KR101583179B1 - 내고부하용 산소 발생용 양극 및 그의 제조방법 - Google Patents
내고부하용 산소 발생용 양극 및 그의 제조방법 Download PDFInfo
- Publication number
- KR101583179B1 KR101583179B1 KR1020147019024A KR20147019024A KR101583179B1 KR 101583179 B1 KR101583179 B1 KR 101583179B1 KR 1020147019024 A KR1020147019024 A KR 1020147019024A KR 20147019024 A KR20147019024 A KR 20147019024A KR 101583179 B1 KR101583179 B1 KR 101583179B1
- Authority
- KR
- South Korea
- Prior art keywords
- catalyst layer
- iridium oxide
- iridium
- oxide
- conductive metal
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 title claims abstract description 39
- 229910052760 oxygen Inorganic materials 0.000 title claims abstract description 39
- 239000001301 oxygen Substances 0.000 title claims abstract description 39
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 17
- 239000003054 catalyst Substances 0.000 claims abstract description 138
- HTXDPTMKBJXEOW-UHFFFAOYSA-N dioxoiridium Chemical compound O=[Ir]=O HTXDPTMKBJXEOW-UHFFFAOYSA-N 0.000 claims abstract description 100
- 229910000457 iridium oxide Inorganic materials 0.000 claims abstract description 98
- 229910052751 metal Inorganic materials 0.000 claims abstract description 64
- 239000002184 metal Substances 0.000 claims abstract description 64
- 239000011248 coating agent Substances 0.000 claims abstract description 42
- 238000000576 coating method Methods 0.000 claims abstract description 42
- 239000000758 substrate Substances 0.000 claims abstract description 40
- 238000000034 method Methods 0.000 claims abstract description 29
- 230000003197 catalytic effect Effects 0.000 claims abstract description 4
- 238000010304 firing Methods 0.000 claims description 38
- 229910052741 iridium Inorganic materials 0.000 claims description 21
- GKOZUEZYRPOHIO-UHFFFAOYSA-N iridium atom Chemical compound [Ir] GKOZUEZYRPOHIO-UHFFFAOYSA-N 0.000 claims description 21
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims description 17
- 239000010936 titanium Substances 0.000 claims description 17
- 229910052719 titanium Inorganic materials 0.000 claims description 17
- BPUBBGLMJRNUCC-UHFFFAOYSA-N oxygen(2-);tantalum(5+) Chemical compound [O-2].[O-2].[O-2].[O-2].[O-2].[Ta+5].[Ta+5] BPUBBGLMJRNUCC-UHFFFAOYSA-N 0.000 claims description 16
- 229910001936 tantalum oxide Inorganic materials 0.000 claims description 16
- 239000007789 gas Substances 0.000 claims description 10
- GUVRBAGPIYLISA-UHFFFAOYSA-N tantalum atom Chemical compound [Ta] GUVRBAGPIYLISA-UHFFFAOYSA-N 0.000 claims description 9
- 229910052715 tantalum Inorganic materials 0.000 claims description 8
- 238000010438 heat treatment Methods 0.000 claims description 7
- 238000007733 ion plating Methods 0.000 claims description 7
- 230000001590 oxidative effect Effects 0.000 claims description 3
- 150000002503 iridium Chemical class 0.000 claims 1
- 239000002994 raw material Substances 0.000 claims 1
- 150000003481 tantalum Chemical class 0.000 claims 1
- 238000005868 electrolysis reaction Methods 0.000 abstract description 29
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 abstract description 7
- 239000011889 copper foil Substances 0.000 abstract description 6
- 229910001335 Galvanized steel Inorganic materials 0.000 abstract description 3
- 229910052782 aluminium Inorganic materials 0.000 abstract description 3
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 abstract description 3
- 239000011888 foil Substances 0.000 abstract description 3
- 239000008397 galvanized steel Substances 0.000 abstract description 3
- 239000007788 liquid Substances 0.000 abstract description 3
- 238000000605 extraction Methods 0.000 abstract 1
- 239000000047 product Substances 0.000 description 35
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 18
- 238000002425 crystallisation Methods 0.000 description 15
