JPS5714596A - Accelerating method of disproportionation - Google Patents
Accelerating method of disproportionationInfo
- Publication number
- JPS5714596A JPS5714596A JP8903880A JP8903880A JPS5714596A JP S5714596 A JPS5714596 A JP S5714596A JP 8903880 A JP8903880 A JP 8903880A JP 8903880 A JP8903880 A JP 8903880A JP S5714596 A JPS5714596 A JP S5714596A
- Authority
- JP
- Japan
- Prior art keywords
- accelerator
- dicobalt
- formula
- expressed
- disproportionation
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 238000007323 disproportionation reaction Methods 0.000 title 1
- 238000000034 method Methods 0.000 title 1
- WEVYAHXRMPXWCK-UHFFFAOYSA-N Acetonitrile Chemical compound CC#N WEVYAHXRMPXWCK-UHFFFAOYSA-N 0.000 abstract 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 abstract 3
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 abstract 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 abstract 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 abstract 2
- JUJWROOIHBZHMG-UHFFFAOYSA-N Pyridine Chemical compound C1=CC=NC=C1 JUJWROOIHBZHMG-UHFFFAOYSA-N 0.000 abstract 2
- 229910017052 cobalt Inorganic materials 0.000 abstract 2
- 239000010941 cobalt Substances 0.000 abstract 2
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 abstract 2
- 150000001875 compounds Chemical class 0.000 abstract 2
- MQIKJSYMMJWAMP-UHFFFAOYSA-N dicobalt octacarbonyl Chemical group [Co+2].[Co+2].[O+]#[C-].[O+]#[C-].[O+]#[C-].[O+]#[C-].[O+]#[C-].[O+]#[C-].[O+]#[C-].[O+]#[C-] MQIKJSYMMJWAMP-UHFFFAOYSA-N 0.000 abstract 2
- DNIAPMSPPWPWGF-GSVOUGTGSA-N (R)-(-)-Propylene glycol Chemical compound C[C@@H](O)CO DNIAPMSPPWPWGF-GSVOUGTGSA-N 0.000 abstract 1
- 229910021012 Co2(CO)8 Inorganic materials 0.000 abstract 1
- 229910021529 ammonia Inorganic materials 0.000 abstract 1
- 150000001450 anions Chemical class 0.000 abstract 1
- OIQOECYRLBNNBQ-UHFFFAOYSA-N carbon monoxide;cobalt Chemical compound [Co].[O+]#[C-].[O+]#[C-].[O+]#[C-].[O+]#[C-] OIQOECYRLBNNBQ-UHFFFAOYSA-N 0.000 abstract 1
- 239000003054 catalyst Substances 0.000 abstract 1
- 150000004820 halides Chemical class 0.000 abstract 1
- 239000011261 inert gas Substances 0.000 abstract 1
- 229910052757 nitrogen Inorganic materials 0.000 abstract 1
- UMJSCPRVCHMLSP-UHFFFAOYSA-N pyridine Natural products COC1=CC=CN=C1 UMJSCPRVCHMLSP-UHFFFAOYSA-N 0.000 abstract 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 1
Abstract
PURPOSE: To obtain cobalt tetracarboynl aninons useful as a carbonylating catalyst, etc. of an organic halide efficientyl at a high reaction rate, by disproportionating dicobalt octancarbonly in the presence of a specific compound in acetone.
CONSTITUTION: Dicobalt octacarbonyl expressed by the formula Co2(CO)8 is disportionated in the presence of one or more compounds, e.g. an aliphatic alcohol, e.g. methanol, acetonitrile, pyridine or ammonia and water, as an accelerator, in an inert gas atmosphere, e.g. nitrogen, at 0W50°C, preferably 10W30°C, to give cobalt tetracarbonyl anions expressed by the formula Co(CO)4 -. The molar amount of the accelerator to be used is 0.1W4 times, preferably 0.5W3 times, that of the dicobalt octacarbonyl.
