KR870007951A - 흡수성 수지 및 그 제조방법 - Google Patents
흡수성 수지 및 그 제조방법 Download PDFInfo
- Publication number
- KR870007951A KR870007951A KR870000964A KR870000964A KR870007951A KR 870007951 A KR870007951 A KR 870007951A KR 870000964 A KR870000964 A KR 870000964A KR 870000964 A KR870000964 A KR 870000964A KR 870007951 A KR870007951 A KR 870007951A
- Authority
- KR
- South Korea
- Prior art keywords
- absorbent resin
- aluminum
- polyacrylic acid
- producing
- polyhydric alcohol
- Prior art date
Links
- 230000002745 absorbent Effects 0.000 title claims 22
- 239000002250 absorbent Substances 0.000 title claims 22
- 239000011347 resin Substances 0.000 title claims 22
- 229920005989 resin Polymers 0.000 title claims 22
- 238000004519 manufacturing process Methods 0.000 title claims 14
- 229920002125 Sokalan® Polymers 0.000 claims 20
- 239000004584 polyacrylic acid Substances 0.000 claims 20
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims 12
- -1 aluminum compound Chemical class 0.000 claims 10
- 150000005846 sugar alcohols Polymers 0.000 claims 10
- SVTBMSDMJJWYQN-UHFFFAOYSA-N 2-methylpentane-2,4-diol Chemical compound CC(O)CC(C)(C)O SVTBMSDMJJWYQN-UHFFFAOYSA-N 0.000 claims 8
- 229910052782 aluminium Inorganic materials 0.000 claims 8
- 239000000654 additive Substances 0.000 claims 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims 5
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims 4
- 239000002202 Polyethylene glycol Substances 0.000 claims 4
- AZDRQVAHHNSJOQ-UHFFFAOYSA-N alumane Chemical class [AlH3] AZDRQVAHHNSJOQ-UHFFFAOYSA-N 0.000 claims 4
- WNROFYMDJYEPJX-UHFFFAOYSA-K aluminium hydroxide Chemical compound [OH-].[OH-].[OH-].[Al+3] WNROFYMDJYEPJX-UHFFFAOYSA-K 0.000 claims 4
- 229940024545 aluminum hydroxide Drugs 0.000 claims 4
- CDQSJQSWAWPGKG-UHFFFAOYSA-N butane-1,1-diol Chemical compound CCCC(O)O CDQSJQSWAWPGKG-UHFFFAOYSA-N 0.000 claims 4
- TZMQHOJDDMFGQX-UHFFFAOYSA-N hexane-1,1,1-triol Chemical compound CCCCCC(O)(O)O TZMQHOJDDMFGQX-UHFFFAOYSA-N 0.000 claims 4
- ACCCMOQWYVYDOT-UHFFFAOYSA-N hexane-1,1-diol Chemical compound CCCCCC(O)O ACCCMOQWYVYDOT-UHFFFAOYSA-N 0.000 claims 4
- 239000000203 mixture Substances 0.000 claims 4
- UWJJYHHHVWZFEP-UHFFFAOYSA-N pentane-1,1-diol Chemical compound CCCCC(O)O UWJJYHHHVWZFEP-UHFFFAOYSA-N 0.000 claims 4
- 229920001223 polyethylene glycol Polymers 0.000 claims 4
- ULWHHBHJGPPBCO-UHFFFAOYSA-N propane-1,1-diol Chemical compound CCC(O)O ULWHHBHJGPPBCO-UHFFFAOYSA-N 0.000 claims 4
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 claims 2
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims 2
- 150000008044 alkali metal hydroxides Chemical class 0.000 claims 2
- 150000004645 aluminates Chemical class 0.000 claims 2
- VSCWAEJMTAWNJL-UHFFFAOYSA-K aluminium trichloride Chemical compound Cl[Al](Cl)Cl VSCWAEJMTAWNJL-UHFFFAOYSA-K 0.000 claims 2
- 229940024546 aluminum hydroxide gel Drugs 0.000 claims 2
- SMYKVLBUSSNXMV-UHFFFAOYSA-K aluminum;trihydroxide;hydrate Chemical compound O.[OH-].[OH-].[OH-].[Al+3] SMYKVLBUSSNXMV-UHFFFAOYSA-K 0.000 claims 2
- 235000011187 glycerol Nutrition 0.000 claims 2
- 238000000034 method Methods 0.000 claims 2
