[go: up one dir, main page]

KR880011066A - (페닐에테닐) 페닐프로피온산과 그 에스테르 및 (벤조일페닐) 프로피온산 또는 그 에스테르의 제조방법 - Google Patents

(페닐에테닐) 페닐프로피온산과 그 에스테르 및 (벤조일페닐) 프로피온산 또는 그 에스테르의 제조방법 Download PDF

Info

Publication number
KR880011066A
KR880011066A KR1019880002452A KR880002452A KR880011066A KR 880011066 A KR880011066 A KR 880011066A KR 1019880002452 A KR1019880002452 A KR 1019880002452A KR 880002452 A KR880002452 A KR 880002452A KR 880011066 A KR880011066 A KR 880011066A
Authority
KR
South Korea
Prior art keywords
propionic acid
phenylethenyl
residue
phenyl
alkyl ester
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
KR1019880002452A
Other languages
English (en)
Other versions
KR950014219B1 (ko
Inventor
이소오 시미즈
야스오 마쓰무라
유다까 아라이
Original Assignee
가다야마 유다까
니혼세끼유 가가꾸 가부시끼가이샤
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 가다야마 유다까, 니혼세끼유 가가꾸 가부시끼가이샤 filed Critical 가다야마 유다까
Publication of KR880011066A publication Critical patent/KR880011066A/ko
Application granted granted Critical
Publication of KR950014219B1 publication Critical patent/KR950014219B1/ko
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C57/00—Unsaturated compounds having carboxyl groups bound to acyclic carbon atoms
    • C07C57/46—Unsaturated compounds having carboxyl groups bound to acyclic carbon atoms containing six-membered aromatic rings and other rings, e.g. cyclohexylphenylacetic acid
    • C07C57/48—Unsaturated compounds having carboxyl groups bound to acyclic carbon atoms containing six-membered aromatic rings and other rings, e.g. cyclohexylphenylacetic acid having unsaturation outside the aromatic rings
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C1/00—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
    • C07C1/20—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from organic compounds containing only oxygen atoms as heteroatoms
    • C07C1/24—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from organic compounds containing only oxygen atoms as heteroatoms by elimination of water
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C1/00—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
    • C07C1/32—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from compounds containing hetero-atoms other than or in addition to oxygen or halogen
    • C07C1/325—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from compounds containing hetero-atoms other than or in addition to oxygen or halogen the hetero-atom being a metal atom
    • C07C1/326—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from compounds containing hetero-atoms other than or in addition to oxygen or halogen the hetero-atom being a metal atom the hetero-atom being a magnesium atom
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C15/00—Cyclic hydrocarbons containing only six-membered aromatic rings as cyclic parts
    • C07C15/40—Cyclic hydrocarbons containing only six-membered aromatic rings as cyclic parts substituted by unsaturated carbon radicals
    • C07C15/50—Cyclic hydrocarbons containing only six-membered aromatic rings as cyclic parts substituted by unsaturated carbon radicals polycyclic non-condensed
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
    • C07C5/32—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with formation of free hydrogen
    • C07C5/327—Formation of non-aromatic carbon-to-carbon double bonds only
    • C07C5/333—Catalytic processes
    • C07C5/3332—Catalytic processes with metal oxides or metal sulfides
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/10—Preparation of carboxylic acids or their salts, halides or anhydrides by reaction with carbon monoxide
    • C07C51/14—Preparation of carboxylic acids or their salts, halides or anhydrides by reaction with carbon monoxide on a carbon-to-carbon unsaturated bond in organic compounds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C57/00—Unsaturated compounds having carboxyl groups bound to acyclic carbon atoms
    • C07C57/30—Unsaturated compounds having carboxyl groups bound to acyclic carbon atoms containing six-membered aromatic rings
    • C07C57/42—Unsaturated compounds having carboxyl groups bound to acyclic carbon atoms containing six-membered aromatic rings having unsaturation outside the rings
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C69/00—Esters of carboxylic acids; Esters of carbonic or haloformic acids
    • C07C69/612—Esters of carboxylic acids having a carboxyl group bound to an acyclic carbon atom and having a six-membered aromatic ring in the acid moiety
    • C07C69/618—Esters of carboxylic acids having a carboxyl group bound to an acyclic carbon atom and having a six-membered aromatic ring in the acid moiety having unsaturation outside the six-membered aromatic ring
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the iron group metals or copper
    • C07C2523/74—Iron group metals
    • C07C2523/745—Iron
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

