KR830004375A - 구리 포르마잔 화합물 및 그 제법 - Google Patents
구리 포르마잔 화합물 및 그 제법 Download PDFInfo
- Publication number
- KR830004375A KR830004375A KR1019800004258A KR800004258A KR830004375A KR 830004375 A KR830004375 A KR 830004375A KR 1019800004258 A KR1019800004258 A KR 1019800004258A KR 800004258 A KR800004258 A KR 800004258A KR 830004375 A KR830004375 A KR 830004375A
- Authority
- KR
- South Korea
- Prior art keywords
- carbon atoms
- substituted
- alkyl
- unsubstituted
- ethyl
- Prior art date
Links
- -1 Copper formazan compound Chemical class 0.000 title claims 6
- 125000004432 carbon atom Chemical group C* 0.000 claims 8
- 125000000217 alkyl group Chemical group 0.000 claims 7
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 claims 4
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims 4
- 239000010949 copper Substances 0.000 claims 3
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims 3
- 125000001424 substituent group Chemical group 0.000 claims 3
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims 2
- YLQBMQCUIZJEEH-UHFFFAOYSA-N Furan Chemical compound C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 claims 2
- SIKJAQJRHWYJAI-UHFFFAOYSA-N Indole Chemical compound C1=CC=C2NC=CC2=C1 SIKJAQJRHWYJAI-UHFFFAOYSA-N 0.000 claims 2
- JUJWROOIHBZHMG-UHFFFAOYSA-N Pyridine Chemical compound C1=CC=NC=C1 JUJWROOIHBZHMG-UHFFFAOYSA-N 0.000 claims 2
- SMWDFEZZVXVKRB-UHFFFAOYSA-N Quinoline Chemical compound N1=CC=CC2=CC=CC=C21 SMWDFEZZVXVKRB-UHFFFAOYSA-N 0.000 claims 2
- YTPLMLYBLZKORZ-UHFFFAOYSA-N Thiophene Chemical compound C=1C=CSC=1 YTPLMLYBLZKORZ-UHFFFAOYSA-N 0.000 claims 2
- 125000003545 alkoxy group Chemical group 0.000 claims 2
- 125000004397 aminosulfonyl group Chemical group NS(=O)(=O)* 0.000 claims 2
- 229910052801 chlorine Inorganic materials 0.000 claims 2
- 239000000460 chlorine Substances 0.000 claims 2
- 229910052802 copper Inorganic materials 0.000 claims 2
- 229910052736 halogen Inorganic materials 0.000 claims 2
- 150000002367 halogens Chemical class 0.000 claims 2
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims 2
- 125000001624 naphthyl group Chemical group 0.000 claims 2
- 125000000449 nitro group Chemical group [O-][N+](*)=O 0.000 claims 2
- 229910052757 nitrogen Inorganic materials 0.000 claims 2
- HYZJCKYKOHLVJF-UHFFFAOYSA-N 1H-benzimidazole Chemical compound C1=CC=C2NC=NC2=C1 HYZJCKYKOHLVJF-UHFFFAOYSA-N 0.000 claims 1
- YRBRVMGXTWJLBZ-UHFFFAOYSA-N 1h-imidazole;1h-pyrrole Chemical compound C=1C=CNC=1.C1=CNC=N1 YRBRVMGXTWJLBZ-UHFFFAOYSA-N 0.000 claims 1
- OJWYYSVOSNWCCE-UHFFFAOYSA-N 2-methoxyethyl hypofluorite Chemical compound COCCOF OJWYYSVOSNWCCE-UHFFFAOYSA-N 0.000 claims 1
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 claims 1
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 claims 1