- BNGXYYYYKUGPPF-UHFFFAOYSA-M (3-methylphenyl)methyl-triphenylphosphanium;chloride Chemical compound [Cl-].CC1=CC=CC(C[P+](C=2C=CC=CC=2)(C=2C=CC=CC=2)C=2C=CC=CC=2)=C1 BNGXYYYYKUGPPF-UHFFFAOYSA-M 0.000 claims 1
- 239000003513 alkali Substances 0.000 claims 1
- 229910052783 alkali metal Inorganic materials 0.000 claims 1
- 150000004703 alkoxides Chemical class 0.000 claims 1
- SMZOGRDCAXLAAR-UHFFFAOYSA-N aluminium isopropoxide Chemical compound [Al+3].CC(C)[O-].CC(C)[O-].CC(C)[O-] SMZOGRDCAXLAAR-UHFFFAOYSA-N 0.000 claims 1
- ILRRQNADMUWWFW-UHFFFAOYSA-K aluminium phosphate Chemical compound O1[Al]2OP1(=O)O2 ILRRQNADMUWWFW-UHFFFAOYSA-K 0.000 claims 1
- DIZPMCHEQGEION-UHFFFAOYSA-H aluminium sulfate (anhydrous) Chemical compound [Al+3].[Al+3].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O DIZPMCHEQGEION-UHFFFAOYSA-H 0.000 claims 1
- JPUHCPXFQIXLMW-UHFFFAOYSA-N aluminium triethoxide Chemical compound CCO[Al](OCC)OCC JPUHCPXFQIXLMW-UHFFFAOYSA-N 0.000 claims 1
- ZCLVNIZJEKLGFA-UHFFFAOYSA-H bis(4,5-dioxo-1,3,2-dioxalumolan-2-yl) oxalate Chemical compound [Al+3].[Al+3].[O-]C(=O)C([O-])=O.[O-]C(=O)C([O-])=O.[O-]C(=O)C([O-])=O ZCLVNIZJEKLGFA-UHFFFAOYSA-H 0.000 claims 1
- 229920001577 copolymer Polymers 0.000 claims 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 claims 1
- 239000000178 monomer Substances 0.000 claims 1
- WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 claims 1
- 229920000642 polymer Polymers 0.000 claims 1
- 229920001451 polypropylene glycol Polymers 0.000 claims 1
- 150000003839 salts Chemical class 0.000 claims 1
- MDDPTCUZZASZIQ-UHFFFAOYSA-N tris[(2-methylpropan-2-yl)oxy]alumane Chemical compound [Al+3].CC(C)(C)[O-].CC(C)(C)[O-].CC(C)(C)[O-] MDDPTCUZZASZIQ-UHFFFAOYSA-N 0.000 claims 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J3/00—Processes of treating or compounding macromolecular substances
- C08J3/24—Crosslinking, e.g. vulcanising, of macromolecules
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61L—METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
- A61L15/00—Chemical aspects of, or use of materials for, bandages, dressings or absorbent pads
- A61L15/16—Bandages, dressings or absorbent pads for physiological fluids such as urine or blood, e.g. sanitary towels, tampons
- A61L15/42—Use of materials characterised by their function or physical properties
- A61L15/60—Liquid-swellable gel-forming materials, e.g. super-absorbents
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F8/00—Chemical modification by after-treatment
- C08F8/42—Introducing metal atoms or metal-containing groups
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- Polymers & Plastics (AREA)
- Medicinal Chemistry (AREA)
- Materials Engineering (AREA)
- Epidemiology (AREA)
- Animal Behavior & Ethology (AREA)
- General Health & Medical Sciences (AREA)
- Public Health (AREA)
- Veterinary Medicine (AREA)
- General Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Hematology (AREA)
- Dispersion Chemistry (AREA)
- Processes Of Treating Macromolecular Substances (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Solid-Sorbent Or Filter-Aiding Compositions (AREA)
Abstract
Description
Claims (15)
- 다가알코올과 물의 존재하에서 분말상의 폴리아크릴산계 흡수성 수지를 그것과 반응시켜 얻은 알루미늄 화합물로서 처리하는 것을 특징으로 하는 폴리아크릴산계 흡수성 수지의 제조방법.