내용 없음

Description

(페닐에테닐) 페닐프로피온산과 그 에스테르 및 (벤조일페닐) 프로피온산 또는 그 에스테르의 제조방법
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (8)

  1. 하기 구조식으로 표시되는 ??-(3-1-페닐에테닐)페닐)프로피온산 및 그 알킬 에스테르
    (여기서, R은 H 또는 탄소수 1 내지 4개의 저급알킬기).
  2. 제1항에 있어서, 상기 저급알킬기가 메틸기인 것을 특징으로 하는 알킬에스테르.
  3. 상기식 (Ⅱ)로 표시되는 ??-(3-(1-페닐에테닐)페닐-프로피온산 또는 그 알킬에스테르를 산화시키는 것을 특징으로 하는 식 (I)의 ??-(3-(1-벤조닐페닐)프로피온산 또는 그 알킬에스테르의 제조방법.
    (여기서, R은 H 또는 탄소 1 내지 4개의 저급알킬기이다).
    (여기서, R은 H 또는 탄소수 1 내지 4개의 저급알킬기이다).
  4. 제3항에 있어서, 상기 산화가 산화촉매의 존재하의 분자상 산소에 의한 산화 또는 산화제에 의한 산화인 것을 특징으로 하는 제조방법.
  5. 제3항에 있어서, ??-(3-(1-페닐에테닐)페닐)프로피온산 또는 그 알킬에스테르가 1- (3-비닐페닐)-1-페닐에틸렌을 함유한 잔류분을 귀금속 착체 촉매의 존재하에 일산화탄소와 물 또는 저급알코올을 반응시킴으로써 얻어지는 것을 특징으로 하는 ??-(3-(1-페닐에테닐)페닐)프로피온산 또는 그 알킬에스테르의 제조방법.
  6. 제5항에 있어서, 상기 1-(3-비닐페닐)-1-페닐에틸렌을 함유한 잔류분이 1-(3-에틸페닐)-1-페닐에탄을 함유한 잔류분을 탈수소함으로써 제조되는 것을 특징으로 하는 제조방법.
  7. 제6항에 있어서, 상기 1-(3-에틸페닐)-1-페닐에탄을 함유한 잔류분이 벤젠을 에틸렌으로 알킬화촉매의 의하여 알킬화할 때에 비점 285℃ 내지 290℃ (상압환산)의 범위에 있는 잔류분으로서 회수되는 것을 특징으로 하는 제조방법.
  8. 제8항에 있어서, 상기 알킬화촉매가 루이스산 또는 프로톤산인 것을 특징으로 하는 제조방법.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019880002452A 1987-03-12 1988-03-09 (페닐에테닐)페닐프로피온산과 그 에스테르 및 (벤조일페닐)프로피온산 또는 그 에스테르의 제조방법 Expired - Fee Related KR950014219B1 (ko)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP62-57099 1987-03-12
JP62057099A JPH07100679B2 (ja) 1987-03-12 1987-03-12 α−（３−ベンゾイルフエニル）プロピオン酸またはそのエステルの製造方法

Publications (2)

Publication Number Publication Date
KR880011066A true KR880011066A (ko) 1988-10-26
KR950014219B1 KR950014219B1 (ko) 1995-11-23

Family

ID=13046057

Family Applications (3)

Application Number Title Priority Date Filing Date
KR1019880002348A Expired - Fee Related KR930006077B1 (ko) 1987-03-12 1988-03-07 1-(3-비닐페닐)-1-페닐에틸렌류 및 그의 제조방법
KR1019880002452A Expired - Fee Related KR950014219B1 (ko) 1987-03-12 1988-03-09 (페닐에테닐)페닐프로피온산과 그 에스테르 및 (벤조일페닐)프로피온산 또는 그 에스테르의 제조방법
KR1019880701415A Expired - Fee Related KR950014220B1 (ko) 1987-03-12 1988-03-12 디올레핀의 선택적 히드로에스테르화 방법

Family Applications Before (1)

Application Number Title Priority Date Filing Date
KR1019880002348A Expired - Fee Related KR930006077B1 (ko) 1987-03-12 1988-03-07 1-(3-비닐페닐)-1-페닐에틸렌류 및 그의 제조방법

Family Applications After (1)

Application Number Title Priority Date Filing Date
KR1019880701415A Expired - Fee Related KR950014220B1 (ko) 1987-03-12 1988-03-12 디올레핀의 선택적 히드로에스테르화 방법

Country Status (7)