- 230000008025 crystallization Effects 0.000 description 15
- 239000000243 solution Substances 0.000 description 15
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 10
- 238000011156 evaluation Methods 0.000 description 9
- 238000002441 X-ray diffraction Methods 0.000 description 8
- 230000000052 comparative effect Effects 0.000 description 7
- 239000013078 crystal Substances 0.000 description 7
- 238000006243 chemical reaction Methods 0.000 description 6
- 230000007423 decrease Effects 0.000 description 5
- 108010010803 Gelatin Proteins 0.000 description 4
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 4
- 239000007864 aqueous solution Substances 0.000 description 4
- 230000015572 biosynthetic process Effects 0.000 description 4
- 238000009826 distribution Methods 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- 229920000159 gelatin Polymers 0.000 description 4
- 239000008273 gelatin Substances 0.000 description 4
- 235000019322 gelatine Nutrition 0.000 description 4
- 235000011852 gelatine desserts Nutrition 0.000 description 4
- 229910001362 Ta alloys Inorganic materials 0.000 description 3
- 238000001354 calcination Methods 0.000 description 3
- 238000004140 cleaning Methods 0.000 description 3
- 238000005260 corrosion Methods 0.000 description 3
- 230000007797 corrosion Effects 0.000 description 3
- 238000002484 cyclic voltammetry Methods 0.000 description 3
- 150000004706 metal oxides Chemical class 0.000 description 3
- 238000005979 thermal decomposition reaction Methods 0.000 description 3
- DOBUSJIVSSJEDA-UHFFFAOYSA-L 1,3-dioxa-2$l^{6}-thia-4-mercuracyclobutane 2,2-dioxide Chemical compound [Hg+2].[O-]S([O-])(=O)=O DOBUSJIVSSJEDA-UHFFFAOYSA-L 0.000 description 2
- 229910021639 Iridium tetrachloride Inorganic materials 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 2
- 238000009835 boiling Methods 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- 238000003487 electrochemical reaction Methods 0.000 description 2
- 239000003792 electrolyte Substances 0.000 description 2
- 238000001704 evaporation Methods 0.000 description 2
- 230000008020 evaporation Effects 0.000 description 2
- 238000002474 experimental method Methods 0.000 description 2
- 238000003837 high-temperature calcination Methods 0.000 description 2
- GPRLSGONYQIRFK-UHFFFAOYSA-N hydron Chemical compound [H+] GPRLSGONYQIRFK-UHFFFAOYSA-N 0.000 description 2
- 239000012535 impurity Substances 0.000 description 2
- 229910052742 iron Inorganic materials 0.000 description 2
- HTUMBQDCCIXGCV-UHFFFAOYSA-N lead oxide Chemical compound [O-2].[Pb+2] HTUMBQDCCIXGCV-UHFFFAOYSA-N 0.000 description 2
- 238000005259 measurement Methods 0.000 description 2
- 229910000370 mercury sulfate Inorganic materials 0.000 description 2
- 229910044991 metal oxide Inorganic materials 0.000 description 2
- 229910000510 noble metal Inorganic materials 0.000 description 2
- 239000006259 organic additive Substances 0.000 description 2
- 230000001737 promoting effect Effects 0.000 description 2
- 238000005245 sintering Methods 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- CALMYRPSSNRCFD-UHFFFAOYSA-J tetrachloroiridium Chemical compound Cl[Ir](Cl)(Cl)Cl CALMYRPSSNRCFD-UHFFFAOYSA-J 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- 229910000831 Steel Inorganic materials 0.000 description 1
- 229910001069 Ti alloy Inorganic materials 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- AZDRQVAHHNSJOQ-UHFFFAOYSA-N alumane Chemical compound [AlH3] AZDRQVAHHNSJOQ-UHFFFAOYSA-N 0.000 description 1
- 229910003481 amorphous carbon Inorganic materials 0.000 description 1
- 229910017052 cobalt Inorganic materials 0.000 description 1
- 239000010941 cobalt Substances 0.000 description 1
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 1