- 제 1 항에 있어서, 폴리아크릴산계 흡수성 수지가 주쇄에 적어도 아크릴산 및/또는 아크릴산 알카리 금속염의 모노머 단위를 가지는 중합체의 가교물인 폴리아크릴산계 흡수성 수지의 제조방법.
- 제 2 항에 있어서 알루미늄 화합물이 알루미늄염, 수산화물 및/또는 알콕시 드인 폴리아크릴산계 흡수성 수지의 제조방법.
- 제 3 항에 있어서 알루미늄 화합물이 염화알루미늄, 질산알루미늄, 황산알루미늄, 인산알루미늄, 삭산알루미늄, 수산화알루미늄, 알루미늄이소프로폭시드, 알루미늄에톡시드, 알루미늄 제 3 급 부톡시드로된 군으로부터 선택한 1가지 또는 2가지 이상의 혼합물인 폴리아크릴산계 흡수성 수지의 제조방법.
- 제 4 항에 있어서 알루미늄 화합물이 수산화알루미늄인 폴리아크릴산계 흡수성 수지의 제조방법.
- 제 5 항에 있어서 수산화알루미늄이 수산화알루미늄과 알루민산염 또는 알루미늄염과 알카리금속 수산화물과의 반응에 의하여 형성되는 수산화 알루미늄겔인 폴리아크릴산계 흡수성 수지의 제조방법.
- 제 2 항에 있어서 다가알코올은 에틸렌 글리콜, 프로판디올, 부탄디올, 펜탄디올, 헥산디올, 2-메틸-2,4-펜탄디올, 헥산트리올, 글리세린, 펜타에리스리톨, 솔빗트, 폴리에틸렌글리콜, 폴리프로필렌글리콜, 글리세린-EO부가물 글리세린 PO부가물, 펜타에리스리톨-EO부가물, 펜타에리스리톨-PO부가물, 솔빗트-EO부가물로 된 군으로부터 선택한 한가지 또는 2가지 이상의 혼합물인 폴리아크릴산계 흡수성 수지의 제조방법.
- 제 7 항에 있어서 다가알코올은 에틸렌 글리콜, 프로판디올, 부탄디올, 펜탄디올, 헥산디올, 2-메틸-2,4-펜탄디올, 헥산트리올, 폴리에틸렌 글리콜로 이루어진 군으로부터 선택한 1종 또는 2종 이상의 혼합물인 폴리아크릴산계 흡수성 수지의 제조방법.
- 제 8 항에 있어서 다가알코올은 에틸렌 글리콜, 프로판디올, 부탄디올, 펜탄디올, 헥산디올, 2-메틸-2,4-펜탄디올, 헥산트리올로 이루어진 군으로부터 선택한 1종 또는 2종 이상의 혼합물인 폴리아크릴산계 흡수성 수지의 제조방법.
- 제 8 항에 있어서 다가알코올이 폴리에틸렌 글리콜인 폴리아크릴산계 흡수성 수지의 제조방법.
- 제 2 항에 있어서 다가알코올은 에틸렌 글리콜, 프로판디올, 부탄디올, 펜탄디올, 헥산디올, 2-메틸-2,4-펜탄디올, 헥산트리올, 폴리에틸렌글리콜으로 된 군으로부터 선택한 1종 또는 2종 이상의 혼합물이며, 알루미늄 화합물은 알루미늄염과 알루민산염 또는 알루미늄염과 알카리금속 수산화물과의 반응에 의하여 생성되는 수산화 알루미늄 겔인 폴리아크릴산계 흡수성 수지의 제조방법.
- 제 1 항에 있어서 폴리아크릴산계 흡수성 수지가 다당류-아크릴산 그래프로 공중합체 또는 그 염인 폴리아크릴산계 흡수성 수지의 제조방법.
- 제 1 항에 있어서 분말상 폴리아크릴산계 흡수성 수지에 대하여 다가알코올의 첨가량이 0.01 내지 50중량% 알루미늄화합물의 첨가량이 0.1 내지 40중량%인 폴리아크릴산계 흡수성 수지의 제조방법.