Country Link
US (3) US4937375A (ko)
EP (3) EP0282063B1 (ko)
JP (1) JPH07100679B2 (ko)
KR (3) KR930006077B1 (ko)
CA (1) CA1299189C (ko)
DE (3) DE3871409D1 (ko)
WO (1) WO1988007034A1 (ko)

Families Citing this family (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH07100678B2 (ja) * 1987-03-12 1995-11-01 日本石油化学株式会社 α−（３−ベンゾイルフエニル）プロピオン酸の製造方法
JPS63233949A (ja) * 1987-03-23 1988-09-29 Nippon Petrochem Co Ltd ジオレフインの選択的ヒドロエステル化方法
US5237116A (en) * 1989-10-31 1993-08-17 Shell Oil Company Catalyst and process for coupling organometallic reagents with aryl or vinylic halides
US5059572A (en) * 1989-10-31 1991-10-22 Shell Oil Company Catalyst and process for coupling organometallic reagents with aryl or vinylic halides
CN101500984A (zh) * 2006-07-27 2009-08-05 于崇曦 具有快速皮肤穿透速度的带正电荷的水溶性酮洛芬及相关化合物的前药
WO2008048106A1 (en) * 2006-10-17 2008-04-24 Ge Healthcare As Method for the production of alpha-keto acids and esters thereof

Family Cites Families (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4257973A (en) * 1971-11-05 1981-03-24 E. I. Du Pont De Nemours And Company Process of making acids or esters from unsaturated compounds
DE2646792C2 (de) * 1975-10-23 1985-05-09 Mitsubishi Petrochemical Co., Ltd., Tokio/Tokyo Verfahren zur Herstellung einer α-(arylsubstituierten)-Propionsäure und/oder eines Esters derselben
US4172087A (en) * 1978-02-13 1979-10-23 Texaco Development Corporation Process for preparing unsaturated aliphatic esters from aliphatic dienes
IT8123391A0 (it) * 1981-08-08 1981-08-08 Montedison Spa Processo per la preparazione di esteri di acidi arilpropionici otticamente attivi.
CA1194284A (en) * 1982-09-16 1985-10-01 Atsushi Sato Electrical insulating oil and oil-filled electrical appliances
CA1211761A (en) * 1982-12-25 1986-09-23 Atsushi Sato Electrical insulating substance and oil-filled electrical appliances containing the same
JPS59216849A (ja) * 1983-05-24 1984-12-06 Nissan Chem Ind Ltd α−フエニルプロピオン酸エステルの製造方法
JPS60189108A (ja) * 1984-03-08 1985-09-26 日本石油化学株式会社 電気絶縁油
US4694100A (en) * 1984-07-14 1987-09-15 Nippon Petrochemicals Company, Ltd. Method for producing α-(p-isobutylphenyl)propionic acid or its alkyl esters
JPS6222732A (ja) * 1985-07-24 1987-01-30 Nippon Petrochem Co Ltd １，１−（３−エチルフエニル）フエニルエチレン
GB8705699D0 (en) * 1987-03-11 1987-04-15 Shell Int Research Carbonylation of olefinically unsaturated compounds
JPH05170745A (ja) * 1991-12-25 1993-07-09 Kanebo Ltd ベンズイミダゾール誘導体、その製造法、それを有効成分とする制吐剤およびその製造用中間体

Also Published As

Publication number Publication date
EP0282063B1 (en) 1991-10-16
EP0282063A1 (en) 1988-09-14
EP0282065B1 (en) 1992-05-27
WO1988007034A1 (en) 1988-09-22
US4908473A (en) 1990-03-13
EP0304495A4 (en) 1989-12-19
EP0304495B1 (en) 1992-05-27
CA1299189C (en) 1992-04-21
EP0282065A2 (en) 1988-09-14
KR950014219B1 (ko) 1995-11-23
DE3865464D1 (de) 1991-11-21
EP0304495A1 (en) 1989-03-01
DE3871461D1 (de) 1992-07-02
JPS63225335A (ja) 1988-09-20
KR880011055A (ko) 1988-10-26
US4822934A (en) 1989-04-18
KR930006077B1 (ko) 1993-07-07
KR890700566A (ko) 1989-04-25
EP0282065A3 (en) 1990-03-28
US4937375A (en) 1990-06-26
JPH07100679B2 (ja) 1995-11-01
KR950014220B1 (ko) 1995-11-23
DE3871409D1 (de) 1992-07-02

