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KR830007491A - 카르복실산의 제조방법 - Google Patents

카르복실산의 제조방법 Download PDF

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Publication number
KR830007491A
KR830007491A KR1019810005093A KR810005093A KR830007491A KR 830007491 A KR830007491 A KR 830007491A KR 1019810005093 A KR1019810005093 A KR 1019810005093A KR 810005093 A KR810005093 A KR 810005093A KR 830007491 A KR830007491 A KR 830007491A
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Prior art keywords
nickel
iodide
molybdenum
catalyst
tungsten
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KR1019810005093A
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KR870001482B1 (ko
Inventor
리즈칼라 네이빌
Original Assignee
윌리암 시이 롱
더 헬콘 에스디이 그루우프 인코포레이팃드
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Publication of KR830007491A publication Critical patent/KR830007491A/ko
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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/24—Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
    • B01J31/2404—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/0231—Halogen-containing compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
    • B01J31/1805—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing nitrogen
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/20—Carbonyls
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/24—Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/10—Preparation of carboxylic acids or their salts, halides or anhydrides by reaction with carbon monoxide
    • C07C51/12—Preparation of carboxylic acids or their salts, halides or anhydrides by reaction with carbon monoxide on an oxygen-containing group in organic compounds, e.g. alcohols
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/30—Addition reactions at carbon centres, i.e. to either C-C or C-X multiple bonds
    • B01J2231/34—Other additions, e.g. Monsanto-type carbonylations, addition to 1,2-C=X or 1,2-C-X triplebonds, additions to 1,4-C=C-C=X or 1,4-C=-C-X triple bonds with X, e.g. O, S, NH/N
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/60—Complexes comprising metals of Group VI (VIA or VIB) as the central metal
    • B01J2531/64—Molybdenum
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/60—Complexes comprising metals of Group VI (VIA or VIB) as the central metal
    • B01J2531/66—Tungsten
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/84—Metals of the iron group
    • B01J2531/847—Nickel
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/04—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing carboxylic acids or their salts
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/26—Catalysts comprising hydrides, coordination complexes or organic compounds containing in addition, inorganic metal compounds not provided for in groups B01J31/02 - B01J31/24
    • B01J31/28—Catalysts comprising hydrides, coordination complexes or organic compounds containing in addition, inorganic metal compounds not provided for in groups B01J31/02 - B01J31/24 of the platinum group metals, iron group metals or copper
    • B01J31/30—Halides

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

내용 없음

Description

카르복실산의 제조방법
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (15)

  1. 요오드화물 존재하의 몰리브덴-니켈 또는 텅스텐-니켈공동 촉매성분으로 구성으로 구성된 촉매존재하와 유기인화합물 또는 유기질소화합물(여기서, 인과질소는 3가임)로 구성된 촉진제 존재하에서 하이드로카르빌 알콜을 일산화탄소와 반응시키는 것을 특징으로 하는 카르복실산의 제조방법.
  2. 제1항에 있어서, 공동촉매성분에 몰리브덴-니켈로 구성된 것을 특징으로 하는 방법.
  3. 제1항에 있어서, 촉진제가 포스핀인 방법.
  4. 제3항에 있어서, 공동촉매는 몰리브델-니켈이고 촉진제는 포스핀인 것을 특징으로 하는 방법.
  5. 하기 구조식으로 나타내지는 몰리브델-니켈 또는 텅스텐-니켈공동 촉매성분, 유기촉진제 성분과 요오드화물 성분으로 구성된 액상 카르보닐화 촉매.
  6. X : T : Z : Q
  7. 상기 식에서,
  8. X는 몰리브델 또는 텅스텐이고,
  9. T는 니켈이며(X와 T는 0원자가 형태 또는 할로겐화물, 산화물, 탄소수 1-20인 카르복실레이트, 카르보닐 또는 수화물 형태임.)
  10. Z는 수소요오드화물, 요오드, 알킬요오드화물(알킬기는 탄소원자 1-20을 포함함) 또는 알카리금속 요오드화물인 요오드화물 공급원이고,
  11. Q는 유기인 화합물 또는 유기질소화하물이다.
  12. (여기서, 인과 질소는 3가이며, X : T의 몰비는 0.1-10:1이고, X+T:Q의 몰비는 0.05-20:1이며 Z:X+T의 몰비는 1-1,000 : 1임).
  13. 제5항에 있어서, X가 몰디브델인 것을 특징으로 하는 촉매.
  14. 본 명세서에 기술된 방법 또는 생성물 또는 장치중 어느 하나, 또는 이들의 조합.
  15. ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019810005093A 1980-12-24 1981-12-23 카르복실산의 제조방법 Expired KR870001482B1 (ko)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US06/219,786 US4659518A (en) 1980-12-24 1980-12-24 Preparation of carboxylic acids
US219786 1980-12-24

Publications (2)

Publication Number Publication Date
KR830007491A true KR830007491A (ko) 1983-10-21
KR870001482B1 KR870001482B1 (ko) 1987-08-13

Family

ID=22820779

Family Applications (1)

Application Number Title Priority Date Filing Date
KR1019810005093A Expired KR870001482B1 (ko) 1980-12-24 1981-12-23 카르복실산의 제조방법

