] WATWJIUSRGPENY-UHFFFAOYSA-N 0.000 claims 1
- 229910052785 arsenic Inorganic materials 0.000 claims 1
- RQNWIZPPADIBDY-UHFFFAOYSA-N arsenic atom Chemical compound [As] RQNWIZPPADIBDY-UHFFFAOYSA-N 0.000 claims 1
- 125000004432 carbon atom Chemical group C* 0.000 claims 1
- 239000003085 diluting agent Substances 0.000 claims 1
- 229930195733 hydrocarbon Natural products 0.000 claims 1
- 150000002430 hydrocarbons Chemical class 0.000 claims 1
- 239000007788 liquid Substances 0.000 claims 1
- 229910052757 nitrogen Inorganic materials 0.000 claims 1
- 229910052763 palladium Inorganic materials 0.000 claims 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims 1
- 229910052698 phosphorus Inorganic materials 0.000 claims 1
- 239000011574 phosphorus Substances 0.000 claims 1
- 125000001424 substituent group Chemical group 0.000 claims 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G67/00—Macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing oxygen or oxygen and carbon, not provided for in groups C08G2/00 - C08G65/00
- C08G67/02—Copolymers of carbon monoxide and aliphatic unsaturated compounds
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Polyethers (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
Abstract
내용 없음
Description
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음
Claims (10)
- 하나이상의 올레핀형 불포화 합합물과 일산화탄소의 혼합물을 정상상태에서 공중합체가 거의 또는 전부 불용성인 액체 희석제 존재하에 팔라디움-함유 촉매 조성물의 용액과 연속적으로 접촉시킴으로써 공중합화 시키는 것으로서, 이때 시간당 형성되는 공중합체의 양 및 반응기내 공중합체 양의 비가 언제든지 0.2이하 인것을 특징으로 하는 공중합체의 제조방법.
- 제1항에 있어서, 상기 비가 0.15이하 인것을 특징으로 하는 방법.
- 제2항에 있어서, 상기 비가 0.1이하 인것을 특징으로 하는 방법.
- 제1항 내지 제3항중 어느 하나에 있어서, 촉매 조성물이 하기 a)-c)를 기초로 적용되는 것을 특징으로 하는 방법:a)팔라디움 화합물, b)pKa6이하를 갖는 산의 음이온, 및 c)일반식R1R2M1-R-M2R3R4를 갖는 화합물(이때 M1및 M2는 비소, 안티몬, 인 및 질소로 이루어진 군으로 부터 선택된 같거나 다른 원소이며, R1-R4는 극성기에 의해 임의로 치환된 같거나 다른 탄화수소이고, R은 다리내 탄소원자를 적어도 2개 함유하는 2가 다리기를 나타낸다.)
- 제5항에 있어서, 성분 c)가 팔라디움 화합물 1몰당 0.75-1.5몰의 양으로 존재하는 촉매 조성물이 적용되는 것을 특징으로 하는 방법.
- 제4항에 있어서, 성분c)내 존재하는 R1-R4기중 적어도 하나가 극성 치환체 적어도 하나, 바람직하게는 오르쏘-알콕시기를 적어도 하나 함유하는 페닐기인 촉매 조성물이 적용되는 것을 특징으로 하는 방법.
- 제6항에 있어서, 성분 c)내 존재하는 R1-R4기가 2-메톡시 페닐기인 촉매 조성물이 적용되는 것을 특징으로 하는 방법.
- 제1항 내지 제7항중 어느 하나에 있어서, 에틸렌 또는 프로펜과 에틸렌의 혼합물이 올레핀형 불포화화합물로서 적용되는 것을 특징으로 하는 방법.
- 하기 a)-c)를 특징으로 하는 하나이상의 올레핀형 불포화 화합물과 일산화탄소의 신규 공중합체:a)선형 구조를 갖고, b)일반식-(CO)-A′-을 갖는 단위로 구성되며(이때A′는 적용된 단량체 A로부터 유래하는 단량체 단위를 나타낸다), c)0.3g/ml이상의 벌크밀도(bulk density)를 갖는다.