- WTKZEGDFNFYCGP-UHFFFAOYSA-N Pyrazole Chemical compound C=1C=NNC=1 WTKZEGDFNFYCGP-UHFFFAOYSA-N 0.000 claims 1
- CZPWVGJYEJSRLH-UHFFFAOYSA-N Pyrimidine Chemical compound C1=CN=CN=C1 CZPWVGJYEJSRLH-UHFFFAOYSA-N 0.000 claims 1
- 125000003342 alkenyl group Chemical group 0.000 claims 1
- 125000004390 alkyl sulfonyl group Chemical group 0.000 claims 1
- 150000004982 aromatic amines Chemical class 0.000 claims 1
- 125000003118 aryl group Chemical group 0.000 claims 1
- 125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 claims 1
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 claims 1
- 229910052794 bromium Inorganic materials 0.000 claims 1
- 229910052799 carbon Inorganic materials 0.000 claims 1
- 125000005708 carbonyloxy group Chemical group [*:2]OC([*:1])=O 0.000 claims 1
- 125000001309 chloro group Chemical group Cl* 0.000 claims 1
- 150000001989 diazonium salts Chemical class 0.000 claims 1
- 125000000623 heterocyclic group Chemical group 0.000 claims 1
- 239000001257 hydrogen Substances 0.000 claims 1
- 229910052739 hydrogen Inorganic materials 0.000 claims 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims 1
- PZOUSPYUWWUPPK-UHFFFAOYSA-N indole Natural products CC1=CC=CC2=C1C=CN2 PZOUSPYUWWUPPK-UHFFFAOYSA-N 0.000 claims 1
- RKJUIXBNRJVNHR-UHFFFAOYSA-N indolenine Natural products C1=CC=C2CC=NC2=C1 RKJUIXBNRJVNHR-UHFFFAOYSA-N 0.000 claims 1
- 238000004519 manufacturing process Methods 0.000 claims 1
- 239000002184 metal Substances 0.000 claims 1
- 229910052751 metal Inorganic materials 0.000 claims 1
- VMGAPWLDMVPYIA-HIDZBRGKSA-N n'-amino-n-iminomethanimidamide Chemical compound N\N=C\N=N VMGAPWLDMVPYIA-HIDZBRGKSA-N 0.000 claims 1
- UFWIBTONFRDIAS-UHFFFAOYSA-N naphthalene-acid Chemical group C1=CC=CC2=CC=CC=C21 UFWIBTONFRDIAS-UHFFFAOYSA-N 0.000 claims 1
- 125000004433 nitrogen atom Chemical group N* 0.000 claims 1
- 125000004430 oxygen atom Chemical group O* 0.000 claims 1
- 125000000843 phenylene group Chemical group C1(=C(C=CC=C1)*)* 0.000 claims 1
- UMJSCPRVCHMLSP-UHFFFAOYSA-N pyridine Natural products COC1=CC=CN=C1 UMJSCPRVCHMLSP-UHFFFAOYSA-N 0.000 claims 1
- 150000003254 radicals Chemical class 0.000 claims 1
- BOLDJAUMGUJJKM-LSDHHAIUSA-N renifolin D Natural products CC(=C)[C@@H]1Cc2c(O)c(O)ccc2[C@H]1CC(=O)c3ccc(O)cc3O BOLDJAUMGUJJKM-LSDHHAIUSA-N 0.000 claims 1
- 229930192474 thiophene Natural products 0.000 claims 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 claims 1
- 229920002554 vinyl polymer Polymers 0.000 claims 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
- C09B50/00—Formazane dyes; Tetrazolium dyes
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
- C09B62/00—Reactive dyes, i.e. dyes which form covalent bonds with the substrates or which polymerise with themselves
