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KR870010100A - 에폭시드기를 함유하는 페놀 에테르 - Google Patents

에폭시드기를 함유하는 페놀 에테르 Download PDF

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Publication number
KR870010100A
KR870010100A KR870003871A KR870003871A KR870010100A KR 870010100 A KR870010100 A KR 870010100A KR 870003871 A KR870003871 A KR 870003871A KR 870003871 A KR870003871 A KR 870003871A KR 870010100 A KR870010100 A KR 870010100A
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South Korea
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compound
formula
group
general formula
radical
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KR870003871A
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KR910004902B1 (ko
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에드워드 몬니에르 찰스
로쯔 마르틴
Original Assignee
칼 에프. 조르다
시바-가이기 코오포레이숀
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Publication of KR870010100A publication Critical patent/KR870010100A/ko
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Publication of KR910004902B1 publication Critical patent/KR910004902B1/ko

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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
    • C08G59/18—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
    • H01B3/00—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties
    • H01B3/18—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances
    • H01B3/30—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes
    • H01B3/40—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes epoxy resins
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
    • C08G59/02—Polycondensates containing more than one epoxy group per molecule
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
    • C08G59/02—Polycondensates containing more than one epoxy group per molecule
    • C08G59/04—Polycondensates containing more than one epoxy group per molecule of polyhydroxy compounds with epihalohydrins or precursors thereof
    • C08G59/06—Polycondensates containing more than one epoxy group per molecule of polyhydroxy compounds with epihalohydrins or precursors thereof of polyhydric phenols
    • C08G59/08—Polycondensates containing more than one epoxy group per molecule of polyhydroxy compounds with epihalohydrins or precursors thereof of polyhydric phenols from phenol-aldehyde condensates
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
    • C08G59/18—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
    • C08G59/20—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the epoxy compounds used
    • C08G59/32—Epoxy compounds containing three or more epoxy groups
    • C08G59/3218—Carbocyclic compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
    • C08G59/18—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
    • C08G59/20—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the epoxy compounds used
    • C08G59/32—Epoxy compounds containing three or more epoxy groups
    • C08G59/38—Epoxy compounds containing three or more epoxy groups together with di-epoxy compounds

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • Spectroscopy & Molecular Physics (AREA)
  • Epoxy Resins (AREA)
  • Epoxy Compounds (AREA)
  • Organic Insulating Materials (AREA)
  • Structures Or Materials For Encapsulating Or Coating Semiconductor Devices Or Solid State Devices (AREA)

Abstract

내용 없음

Description

에폭시드기를 함유하는 페놀 에테르
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (18)

  1. 하기 일반식(Ⅰ)의 화합물 :
    상기 식에서, R1은 C1-C20알킬, C5-C9시클로알킬 또는 CC7-Cl4아르알킬 이고 ; R2는 R1의 의미중 하나 이거나, 추가로 수소 또는 다음 일반식(Ⅱ) 라디칼이며 ;
    R3은 C1-C6알킬 또는 할로겐이고 ; R4및 R5는 각각 독립적으로 수소 또는 C1-C6알킬이며 ; R6은 수소 또는 메틸이고 : m은 0, 1 또는 2이며, n은 0 내지 30의 정수이고 단, 화합물(Ⅰ)에서 2개 이상의 R2라디칼은 일반식(Ⅱ)의 에폭시기이어야 함.
  2. 제1항에 있어서, 라디칼 R2가 모두 일반식(Ⅱ)의 기인 일반식(Ⅰ)의 화합물.
  3. 제 2항에 있어서, 에폭시드기 R2가 하기 일반식(Ⅲ)의 에폭시프로필 라디칼인 일반식 (Ⅰ)의 화합물.
  4. 제 1항에 있어서, R1이 C1-C6알킬인 일반식(Ⅰ)의 화합물.
  5. 제 4항에 있어서, R1이 메틸인 일반식(Ⅰ)의 화합물.
  6. 제 1항에 있어서, n이 0인 일반식(Ⅰ)의 화합물.
  7. 제 1항에 있어서, n이 1 내지 20의 정수인 일반식(Ⅰ)의 화합물.
  8. 제 1항에 있어서, R4및 R5가 각각 독립적으로 수소 또는 메틸인 일반식(Ⅰ)와 화합물.
  9. 제 1항에 있어서, R2가 일반식(Ⅱ)의 라디칼이고, -OR1라디칼에 대하여 오르토-또는 파라-위치에 존재하는 일반식(Ⅰ)의 화합물.
  10. 제 1항에 있어서, n이 0보다 크고 또 비말단 페닐핵상의 -C(R4R5)-기 및 R2가 각각 라디칼 -O-R1에 대하여 2개의 오르토-위치 및 파라-위치에 존재하는 일반식 (Ⅰ)의 화합물.
  11. 제 1항에 있어서, R1이 C1-C6알킬 또는 벤질이고 : R2가 제 3항에서 정의한 바와 같이 일반식(Ⅲ)의 기이고 -O-R1기에 대하여 오르토위치에 존재하며 ; R3이 C1-C4알킬, 염소 또는 브롬이고 ; m이 0, 1또는 2이며 ; n이 3 내지 20의 정수인 일반식(Ⅰ)의 화합물.
  12. 제 1항에 있어서, m이 1 또는 2이고, R3이 염소 또는 브롬인 일반식(Ⅰ)의 화합물.
  13. a) 제 1항에서 청구한 일반식(Ⅰ)의 폴리에폭시드와 b) 성분 a)에 대한 경화제를 함유하는 혼합물.
  14. 제 13항에 있어서, 촉진제 c) 또는 그 밖의 에폭시 수지 d) 또는 c) 및 d)의 혼합물을 추가 성분으로서 함유하는 혼합물.
  15. a) 라디칼 R1의 도입에 적합한 시약으로 하기 일반식 (Ⅳ) 화합물의 폐놀형 히드록시기를 에테르화 시키고 또 b) 2,3-에폭시드기의 도입에 적합한 시약으로 하기 일반식(Ⅴ)의 알켄일기를 에폭시화시키는 단계로 구성되는, 일반식(Ⅳ)의 화합물로부터 하기 일반식(Ⅰ)의 화합물을 제조하는 방법.
    상기 식에서, 라디칼 R1내지 R6및 지수 m 및 n은 상기 제 1항에서 정의한 바와 같고 ; R1은 상기 제 1항에서 청구한 R1의 의미중 하나이거나, 또는 추가로 수소 또는 일반식(Ⅴ)의 라디칼이며, 단 화합물(Ⅳ)에서 2 이상의 R7기는 반드시 알켄일기(Ⅴ)이어야 함.
  16. 제15항에 있어서, 에테르화 시약이 할로겐원자를 이탈기로서 함유하지 않는 일반식(Ⅰ) 화합물의 제조방법.
  17. 제15항에 있어서, 에폭시화제가 과산화카르복시산(Percarboxylic acid)인 일반식(Ⅰ) 화합물의 제조방법.
  18. 전자부품용 케이스화 재료로서 제 1항에서 청구한 일반식(Ⅰ) 화합물의 이용방법.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019870003871A 1986-04-22 1987-04-22 에폭시드기를 함유하는 페놀 에테르 KR910004902B1 (ko)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
CH162086 1986-04-22
CH1620/86-5 1986-04-22
CH01620/86-5 1986-04-24