- 제9항에 있어서, 벌크밀도가 적어도0.5g/ml인 신규 공중합체.※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| NL8702031 | 1987-08-28 | ||
| NL8702031 | 1987-08-28 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| KR890003815A true KR890003815A (ko) | 1989-04-18 |
| KR0134623B1 KR0134623B1 (ko) | 1998-04-20 |
Family
ID=19850521
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| KR1019880010903A KR0134623B1 (ko) | 1987-08-28 | 1988-08-26 | 올레핀/co 공중합체 및 이의 제조방법 |
Country Status (15)
| Country | Link |
|---|---|
| US (1) | US4914183A (ko) |
| EP (1) | EP0305011B1 (ko) |
| JP (1) | JP2625517B2 (ko) |
| KR (1) | KR0134623B1 (ko) |
| CN (1) | CN1019305B (ko) |
| AT (1) | ATE132516T1 (ko) |
| AU (1) | AU612173B2 (ko) |
| BR (1) | BR8804293A (ko) |
| CA (1) | CA1315460C (ko) |
| DE (1) | DE3854852T2 (ko) |
| DK (1) | DK475888A (ko) |
| ES (1) | ES2081803T3 (ko) |
| GR (1) | GR3019510T3 (ko) |
| NO (1) | NO171793C (ko) |
| ZA (1) | ZA886361B (ko) |
Families Citing this family (26)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5077385A (en) * | 1987-12-04 | 1991-12-31 | Shell Oil Company | Melt processed polyketone-based barrier polymer materials |
| CA1338576C (en) * | 1988-02-10 | 1996-09-03 | Maarten Marinus Geuze | Polyketone polymer preparation |
| US4965341A (en) * | 1988-06-08 | 1990-10-23 | Shell Oil Company | Polymerization of co/olefin with catalyst comprising sulfur bidentate ligand |
| US5001221A (en) * | 1988-09-19 | 1991-03-19 | Shell Oil Company | Polymerization of carbon monoxide/olefin with catalyst/diluent recycle |
| US5010171A (en) * | 1988-09-22 | 1991-04-23 | Shell Oil Company | Carbon monoxide/olefin polymerization with catalyst comprising p. bidentate ligand having non-hydrocarbyl substituent |
| CN1025039C (zh) * | 1989-04-19 | 1994-06-15 | 国际壳牌研究有限公司 | 制备一氧化碳与烯烃的共聚物的方法 |
| US5021547A (en) * | 1989-08-07 | 1991-06-04 | Shell Oil Company | Continuous polymerization of Co/olefin in plurality of reactors in series |
| US5115094A (en) * | 1990-01-30 | 1992-05-19 | Shell Oil Company | Polymerization of co/olefin with molar ratio of non hydrohalogenic acid to palladium compound |
| US5122591A (en) * | 1990-03-22 | 1992-06-16 | Shell Oil Company | Polymerization of co/olefin with increased catalyst composition concentration during polymerization start up |
| NL9000812A (nl) * | 1990-04-06 | 1991-11-01 | Shell Int Research | Bereiding van polymeren. |
| US5516739A (en) * | 1990-04-20 | 1996-05-14 | The University Of North Carolina At Chapel Hill | Late transition metal catalysts for the co- and terpolymerization of olefin and alkyne monomers with carbon monoxide |
| US5162493A (en) * | 1990-06-22 | 1992-11-10 | Shell Oil Company | Polymerization of co/olefin/functionally substituted olefin with tetra alkyl diphosphine |
| US5227464A (en) * | 1991-03-21 | 1993-07-13 | Shell Oil Company | Gas phase polymerization of co/olefin with particular catalyst support |
| US5247064A (en) * | 1991-08-06 | 1993-09-21 | Shell Oil Company | Polymerization of co/olefin with p bidentate ligand |
| US5567801A (en) * | 1992-06-15 | 1996-10-22 | Akzo Nobel Nv | Gas phase process for forming polyketones |
| EP0605062B1 (en) * | 1992-12-31 | 1999-07-14 | Shell Internationale Researchmaatschappij B.V. | Preparation of co-polymers of carbon monoxide and ethylenically unsaturated compounds |
| US5352766A (en) * | 1992-12-31 | 1994-10-04 | Shell Oil Company | Preparation of copolymers |
| ZA953387B (en) * | 1994-04-29 | 1995-11-29 | Shell Int Research | Catalyst system and process for the preparation of copolymers of carbon monoxide and olefinically unsaturated compounds |
| US5561216A (en) * | 1994-07-01 | 1996-10-01 | University Of North Carolina At Chapel Hill | Late transition metal catalysts for the CO- and terpolymerization of olefin and alkyne monomers with carbon monoxide |
| GB9712086D0 (en) * | 1997-06-10 | 1997-08-13 | Bp Chem Int Ltd | Process for preparing polyketones |
| US6852662B2 (en) | 1998-07-02 | 2005-02-08 | Basf Aktiengesellschaft | Catalyst systems based on transition metal complexes for carbon monoxide copolymerization in an aqueous medium |