- C09B62/44—Reactive dyes, i.e. dyes which form covalent bonds with the substrates or which polymerise with themselves with the reactive group not directly attached to a heterocyclic ring
- C09B62/503—Reactive dyes, i.e. dyes which form covalent bonds with the substrates or which polymerise with themselves with the reactive group not directly attached to a heterocyclic ring the reactive group being an esterified or non-esterified hydroxyalkyl sulfonyl or mercaptoalkyl sulfonyl group, a quaternised or non-quaternised aminoalkyl sulfonyl group, a heterylmercapto alkyl sulfonyl group, a vinyl sulfonyl or a substituted vinyl sulfonyl group, or a thiophene-dioxide group
- C09B62/5036—Formazane dyes
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Coloring (AREA)
- Plural Heterocyclic Compounds (AREA)
Abstract
Description
Claims (1)
- 다음 일반식(2)의 방향족 하이드라존 화합물을 다음 일반식(3)의 방향족아민의 디아조늄 화합물 및 구리공여제와 반응시켜, 다음 일반식(1)의 구리포르마잔 화합물을 제조하는 방법.상기에서A는 비치환되거나 할로겐, 니트로, 탄소수 1내지 5의 알킬, 탄소수 1내지 4의 알콕시, 탄소수 1내지 4의 알킬설포닐, 페닐설포일, 설파모일 및 각각 알킬의 탄소수 1내지 4인 N-모노-및 N,N-디알킬-설파모일로 치환된 페닐렌 또는 나프탈렌이며, Z에 의해 치환될 수 있으며;B는 직쇄 또는 측쇄의 탄소수 1내지 8인 알킬그룹 또는 직쇄 또는 측쇄의 탄소수 2내지 8인 알케닐 그룹으로 이들 알킬 및 알케닐그룹은 비치환되거나, 메틸, 에틸, 메톡시, 에톡시, 불소, 염소, 브롬 및 설파모일중의 치환기로 치환된 페닐 또는 페닐로 치환되며, 또는 B는 페닐 또는 나프틸인데 각각은 비치환되거나 하이드록시, 니트로, 할로겐, 탄소수 1내지 5의 알킬, 탄소수 1내지 4의 알콕시 및 알킬기가 탄소수 1내지 4인 카브알콕시중 치환기로 치환되며, 또는 B는 푸란, 티오펜, 피롤 이미다졸, 인돌, 피라졸, 피리딘, 피리미딘, 퀴놀린 또는 벤즈이미다졸의 일가 라디칼인데, 이들 복소환 라디칼은 비치환되거나 방향족 탄소원자가 염소, 페닐, 메톡시, 에톡시, 메틸 또는 에틸로 치환되고 이들 복소환의 NH그룹의 H원자는 메틸, 에틸 또는 벤질로 치환될 수 있으며, 또는B는 수소원자이며;Z는 수용성 그룹이며, A 및 B또는 둘다의 치환기이며 포르마잔 분자에 하나, 둘 또는 셋이 존재해야하며,A 또는 B의 방향족 탄소원자 또는 지방족 탄소원자에 결합되며;Cu는 구리이며,X는 일반식 -Co-0-의 카보닐옥시 그룹 또는 산소원자이며,A환의 질소원자에 대해 오르토-위치로 결합되며;Y는 비닐 또는 p-티오설페이토 에틸이며;M은 수소 또는 이와 등가의 금속이다.※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DEP3035562.5 | 1980-09-20 | ||
| DE19803035562 DE3035562A1 (de) | 1980-09-20 | 1980-09-20 | Kupfer-formazanverbindungen, verfahren zu ihrer herstellung und ihre verwendung als farbstoffe |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| KR830004375A true KR830004375A (ko) | 1983-07-09 |
| KR860001304B1 KR860001304B1 (ko) | 1986-09-11 |
Family
ID=6112459
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| KR1019800004258A KR860001304B1 (ko) | 1980-09-20 | 1980-11-06 | 구리 포르마잔 화합물의 제법 |
Country Status (2)
| Country | Link |
|---|---|
| KR (1) | KR860001304B1 (ko) |
| DE (1) | DE3035562A1 (ko) |
-
1980
- 1980-09-20 DE DE19803035562 patent/DE3035562A1/de not_active Withdrawn
- 1980-11-06 KR KR1019800004258A patent/KR860001304B1/ko active
Also Published As
| Publication number | Publication date |
|---|---|
| DE3035562A1 (de) | 1982-05-06 |
| KR860001304B1 (ko) | 1986-09-11 |
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