- 239000004020 conductor Substances 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 230000005764 inhibitory process Effects 0.000 description 1
- 229910000464 lead oxide Inorganic materials 0.000 description 1
- RVPVRDXYQKGNMQ-UHFFFAOYSA-N lead(2+) Chemical compound [Pb+2] RVPVRDXYQKGNMQ-UHFFFAOYSA-N 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- YEXPOXQUZXUXJW-UHFFFAOYSA-N oxolead Chemical compound [Pb]=O YEXPOXQUZXUXJW-UHFFFAOYSA-N 0.000 description 1
- 238000005554 pickling Methods 0.000 description 1
- 238000007747 plating Methods 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 238000005070 sampling Methods 0.000 description 1
- 239000004065 semiconductor Substances 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
Images
Classifications
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- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B1/00—Electrolytic production of inorganic compounds or non-metals
- C25B1/01—Products
- C25B1/02—Hydrogen or oxygen
- C25B1/04—Hydrogen or oxygen by electrolysis of water
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B11/00—Electrodes; Manufacture thereof not otherwise provided for
- C25B11/04—Electrodes; Manufacture thereof not otherwise provided for characterised by the material
- C25B11/051—Electrodes formed of electrocatalysts on a substrate or carrier
- C25B11/052—Electrodes comprising one or more electrocatalytic coatings on a substrate
- C25B11/053—Electrodes comprising one or more electrocatalytic coatings on a substrate characterised by multilayer electrocatalytic coatings
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C14/00—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material
- C23C14/22—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material characterised by the process of coating
- C23C14/24—Vacuum evaporation
- C23C14/32—Vacuum evaporation by explosion; by evaporation and subsequent ionisation of the vapours, e.g. ion-plating
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B1/00—Electrolytic production of inorganic compounds or non-metals
- C25B1/01—Products
- C25B1/02—Hydrogen or oxygen
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B11/00—Electrodes; Manufacture thereof not otherwise provided for
- C25B11/04—Electrodes; Manufacture thereof not otherwise provided for characterised by the material
- C25B11/051—Electrodes formed of electrocatalysts on a substrate or carrier
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B11/00—Electrodes; Manufacture thereof not otherwise provided for
- C25B11/04—Electrodes; Manufacture thereof not otherwise provided for characterised by the material
- C25B11/051—Electrodes formed of electrocatalysts on a substrate or carrier
- C25B11/073—Electrodes formed of electrocatalysts on a substrate or carrier characterised by the electrocatalyst material
- C25B11/075—Electrodes formed of electrocatalysts on a substrate or carrier characterised by the electrocatalyst material consisting of a single catalytic element or catalytic compound
- C25B11/081—Electrodes formed of electrocatalysts on a substrate or carrier characterised by the electrocatalyst material consisting of a single catalytic element or catalytic compound the element being a noble metal
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B11/00—Electrodes; Manufacture thereof not otherwise provided for
- C25B11/04—Electrodes; Manufacture thereof not otherwise provided for characterised by the material
- C25B11/051—Electrodes formed of electrocatalysts on a substrate or carrier
- C25B11/073—Electrodes formed of electrocatalysts on a substrate or carrier characterised by the electrocatalyst material