| DE19829519A1 (de) | 1998-07-02 | 2000-01-05 | Basf Ag | Wasserlösliche Übergangsmetallkomplexe |
| DE19933383A1 (de) | 1999-07-21 | 2001-01-25 | Basf Ag | Verfahren zur Herstellung von Olefin/Kohlenmonoxid-Copolymeren |
| DE10125138A1 (de) | 2001-05-22 | 2002-12-05 | Basf Ag | Verfahren zur Herstellung von Copolymerisaten aus Kohlenmonoxid und einer olefinisch ungesättigten Verbindung in wässrigem Medium |
| WO2008032679A1 (en) | 2006-09-11 | 2008-03-20 | Asahi Kasei Kabushiki Kaisha | Polymeric electrolyte, method for production thereof, and electrochemical element |
| CA2620852A1 (en) * | 2007-02-28 | 2008-08-28 | Rohm And Haas Company | A porous linear polymer composition and method of making same |
Family Cites Families (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2495286A (en) * | 1949-06-08 | 1950-01-24 | Du Pont | Interpolymers of carbon monoxide and method for preparing the same |
| GB1081304A (en) * | 1965-03-23 | 1967-08-31 | Ici Ltd | Improvements in or relating to chemical compounds |
| US3694412A (en) * | 1971-03-04 | 1972-09-26 | Shell Oil Co | Process for preparing interpolymers of carbon monoxide in the presence of aryl phosphine-palladium halide complex |
| EP0121965B1 (en) * | 1983-04-06 | 1989-12-27 | Shell Internationale Researchmaatschappij B.V. | Process for the preparation of polyketones |
| NL8403035A (nl) * | 1984-10-05 | 1986-05-01 | Shell Int Research | Werkwijze ter bereiding van polyketonen. |
| IN167917B (ko) * | 1985-11-14 | 1991-01-05 | Shell Int Research | |
| CA1271291A (en) * | 1985-11-26 | 1990-07-03 | Johannes Adrianus Maria Van Broekhoven | Removal of catalyst remnants from ethene/co copolymers |
| IE60363B1 (en) * | 1986-05-27 | 1994-07-13 | Shell Int Research | Process for the preparation of polymers |
| IN171627B (ko) * | 1986-08-26 | 1992-11-28 | Shell Int Research | |
| US4831114A (en) * | 1986-10-01 | 1989-05-16 | Shell Oil Company | Polymerization of carbon monoxide and olefin with acid catalyst |
| NL8701799A (nl) * | 1987-07-30 | 1989-02-16 | Shell Int Research | Bereiding van polymeren. |
-
1988
- 1988-08-18 AU AU21165/88A patent/AU612173B2/en not_active Ceased
- 1988-08-22 CA CA000575370A patent/CA1315460C/en not_active Expired - Fee Related
- 1988-08-23 US US07/235,265 patent/US4914183A/en not_active Expired - Lifetime
- 1988-08-24 ES ES88201802T patent/ES2081803T3/es not_active Expired - Lifetime
- 1988-08-24 DE DE3854852T patent/DE3854852T2/de not_active Expired - Fee Related
- 1988-08-24 EP EP88201802A patent/EP0305011B1/en not_active Expired - Lifetime
- 1988-08-24 AT AT88201802T patent/ATE132516T1/de not_active IP Right Cessation
- 1988-08-24 BR BR8804293A patent/BR8804293A/pt not_active IP Right Cessation
- 1988-08-24 CN CN88106211A patent/CN1019305B/zh not_active Expired
- 1988-08-24 JP JP63210406A patent/JP2625517B2/ja not_active Expired - Lifetime
- 1988-08-25 DK DK475888A patent/DK475888A/da not_active Application Discontinuation
- 1988-08-26 NO NO883823A patent/NO171793C/no unknown
- 1988-08-26 ZA ZA886361A patent/ZA886361B/xx unknown
- 1988-08-26 KR KR1019880010903A patent/KR0134623B1/ko not_active IP Right Cessation
-
1996
- 1996-04-02 GR GR960400898T patent/GR3019510T3/el unknown
Also Published As
| Publication number | Publication date |
|---|---|
| KR0134623B1 (ko) | 1998-04-20 |
| BR8804293A (pt) | 1989-03-21 |
| NO171793C (no) | 1993-05-05 |
| JPH0192222A (ja) | 1989-04-11 |
| EP0305011A2 (en) | 1989-03-01 |
| DK475888A (da) | 1989-03-01 |
| US4914183A (en) | 1990-04-03 |
| EP0305011A3 (en) | 1989-05-10 |
| CN1031542A (zh) | 1989-03-08 |
| CN1019305B (zh) | 1992-12-02 |
| NO171793B (no) | 1993-01-25 |
| ZA886361B (en) | 1989-04-26 |
| DK475888D0 (da) | 1988-08-25 |
| AU2116588A (en) | 1989-03-02 |
| GR3019510T3 (en) | 1996-07-31 |
| DE3854852D1 (de) | 1996-02-15 |
| CA1315460C (en) | 1993-03-30 |
| ES2081803T3 (es) | 1996-03-16 |
| DE3854852T2 (de) | 1996-07-04 |
| AU612173B2 (en) | 1991-07-04 |
| ATE132516T1 (de) | 1996-01-15 |
| NO883823D0 (no) | 1988-08-26 |
| EP0305011B1 (en) | 1996-01-03 |
| NO883823L (no) | 1989-03-01 |
| JP2625517B2 (ja) | 1997-07-02 |
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