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KR840004771A - 수인성 피복조성물 - Google Patents

수인성 피복조성물 Download PDF

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Publication number
KR840004771A
KR840004771A KR1019830001602A KR830001602A KR840004771A KR 840004771 A KR840004771 A KR 840004771A KR 1019830001602 A KR1019830001602 A KR 1019830001602A KR 830001602 A KR830001602 A KR 830001602A KR 840004771 A KR840004771 A KR 840004771A
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KR
South Korea
Prior art keywords
carboxyl
reaction product
carboxyl group
composition
epoxy
Prior art date
Application number
KR1019830001602A
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English (en)
Other versions
KR920000624B1 (ko
Inventor
리차아드 하아퍼 리 (외 2)
Original Assignee
도놀드 에이 후스
이 아이 듀우판 디 네모아 앤드 캄파니
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 도놀드 에이 후스, 이 아이 듀우판 디 네모아 앤드 캄파니 filed Critical 도놀드 에이 후스
Publication of KR840004771A publication Critical patent/KR840004771A/ko
Application granted granted Critical
Publication of KR920000624B1 publication Critical patent/KR920000624B1/ko

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D163/00—Coating compositions based on epoxy resins; Coating compositions based on derivatives of epoxy resins
    • C09D163/10—Epoxy resins modified by unsaturated compounds
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/44—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes for electrophoretic applications
    • C09D5/4473—Mixture of polymers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
    • C08G59/02—Polycondensates containing more than one epoxy group per molecule
    • C08G59/12—Polycondensates containing more than one epoxy group per molecule of polycarboxylic acids with epihalohydrins or precursors thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
    • C08G59/18—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
    • C08G59/40—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the curing agents used
    • C08G59/42—Polycarboxylic acids; Anhydrides, halides or low molecular weight esters thereof
    • C08G59/4246—Polycarboxylic acids; Anhydrides, halides or low molecular weight esters thereof polymers with carboxylic terminal groups
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D163/00—Coating compositions based on epoxy resins; Coating compositions based on derivatives of epoxy resins

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Polymers & Plastics (AREA)
  • Medicinal Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Molecular Biology (AREA)
  • Paints Or Removers (AREA)
  • Epoxy Resins (AREA)
  • Application Of Or Painting With Fluid Materials (AREA)

Abstract

내용 없음

Description

인 피복조성물
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (8)