Similar Documents

Publication Publication Date Title
FR2060622A5 (en) Pure esters recovery - from a crude esterification mixture
KR860003197A (ko) 알킬 방향족 화합물의 액상 산화반응에 의한 방향족 카르복실산의 연속제조방법
KR860001047A (ko) α-(p-이소부틸페닐)프로피온산 또는 그의 알킬에스테르의 제조방법
KR850008657A (ko) 포름산의 제조방법
KR860004002A (ko) 3-펜테노산의 제조방법
KR840005439A (ko) 푸라논 유도체의 제조방법
KR880011061A (ko) (페닐에테닐) 페닐 프로피온알데히드 및 그것을 사용하는 (벤조일페일) 프로피온산의 제조방법
KR830005092A (ko) 시클로프로판 카르복실산의 새로운 유도체
KR880011066A (ko) (페닐에테닐) 페닐프로피온산과 그 에스테르 및 (벤조일페닐) 프로피온산 또는 그 에스테르의 제조방법
GB792558A (en) Manufacture of organic peroxides
KR830008969A (ko) 퀴논 유도체의 제법
KR880013956A (ko) 포스피닐아미노산 유도체의 제조방법
KR850004568A (ko) 카복실산의 제조방법
KR850002956A (ko) 불화탄소 화합물의 정제법
KR920007975A (ko) d-2-(6-메톡시-2-나프틸)-프로피온산의 제조방법 및 그 중간체
US2960519A (en) Process for the oxidation of paraffin wax whereby a high saponification number product is obtained by use of a silicone
US2821551A (en) Process for production of aromatic carboxylic acids
KR840004053A (ko) 페닐알카노산의 제조방법
US2820046A (en) Oxidation of fatty acids
KR890700568A (ko) 방향족 카복실레이트와 요오드화알킬의 공동생산 방법
KR910006234A (ko) 3-메틸퀴놀린-8-카르복실산의 제조방법
KR840000512A (ko) 벤조트리아졸의 제조방법
GB814360A (en) Improvements in the production of esters of tertiary alcohols with unsaturated acids
KR880002800A (ko) 시클로헥산온 카르복실산류의 제조방법
KR890000391A (ko) 카르복실산혼합물 및 그 제조방법

Legal Events

Date Code Title Description
PA0109 Patent application

St.27 status event code: A-0-1-A10-A12-nap-PA0109

R17-X000 Change to representative recorded

St.27 status event code: A-3-3-R10-R17-oth-X000

PG1501 Laying open of application

St.27 status event code: A-1-1-Q10-Q12-nap-PG1501

A201 Request for examination
PA0201 Request for examination

St.27 status event code: A-1-2-D10-D11-exm-PA0201

G160 Decision to publish patent application
PG1605 Publication of application before grant of patent

St.27 status event code: A-2-2-Q10-Q13-nap-PG1605

E701 Decision to grant or registration of patent right
PE0701 Decision of registration

St.27 status event code: A-1-2-D10-D22-exm-PE0701

GRNT Written decision to grant
PR0701 Registration of establishment

St.27 status event code: A-2-4-F10-F11-exm-PR0701

PR1002 Payment of registration fee

St.27 status event code: A-2-2-U10-U11-oth-PR1002

Fee payment year number: 1

PR1001 Payment of annual fee

St.27 status event code: A-4-4-U10-U11-oth-PR1001

Fee payment year number: 4

FPAY Annual fee payment

Payment date: 19991029

Year of fee payment: 5

PR1001 Payment of annual fee

St.27 status event code: A-4-4-U10-U11-oth-PR1001

Fee payment year number: 5

PN2301 Change of applicant

St.27 status event code: A-5-5-R10-R13-asn-PN2301

St.27 status event code: A-5-5-R10-R11-asn-PN2301

LAPS Lapse due to unpaid annual fee
PC1903 Unpaid annual fee

St.27 status event code: A-4-4-U10-U13-oth-PC1903

Not in force date: 20001124

Payment event data comment text: Termination Category : DEFAULT_OF_REGISTRATION_FEE

PC1903 Unpaid annual fee

St.27 status event code: N-4-6-H10-H13-oth-PC1903

Ip right cessation event data comment text: Termination Category : DEFAULT_OF_REGISTRATION_FEE

Not in force date: 20001124

R18-X000 Changes to party contact information recorded

St.27 status event code: A-5-5-R10-R18-oth-X000

P22-X000 Classification modified

St.27 status event code: A-4-4-P10-P22-nap-X000