[go: up one dir, main page]

KR870005028A - 에텐 및 1산화탄소의 공중합체로부터 촉매 잔류물을 제거하는 방법. - Google Patents

에텐 및 1산화탄소의 공중합체로부터 촉매 잔류물을 제거하는 방법. Download PDF

Info

Publication number
KR870005028A
KR870005028A KR860009914A KR860009914A KR870005028A KR 870005028 A KR870005028 A KR 870005028A KR 860009914 A KR860009914 A KR 860009914A KR 860009914 A KR860009914 A KR 860009914A KR 870005028 A KR870005028 A KR 870005028A
Authority
KR
South Korea
Prior art keywords
carbon monoxide
polymer
ethene
acid
suspension
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
KR860009914A
Other languages
English (en)
Inventor
아드리아누스 마리아 요하네스
Original Assignee
오노알버어스
셀 인터나쵸 나아레 레사아치 마아츠샤피 비이부이
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 오노알버어스, 셀 인터나쵸 나아레 레사아치 마아츠샤피 비이부이 filed Critical 오노알버어스
Publication of KR870005028A publication Critical patent/KR870005028A/ko
Withdrawn legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G67/00—Macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing oxygen or oxygen and carbon, not provided for in groups C08G2/00 - C08G65/00
    • C08G67/02—Copolymers of carbon monoxide and aliphatic unsaturated compounds

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Polyethers (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Carbon And Carbon Compounds (AREA)

Abstract

내용 없음

Description

에텐 및 1산화탄소의 공중합체로부터 촉매 잔류물을 제거하는 방법
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (8)

  1. 팔라듐 포스핀 촉매 존재하에 중합 반응시켜, 1산화탄소와 에텐 그리고 임의의 울레핀성 불포화 수소로 이루어진 공중합체를 제조함에 있어서, 공중합체와 1산화탄소를 유기액내 현탁액중에서 1산화탄소 분압 0.1bar 이상의 압력과 중합반응 온도도보다 20°이상 높으며 60℃이상의 온도에서 접촉시켜 공중합체로 부터 촉매 잔류물을 제거하는 방법.
  2. 제1항에 있어서, 1산화탄소의 분압이 1bar이상이고, 온도가 80°내지 200℃인 방법.
  3. 제1항 또는 제2항에서, 중합체가 메탄올 또는 에탄올중의 현탁액으로 존재하는 방법.
  4. 제1항 내지 제3항의 어느 한 항에 있어서, 1산화탄소와 접촉시킨 후의 중합체를 현탁액으로부터 분리하고, 잔류하는 팔라듐 함유 용액을 추가 중합반응을 위해 촉매용액으로 사용하는 방법.
  5. 제1항 내지 제4항의 어느 한 항에 있어서, 중합체가 1산화탄소 및 에텐의 공중합체인 방법.
  6. 제5항에 있어서, 중합체가 1산화탄소, 에텐 및 프로펜의 터폴리머인 방법.
  7. 제1항 내지 제6항의 어느 한항에 있어서, 중합체가 팔라듐 화합물, pKa 2이하인 산의 음이온(단, 산은 하이드로할로겐 산 이외의 산 임) 및 일반식 R1R2-P-R-P-R3R4(R1,R2,R3및 R4는임의로 극성그룹으로 치환될 수 있거나 치환되지 않을 수 있는 탄화수소 그룹이고, R은 2이상의 탄소로 결합된 2가, 유기 가교 그룹임)의 2좌 배위자 포스핀(bidentate ligand phosphine)으로 이루어진 촉매 존재하에 제조한 것인 방법.
  8. 제7항에 있어서, 사용한 2좌 배위자 포스핀은 1,3-비스(디페닐포스핀)프로판, 또는 2-메틸-2-(메틸디페닐포스핀)-1,3-비스(디페닐포스핀) 프로판인 방법.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR860009914A 1985-11-26 1986-11-24 에텐 및 1산화탄소의 공중합체로부터 촉매 잔류물을 제거하는 방법. Withdrawn KR870005028A (ko)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
NL8503259 1985-11-26
NL8503259 1985-11-26

Publications (1)

Publication Number Publication Date
KR870005028A true KR870005028A (ko) 1987-06-04

Family

ID=19846922

Family Applications (1)

Application Number Title Priority Date Filing Date
KR860009914A Withdrawn KR870005028A (ko) 1985-11-26 1986-11-24 에텐 및 1산화탄소의 공중합체로부터 촉매 잔류물을 제거하는 방법.