  1. 제2카르복실기 함유 중합체를 제1반응 생성물과 혼합하여 제조된 제2반응 생성물과 액체 담체로 주로 구성된 수용성 피복 조성물에 있어서, 상기 제1반응 생성물이 유기 매체중에서 (A)-(B)성분의 반응 생성물인 것을 특징으로 하는 수용성 피복 조성물; (A) 750-5000의 에폭시 당량을 갖고 분자당 평균 1.5-2의 말단 1,2-에폭시기를 갖는 에폭시 수지 50-90중량%((A)와 (B)의 중량기준); (B) 평균 분자량(광산란에 의해 측정)이 10000-160000이 고산가가 100-500이며, 에폭시 수지에서, 1,2-에폭시기의 당량당, 카르복실기의 공급원이 모노-프로틴산일 때 적어도 1.25당량의 카르복실기와 카르복실기의 공급원이 디프로틴산 일 때 적어도 2.0당량의 카르복실기를 제공하기에 충분한 양의 제1카르복실기 함유 중합체; (C) 에폭시 수지에서 1,2-에폭시기 당량당, R1R2R3N(여기서, R1및 R2는 알킬 부분에 1 또는 2의 탄소원자를 갖고 치환되거나 치환되지 않은 1가 알킬기이며 R3은 1-4의 탄소원자를 갖고 치환되거나 치환되지 않은 1각 알킬기임), 피리딘, N-메틸피롤, N-메틸 피페리딘, N-메틸 피롤리딘, N-메틸 모르폴린 및 이들의 혼합물로부터 선정되는 적어도 1.25당량의 3급 아민; (D)선택적으로, (B)의 카르복실-기능 중합체와 화학 양론적으로 반응하기에 필요한 적어도 하나의1급. 2급 또는 3급 아민 또는 단일기능의 4급 암모늄 수산화물10-90%(1,2-에폭시기에 대한 카르복실기의 비를 증가시키기 위해서 카르복실-기능 중합체가 물에 분산될 수 있도록 아민의 양을 증가시킴); (E) (A)와 (B)의 100중량부당 5-200중량부의 양으로 혼합되고 평균 분자량(광산란에 의해 측정됨)이 약10,000-160,000이며 산가가 상기 제1카르복실-기능 중합체보다 적어도 50단위 큰 제2카르복실-기능 중합체(상기 제2반응 생성물은 (A),(B) 및 (E)를 기준으로 에폭시 수지(A) 30중량% 이상을 함유함).
  2. 제1항에 있어서, 연속적인 상이 수성상이 되고 (E)가 제1반응 생성물과 혼합되기에 충분한 양으로 물이 제1반응 생성물과 혼합되는 것을 특징으로 하는 조성물.
  3. 제1항에 있어서, (E)가 제1반응 생성물과 혼합되어 제2반응 생성물을 만든 다음, 연속적인 수성상이 되기에 충분한 양으로 물이 제2반응 생성물과 혼합되는 것을 특징으로 하는 조성물.
  4. 제2항 또는 3항에 있어서, (E)가 제1반응 생성물과 혼합되기 전에 제2 카르복실-기능 중합체(E)가 아민으로 중화되는 것을 특징으로 하는 조성물.
  5. 제1항에 있어서, 3차 아민(C)이 수용액으로서 제공되는 것을 특징으로 하는 조성물.
  6. 제1항에 있어서, 상기 제1카르복실기 함유 중합체의 산가가 상기 제2카르복실기 함유 중합체의 산가보다 적어도 100단위 더 큰 것을 특징으로 하는 조성물.
  7. 제1항에 있어서, 성분(A),(B),(C),(D) 및 (E)가 약 1.0-50중량%의 피복조성물로 구성되고, 나머지는 물과 선택적으로는 유기액체(부피비 70:30 내지 100:0)인 액체 담체로 구성되는 것을 특징으로 하는 조성물.
  8. 제1항에 있어서, 상기 카르복실기의 공급원이 모노-프로틴산이고, 상기 제1카르복실기 함유 중합체는 1,2-에폭시기의 당량당 카르복실기 1.5-2.5당량을 제공하기에 충분한 양으로 존재하며 상기 (C)의 3차 아민은 1,2-에폭시기의 당량당 2.0-2.5당량으로 존재하는 것을 특징으로 하는 조성물.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019830001602A 1982-04-16 1983-04-15 수용성 피복조성물 KR920000624B1 (ko)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US369077 1982-04-16
US369,077 1982-04-16
US06/369,077 US4423165A (en) 1982-04-16 1982-04-16 Water-borne coating composition made from epoxy resin, first polymeric acid, tertiary amine and second polymeric acid

Publications (2)

Publication Number Publication Date
KR840004771A true KR840004771A (ko) 1984-10-24
KR920000624B1 KR920000624B1 (ko) 1992-01-17

Family

ID=23454013

Family Applications (1)

Application Number Title Priority Date Filing Date
KR1019830001602A KR920000624B1 (ko) 1982-04-16 1983-04-15 수용성 피복조성물

Country Status (18)

Country Link
US (1) US4423165A (ko)
EP (1) EP0105293B1 (ko)
JP (1) JPS59500565A (ko)
KR (1) KR920000624B1 (ko)
AU (1) AU557446B2 (ko)
CA (1) CA1195036A (ko)
DE (1) DE3361139D1 (ko)
ES (1) ES8502149A1 (ko)
GB (1) GB2127415A (ko)
HK (1) HK56986A (ko)
IE (1) IE54535B1 (ko)
IT (1) IT1212729B (ko)
NO (1) NO834604L (ko)
NZ (1) NZ203900A (ko)
PH (1) PH18969A (ko)
PT (1) PT76561B (ko)
WO (1) WO1983003613A1 (ko)
ZA (1) ZA832616B (ko)