COPYRIGHT: (C)1982,JPO&Japio
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP8903880A JPS5714596A (en) | 1980-06-30 | 1980-06-30 | Accelerating method of disproportionation |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP8903880A JPS5714596A (en) | 1980-06-30 | 1980-06-30 | Accelerating method of disproportionation |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPS5714596A true JPS5714596A (en) | 1982-01-25 |
Family
ID=13959715
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP8903880A Pending JPS5714596A (en) | 1980-06-30 | 1980-06-30 | Accelerating method of disproportionation |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS5714596A (en) |
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2016015019A1 (en) * | 2014-07-25 | 2016-01-28 | Novomer, Inc. | Synthesis of metal complexes and uses thereof |
| US10099989B2 (en) | 2015-02-13 | 2018-10-16 | Novomer, Inc. | Distillation process for production of acrylic acid |
| US10099988B2 (en) | 2015-02-13 | 2018-10-16 | Novomer, Inc. | Process for production of acrylic acid |
| US10221278B2 (en) | 2011-05-13 | 2019-03-05 | Novomer, Inc. | Catalytic carbonylation catalysts and methods |
| US10221150B2 (en) | 2015-02-13 | 2019-03-05 | Novomer, Inc. | Continuous carbonylation processes |
| US10597294B2 (en) | 2014-05-30 | 2020-03-24 | Novomer, Inc. | Integrated methods for chemical synthesis |
| US10858329B2 (en) | 2014-05-05 | 2020-12-08 | Novomer, Inc. | Catalyst recycle methods |
| US11078172B2 (en) | 2015-02-13 | 2021-08-03 | Novomer, Inc. | Integrated methods for chemical synthesis |
-
1980
- 1980-06-30 JP JP8903880A patent/JPS5714596A/en active Pending
Cited By (20)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US10221278B2 (en) | 2011-05-13 | 2019-03-05 | Novomer, Inc. | Catalytic carbonylation catalysts and methods |
| US10479861B2 (en) | 2011-05-13 | 2019-11-19 | Novomer, Inc. | Catalytic carbonylation catalysts and methods |
| US11667617B2 (en) | 2014-05-05 | 2023-06-06 | Novomer, Inc. | Catalyst recycle methods |
| US10858329B2 (en) | 2014-05-05 | 2020-12-08 | Novomer, Inc. | Catalyst recycle methods |
| US10829372B2 (en) | 2014-05-30 | 2020-11-10 | Novomer, Inc. | Integrated methods for chemical synthesis |
| US10597294B2 (en) | 2014-05-30 | 2020-03-24 | Novomer, Inc. | Integrated methods for chemical synthesis |
| CN106714966A (en) * | 2014-07-25 | 2017-05-24 | 诺沃梅尔公司 | Synthesis of metal complexes and uses thereof |
| US10974234B2 (en) | 2014-07-25 | 2021-04-13 | Novomer, Inc. | Synthesis of metal complexes and uses thereof |
| WO2016015019A1 (en) * | 2014-07-25 | 2016-01-28 | Novomer, Inc. | Synthesis of metal complexes and uses thereof |
| CN106714966B (en) * | 2014-07-25 | 2021-02-02 | 诺沃梅尔公司 | Synthesis of metal complexes and their use |
| US10221150B2 (en) | 2015-02-13 | 2019-03-05 | Novomer, Inc. | Continuous carbonylation processes |
| US10738022B2 (en) | 2015-02-13 | 2020-08-11 | Novomer, Inc. | Continuous carbonylation processes |
| US10717695B2 (en) | 2015-02-13 | 2020-07-21 | Novomer, Inc. | Distillation process for production of acrylic acid |
| US10626073B2 (en) | 2015-02-13 | 2020-04-21 | Novomer, Inc. | Process for production of acrylic acid |
| US10927091B2 (en) | 2015-02-13 | 2021-02-23 | Novomer, Inc. | Continuous carbonylation processes |
| US10099988B2 (en) | 2015-02-13 | 2018-10-16 | Novomer, Inc. | Process for production of acrylic acid |
| US11078172B2 (en) | 2015-02-13 | 2021-08-03 | Novomer, Inc. | Integrated methods for chemical synthesis |
| US11155511B2 (en) | 2015-02-13 | 2021-10-26 | Novomer, Inc. | Distillation process for production of acrylic acid |
| US10099989B2 (en) | 2015-02-13 | 2018-10-16 | Novomer, Inc. | Distillation process for production of acrylic acid |
| US11807613B2 (en) | 2015-02-13 | 2023-11-07 | Novomer, Inc. | Integrated methods for chemical synthesis |
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