Publications (2)

Publication Number Publication Date
KR870010100A true KR870010100A (ko) 1987-11-30
KR910004902B1 KR910004902B1 (ko) 1991-07-15

Family

ID=4214699

Family Applications (1)

Application Number Title Priority Date Filing Date
KR1019870003871A KR910004902B1 (ko) 1986-04-22 1987-04-22 에폭시드기를 함유하는 페놀 에테르

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Country Link
US (1) US4754003A (ko)
EP (1) EP0243318B1 (ko)
JP (1) JPS62256822A (ko)
KR (1) KR910004902B1 (ko)
CA (1) CA1287640C (ko)
DE (1) DE3768696D1 (ko)

Families Citing this family (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4877859A (en) * 1987-03-24 1989-10-31 Daikin Industries, Ltd. Fluorine-containing novolak resin and derivative thereof
US4996279A (en) * 1988-10-07 1991-02-26 Shell Oil Company Dissymmetric polymer materials
JPH02210905A (ja) * 1989-02-09 1990-08-22 Ngk Spark Plug Co Ltd 電気濾波器の封止方法
US5578740A (en) * 1994-12-23 1996-11-26 The Dow Chemical Company Process for preparation of epoxy compounds essentially free of organic halides
ATE209226T1 (de) * 1996-08-06 2001-12-15 Vantico Ag Polyglycidylether von sekundären alkoholen
PL2880072T3 (pl) * 2012-08-02 2017-03-31 Alzchem Ag Ciekłe utwardzacze do utwardzania żywic epoksydowych (ii)
CN103709718B (zh) * 2013-12-19 2016-08-17 华为技术有限公司 一种热固性树脂组合物及其应用

Family Cites Families (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE352003C (de) * 1920-04-28 1922-04-20 Meilach Melamid Dr Verfahren zur Darstellung von AEthern der kernmethylierten Homologen der Oxybenzylalkohole
US2983703A (en) * 1954-10-20 1961-05-09 Koppers Co Inc Epoxyalkyl allylarylethers
NL216211A (ko) * 1956-04-12
CH397626A (de) * 1960-11-07 1965-08-31 Ciba Geigy Verfahren zur Herstellung von epoxydierten Dien-Anlagerungsprodukten
US3291770A (en) * 1962-03-07 1966-12-13 Interchem Corp Coatings from partial condensation of allylated phenolic resin with epoxy resin
US3329737A (en) * 1964-03-09 1967-07-04 Minnesota Mining & Mfg Curable composition containing a polyepoxide and an allylic polyphenolic novolac, free of methylol groups
FR2315925A1 (fr) * 1975-07-04 1977-01-28 Nippon Chemiphar Co Nouveaux derives de 5-benzyle-2-oxazolidone, leur procede de preparation et leur application en therapeutique
DE2963311D1 (en) * 1978-12-29 1982-08-26 Ciba Geigy Ag Propenyl-substituted phenolglycidyl ethers, process for their preparation and their use
JPS6060123A (ja) * 1983-09-13 1985-04-06 Sumitomo Chem Co Ltd エポキシ化物の製造法
EP0204659B1 (de) * 1985-06-06 1991-11-21 Ciba-Geigy Ag Polyepoxide und deren Verwendung

Also Published As

Publication number Publication date
KR910004902B1 (ko) 1991-07-15
EP0243318A3 (en) 1988-10-12
DE3768696D1 (de) 1991-04-25
US4754003A (en) 1988-06-28
CA1287640C (en) 1991-08-13
JPS62256822A (ja) 1987-11-09
EP0243318B1 (de) 1991-03-20
EP0243318A2 (de) 1987-10-28

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