Country Status (20)

Country Link
US (1) US4791190A (ko)
EP (1) EP0224304B1 (ko)
JP (1) JPH0689131B2 (ko)
KR (1) KR870005028A (ko)
CN (1) CN1009370B (ko)
AR (1) AR243542A1 (ko)
AT (1) ATE57387T1 (ko)
AU (1) AU589710B2 (ko)
BR (1) BR8605760A (ko)
CA (1) CA1271291A (ko)
DE (1) DE3674886D1 (ko)
DK (1) DK563286A (ko)
ES (1) ES2017926B3 (ko)
FI (1) FI89933C (ko)
IL (1) IL80740A0 (ko)
IN (1) IN167586B (ko)
MX (1) MX163270B (ko)
NO (1) NO168050C (ko)
NZ (1) NZ218381A (ko)
ZA (1) ZA868871B (ko)

Families Citing this family (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CA1275532C (en) * 1985-11-26 1990-10-23 Johannes A. M. Van Broekhoven Removal of catalyst remnants from ethene/co copolymers
AU606665B2 (en) * 1987-03-27 1991-02-14 Shell Internationale Research Maatschappij B.V. Removal of catalyst remnants from olefin/co copolymers
AU612173B2 (en) * 1987-08-28 1991-07-04 Shell Internationale Research Maatschappij B.V. Preparation of olefin/CO copolymers
AU2663988A (en) * 1987-12-09 1989-06-15 Shell Internationale Research Maatschappij B.V. Polyketone polymer preparation
CA1338577C (en) * 1988-04-27 1996-09-03 Jacobus Adrianus Bakkum Process for the preparation of polymers of carbon monoxide with unsaturated compounds
US5001221A (en) * 1988-09-19 1991-03-19 Shell Oil Company Polymerization of carbon monoxide/olefin with catalyst/diluent recycle
US5006638A (en) * 1989-05-26 1991-04-09 Shell Oil Company Melt processing of carbon monoxide/olefin copolymer with carbon dioxide
DE69310557T2 (de) * 1992-01-23 1997-09-04 Shell Int Research Gewinnung von Edelmetallen aus Katalysatorrückständen
GB9203988D0 (en) * 1992-02-25 1992-04-08 British Petroleum Co Plc Process for removing palladium from polyketones
EP0733661B1 (en) * 1995-03-22 1999-11-03 Shell Internationale Researchmaatschappij B.V. Process for the copolymerization of carbon monoxide with an olefinically unsaturated compound
TR200002321T2 (tr) 1998-02-12 2000-11-21 Acordis Industrial Fibers B.V. Poliketon liflerin hazırlanmasına mahsus yöntem
US6169145B1 (en) 1999-05-20 2001-01-02 Advanced Elastomer Systems, L.P. Vulcanization of carboxyl containing elastomers using reductive hydrosilylation with extension into dynamic vulcanization

Family Cites Families (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1081304A (en) * 1965-03-23 1967-08-31 Ici Ltd Improvements in or relating to chemical compounds
US3689460A (en) * 1971-03-04 1972-09-05 Shell Oil Co Interpolymers of carbon monoxide and process for preparing same
US3694412A (en) * 1971-03-04 1972-09-26 Shell Oil Co Process for preparing interpolymers of carbon monoxide in the presence of aryl phosphine-palladium halide complex
US3835123A (en) * 1973-03-26 1974-09-10 Shell Oil Co Process for preparing interpolymers of carbon monoxide and ethylenically unsaturated compounds
US3984388A (en) * 1975-06-02 1976-10-05 Shell Oil Company Process to prepare polyketones
US4076911A (en) * 1975-11-05 1978-02-28 Union Oil Company Of California Ethylene-carbon monoxide copolymers
ATE49010T1 (de) * 1983-04-06 1990-01-15 Shell Int Research Verfahren zur herstellung von polyketonen.
NL8403035A (nl) * 1984-10-05 1986-05-01 Shell Int Research Werkwijze ter bereiding van polyketonen.
CA1275532C (en) * 1985-11-26 1990-10-23 Johannes A. M. Van Broekhoven Removal of catalyst remnants from ethene/co copolymers

