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KR880013956A - 포스피닐아미노산 유도체의 제조방법 - Google Patents

포스피닐아미노산 유도체의 제조방법 Download PDF

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KR880013956A
KR880013956A KR1019880006214A KR880006214A KR880013956A KR 880013956 A KR880013956 A KR 880013956A KR 1019880006214 A KR1019880006214 A KR 1019880006214A KR 880006214 A KR880006214 A KR 880006214A KR 880013956 A KR880013956 A KR 880013956A
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group
compound
formula
substituted
alkyl group
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KR1019880006214A
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KR950011771B1 (ko
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히데끼 다까마쯔
히로유끼 무또
후미오 스즈끼
신이찌로 다끼가와
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나까이 다께오
닛산가가꾸고오교오 가부시끼가이샤
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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02—Phosphorus compounds
    • C07F9/28—Phosphorus compounds with one or more P—C bonds
    • C07F9/30—Phosphinic acids [R2P(=O)(OH)]; Thiophosphinic acids ; [R2P(=X1)(X2H) (X1, X2 are each independently O, S or Se)]
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02—Phosphorus compounds
    • C07F9/28—Phosphorus compounds with one or more P—C bonds
    • C07F9/30—Phosphinic acids [R2P(=O)(OH)]; Thiophosphinic acids ; [R2P(=X1)(X2H) (X1, X2 are each independently O, S or Se)]
    • C07F9/301—Acyclic saturated acids which can have further substituents on alkyl
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02—Phosphorus compounds
    • C07F9/28—Phosphorus compounds with one or more P—C bonds
    • C07F9/30—Phosphinic acids [R2P(=O)(OH)]; Thiophosphinic acids ; [R2P(=X1)(X2H) (X1, X2 are each independently O, S or Se)]
    • C07F9/32—Esters thereof
    • C07F9/3205—Esters thereof the acid moiety containing a substituent or a structure which is considered as characteristic
    • C07F9/3211—Esters of acyclic saturated acids which can have further substituents on alkyl

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Biochemistry (AREA)
  • General Health & Medical Sciences (AREA)
  • Molecular Biology (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

내용 없음

Description

포스피닐아미노산 유도체의 제조방법
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (9)

  1. 하기 일반식(Ⅱ)의 화합물 및 또는 하기 일반식(Ⅲ)의 화합물을 주기울표의 Ⅷ족 금속을 함유하는 촉매의 존재하에서 하기 일반식(Ⅳ)의 화합물, 일산화탄소 및 수소와 반응시킴을 특징으로 하는 하기 일반식(Ⅰ)의 포스피닐 아미노산유도체의 제조방법.
    식중, R1은 저급 알키리이고, R2는 수소원자, 저급알킬기, 할로-저급 알킬기 또는 치환 또는 비치환된 페닐기이며, R3는 치환 또는 비치환된 알킬기 또는 치환 또는 비치환된 페닐기 이다.
  2. 제1항에 있어서, R1이 메틸기이며, R2가 수소원자, 메틸기 또는 할로게노에틸기이고, R3가 저급알킬기 또는 페닐기인 방법.
  3. 제1항에 있어서, 반응을 40 내지 350kg/cm2G의 압력하에 수행하는 방법.
  4. 제1항에 있어서, 반응을 40 내지 200℃의 온도에서 수행하는 방법.
  5. 제1항에 있어서,촉매가 코발트 카르보닐 화합물 및/또는 로륨 카르보닐 화합물인 방법.
  6. 하기 일반식(Ⅱ)의 화합물 및/또는 하기 일반식(Ⅲ)의 화합물을 주기율표의 Ⅷ족 금속을 함유하는 촉매의 존하에서 하기 일반식(Ⅳ)의 화합물, 일산화탄소 및 수소와 반응시킨다음, 무기산의 존재하에 반응 용매중에서 촉매를 산화시킴으로써 Ⅷ족 금속율 함유하는 촉매를 반응 용액으로부터 분리하고 이를 양이온 교환수지상에 흡착시킴을 특징으로 하는 하기 일반식(Ⅰ)의 포스피닐아미노산 유도체의 제조방법.
    식중, R1은 저급 알키리이고, R2는 수소원자, 저급알킬기, 할로-저급 알킬기 또는 치환 또는 비치환된 페닐기이며, R3는 치환 또는 비치환된 알킬기 또는 치환 또는 비치환된 페닐기 이다.
  7. 제6항에 있어서, 무기산이 염산 또는 황산인 방법.
  8. 제6항에 있어서, 산화를 산소, 함유 가스, 염소 또는 과산화수소로 이루어진 군으로부터 선택된 산화제로 수행하는 방법.
  9. 제6항에 있어서 Ⅷ족 금속을 함유하는 촉매가 코발트 카르보닐 화합물 및/또는 로듐 카르보닐화합물인 방법.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019880006214A 1987-05-26 1988-05-26 포스피닐아미노산 유도체의 제조 방법 KR950011771B1 (ko)