- C25B11/091—Electrodes formed of electrocatalysts on a substrate or carrier characterised by the electrocatalyst material consisting of at least one catalytic element and at least one catalytic compound; consisting of two or more catalytic elements or catalytic compounds
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B11/00—Electrodes; Manufacture thereof not otherwise provided for
- C25B11/04—Electrodes; Manufacture thereof not otherwise provided for characterised by the material
- C25B11/051—Electrodes formed of electrocatalysts on a substrate or carrier
- C25B11/073—Electrodes formed of electrocatalysts on a substrate or carrier characterised by the electrocatalyst material
- C25B11/091—Electrodes formed of electrocatalysts on a substrate or carrier characterised by the electrocatalyst material consisting of at least one catalytic element and at least one catalytic compound; consisting of two or more catalytic elements or catalytic compounds
- C25B11/093—Electrodes formed of electrocatalysts on a substrate or carrier characterised by the electrocatalyst material consisting of at least one catalytic element and at least one catalytic compound; consisting of two or more catalytic elements or catalytic compounds at least one noble metal or noble metal oxide and at least one non-noble metal oxide
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/30—Hydrogen technology
- Y02E60/36—Hydrogen production from non-carbon containing sources, e.g. by water electrolysis
Landscapes
- Chemical & Material Sciences (AREA)
- Metallurgy (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Electrochemistry (AREA)
- Inorganic Chemistry (AREA)
- Mechanical Engineering (AREA)
- Electrodes For Compound Or Non-Metal Manufacture (AREA)
- Electrolytic Production Of Non-Metals, Compounds, Apparatuses Therefor (AREA)
- Catalysts (AREA)
- Electrolytic Production Of Metals (AREA)
- Laminated Bodies (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JPJP-P-2011-283846 | 2011-12-26 | ||
| JP2011283846 | 2011-12-26 | ||
| PCT/JP2012/083168 WO2013099780A2 (en) | 2011-12-26 | 2012-12-14 | High-load durable anode for oxygen generation and manufacturing method for the same |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| KR20140101425A KR20140101425A (ko) | 2014-08-19 |
| KR101583179B1 true KR101583179B1 (ko) | 2016-01-07 |
Family
ID=47559625
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| KR1020147019024A Expired - Fee Related KR101583179B1 (ko) | 2011-12-26 | 2012-12-14 | 내고부하용 산소 발생용 양극 및 그의 제조방법 |
Country Status (14)
| Country | Link |
|---|---|
| US (1) | US20150075978A1 (ja) |
| JP (1) | JP5686455B2 (ja) |
| KR (1) | KR101583179B1 (ja) |
| CN (1) | CN104024481A (ja) |
| AU (1) | AU2012361801A1 (ja) |
| CA (1) | CA2859939A1 (ja) |
| CL (1) | CL2014001717A1 (ja) |
| MX (1) | MX2014007759A (ja) |
| MY (1) | MY162043A (ja) |
| PE (1) | PE20142157A1 (ja) |
| PH (1) | PH12014501345B1 (ja) |
| TW (1) | TWI541385B (ja) |
| WO (1) | WO2013099780A2 (ja) |
| ZA (1) | ZA201404259B (ja) |
Families Citing this family (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP6498305B2 (ja) * | 2015-09-18 | 2019-04-10 | 旭化成株式会社 | 水電解用陽極、電解セル、並びに水電解用陽極の製造方法 |
| JP2017115232A (ja) * | 2015-12-25 | 2017-06-29 | 株式会社東芝 | 電極、膜電極複合体、電気化学セルおよびスタック |
| ES2850501T3 (es) * | 2016-11-22 | 2021-08-30 | Asahi Chemical Ind | Electrodo para electrólisis |
| KR102126183B1 (ko) * | 2017-11-29 | 2020-06-24 | 한국과학기술연구원 | 고분자 전해질 막 물 전기분해장치의 확산층 및 산소 전극 복합층 및 그 제조 방법, 이를 이용한 고분자 전해질 막 물 전기 분해 장치 |
| CN112368073B (zh) * | 2018-06-12 | 2024-04-09 | 国立研究开发法人科学技术振兴机构 | 催化剂及其使用方法 |
| CN110760894A (zh) * | 2019-10-28 | 2020-02-07 | 昆明冶金研究院 | 一种钛涂层阳极的制备方法 |
| KR20240113932A (ko) * | 2022-03-31 | 2024-07-23 | 드 노라 페르멜렉 가부시키가이샤 | 전해용 전극 및 그 제조 방법 |
| WO2025079555A1 (ja) * | 2023-10-11 | 2025-04-17 | デノラ・ペルメレック株式会社 | 酸素発生用電極及びその製造方法 |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2006515389A (ja) | 2003-03-24 | 2006-05-25 | エルテック・システムズ・コーポレーション | 白金族金属を有する電気触媒コーティング及びこれから製造された電極 |