- 제13항에 있어서 분말상 폴리아크릴산계 흡수성 수지에 대하여 다가알코올의 첨가량이 0.1내지 20중량% 알루미늄화합물의 첨가량이 0.5 내지 2.5중량%인 폴리아크릴산계 흡수성 수지의 제조방법.
- 제14항에 있어서 분말상 폴리아크릴산계 흡수성 수지에 대하여 다가알코올의 첨가량이 1내지 15중량% 알루미늄화합물의 첨가량이 1 내지 15중량%인 폴리아크릴산계 흡수성 수지의 제조방법.※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
Applications Claiming Priority (5)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2346286 | 1986-02-05 | ||
JP86-23462 | 1986-02-05 | ||
JP23462 | 1986-02-10 | ||
JP86-314449 | 1986-12-27 | ||
JP31444986 | 1986-12-27 |
Publications (2)
Publication Number | Publication Date |
---|---|
KR870007951A true KR870007951A (ko) | 1987-09-23 |
KR940000965B1 KR940000965B1 (ko) | 1994-02-07 |
Family
ID=26360816
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
KR1019870000964A KR940000965B1 (ko) | 1986-02-05 | 1987-02-05 | 흡수성 수지 및 그 제조방법 |
Country Status (5)
Country | Link |
---|---|
US (1) | US4771105A (ko) |
EP (1) | EP0233067B1 (ko) |
KR (1) | KR940000965B1 (ko) |
CA (1) | CA1280398C (ko) |
DE (1) | DE3762418D1 (ko) |
Families Citing this family (93)
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JPH0253965A (ja) * | 1988-08-19 | 1990-02-22 | Nippon Shokubai Kagaku Kogyo Co Ltd | 吸水性ポリマーの繊維状基材への固定化方法 |
US5002986A (en) * | 1989-02-28 | 1991-03-26 | Hoechst Celanese Corporation | Fluid absorbent compositions and process for their preparation |
US5149745A (en) * | 1989-05-12 | 1992-09-22 | Rohm And Haas Company | Transition metal crosslinking of acid-containing polymers |
US5298258A (en) * | 1989-12-28 | 1994-03-29 | Nitto Denko Corporation | Acrylic oily gel bioadhesive material and acrylic oily gel preparation |
US5185412A (en) * | 1990-01-18 | 1993-02-09 | Rohm And Haas Company | Functionally terminated acrylic acid telomer |
GB9107952D0 (en) * | 1991-04-15 | 1991-05-29 | Dow Rheinmuenster | Surface crosslinked and surfactant coated absorbent resin particles and method of preparation |
US5319018A (en) * | 1991-04-23 | 1994-06-07 | Rohm And Haas Company | Transition metal crosslinking of acid-containing polymers |
CA2072918A1 (en) * | 1992-02-14 | 1993-08-15 | Jian Qin | Modified polysaccharides having improved absorbent properties and process for the preparation thereof |
US5998032A (en) | 1992-08-17 | 1999-12-07 | Weyerhaeuser Company | Method and compositions for enhancing blood absorbence by superabsorbent materials |
ES2230413T3 (es) | 1992-08-17 | 2005-05-01 | Weyerhaeuser Company | Ligantes de particulas. |
US7144474B1 (en) | 1992-08-17 | 2006-12-05 | Weyerhaeuser Co. | Method of binding particles to binder treated fibers |
US6340411B1 (en) | 1992-08-17 | 2002-01-22 | Weyerhaeuser Company | Fibrous product containing densifying agent |
US5612411A (en) * | 1992-11-18 | 1997-03-18 | Kimberly-Clark Corporation | Absorbent phycocolloids and a method for their manufacture |
TW326051B (en) * | 1994-08-12 | 1998-02-01 | Kao Corp | Process for producing an improved super absorbent polymer |
US5498705A (en) * | 1995-02-22 | 1996-03-12 | Kimberly-Clark Corporation | Modified polysaccharides having improved absorbent properties and process for the preparation thereof |
US5739210A (en) * | 1995-11-03 | 1998-04-14 | Michigan State University | Polymers comprising reversible hydrophobic functionalities |
US6228930B1 (en) | 1997-06-18 | 2001-05-08 | Nippon Shokubai Co., Ltd. | Water-absorbent resin granule-containing composition and production process for water-absorbent resin granule |
