KR890001758B1 - 양이온 교환수지의 제조방법 - Google Patents
양이온 교환수지의 제조방법 Download PDFInfo
- Publication number
- KR890001758B1 KR890001758B1 KR8203757A KR820003757A KR890001758B1 KR 890001758 B1 KR890001758 B1 KR 890001758B1 KR 8203757 A KR8203757 A KR 8203757A KR 820003757 A KR820003757 A KR 820003757A KR 890001758 B1 KR890001758 B1 KR 890001758B1
- Authority
- KR
- South Korea
- Prior art keywords
- cation exchange
- styrene
- exchange resin
- sulfonation reaction
- copolymer particles
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J39/00—Cation exchange; Use of material as cation exchangers; Treatment of material for improving the cation exchange properties
- B01J39/08—Use of material as cation exchangers; Treatment of material for improving the cation exchange properties
- B01J39/16—Organic material
- B01J39/18—Macromolecular compounds
- B01J39/20—Macromolecular compounds obtained by reactions only involving unsaturated carbon-to-carbon bonds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F8/00—Chemical modification by after-treatment
- C08F8/34—Introducing sulfur atoms or sulfur-containing groups
- C08F8/36—Sulfonation; Sulfation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
- C08J5/20—Manufacture of shaped structures of ion-exchange resins
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2800/00—Copolymer characterised by the proportions of the comonomers expressed
- C08F2800/20—Copolymer characterised by the proportions of the comonomers expressed as weight or mass percentages
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- General Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Materials Engineering (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Abstract
Description
Claims (4)
- (1)스티렌, (2)스티렌 몰당 0.8내지 55몰%의 디비닐벤젠 및 (3) 스티렌 몰당 2내지 20몰%의 아크릴산, 메타크릴산, 및 이들의 저급 알킬에스테르의 그룹중에서 선택된 적어도 하나의 화합물을 포함하는 단량체 혼합물을 현탁중합시키고, 생성된 공중합체 입자를 실질적으로 팽윤제의 부재하에서 설폰화시킴을 특징으로 하여, 양이온 교환수지를 제조하는 방법.
- 제1항에 있어서, 공중합체 입자가 0.1내지 1.0㎜의 입자직경을 갖는 방법.
- 제1항에 있어서, 설폰화반응을 95내지 100% 황산을 사용하여 수행하는 방법.
- 제1항에 있어서, 설폰화반응온도가 50내지 150℃인 방법.
Applications Claiming Priority (5)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP56131356A JPS6050361B2 (ja) | 1981-08-21 | 1981-08-21 | 陽イオン交換樹脂の製造法 |
JP13156 | 1981-08-21 | ||
JP131356/81 | 1981-08-21 | ||
JP57070652A JPS58187405A (ja) | 1982-04-27 | 1982-04-27 | 強酸性陽イオン交換樹脂の製造法 |
JP70652 | 1982-04-27 |
Publications (2)
Publication Number | Publication Date |
---|---|
KR840001185A KR840001185A (ko) | 1984-03-28 |
KR890001758B1 true KR890001758B1 (ko) | 1989-05-19 |
Family
ID=26411786
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
KR8203757A Expired KR890001758B1 (ko) | 1981-08-21 | 1982-08-21 | 양이온 교환수지의 제조방법 |
Country Status (5)
Country | Link |
---|---|
KR (1) | KR890001758B1 (ko) |
DE (1) | DE3230559A1 (ko) |
FR (1) | FR2511614B1 (ko) |
GB (1) | GB2105346B (ko) |
NL (1) | NL8203274A (ko) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
KR101294631B1 (ko) * | 2011-04-28 | 2013-08-09 | 충남대학교산학협력단 | 팽윤성과 흡착성이 우수한 인듐회수용 이온교환수지 및 이를 제조하는 방법 |
KR101294632B1 (ko) * | 2011-04-28 | 2013-08-09 | 충남대학교산학협력단 | 팽윤성이 우수한 코발트 이온 회수용 이온교환수지 및 이를 제조하는 방법 |
Families Citing this family (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2587708B1 (fr) * | 1985-09-20 | 1988-03-18 | Ceca Sa | Copolymeres d'acides styrene sulfoniques a stabilite thermique amelioree. application, notamment aux fluides forage |
CA2061250A1 (en) * | 1991-02-20 | 1992-08-21 | Nobuyuki Higosaki | Process of removing suspended metal corrosion products insoluble or sparingly soluble in water and condensate treating equipment |
US6784213B2 (en) * | 2001-06-22 | 2004-08-31 | Rohm And Haas Company | Method for preparation of strong acid cation exchange resins |
DE10353534A1 (de) * | 2003-11-14 | 2005-06-16 | Bayer Chemicals Ag | Chelataustauscher |
DE102007060790A1 (de) | 2007-12-18 | 2009-06-25 | Lanxess Deutschland Gmbh | Verfahren zur Herstellung von Kationenaustauschern |
CN108623733A (zh) * | 2017-03-24 | 2018-10-09 | 鹤壁市山城区牟山大道大唐离子交换树脂应用研究所 | 含有第三单体的树脂中间体 |
Family Cites Families (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR1068153A (fr) * | 1951-11-28 | 1954-06-23 | Rohm & Haas | Perfectionnements relatifs à une résine insoluble échangeuse de cations et à sonprocédé de préparation |
DE1155603B (de) * | 1961-10-26 | 1963-10-10 | Wolfen Filmfab Veb | Verfahren zur Herstellung von sulfonsaeuregruppenhaltigen Kationenaustauscherharzen |
-
1982
- 1982-08-17 DE DE19823230559 patent/DE3230559A1/de not_active Withdrawn
- 1982-08-17 GB GB08223643A patent/GB2105346B/en not_active Expired
- 1982-08-20 FR FR8214418A patent/FR2511614B1/fr not_active Expired
- 1982-08-20 NL NL8203274A patent/NL8203274A/nl not_active Application Discontinuation
- 1982-08-21 KR KR8203757A patent/KR890001758B1/ko not_active Expired
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
KR101294631B1 (ko) * | 2011-04-28 | 2013-08-09 | 충남대학교산학협력단 | 팽윤성과 흡착성이 우수한 인듐회수용 이온교환수지 및 이를 제조하는 방법 |
KR101294632B1 (ko) * | 2011-04-28 | 2013-08-09 | 충남대학교산학협력단 | 팽윤성이 우수한 코발트 이온 회수용 이온교환수지 및 이를 제조하는 방법 |
Also Published As
Publication number | Publication date |
---|---|
DE3230559A1 (de) | 1983-03-03 |
KR840001185A (ko) | 1984-03-28 |
FR2511614A1 (fr) | 1983-02-25 |
GB2105346B (en) | 1985-01-03 |
FR2511614B1 (fr) | 1987-05-07 |
GB2105346A (en) | 1983-03-23 |
NL8203274A (nl) | 1983-03-16 |
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