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KR870011055A - 내알칼리성 유리섬유의 제조방법 - Google Patents

내알칼리성 유리섬유의 제조방법 Download PDF

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Publication number
KR870011055A
KR870011055A KR870005253A KR870005253A KR870011055A KR 870011055 A KR870011055 A KR 870011055A KR 870005253 A KR870005253 A KR 870005253A KR 870005253 A KR870005253 A KR 870005253A KR 870011055 A KR870011055 A KR 870011055A
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KR
South Korea
Prior art keywords
oxide
weight percent
glass
small amount
weight
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Granted
Application number
KR870005253A
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English (en)
Inventor
챈드라칸트 트리베디 니킬
더글라스 맥켄지 존
Original Assignee
엘렌 제이, 스피겔
화이자 인코포레이티드
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Publication of KR870011055A publication Critical patent/KR870011055A/ko
Granted legal-status Critical Current

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C13/00—Fibre or filament compositions
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C13/00—Fibre or filament compositions
    • C03C13/001—Alkali-resistant fibres
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03B—MANUFACTURE, SHAPING, OR SUPPLEMENTARY PROCESSES
    • C03B37/00—Manufacture or treatment of flakes, fibres, or filaments from softened glass, minerals, or slags
    • C03B37/01—Manufacture of glass fibres or filaments
    • C03B37/02—Manufacture of glass fibres or filaments by drawing or extruding, e.g. direct drawing of molten glass from nozzles; Cooling fins therefor
    • C03B37/022—Manufacture of glass fibres or filaments by drawing or extruding, e.g. direct drawing of molten glass from nozzles; Cooling fins therefor from molten glass in which the resultant product consists of different sorts of glass or is characterised by shape, e.g. hollow fibres, undulated fibres, fibres presenting a rough surface
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03B—MANUFACTURE, SHAPING, OR SUPPLEMENTARY PROCESSES
    • C03B37/00—Manufacture or treatment of flakes, fibres, or filaments from softened glass, minerals, or slags
    • C03B37/075—Manufacture of non-optical fibres or filaments consisting of different sorts of glass or characterised by shape, e.g. undulated fibres
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C13/00—Fibre or filament compositions
    • C03C13/001—Alkali-resistant fibres
    • C03C13/002—Alkali-resistant fibres containing zirconium
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C3/00—Glass compositions
    • C03C3/04—Glass compositions containing silica
    • C03C3/076—Glass compositions containing silica with 40% to 90% silica, by weight
    • C03C3/083—Glass compositions containing silica with 40% to 90% silica, by weight containing aluminium oxide or an iron compound
    • C03C3/085—Glass compositions containing silica with 40% to 90% silica, by weight containing aluminium oxide or an iron compound containing an oxide of a divalent metal
    • C03C3/087—Glass compositions containing silica with 40% to 90% silica, by weight containing aluminium oxide or an iron compound containing an oxide of a divalent metal containing calcium oxide, e.g. common sheet or container glass

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Geochemistry & Mineralogy (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Manufacturing & Machinery (AREA)
  • Glass Compositions (AREA)
  • Manufacture, Treatment Of Glass Fibers (AREA)

Abstract

내용 없음

Description

내알칼리성 유리섬유의 제조방법
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (11)