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ES8602873A1 (es) * 1983-08-10 1985-12-01 Kao Corp Un procedimiento para preparar una resina absorbente de agua y muy reactiva
AU576645B2 (en) * 1984-12-06 1988-09-01 Bpa Industries Pty. Limited Modified epoxy resin dispersion
GB8507221D0 (en) * 1985-03-20 1985-04-24 Courtaulds Plc Polymer compositions
DE3627860A1 (de) * 1986-08-16 1988-02-18 Basf Lacke & Farben Waessriges ueberzugsmittel, verfahren zu seiner herstellung sowie seine verwendung zur beschichtung von dosen
US4797444A (en) * 1987-02-03 1989-01-10 Basf Corporation Waterborne pigmented acrylic hydrosol coating composition and process
US5047454A (en) * 1987-02-03 1991-09-10 Basf Corporation Waterborne pigmented acrylic hydrosol coating composition
CA2010205A1 (en) * 1989-02-20 1990-08-20 Osamu Isozaki Self-curing aqueous resin dispersion
JPH05138121A (ja) * 1991-11-20 1993-06-01 Nippon Paint Co Ltd 缶体の塗膜形成方法
DE69202909T2 (de) * 1991-03-11 1995-11-30 Nippon Paint Co Ltd Wässrige Harzzusammensetzung und Verfahren zur Beschichtung von Dosen.
US5500463A (en) * 1991-03-11 1996-03-19 Nippon Paint Co., Ltd. Aqueous resin composition and method for forming coating film on can body
US5527840B1 (en) * 1994-10-04 1999-08-10 Valspar Corp Aqueous coating composition
JPH08311390A (ja) * 1995-05-23 1996-11-26 W R Grace & Co 水性塗料組成物
DE19528939A1 (de) 1995-08-07 1997-02-13 Bayer Ag Wäßrige, vernetzbare Bindemitteldispersionen mit niedrigem Lösemittelgehalt
JPH09124717A (ja) * 1995-10-16 1997-05-13 W R Grace & Co 水分散性樹脂の製造方法及びそれを用いた水性被覆組成物
JPH09124718A (ja) * 1995-10-20 1997-05-13 W R Grace & Co 水分散性樹脂の製造方法
US5686511A (en) * 1996-06-28 1997-11-11 The Valspar Corporation Esterifying epoxy resin with carboxyl polymer and quenching
GB2353999B (en) * 1999-09-07 2003-04-30 Chinese Petroleum Corp Curable system of self-emulsified aqueous epoxy resin and its polymeric hybrids
BRPI0408909B1 (pt) 2003-04-02 2016-08-02 Valspar Sourcing Inc método para formar uma dispersão, composição, método para revestir um artigo, e, artigo
DE10361274A1 (de) * 2003-12-24 2005-07-28 Bayer Materialscience Ag Lösemittelarme, OH-funktionelle Dispersionen
JP4661048B2 (ja) * 2003-12-26 2011-03-30 東洋インキ製造株式会社 水性塗料組成物及び被塗物
DE102004003894A1 (de) * 2004-01-27 2005-08-11 Bayer Materialscience Ag Lösemittelarme, OH-funktionelle Dispersionen II
ATE513025T1 (de) 2004-10-20 2011-07-15 Valspar Sourcing Inc Beschichtungszusammensetzungen für dosen und beschichtungsverfahren
DE102005010694A1 (de) * 2005-03-09 2006-09-14 Bayer Materialscience Ag Wässrige Copolymerisatdispersionen mit Reaktivverdünner
US7910170B2 (en) 2005-10-18 2011-03-22 Valspar Sourcing, Inc. Coating compositions for containers and methods of coating
WO2008036628A2 (en) 2006-09-19 2008-03-27 Valspar Sourcing, Inc. Food and beverage coated containers, method of coating and coating composition
AU2010233173B2 (en) 2009-04-09 2014-05-15 Swimc Llc Polymer having unsaturated cycloaliphatic functionality and coating compositions formed therefrom
CN102712727B (zh) 2009-07-17 2014-08-27 威士伯采购公司 涂料组合物以及被其涂布的制品
WO2011035172A1 (en) 2009-09-18 2011-03-24 Valspar Sourcing, Inc. Polyurethane coating composition

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US2784128A (en) * 1954-03-24 1957-03-05 Union Carbide & Carbon Corp Laminating composition and laminate made therefrom
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Also Published As

Publication number Publication date
ES521537A0 (es) 1984-12-16
EP0105293A1 (en) 1984-04-18
IT8320628A0 (it) 1983-04-15
CA1195036A (en) 1985-10-08
IT1212729B (it) 1989-11-30
ZA832616B (en) 1984-11-28
AU1339783A (en) 1983-11-04
ES8502149A1 (es) 1984-12-16
DE3361139D1 (en) 1985-12-12
PT76561B (en) 1986-01-21
PT76561A (en) 1983-05-01
GB2127415A (en) 1984-04-11
WO1983003613A1 (en) 1983-10-27
PH18969A (en) 1985-11-26
EP0105293B1 (en) 1985-11-06
IE54535B1 (en) 1989-11-08
IE830839L (en) 1983-10-16
GB8330075D0 (en) 1983-12-14
JPS59500565A (ja) 1984-04-05
US4423165A (en) 1983-12-27
NZ203900A (en) 1986-01-24
NO834604L (no) 1983-12-14
KR920000624B1 (ko) 1992-01-17
JPH045072B2 (ko) 1992-01-30
HK56986A (en) 1986-08-08
AU557446B2 (en) 1986-12-18

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