Also Published As

Publication number Publication date
AR243542A1 (es) 1993-08-31
ATE57387T1 (de) 1990-10-15
AU589710B2 (en) 1989-10-19
DE3674886D1 (de) 1990-11-15
DK563286D0 (da) 1986-11-24
JPS62131024A (ja) 1987-06-13
CN86107929A (zh) 1987-05-27
EP0224304B1 (en) 1990-10-10
US4791190A (en) 1988-12-13
NO168050B (no) 1991-09-30
FI864773A0 (fi) 1986-11-24
NO864690D0 (no) 1986-11-24
MX163270B (es) 1992-03-31
BR8605760A (pt) 1987-08-25
JPH0689131B2 (ja) 1994-11-09
CA1271291A (en) 1990-07-03
DK563286A (da) 1987-05-27
IL80740A0 (en) 1987-02-27
CN1009370B (zh) 1990-08-29
IN167586B (ko) 1990-11-17
FI864773L (fi) 1987-05-27
FI89933B (fi) 1993-08-31
ZA868871B (en) 1987-07-29
EP0224304A1 (en) 1987-06-03
ES2017926B3 (es) 1991-03-16
NZ218381A (en) 1989-05-29
NO168050C (no) 1992-01-08
FI89933C (fi) 1993-12-10
AU6561486A (en) 1987-05-28

Similar Documents

Publication Publication Date Title
KR870005028A (ko) 에텐 및 1산화탄소의 공중합체로부터 촉매 잔류물을 제거하는 방법.
KR870004730A (ko) 신규 비스포스핀 화합물, 신규 촉매 조성물 및 에텐과 일산화탄소의 공중합방법
MX170155B (es) Proceso para la preparacion de polimeros
KR870002169A (ko) 일산화탄소와 에텐과의 중합체 및 그의 제조방법
ES2028048T3 (es) Composiciones cataliticas y procedimiento de copolimerizacion de olefinas/monoxido de carbono.
KR870008616A (ko) 신규 촉매 조성물
KR920019712A (ko) 올레핀의 제조 방법
DE69811703D1 (de) Verfahren zur herstellung von konjugierten polymeren
DE3777027D1 (de) Katalytische zusammensetzungen und verfahren zur copolymerisation von olefinen und kohlenstoffmonoxiden.
KR900007908A (ko) 한개이상의 알파-올레핀과 일산화 탄소의 중합체 및 그의 제조방법
KR830009804A (ko) 8족 귀금속촉매의 제조방법
KR890013074A (ko) 폴리케톤 중합체 제조방법
ATE73469T1 (de) Katalytische zusammensetzungen und verfahren zur copolymerisation von olefin-kohlenmonoxid.
KR900012870A (ko) 니켈촉매 치환반응
BR8904887A (pt) Processo para a preparacao de polimeros de monoxido de carbono com um ou mais compostos olefinicamente insaturados
KR900016277A (ko) 일산화 탄소와 불포화 화합물과의 중합체 제조방법
ATE147769T1 (de) Herstellung von polymeren
KR900007893A (ko) 탄화수소-방향족 하이드 록실-함유 수지의 제조방법
KR900012956A (ko) 알파-올레핀과 일산화탄소의 공중합체 및 그의 제조방법
ATE128474T1 (de) Herstellung von polymeren aus kohlenmonoxid und ungesättigten kohlenwasserstoffen.
KR890009603A (ko) 섬유 보강 열가소성 복합재 및 그의 제조방법.
ES2037943T3 (es) Procedimiento para la preparacion de alcanodioles.
NO900944D0 (no) Polymerer av karbonmonoksyd med monoolefiner, samt fremgangsmaate for fremstilling av slike polymerer.
KR910014412A (ko) 하나이상의 올레핀형 불포화 화합물과 일산화탄소의 중합체 제조를 위한 연속적인 방법
MY131009A (en) Catalyst compositions and process for the preparation of polymers

Legal Events

Date Code Title Description
PA0109 Patent application

Patent event code: PA01091R01D

Comment text: Patent Application

Patent event date: 19861124

PG1501 Laying open of application
A201 Request for examination
PA0201 Request for examination

Patent event code: PA02012R01D

Patent event date: 19911107

Comment text: Request for Examination of Application

Patent event code: PA02011R01I

Patent event date: 19861124

Comment text: Patent Application

PC1202 Submission of document of withdrawal before decision of registration

Comment text: [Withdrawal of Procedure relating to Patent, etc.] Withdrawal (Abandonment)

Patent event code: PC12021R01D

Patent event date: 19940516

WITB Written withdrawal of application