Country Status (11)

Country Link
US (1) US4659518A (ko)
JP (1) JPS57134438A (ko)
KR (1) KR870001482B1 (ko)
BE (1) BE891609A (ko)
CA (1) CA1164438A (ko)
DE (2) DE3153115C2 (ko)
FR (1) FR2496643B1 (ko)
GB (1) GB2089803B (ko)
IT (1) IT1148024B (ko)
NL (1) NL188992C (ko)
ZA (1) ZA818908B (ko)

Families Citing this family (20)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4372889A (en) * 1980-12-24 1983-02-08 The Halcon Sd Group, Inc. Preparation of carboxylic acids
ZA831987B (en) * 1982-03-26 1984-04-25 Davy Mckee London Process for the production of ethanol
EP0090443B1 (en) * 1982-03-30 1988-06-22 Shell Internationale Researchmaatschappij B.V. A process for carbonylating methanol to acetic acid and/or methyl acetate
DE3319361A1 (de) * 1982-05-28 1983-12-01 The Halcon SD Group, Inc., 10016 New York, N.Y. Verfahren zur herstellung von essigsaeure
BE896869A (fr) * 1982-05-28 1983-11-28 Halcon Sd Group Inc Procede de preparation d'acide acetique.
US4625049A (en) * 1982-06-30 1986-11-25 Chevron Research Company Alcohol carbonylation process using a bimetallic nickel catalyst
US4628113A (en) * 1982-06-30 1986-12-09 Chevron Research Company Alcohol carbonylation process using a bimetallic cobalt catalyst
CA1212689A (en) * 1982-06-30 1986-10-14 Steven P. Current Alcohol carbonylation process using a nickel catalyst
CA1261815A (en) * 1984-11-05 1989-09-26 Mark S. Thompson Preparation of high activity silica-supported hydrotreating catalysts and catalysts thus prepared
JPH0729978B2 (ja) * 1986-12-24 1995-04-05 ダイセル化学工業株式会社 α−フエニルプロピオン酸誘導体の製造法
GB8807284D0 (en) * 1988-03-26 1988-04-27 Bp Chem Int Ltd Chemical process
US4902659A (en) * 1988-07-26 1990-02-20 Council Of Scientific And Industrial Research Preparation of improved nickel-containing catalyst and process for conversion of alcohols to carboxylic acids therewith
JP2689517B2 (ja) * 1988-09-22 1997-12-10 三菱瓦斯化学株式会社 α−（４−イソブチルフェニル）プロピオン酸の製造法
DE4029917A1 (de) * 1990-09-21 1992-03-26 Hoechst Ag Verfahren zur gleichzeitigen herstellung von essigsaeure und essigsaeureanhydrid
US5189214A (en) * 1991-08-15 1993-02-23 Dairen Chemical Corp. Production of acetic acid
US5218144A (en) * 1991-12-10 1993-06-08 E. I. Du Pont De Nemours And Company Process for the manufacture of adipic acid
US5292944A (en) * 1993-06-29 1994-03-08 E. I. Du Pont De Nemours And Company Process for the preparation of adipic acid or pentenoic acid
US5900504A (en) * 1996-02-20 1999-05-04 Eastman Chemical Company Nickel-catalyzed carbonylation process
DE19706876A1 (de) * 1997-02-21 1998-08-27 Basf Ag Verfahren zur Herstellung von Carbonsäuren oder deren Estern durch Carbonylierung von Olefinen
EP1575705A2 (en) * 2002-12-23 2005-09-21 Eastman Chemical Company Process for the recovery of phosphorus and iodine containing catalyst components

Family Cites Families (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2650245A (en) * 1949-04-08 1953-08-25 British Celanese Synthesis of acetic acid from co and methanol
US4133963A (en) * 1975-11-19 1979-01-09 Eastman Kodak Company Process for the production of carboxylic acids
BE860557A (fr) * 1976-11-08 1978-05-08 Halcon International Inc Procede de preparation d'acides carboxyliques
US4356320A (en) * 1976-11-08 1982-10-26 The Halcon Sd Group, Inc. Preparation of carboxylic acids
US4482497A (en) * 1982-09-30 1984-11-13 The Halcon Sd Group, Inc. Preparation of carboxylic acids

Also Published As

Publication number Publication date
ZA818908B (en) 1983-08-31
NL188992C (nl) 1992-12-01
IT1148024B (it) 1986-11-26
GB2089803A (en) 1982-06-30
DE3151495A1 (de) 1982-08-12
NL8105841A (nl) 1982-07-16
CA1164438A (en) 1984-03-27
US4659518A (en) 1987-04-21
KR870001482B1 (ko) 1987-08-13
BE891609A (fr) 1982-06-23
JPS57134438A (en) 1982-08-19
DE3153115C2 (de) 1985-11-07
DE3151495C2 (de) 1986-06-19
GB2089803B (en) 1985-01-16
FR2496643B1 (fr) 1986-04-04
FR2496643A1 (fr) 1982-06-25
IT8149997A0 (it) 1981-12-23
JPS6312456B2 (ko) 1988-03-18

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