| JP2008511755A (ja) | 2004-09-01 | 2008-04-17 | エルテック・システムズ・コーポレーション | 低い塩素過電圧のためのＰｄ含有コーティング |
| JP2009263770A (ja) | 2008-03-31 | 2009-11-12 | Permelec Electrode Ltd | 電解用電極の製造方法 |
| JP2009293117A (ja) | 2008-06-09 | 2009-12-17 | Doshisha | 亜鉛の電解採取用陽極および電解採取法 |
Family Cites Families (16)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS56116892A (en) * | 1980-02-20 | 1981-09-12 | Japan Carlit Co Ltd:The | Insoluble anode for generating oxygen and preparation thereof |
| DE3731285A1 (de) * | 1987-09-17 | 1989-04-06 | Conradty Metallelek | Dimensionsstabile anode, verfahren zu deren herstellung und verwendung derselben |
| JPH0499294A (ja) * | 1990-08-09 | 1992-03-31 | Daiso Co Ltd | 酸素発生用陽極及びその製法 |
| NL9101753A (nl) * | 1991-10-21 | 1993-05-17 | Magneto Chemie Bv | Anodes met verlengde levensduur en werkwijzen voor hun vervaardiging. |
| US5587058A (en) * | 1995-09-21 | 1996-12-24 | Karpov Institute Of Physical Chemicstry | Electrode and method of preparation thereof |
| US7247229B2 (en) * | 1999-06-28 | 2007-07-24 | Eltech Systems Corporation | Coatings for the inhibition of undesirable oxidation in an electrochemical cell |
| US6527939B1 (en) * | 1999-06-28 | 2003-03-04 | Eltech Systems Corporation | Method of producing copper foil with an anode having multiple coating layers |
| JP3654204B2 (ja) | 2001-03-15 | 2005-06-02 | ダイソー株式会社 | 酸素発生用陽極 |
| JP3914162B2 (ja) | 2003-02-07 | 2007-05-16 | ダイソー株式会社 | 酸素発生用電極 |
| JP4771130B2 (ja) | 2005-11-25 | 2011-09-14 | ダイソー株式会社 | 酸素発生用電極 |
| CN1995464A (zh) * | 2006-11-28 | 2007-07-11 | 北京科技大学 | 一种纳米晶铱系氧化物涂层电极制备方法 |
| JP4516618B2 (ja) | 2008-06-23 | 2010-08-04 | 学校法人同志社 | コバルトの電解採取用陽極および電解採取法 |
| JP5681343B2 (ja) * | 2008-09-01 | 2015-03-04 | 旭化成ケミカルズ株式会社 | 電解用電極 |
| CN102666932B (zh) * | 2009-12-25 | 2015-08-05 | 旭化成化学株式会社 | 阴极、碱金属氯化物的电解用电解槽和阴极的制造方法 |
| CN101914782A (zh) * | 2010-07-27 | 2010-12-15 | 武汉大学 | 适用于电Fenton体系的金属氧化物阳极及其制备方法 |
| CN102168283B (zh) * | 2011-04-08 | 2014-01-15 | 江苏美特林科特殊合金有限公司 | 一种电极涂层及其制备方法 |
-
2012
- 2012-12-14 MX MX2014007759A patent/MX2014007759A/es unknown
- 2012-12-14 WO PCT/JP2012/083168 patent/WO2013099780A2/en active Application Filing
- 2012-12-14 PE PE2014001028A patent/PE20142157A1/es not_active Application Discontinuation
- 2012-12-14 AU AU2012361801A patent/AU2012361801A1/en not_active Abandoned
- 2012-12-14 US US14/367,309 patent/US20150075978A1/en not_active Abandoned
- 2012-12-14 MY MYPI2014701496A patent/MY162043A/en unknown
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Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2006515389A (ja) | 2003-03-24 | 2006-05-25 | エルテック・システムズ・コーポレーション | 白金族金属を有する電気触媒コーティング及びこれから製造された電極 |
| JP2008511755A (ja) | 2004-09-01 | 2008-04-17 | エルテック・システムズ・コーポレーション | 低い塩素過電圧のためのＰｄ含有コーティング |
| JP2009263770A (ja) | 2008-03-31 | 2009-11-12 | Permelec Electrode Ltd | 電解用電極の製造方法 |
| JP2009293117A (ja) | 2008-06-09 | 2009-12-17 | Doshisha | 亜鉛の電解採取用陽極および電解採取法 |
Also Published As
| Publication number | Publication date |
|---|---|
| CA2859939A1 (en) | 2013-07-04 |
| CL2014001717A1 (es) | 2014-09-05 |
| ZA201404259B (en) | 2015-09-30 |
| PE20142157A1 (es) | 2015-01-17 |
| WO2013099780A2 (en) | 2013-07-04 |
| WO2013099780A3 (en) | 2013-10-10 |
| US20150075978A1 (en) | 2015-03-19 |
| PH12014501345B1 (en) | 2018-07-13 |
| JP2014530292A (ja) | 2014-11-17 |
| CN104024481A (zh) | 2014-09-03 |
| MY162043A (en) | 2017-05-31 |
| KR20140101425A (ko) | 2014-08-19 |
| MX2014007759A (es) | 2015-04-14 |
| TW201339372A (zh) | 2013-10-01 |
| TWI541385B (zh) | 2016-07-11 |
| AU2012361801A1 (en) | 2014-06-26 |
| PH12014501345A1 (en) | 2014-09-15 |
| JP5686455B2 (ja) | 2015-03-18 |
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