SG86324A1 (en) | 1997-07-03 | 2002-02-19 | Kao Corp | Superabsorbent resin composition |
US6639120B1 (en) | 1997-12-12 | 2003-10-28 | Kimberly-Clark Worldwide, Inc. | Structure having balanced pH profile |
ZA9810779B (en) * | 1997-12-12 | 1999-09-21 | Kimberly Clark Co | Structure having balanced pH profile. |
FR2781232B1 (fr) * | 1998-07-15 | 2000-09-08 | Centre Nat Rech Scient | Polymere reactif utilisable pour la separation et l'adsorption de substances organiques, et materiau le contenant |
DE19909653A1 (de) | 1999-03-05 | 2000-09-07 | Stockhausen Chem Fab Gmbh | Pulverförmige, vernetzte, wässrige Flüssigkeiten sowie Blut absorbierende Polymere, Verfahren zu ihrer Herstellung und ihre Verwendung |
DE19909838A1 (de) * | 1999-03-05 | 2000-09-07 | Stockhausen Chem Fab Gmbh | Pulverförmige, vernetzte, wässrige Flüssigkeiten sowie Blut absorbierende Polymere, Verfahren zu ihrer Herstellung und ihre Verwendung |
JP3655781B2 (ja) * | 1999-08-25 | 2005-06-02 | 帝國製薬株式会社 | ビタミンc又はその誘導体を配合したパップ剤 |
CN100471526C (zh) | 2000-03-31 | 2009-03-25 | 施托克赫森有限公司 | 包括在表面上交联的粉末聚合物的吸液吸收层 |
DE10016041A1 (de) * | 2000-03-31 | 2001-10-04 | Stockhausen Chem Fab Gmbh | Pulverförmige an der Oberfläche vernetzte Polymerisate |
USRE44145E1 (en) | 2000-07-07 | 2013-04-09 | A.V. Topchiev Institute Of Petrochemical Synthesis | Preparation of hydrophilic pressure sensitive adhesives having optimized adhesive properties |
DE10139475A1 (de) * | 2000-08-11 | 2002-02-21 | Nippon Catalytic Chem Ind | Reibungsmindernde Beschichtung für Tiefbaumaßnahmen, Pfahlwandelement und rundes Stahlrohr, Bauverfahren |
DE10043706A1 (de) * | 2000-09-04 | 2002-04-25 | Stockhausen Chem Fab Gmbh | Pulverförmige, vernetzte, wässrige Flüssigkeiten sowie Blut absorbierende Polymere, Verfahren zu ihrer Herstellung und ihre Verwendung |
DE10043710B4 (de) | 2000-09-04 | 2015-01-15 | Evonik Degussa Gmbh | Verwendung pulverförmiger an der Oberfläche nachvernetzter Polymerisate und Hygieneartikel |
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JPS51107389A (ja) * | 1975-03-18 | 1976-09-22 | Kojin Kk | Horiakurirusanaruminiumuenno seizohoho |
JPS51125468A (en) * | 1975-03-27 | 1976-11-01 | Sanyo Chem Ind Ltd | Method of preparing resins of high water absorbency |
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US4558091A (en) * | 1983-05-13 | 1985-12-10 | Grain Processing Corporation | Method for preparing aluminum and polyhydric alcohol modified liquid absorbing composition |
-
1987
- 1987-02-04 CA CA000528981A patent/CA1280398C/en not_active Expired - Lifetime
- 1987-02-04 US US07/010,666 patent/US4771105A/en not_active Expired - Fee Related
- 1987-02-05 KR KR1019870000964A patent/KR940000965B1/ko not_active IP Right Cessation
- 1987-02-05 EP EP87301047A patent/EP0233067B1/en not_active Expired - Lifetime
- 1987-02-05 DE DE8787301047T patent/DE3762418D1/de not_active Expired - Lifetime
Also Published As
Publication number | Publication date |
---|---|
US4771105A (en) | 1988-09-13 |
CA1280398C (en) | 1991-02-19 |
EP0233067B1 (en) | 1990-04-25 |
DE3762418D1 (de) | 1990-05-31 |
EP0233067A3 (en) | 1988-03-23 |
EP0233067A2 (en) | 1987-08-19 |
KR940000965B1 (ko) | 1994-02-07 |
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