  1. 규산마그네슘 및 CaO-함유 화합물 또는 규산칼슘 및 MgO-함유 화합물을 포함하는 혼합물을 혼합물의 액화온도 이상으로 가열하여 점성액체를 형성시키고, 이 점성액체를 연신하여 섬유를 형성시킨 다음, 상기 섬유를 액화온도 이하로 냉각시킴을 포함하는 내알칼리성 유리섬유의 제조방법.
  2. 제1항에 있어서, 상기 혼합물이 규산마그네슘 약 30 내지 63중량%, 실리카 0 내지 약 47중량%, 탄산칼슘 약 21 내지 45중량%, 및 리튬옥사이드, 칼륨옥사이드, 나트륨옥사이드, 바륨옥사이드, 카드뮴옥사이드, 납모노옥사이드, 스트론튬옥사이드, 아연옥사이드, 알루미나, 붕소옥사이드, 세륨옥사이드, 주석옥사이드, 티타니아, 산화지르콘, 안티몬 펜톡사이드, 니오브 펜톡사이드, 인 펜톡사이드 및 탄탈펜톡사이드, 또는 그의 혼합물로 이루어진 그룹중에서 선택된 옥사이드 약 5 내지 20중량%을 함유하며, 이때 상기 그룹중의 단일 옥사이드는 약 10중량%의 최대량으로 첨가하는 방법.
  3. 제2항에 있어서, 규산마그네슘이 활석형태이고, 실리카가 모래형태이며, 탄산칼슘이 석회석 형태인 방법.
  4. 제2항에 있어서, 점성 액체를 오리피스를 통해 연신하여 연속섬유를 형성시키는 방법.
  5. 제4항에 있어서, 냉각된 연속 섬유를 내알칼리성 중합체층으로 피복시키는 방법.
  6. CaO-함유 물화합과 혼합된 규산마그네슘 또는 MgO-함유 화합물과 혼합물 유리체(glass body)의 성형시에 높은 내알칼리성을 갖는 유리성형 조성물.
  7. 제6항에 있어서, 상기 조성물이 규산마그네슘 약 30 내지 63중량%, 실리카 0 내지 약 47중량%, 탄산칼슘 약 21 내지 45중량%, 및 리튬옥사이드, 칼륨중사이드, 나트륨옥사이드, 바륨옥사이드, 카드뮴옥사이드, 납모노옥사이드, 스트론튬옥사이드, 아연옥사이드, 알루미나, 붕소옥사이드, 세륨옥사이드, 주석옥사이드, 티타니아, 산화지르콘, 안티몬 펜톡사이드, 니오브 펜톡사이드, 인 펜톡사이드 및 탄탈펜톡사이드, 또는 그의 혼합물로 이루어진 그룹중에서 선택된 옥사이드 약 5 내지 20중량%를 필수적으로 함유하며, 이때 상기 그룹중의 단일 옥사이드는 약 10중량%의 최대량으로 존재하는 조성물.
  8. 실질적으로 SiO2약 30 내지 65중량%, MgO 12 내지 18중량%, CaO 12 내지 18중량, 소량의 옥사이드 5 내지 20중량%로 이루어진 유리를 포함하며, 이때 상기 소량의 옥사이드가 Ra 2O,RbO,Rc 2O3,RdO2및 Re 2O5중에서 선택되며, 여기서, Ra=Li,K,Na, Rb=Ba,Cd,Pb,Sr,Zn, Rc=Ce,Sn,ti,Zr, Re=Sb,Nb,P,Ta이고, 소량의 단일 옥사이드가 상기 유리의 약 10중량%이하로 존재하는 연속상 모노 필라멘트, 내알칼리성을 가진 유리섬유.
  9. 제8항에 있어서, 상기 유리가 SiO2약 55 내지 60중량%, MgO 약 14 내지 16중량% 및 CaO 약 14 내지 16중량%을 함유하고, 소량의 옥사이드가 Na2O,Al2O3,CeO2,TiO2및 Ta2O5중에서 선택되며, 소량의 단일 옥사이드가 상기 유리의 약 2 내지 6중량%로 존재하는 유리섬유.
  10. 제9항에 있어서, 소량의 옥사이드로서 Na2O 약 2 내지 4중량%, Al2O3약 4 내지 6중량% 및 TiO2약 3 내지 5중량%를 함유하는 유리섬유.
  11. 제8항의 유리섬유를 함유하는 섬유강화 접합제품.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR870005253A 1986-05-28 1987-05-27 내알칼리성 유리섬유의 제조방법 Granted KR870011055A (ko)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US86782786A 1986-05-28 1986-05-28
US867827 1986-05-28

Publications (1)

Publication Number Publication Date
KR870011055A true KR870011055A (ko) 1987-12-19

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ID=25350532

Family Applications (2)