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
JP62-129498 1987-05-26
JP12949887 1987-05-26
JP63059872A JP2615777B2 (ja) 1987-05-26 1988-03-14 ホスフィニルアミノ酸誘導体の製造方法
JP63-59872 1988-03-14

Publications (2)

Publication Number Publication Date
KR880013956A true KR880013956A (ko) 1988-12-22
KR950011771B1 KR950011771B1 (ko) 1995-10-10

Family

ID=26400948

Family Applications (1)

Application Number Title Priority Date Filing Date
KR1019880006214A KR950011771B1 (ko) 1987-05-26 1988-05-26 포스피닐아미노산 유도체의 제조 방법

Country Status (8)

Country Link
US (1) US4906764A (ko)
EP (1) EP0292918B1 (ko)
JP (1) JP2615777B2 (ko)
KR (1) KR950011771B1 (ko)
CA (1) CA1299580C (ko)
DE (1) DE3868355D1 (ko)
ES (1) ES2033369T3 (ko)
IL (1) IL86475A (ko)

Families Citing this family (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2615777B2 (ja) * 1987-05-26 1997-06-04 日産化学工業株式会社 ホスフィニルアミノ酸誘導体の製造方法
JP2682833B2 (ja) * 1988-03-03 1997-11-26 日産化学工業株式会社 有機燐誘導体及びその製造法
DE3913891A1 (de) * 1988-07-14 1990-10-31 Hoechst Ag Verfahren zur herstellung von n-acyl-phosphinothricindiestern
DE3907439A1 (de) * 1988-07-14 1990-09-13 Hoechst Ag Verfahren zur herstellung von n-acyl-phosphinothricin-p-estern
DE3903446A1 (de) * 1989-02-06 1990-10-18 Hoechst Ag Verfahren zur enzymatischen trennung von 2-amino-4-methylphosphinobuttersaeurederivaten
DE19545641A1 (de) * 1995-12-07 1997-06-12 Hoechst Ag Verfahren zur Wiedergewinnung von bei der Herstellung von N-Acyl-alpha-aminosäurederivaten durch Amidocarbonylierung eingesetzten Cobaltcarbonylkatalysatoren
DE19736125A1 (de) 1997-08-20 1999-02-25 Hoechst Schering Agrevo Gmbh Verfahren zur Herstellung von Glufosinate und phosphorhaltige alpha-Aminonitrile als Zwischenprodukte
CN104059102B (zh) * 2014-06-12 2017-04-12 浙江工业大学 有机碱脱酸法制备高纯草铵膦的方法
CN105315303B (zh) * 2015-05-29 2017-07-04 山东潍坊润丰化工股份有限公司 一种草铵膦的分离纯化方法

Family Cites Families (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS4817259B1 (ko) * 1970-04-04 1973-05-28
DE2717440C2 (de) 1976-05-17 1984-04-05 Hoechst Ag, 6230 Frankfurt Unkrautbekämpfung mit [(3-Amino-3-carboxy)-propyl-1]-methylphosphinsäure-Derivaten
FR2395252A1 (fr) 1977-06-21 1979-01-19 Inst Francais Du Petrole Procede de fabrication de derive n-acyle d'acide amine
JPS58131993A (ja) 1982-01-29 1983-08-06 Meiji Seika Kaisha Ltd ビニルホスフィン酸誘導体の製造法
US4496756A (en) 1983-09-01 1985-01-29 Ethyl Corporation Process for preparing amino acid esters
DE3542645A1 (de) * 1985-12-03 1987-06-04 Hoechst Ag Verfahren zur herstellung von l-homoalanin-4-yl(methyl)-phosphinsaeure sowie ihrer alkylester
JP2615777B2 (ja) * 1987-05-26 1997-06-04 日産化学工業株式会社 ホスフィニルアミノ酸誘導体の製造方法

Also Published As

Publication number Publication date
IL86475A0 (en) 1988-11-15
ES2033369T3 (es) 1993-03-16
US4906764A (en) 1990-03-06
DE3868355D1 (de) 1992-03-26
JP2615777B2 (ja) 1997-06-04
AU1656788A (en) 1988-12-01
EP0292918A1 (en) 1988-11-30
CA1299580C (en) 1992-04-28
AU596307B2 (en) 1990-04-26
IL86475A (en) 1992-12-01
EP0292918B1 (en) 1992-02-12
JPS6463585A (en) 1989-03-09
KR950011771B1 (ko) 1995-10-10

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