Application Number Title Priority Date Filing Date
KR1019870005253A Expired KR900005180B1 (ko) 1986-05-28 1987-05-27 내알칼리성 유리섬유의 제조방법
KR870005253A Granted KR870011055A (ko) 1986-05-28 1987-05-27 내알칼리성 유리섬유의 제조방법

Family Applications Before (1)

Application Number Title Priority Date Filing Date
KR1019870005253A Expired KR900005180B1 (ko) 1986-05-28 1987-05-27 내알칼리성 유리섬유의 제조방법

Country Status (9)

Country Link
EP (1) EP0247817A1 (ko)
JP (1) JPS62288137A (ko)
KR (2) KR900005180B1 (ko)
CN (1) CN1018635B (ko)
AU (4) AU7345387A (ko)
BR (1) BR8702730A (ko)
CA (1) CA1265165A (ko)
FI (1) FI872349L (ko)
MX (1) MX169258B (ko)

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USRE35557E (en) * 1990-06-01 1997-07-08 Isover-Saint Gobain Mineral fibers decomposable in a physiological medium
US5843854A (en) * 1990-11-23 1998-12-01 Partek Paroc Oy Ab Mineral fibre composition
FI93346C (sv) 1990-11-23 1998-03-07 Partek Ab Mineralfibersammansättning
GB9426429D0 (en) * 1994-12-30 1995-03-01 Rockwool Int Man-made vitreous fibres
US5691255A (en) * 1994-04-19 1997-11-25 Rockwool International Man-made vitreous fiber wool
WO1997039990A1 (en) * 1996-04-24 1997-10-30 Owens Corning Glass compositions having high ki values and fibers therefrom
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CN102992792A (zh) * 2012-11-29 2013-03-27 王忠举 一种耐火纤维
CN104483183B (zh) * 2014-11-19 2017-03-29 华晨汽车集团控股有限公司 一种用于汽车前、后盖刚度试验的工装器具
CN108191234A (zh) * 2018-01-31 2018-06-22 济南大学 锡氧化物掺杂赤泥耐碱玻璃纤维及其制备方法
CN108751726A (zh) * 2018-08-09 2018-11-06 苏州华龙化工有限公司 一种高强度耐高温玻璃棉的制备方法
CN110067136A (zh) * 2019-04-26 2019-07-30 泰山玻璃纤维有限公司 一种高锆高耐碱型玻璃纤维网格布
CN111302641A (zh) * 2020-02-28 2020-06-19 泉州市派腾新材料科技有限公司 一种耐碱蚀型玻璃纤维材料的制备方法
CN112679096A (zh) * 2020-12-31 2021-04-20 山东天舜环保科技有限公司 一种高性能彩色玻璃纤维及其制备方法
CN113121120B (zh) * 2021-05-31 2022-11-22 四川华炫新材料科技有限公司 一种高耐碱玄武岩纤维及其制备方法
CN113562978B (zh) * 2021-07-09 2022-11-18 山东玻纤集团股份有限公司 一种高强度玻璃纤维的生产系统及生产方法
CN113698105B (zh) * 2021-07-09 2022-12-06 山东玻纤集团股份有限公司 一种高强度玻璃纤维组合物及其制备方法
CN113880442B (zh) * 2021-11-18 2022-06-07 浙江大学 一种纳米级玻璃纤维的制备方法及其产品

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Also Published As

Publication number Publication date
AU6897294A (en) 1994-10-20
BR8702730A (pt) 1988-03-01
KR900005180B1 (ko) 1990-07-20
AU7345387A (en) 1987-12-03
CN87103912A (zh) 1988-02-03
AU8999091A (en) 1992-02-13
JPS62288137A (ja) 1987-12-15
FI872349A0 (fi) 1987-05-27
FI872349L (fi) 1987-11-29
CN1018635B (zh) 1992-10-14
AU679536B2 (en) 1997-07-03
CA1265165A (en) 1990-01-30
AU3720389A (en) 1989-10-12
MX169258B (es) 1993-06-28
EP0247817A1 (en) 1987-12-02

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